内部控制“法制化”的思考

中国内控研究起步较晚,经过数十年的努力,内控建设虽已初具规模,2010年更是推出《企业内部控制配套指引》,但仍然跟不上建立现代企业制度的步伐。鉴于此,中国理论界和实务界进行了不懈的探索,试图将治国之"法制"观念根植于企业内控制度,按法制的基本要求建设内控制度,实现内部控制的法制化。

Trigonometric Regularization and Continuation Method Based Time-Optimal Control of Hypersonic Vehicles

Aiming at the time-optimal control problem of hypersonic vehicles(HSV)in ascending stage,a trigonometric regularization method(TRM)is introduced based on the indirect method of optimal control.This method avoids analyzing the switching function and distinguishing between singular control and bang-bang control,where the singular control problem is more complicated.While in bang-bang control,the costate variables are unsmooth due to the control jumping,resulting in difficulty in solving the two-point boundary value problem(TPBVP)induced by the indirect method.Aiming at the easy divergence when solving the TPBVP,the continuation method is introduced.This method uses the solution of the simplified problem as the initial value of the iteration.Then through solving a series of TPBVP,it approximates to the solution of the original complex problem.The calculation results show that through the above two methods,the time-optimal control problem of HSV in ascending stage under the complex model can be solved conveniently.

INNOVATIVE PREDATORY SEARCH ALGORITHM FOR AIRCRAFT ARRIVAL SEQUENCING AND SCHEDULING PROBLEMS

To solve aircraft arrival sequencing and scheduling problems,and improve the typical predatory search algorithm（PSA）,an innovative PSA is developed.The new PSA uses variable constraints of local search and global search to avoid falling into local optimal solutions and the degeneration of solutions.To test the performance of new PSA,a case study with ten arriving flights and two runways is performed.Test results show that the new PSA performs much better than typical PSA and genetic algorithm（GA）in the aspects of the rate of gaining optimal solutions and the computational time.

NSGA-Ⅱ based traffic signal control optimization algorithm for over-saturated intersection group

In order to improve the efficiency of traffic signal control for an over-saturated intersection group, a nondominated sorting genetic algorithm Ⅱ（NSGA-Ⅱ） based traffic signal control optimization algorithm is proposed. The throughput maximum and average queue ratio minimum for the critical route of the intersection group are selected as the optimization objectives of the traffic signal control for the over-saturated condition. The consequences of the efficiency between traffic signal timing plans generated by the proposed algorithm and a commonly utilized signal timing optimization software Synchro are compared in a VISSIM signal control application programming interfaces （SCAPI） simulation environment by using real filed observed traffic data. The simulation results indicate that the signal timing plan generated by the proposed algorithm is more efficient in managing oversaturated flows at intersection groups, and, thus, it has the capability of optimizing signal timing under the over-saturated conditions.

Oxide film on bubble surface of aluminum foams produced by gas injection foaming process

Based on A356 aluminum alloy,aluminum foams were prepared by gas injection foaming process with pure nitrogen,air and some gas mixtures.The oxygen volume fraction of these gas mixtures varied from 0.2%to 8.0%.Optical microscopy,scanning electron microscopy（SEM） and Auger electron spectroscopy（AES） were used to analyze the influence of oxygen content on cell structure,relative density,macro and micro morphology of cell walls,coverage area fraction of oxide film,thickness of oxide film and other aspects.Results indicate that the coverage area fraction of oxide film on bubble surface increases with the increase of oxygen content when the oxygen volume is less than 1.2%.While when the oxygen volume fraction is larger than 1.6%,an oxide film covers the entire bubble surface and aluminum foams with good cell structure can be produced.The thicknesses of oxide films of aluminum foams produced by gas mixtures containing 1.6%-21%oxygen are almost the same.The reasons why the thickness of oxide film nearly does not change with the variation of oxygen content and the amount of oxygen needed to achieve 100%coverage of oxide film are both discussed.In addition,the role of oxide film on bubble surface in foam stability is also analyzed.

Optimal Boundary Control Method for Domain Decomposition Algorithm

To study the domain decomposition algorithms for the equations of elliptic type, the method of optimal boundary control was used to advance a new procedure for domain decomposition algorithms and regularization method to deal with the ill posedness of the control problem. The determination of the value of the solution of the partial differential equation on the interface——the key of the domain decomposition algorithms——was transformed into a boundary control problem and the ill posedness of the control problem was overcome by regularization. The convergence of the regularizing control solution was proven and the equations which characterize the optimal control were given therefore the value of the unknown solution on the interface of the domain would be obtained by solving a series of coupling equations. Using the boundary control method the domain decomposion algorithm can be carried out.

Some Trials of Typical Typhoon Tracks Using the Adjoint Method

In this paper, the adjoint method is applied to the statistical-dynamic model （SD-90） for the prediction of typhoon tracks along with the regularization thinking and optimal control techniques. The adjoint model and the gradient of objective function are deduced with the continual model respectively. For 4 typical typhoons, the forces and the initial velocity can be retrieved well, and the tracks of these typhoons are accurately fitted for an appropriate regularization parameter and optimal control parameter.

Effects of Two Curing Methods on Quality of Yellow Sun-cured Tobacco

[Objective] The aim was to research effects of bamboo split curing method and steely barn curing method on quality of yellow sun-cured tobacco, providing scientific references for optimization of curing technology of yellow sun-cured tobacco. [method] The tobaccos were divided into two groups treated with two methods and the related indices of treated tobaccos were then measured to evaluate effects of curing methods on quality of yellow sun-cured tobacco. [Result] Tobaccos treated with two methods were all dominated by reddish yellow and yellow; exterior quality differed little. In detail, total sugar and reducing sugar in an average level in three locations were all higher with method A than those with method B, but nicotine and total N were lower; comprehensive chemical components in group with method B proved more appropriate with higher K. In addition, sensory qualities of leaves in moderate and bottom locations were better with method B compared with method A; sensory quality of top leaves was better; comprehensive sensory quality of leaves treated with method B proved better. On the other hand, cost for method A was 2.82 times of method B; the area of sun-curing field was 3.27 times and manage- ment work was 1.77 times, which indicated that method B is low-cost and time-saving, which would be a guarantee of tobacco quality. [Conclusion] The research provides scientific references for rational use of tobacco resources and optimization of sun-curing technology.

Synthesis of allyl 4-O-{3-deoxy-3-[4-benzylaminocarbonyl-1H-(1,2,3)-triazol-l-yl]-β-D-galactopyranosyl}-2-deoxy-2-acetamido-β-D-glucopyranoside as a potential inhibitor of galectin-3

Allyl 4-O-{3-deoxy-3-[4-benzylaminocarbonyl-1H-（1,2,3）-triazol-1-yl]-β-D-galactopyranosyl}-2-deoxy-2-acetamido- β-D-glucopyranoside, a potential inhibitor of galectin-3, was designed and synthesized using lactose as stating material. The modifications of lactose included in introducing of N-acetamino group at the C-2 position through an azidoiodoglycosylation meanwhile constructing the [3-aminolactoside stereoselectively and replacing 3＇-OH with substituent 1,2,3-triazolyl group to enhance the affinity toward galeetin-3.

Preparation, characterization and catalytic performance of single-atom catalysts

Supported and colloidal single‐atom catalysts(SACs),which possess excellent catalytic properties,are particularly important in both fundamental studies and practical applications.The progress made in the preparation methods,characterization,catalytic performances and mechanisms of SACs anchored to metal oxides,two‐dimensional materials and the surface of metal nanoclusters(NCs)are reviewed.The different techniques for SAC fabrication,including conventional solution methods based on co‐precipitation,incipient wetness co‐impregnation,and the chemical vapor deposition method,as well as the newer atom layer deposition(ALD)and galvanic replacement methods,are summarized.The main results from experimental and theoretical studies of various catalytic reactions over SACs,including oxidation reactions,hydrogenation,water gas shift,photocatalytic H2evolution and electrochemical reactions,are also discussed.Moreover,the electronic properties of the single atoms and their interactions with the supports are described to assist in understanding the origin of the high catalytic activity and selectivity of SACs.Finally,possible future research directions of SACs and their applications are proposed.

Size control and its mechanism of SnAg nanoparticles

Sn3.5Ag （mass fraction, %） nanoparticles were synthesized by an improved chemical reduction method at room temperature. 1,10-phenanthroline and sodium borohydride were selected as the surfactant and reducing agent, respectively. It was found that no obvious oxidation of the synthesized nanoparticles was traced by X-ray diffraction. In addition, the results show that the density of primary particles decreases with decreasing the addition rate of the reducing agent. Moreover, the slight particle agglomeration and slow secondary particle growth can result in small-sized nanoparticles. Meanwhile, the effect of surfactant concentration on the particle size can effectively be controlled when the reducing agent is added into the precursor at an appropriate rate. In summary, the capping effect caused by the surfactant molecules coordinating with the nanoclusters will restrict the growth of the nanoparticles. The larger the mass ratio of the surfactant to the precursor is, the smaller the particle size is.

Optimum Design of the Control System for a Laser Beam Riding Guidance Anti-Tank Missile

The optimum theory and methods were adopted to design the laser beam riding guidance anti tank missile's control system in the short run. Through building the mathematical model of system, selecting a proper method and taking advantage of computer's high speed calculation and logic traits, an optimal controller was designed. Simulation results showed that the designed control system has fair performance and it satisfies the tactical and technical requirements. The results also demonstrate that by the combination of the optimizing methods and the computer the control system could be designed as soon as possible.

Influence of preparation methods on the physicochemical properties and catalytic performance of MnO_x-CeO_2 catalysts for NH_3-SCR at low temperature

This work examines the influence of preparation methods on the physicochemical properties and catalytic performance of MnOx‐CeO2 catalysts for selective catalytic reduction of NO by NH3 (NH3‐SCR) at low temperature. Five different methods, namely, mechanical mixing, impregnation,hydrothermal treatment, co‐precipitation, and a sol‐gel technique, were used to synthesizeMnOx‐CeO2 catalysts. The catalysts were characterized in detail, and an NH3‐SCR model reaction waschosen to evaluate the catalytic performance. The results showed that the preparation methodsaffected the catalytic performance in the order: hydrothermal treatment > sol‐gel > co‐precipitation> impregnation > mechanical mixing. This order correlated with the surface Ce3+ and Mn4+ content,oxygen vacancies and surface adsorbed oxygen species concentration, and the amount of acidic sitesand acidic strength. This trend is related to redox interactions between MnOx and CeO2. The catalystformed by a hydrothermal treatment exhibited excellent physicochemical properties, optimal catalyticperformance, and good H2O resistance in NH3‐SCR reaction. This was attributed to incorporationof Mnn+ into the CeO2 lattice to form a uniform ceria‐based solid solution (containing Mn‐O‐Cestructures). Strengthening of the electronic interactions between MnOx and CeO2, driven by thehigh‐temperature and high‐pressure conditions during the hydrothermal treatment also improved the catalyst characteristics. Thus, the hydrothermal treatment method is an efficient and environment‐friendly route to synthesizing low‐temperature denitrification (deNOx) catalysts.

Optimal fuzzy PID controller with adjustable factors based on flexible polyhedron search algorithm

A new kind of optimal fuzzy PID controller is proposed, which contains two parts. One is an on line fuzzy inference system, and the other is a conventional PID controller. In the fuzzy inference system, three adjustable factors x p, x i , and x d are introduced. Their functions are to further modify and optimize the result of the fuzzy inference so as to make the controller have the optimal control effect on a given object. The optimal values of these adjustable factors are determined based on the ITAE criterion and the Nelder and Mead′s flexible polyhedron search algorithm. This optimal fuzzy PID controller has been used to control the executive motor of the intelligent artificial leg designed by the authors. The result of computer simulation indicates that this controller is very effective and can be widely used to control different kinds of objects and processes.

Synthesis and characterization of mibolerone

A simple and effective route for the synthesis of mibolerone was described starting from the estr-5(10)-en-3,17-dione in four steps with the overall yield of 47.0 %.Thus,two methods for key intermediate methylnorandrost were investigated:one(method A)starting from estr-4-en-3,17-dione underwent 3-keto group protected with ethyl orthoformate to give 3-ethoxy-3,5-dien-estr-17-one,the other(method B)from estr-5(10)-en-3,17-dione and protected 3-keto group to give 3,3-dimethoxy-estr-5(10)-7-one in a mild acidic condition.Then,two intermediates were subsequently reacted with methyllithium followed by a mild hydrolytic procedure and gave methylnorandrost with total yield 25.0% and 86.0 %,respectively.In the preparation of 6-dehydrogenation product of methylnorandrost,two procedures(method C and method D)were investigated:one was the protected 17α-methyl-17β-hydroxy 3,5-enol ethers estrendiene brominated and the resulting 6-bromo-19-methylnortestosterone was then immediately dehydrohaloenated to give 6-dehydro-19-methylnortestosterone,the total yield only reaches 36.0%;the other was directly dehydrogenated with chloranil and the yield reaches 75.6% under the optimum conditions:in refluxing tetrahydrofuran,the molar ratio of methylnorandrost to chloranil is 0.66 and reaction time of 5 h.The titled compound and intermediates were characterized by 1H and 13C NMR,IRMS and elemental analysis.

Hand-eye-vision based control for an inspection robot's autonomous line grasping

In order to ensure that the off-line arm of a two-arm-wheel combined inspection robot can reliably grasp the line in case of autonomous obstacle crossing,a control method is proposed for line grasping based on hand-eye visual servo.On the basis of the transmission line's geometrical characteristics and the camera's imaging principle,a line recognition and extraction method based on structure constraint is designed.The line's intercept and inclination are defined in an imaging space to represent the robot's change of pose and a law governing the pose decoupling servo control is developed.Under the integrated consideration of the influence of light intensity and background change,noise(from the camera itself and electromagnetic field)as well as the robot's kinetic inertia on the robot's imaging quality in the course of motion and the grasping control precision,a servo controller for grasping the line of the robot's off-line arm is designed with the method of fuzzy control.An experiment is conducted on a 1:1 simulation line using an inspection robot and the robot is put into on-line operation on a real overhead transmission line,where the robot can grasp the line within 18 s in the case of autonomous obstacle-crossing.The robot's autonomous line-grasping function is realized without manual intervention and the robot can grasp the line in a precise,reliable and efficient manner,thus the need of actual operation can be satisfied.

Comparison of microstructural stability of IN939 superalloy with two different manufacturing routes during long-time aging

Microstructural stability of IN939 superalloy with two different manufacturing routes was investigated during long-term aging at elevated temperatures by light optical microscope（OM） and scanning electron microscope（SEM） equipped with an EDS system.The results show mat the coarsening behavior of γ＇ particles is primarily impacted by the initial heat treatment conditions,and the effect of the prior manufacturing route（casting or hot forming） is found to be insignificant,if any,on the γ＇ particles coarsening kinetics.In the temperature range of 790-827 ℃,IN939 cast/wrought-HT2 alloys have more microstructural stability,while in the temperature range of 827-910 ℃,the initial heat treatment marked as HT1 provides more stable microstructure for the cast or wrought IN939 superalloy.

Grassland Degradation and Its Control in Region AroundQinghai Lake

A quite severe degradation was found in all seven types of grasslands in the study area involving 12counties of the northwestern Qinghai Province. The slightly, moderately and severely degraded grasslandsoccupied 49.7%, 32.0% and 18.3% of the area respectively. The major factors resulting in the degradationwere overgrazing, the damages from mice and grasshopper and blown sands, and improper use of grasslands.The measures to deal with these problems should be: 1) to make livestock development in accordancewith grassland carrying capacity for animals; 2) to build more artificial grasslands with a stable and highergraas yield; 3) to put more widely the rotation grazing system into practice; 4) to clear up the poisonousgrass species; and 5) to adopt more effective measures to deal with the damages to grasslands by mice andgrasshoppers.

Heterogeneous photo-assisted Fenton catalytic removal of tetracycline using Fe-Ce pillared bentonite

In the present work, a novel heterogeneous photo-Fenton catalyst was prepared by iron and cerium pillared bentonite. The catalyst Fe-Ce/bentonite was characterized by X-ray diffraction （XRD）, X-ray fluorescence （XRF）, Brunauer-Emmett-Teller （BET） and scanning electron microscopy （SEM） methods. It is found that Fe and Ce intercalate into the silicate layers of bentonite successfully. Tetracycline was removed by heterogeneous photo-Fenton reaction using the catalyst in this work. The effects of different reaction systems, hydrogen peroxide concentration, initial pH, catalyst dosage, UV power and introduction of different anions on degradation were investigated in details. The stability of catalyst was investigated through recycling experiment. The results show that removal rate of tetracycline is 98.13% under the conditions of 15 mmol/L H202, 0.50 g/L catalyst dosage, initial pH 3.0, 11 W UV lamp power and 60 min reaction time. However, the removal rate decreases after adding some anions. The hydroxyl radical plays an important role in heterogeneous photo-assisted Fenton degradation of tetracycline. The catalyst is very stable and can be recycled many times.

Optimal Decoupling Control Method and Its Application to a Ball Mill Coal-pulverizing System

Abstract-The conventional optimal tracking control method cannot realize decoupling control of linear systems with a strong coupling property. To solve this problem, in this paper, an optimal decoupling control method is proposed, which can simultaneousiy provide optimal performance. The optimal decoupling controller is composed of an inner-loop decoupling controller and an outer-loop optimal tracking controller. First, by introducing one virtual control variable, the original differential equation on state is converted to a generalized system on output. Then, by introducing the other virtual control variable, and viewing the coupling terms as the measurable disturbances, the generalized system is open-loop decoupled. Finally, for the decoupled system, the optimal tracking control method is used. It is proved that the decoupling control is optimal for a certain performance index. Simulations on a ball mill coal-pulverizing system are conducted. The results show the effectiveness and superiority of the proposed method as compared with the conventional optimal quadratic tracking （LQT） control method.