Photocatalytic splitting of water over p-type semiconductors is a promising strategy for production of hydrogen.However,the determination of rate law is rarely reported.To this purpose,copper oxide(CuO)is selected as ...Photocatalytic splitting of water over p-type semiconductors is a promising strategy for production of hydrogen.However,the determination of rate law is rarely reported.To this purpose,copper oxide(CuO)is selected as a model photocathode in this study,and the photogenerated surface charge density,interfacial charge transfer rate constant and their relation to the water reduction rate(in terms of photocurrent)were investigated by a combination of(photo)electrochemical techniques.The results showed that the charge transfer rate constant is exponential-dependent on the surface charge density,and that the photocurrent equals to the product of the charge transfer rate constant and surface charge density.The reaction is first-order in terms of surface charge density.Such an unconventional rate law contrasts with the reports in literature.The charge density-dependent rate constant results from the Fermi level pinning(i.e.,Galvani potential is the main driving force for the reaction)due to accumulation of charge in the surface states and/or Frumkin behavior(i.e.,chemical potential is the main driving force).This study,therefore,may be helpful for further investigation on the mechanism of hydrogen evolution over a CuO photocathode and for designing more efficient CuO-based photocatalysts.展开更多
Hydrogen peroxide(H_(2)O_(2))has gained widespread attention as a versatile oxidant and a mild disin-fectant.Here,an electrostatic self-assembly method is applied to couple ZnSe quantum dots(QDs)with a flower-like cov...Hydrogen peroxide(H_(2)O_(2))has gained widespread attention as a versatile oxidant and a mild disin-fectant.Here,an electrostatic self-assembly method is applied to couple ZnSe quantum dots(QDs)with a flower-like covalent organic framework(COF)to form a step-scheme(S-scheme)photocata-lyst for H_(2)O_(2)production.The as-prepared S-scheme photocatalyst exhibits a broad light absorption range with an edge at 810 nm owing to the synergistic effect between the ZnSe QDs and COF.The S-scheme charge-carrier transfer mechanism is validated by performing Fermi level calculations and in-situ X-ray photoelectron and femtosecond transient absorption spectroscopies.Photolumi-nescence,time-resolved photoluminescence,photocurrent response,electrochemical impedance spectroscopy,and electron paramagnetic resonance results show that the S-scheme heterojunction not only promotes charge carrier separation but also boosts the redox ability,resulting in enhanced photocatalytic performance.Remarkably,a 10%-ZnSe QD/COF has excellent photocatalytic H_(2)O_(2)-production activity,and the optimal S-scheme composite with ethanol as the hole scavenger yields a H_(2)O_(2)-production rate of 1895 mol g^(-1)h-1.This study presents an example of a high-performance organic/inorganic S-scheme photocatalyst for H_(2)O_(2)production.展开更多
Chinese fir (Cunninghamia lanceolata (Lamb.) Hook.), a fast-growing, ever-green conifer tree with high yield and excellent quality, is the most important tree species of timber plantations in subtropical China. We inv...Chinese fir (Cunninghamia lanceolata (Lamb.) Hook.), a fast-growing, ever-green conifer tree with high yield and excellent quality, is the most important tree species of timber plantations in subtropical China. We investigated the characteristics of biomass, litterfall and nutrient fluxes in the 8, 14 and 24 year-old stands, representing the young, middle-aged and mature stands. The results showed that Chinese fir plantations in central Fujian province had high productivity, and the proportion of stem mass in total biomass was between 50%-70%. Chinese fir was low nutrient-return tree species with litterfall. Nutrient withdrawal from senescing needles was a strong age-dependence for nitrogen, phosphorous and potassium in Chinese fir. With a management system of such short-rotation and continuously pure-crop planting, harvesting timber can lead to great nutrient loss, which may be one of the causes for site degradation.展开更多
The effect of supercooled melt forced laminar flow at low Reynolds Number on dendritic growth perpendicular to melt flow direction was investigated with the phase-field method by incorporating melt convection and ther...The effect of supercooled melt forced laminar flow at low Reynolds Number on dendritic growth perpendicular to melt flow direction was investigated with the phase-field method by incorporating melt convection and thermal noise under non-isothermal condition. By taking the dendritic growth of high pure succinonitrile （SCN） supercooled melt as an example, side-branching shape difference of melts with flow and without flow was analyzed. Relationships among supercooled melt inflow velocity, deflexion angle of dendritic arm and dendritic tip growth velocity were studied. Results show that the melt inflow velocity has few effects on the dendritic tip growth velocity. A formula of relationship between the velocity of the melt in front of primary dendritic tip and the dendritic growth time was deduced, and the calculated result was in quantitative agreement with the simulation result.展开更多
[Objective] This study was conducted to find a restoration method suitable for urban polluted rivers. [Method] A segment of a representative river in the old part of a certain city in south Jiangsu was selected as a r...[Objective] This study was conducted to find a restoration method suitable for urban polluted rivers. [Method] A segment of a representative river in the old part of a certain city in south Jiangsu was selected as a research area through previous investigation, and the polluted river was cleaned and restored by 3 methods, i.e. artificial wetland, floating island type wetland and purification floating island. [Resuit] Floating plants （Hydrocotyle verticillata and Myriophyllum spicatum） showed better restoration effects than emergent aquatic plants （Iris wilsonii, Arundo donax, reed, water-cultured Ilex chinensis and Lythrum salicaria）. The two types of plants showed the removal rates of total nitrogen of 37.9% and 34.1%, respectively, the removal rates of total phosphorous of 80.1% and 73.5%, respectively, the removal rates of COD of 81.1% and 74.8%, respectively, the removal rates of ammonia nitrogen of 80.6% and 85.9%, respectively, and the removal rates of SS of 59.1% and 77.3%, respectively. Among the purification floating island, the artificial wetland and the floating island type wetland, the purification floating land restoration technique exhibited the best removal effect, with the removal rates of 87.6%, 71.3%, 87.6%, 97.5% and 81.8% for total nitrogen, total phosphorous, ammonia nitrogen COD and SS, respectively. The nitrification and denitdfication rates of bottom mud and water samples in the engineering segment were remarkably higher than those in the reference segment, by 15.4% and 21.1%, respectively. The nitrification and denitrification rates of bottom mud in the engineering segment and the non-engineering segment were higher than those of water samples by 26.9% and 31.8%, respectively. Restoration plants showed better removal effects of total phosphorous, total nitrogen, COD and SS under aeration condition than noeration condition. [Conclusion] The purification floating island has a significant restoration effect on urban polluted river.展开更多
As the most important type or component in the terrestrial ecosystems, forest ecosystem makes its role obviously prominent and important on environment and human being. It possesses non-substitutable functions in the ...As the most important type or component in the terrestrial ecosystems, forest ecosystem makes its role obviously prominent and important on environment and human being. It possesses non-substitutable functions in the process of sustainable development. However, due to the complexity of the forest ecosystem and the relatively delay or lack of the related research technology, the science is still in the case of immature and questions. This paper summarized and reviewed briefly the development and the present case of the forest ecology, then pointed out the existing problems in the forest ecosystem researches. In the end, we discussed several fields that need to pay more attention to in future researches.展开更多
The combination method of intermittent influent and vertical flow wetlands （VFW） was used in the test to treat the domestic wastewater. Four artificial wetlands including Typha latifolia wetland,Phragmites australis...The combination method of intermittent influent and vertical flow wetlands （VFW） was used in the test to treat the domestic wastewater. Four artificial wetlands including Typha latifolia wetland,Phragmites australis （P.H.） wetland,polyculture wetlands （Typha latifolia and Phragmites australis） and non-vegetation wetland were established in the test. The effects of hydraulic retention time （HRT） and plant species on pollutants removal efficiencies were studied. The results showed that when HRT=7,the treatment efficiencies of wetlands with plants for the removal of TN and NH＋4-N were up to 99.65% and 99.58%,respectively. For the control wetland,TN removal efficiency was up to 87.9% when HRT were 6 days,and NH＋4-N removal efficiency was up to 91.8% when HRT were 5 days. TP removal efficiencies of four wetlands were higher than 93% when HRT was 6 days. Through the studies on different plants,it was found that vegetation wetlands had better nitrogen removal efficiency than non-vegetation wetland. The treatment efficacy of Phragmites australis wetland and polyculture wetland was better than Typha latifolia wetland.展开更多
The random distribution problem of dendrite preferred growth direction was settled by random grid method.This method was used to study the influence of forced laminar flow effect on multiple grains during solidificati...The random distribution problem of dendrite preferred growth direction was settled by random grid method.This method was used to study the influence of forced laminar flow effect on multiple grains during solidification.Taking high pure succinonitrile （SCN） undercooled melt as an example,the forced laminar flow effect on multiple grains was studied by phase-field model of single grain which coupled with flow equations at non-isothermal condition.The simulation results show that the random grid method can reasonably settle the problem of random distribution and is more effective.When the solid fraction is relatively low,melt particles flow around the downstream side of dendrite,and the flow velocity between two dendrite arms becomes high.At the stage of solidification time less than 1800Δt,every dendrite grows freely;the upstream dendrites are stronger than the downstream ones.The higher the melt flow rate,the higher the solid fraction.However,when the solid fraction is relatively high,the dendrite arm intertwins and only a little residual melt which is not encapsulated can flow;the solid fraction will gradually tend to equal to solid fraction of melt without flow.展开更多
The reverse generation current under high-gate-voltage stress condition in LDD nMOSFET＇s is studied. We find that the generation current peak decreases as the stress time increases. We ascribe this finding to the dom...The reverse generation current under high-gate-voltage stress condition in LDD nMOSFET＇s is studied. We find that the generation current peak decreases as the stress time increases. We ascribe this finding to the dominating oxide trapped electrons that reduce the effective drain bias, lowering the maximal generation rate. The density of the effective trapped electrons affecting the effective drain bias is calculated with our model.展开更多
Fluidized bed biomass gasifiers can be employed to produce hydrogen-rich gas. A non-premixed combustion model is used for biomass air-steam gasification in the gasifier, and the simulations were carried out by using t...Fluidized bed biomass gasifiers can be employed to produce hydrogen-rich gas. A non-premixed combustion model is used for biomass air-steam gasification in the gasifier, and the simulations were carried out by using the FLUENT 6.0 software. The simulation results are compared with the experimental data. The effects of the steam to biomass ratio （S/B）, the equivalence ratio （ER）, and the size of biomass particles on the hydrogen yield were studied. Meanwhile, the distributions of hydrogen inside the gasifier at different conditions are also described.展开更多
基金the National Basic Research Development of China(2011CB936003)the National Natural Science Foundation of China(50971116)。
文摘Photocatalytic splitting of water over p-type semiconductors is a promising strategy for production of hydrogen.However,the determination of rate law is rarely reported.To this purpose,copper oxide(CuO)is selected as a model photocathode in this study,and the photogenerated surface charge density,interfacial charge transfer rate constant and their relation to the water reduction rate(in terms of photocurrent)were investigated by a combination of(photo)electrochemical techniques.The results showed that the charge transfer rate constant is exponential-dependent on the surface charge density,and that the photocurrent equals to the product of the charge transfer rate constant and surface charge density.The reaction is first-order in terms of surface charge density.Such an unconventional rate law contrasts with the reports in literature.The charge density-dependent rate constant results from the Fermi level pinning(i.e.,Galvani potential is the main driving force for the reaction)due to accumulation of charge in the surface states and/or Frumkin behavior(i.e.,chemical potential is the main driving force).This study,therefore,may be helpful for further investigation on the mechanism of hydrogen evolution over a CuO photocathode and for designing more efficient CuO-based photocatalysts.
文摘Hydrogen peroxide(H_(2)O_(2))has gained widespread attention as a versatile oxidant and a mild disin-fectant.Here,an electrostatic self-assembly method is applied to couple ZnSe quantum dots(QDs)with a flower-like covalent organic framework(COF)to form a step-scheme(S-scheme)photocata-lyst for H_(2)O_(2)production.The as-prepared S-scheme photocatalyst exhibits a broad light absorption range with an edge at 810 nm owing to the synergistic effect between the ZnSe QDs and COF.The S-scheme charge-carrier transfer mechanism is validated by performing Fermi level calculations and in-situ X-ray photoelectron and femtosecond transient absorption spectroscopies.Photolumi-nescence,time-resolved photoluminescence,photocurrent response,electrochemical impedance spectroscopy,and electron paramagnetic resonance results show that the S-scheme heterojunction not only promotes charge carrier separation but also boosts the redox ability,resulting in enhanced photocatalytic performance.Remarkably,a 10%-ZnSe QD/COF has excellent photocatalytic H_(2)O_(2)-production activity,and the optimal S-scheme composite with ethanol as the hole scavenger yields a H_(2)O_(2)-production rate of 1895 mol g^(-1)h-1.This study presents an example of a high-performance organic/inorganic S-scheme photocatalyst for H_(2)O_(2)production.
基金This research was sponsored by National Natural Science Foundation of China (Grant No. 39630240 and 3000132).
文摘Chinese fir (Cunninghamia lanceolata (Lamb.) Hook.), a fast-growing, ever-green conifer tree with high yield and excellent quality, is the most important tree species of timber plantations in subtropical China. We investigated the characteristics of biomass, litterfall and nutrient fluxes in the 8, 14 and 24 year-old stands, representing the young, middle-aged and mature stands. The results showed that Chinese fir plantations in central Fujian province had high productivity, and the proportion of stem mass in total biomass was between 50%-70%. Chinese fir was low nutrient-return tree species with litterfall. Nutrient withdrawal from senescing needles was a strong age-dependence for nitrogen, phosphorous and potassium in Chinese fir. With a management system of such short-rotation and continuously pure-crop planting, harvesting timber can lead to great nutrient loss, which may be one of the causes for site degradation.
基金Project (10964004) supported by the National Natural Science Foundation of ChinaProject (096RJZA104) supported by the Natural Science Foundation of Gansu Province, China
文摘The effect of supercooled melt forced laminar flow at low Reynolds Number on dendritic growth perpendicular to melt flow direction was investigated with the phase-field method by incorporating melt convection and thermal noise under non-isothermal condition. By taking the dendritic growth of high pure succinonitrile （SCN） supercooled melt as an example, side-branching shape difference of melts with flow and without flow was analyzed. Relationships among supercooled melt inflow velocity, deflexion angle of dendritic arm and dendritic tip growth velocity were studied. Results show that the melt inflow velocity has few effects on the dendritic tip growth velocity. A formula of relationship between the velocity of the melt in front of primary dendritic tip and the dendritic growth time was deduced, and the calculated result was in quantitative agreement with the simulation result.
文摘[Objective] This study was conducted to find a restoration method suitable for urban polluted rivers. [Method] A segment of a representative river in the old part of a certain city in south Jiangsu was selected as a research area through previous investigation, and the polluted river was cleaned and restored by 3 methods, i.e. artificial wetland, floating island type wetland and purification floating island. [Resuit] Floating plants （Hydrocotyle verticillata and Myriophyllum spicatum） showed better restoration effects than emergent aquatic plants （Iris wilsonii, Arundo donax, reed, water-cultured Ilex chinensis and Lythrum salicaria）. The two types of plants showed the removal rates of total nitrogen of 37.9% and 34.1%, respectively, the removal rates of total phosphorous of 80.1% and 73.5%, respectively, the removal rates of COD of 81.1% and 74.8%, respectively, the removal rates of ammonia nitrogen of 80.6% and 85.9%, respectively, and the removal rates of SS of 59.1% and 77.3%, respectively. Among the purification floating island, the artificial wetland and the floating island type wetland, the purification floating land restoration technique exhibited the best removal effect, with the removal rates of 87.6%, 71.3%, 87.6%, 97.5% and 81.8% for total nitrogen, total phosphorous, ammonia nitrogen COD and SS, respectively. The nitrification and denitdfication rates of bottom mud and water samples in the engineering segment were remarkably higher than those in the reference segment, by 15.4% and 21.1%, respectively. The nitrification and denitrification rates of bottom mud in the engineering segment and the non-engineering segment were higher than those of water samples by 26.9% and 31.8%, respectively. Restoration plants showed better removal effects of total phosphorous, total nitrogen, COD and SS under aeration condition than noeration condition. [Conclusion] The purification floating island has a significant restoration effect on urban polluted river.
基金This study was supported by the National Natural Science Foundation of China (NSFC39970123 30170744)+1 种基金 Chinese Academy of Sciences (A grant KZCX2-406) and Changbai Mountain Open Research Station.
文摘As the most important type or component in the terrestrial ecosystems, forest ecosystem makes its role obviously prominent and important on environment and human being. It possesses non-substitutable functions in the process of sustainable development. However, due to the complexity of the forest ecosystem and the relatively delay or lack of the related research technology, the science is still in the case of immature and questions. This paper summarized and reviewed briefly the development and the present case of the forest ecology, then pointed out the existing problems in the forest ecosystem researches. In the end, we discussed several fields that need to pay more attention to in future researches.
基金Supported by National Natural Science Foundation of China(50908116 )211 Foundation of Nanjing Normal University(2009112XGQ0054)+1 种基金Jiang su High-funded Construction ProjectsMajor Project of Jiangsu Provincial Department of Education(2009105TSJ0165)~~
文摘The combination method of intermittent influent and vertical flow wetlands （VFW） was used in the test to treat the domestic wastewater. Four artificial wetlands including Typha latifolia wetland,Phragmites australis （P.H.） wetland,polyculture wetlands （Typha latifolia and Phragmites australis） and non-vegetation wetland were established in the test. The effects of hydraulic retention time （HRT） and plant species on pollutants removal efficiencies were studied. The results showed that when HRT=7,the treatment efficiencies of wetlands with plants for the removal of TN and NH＋4-N were up to 99.65% and 99.58%,respectively. For the control wetland,TN removal efficiency was up to 87.9% when HRT were 6 days,and NH＋4-N removal efficiency was up to 91.8% when HRT were 5 days. TP removal efficiencies of four wetlands were higher than 93% when HRT was 6 days. Through the studies on different plants,it was found that vegetation wetlands had better nitrogen removal efficiency than non-vegetation wetland. The treatment efficacy of Phragmites australis wetland and polyculture wetland was better than Typha latifolia wetland.
基金Project(10964004) supported by the National Natural Science Foundation of ChinaProject(20070731001) supported by Research Fund for the Doctoral Program of China+1 种基金 Project(096RJZA104) supported by the Natural Science Foundation of Gansu Province,ChinaProject(SB14200801) supported by the Doctoral Fund of Lanzhou University of Technology,China
文摘The random distribution problem of dendrite preferred growth direction was settled by random grid method.This method was used to study the influence of forced laminar flow effect on multiple grains during solidification.Taking high pure succinonitrile （SCN） undercooled melt as an example,the forced laminar flow effect on multiple grains was studied by phase-field model of single grain which coupled with flow equations at non-isothermal condition.The simulation results show that the random grid method can reasonably settle the problem of random distribution and is more effective.When the solid fraction is relatively low,melt particles flow around the downstream side of dendrite,and the flow velocity between two dendrite arms becomes high.At the stage of solidification time less than 1800Δt,every dendrite grows freely;the upstream dendrites are stronger than the downstream ones.The higher the melt flow rate,the higher the solid fraction.However,when the solid fraction is relatively high,the dendrite arm intertwins and only a little residual melt which is not encapsulated can flow;the solid fraction will gradually tend to equal to solid fraction of melt without flow.
文摘The reverse generation current under high-gate-voltage stress condition in LDD nMOSFET＇s is studied. We find that the generation current peak decreases as the stress time increases. We ascribe this finding to the dominating oxide trapped electrons that reduce the effective drain bias, lowering the maximal generation rate. The density of the effective trapped electrons affecting the effective drain bias is calculated with our model.
文摘Fluidized bed biomass gasifiers can be employed to produce hydrogen-rich gas. A non-premixed combustion model is used for biomass air-steam gasification in the gasifier, and the simulations were carried out by using the FLUENT 6.0 software. The simulation results are compared with the experimental data. The effects of the steam to biomass ratio （S/B）, the equivalence ratio （ER）, and the size of biomass particles on the hydrogen yield were studied. Meanwhile, the distributions of hydrogen inside the gasifier at different conditions are also described.
