Electrochemical hydrogen storage properties of non-equilibrium Ti_(2-x)Mg_xNi alloys

Amorphous Ti2?xMgxNi (x=0?0.3) alloys were prepared by mechanical milling of elemental powders. Charge and discharge test, linear polarization (LP) and potential-step measurement were carried out to investigate the electrochemical hydrogen storage properties of the alloys before and after heat treatment. The results show that the maximum discharge capacity of heat-treated Ti2?xMgxNi alloy can reach 275.3 mA·h/g, which is 100 mA·h/g higher than that of the amorphous Ti2?xMgxNi alloy. The heat-treated Ti1.9Mg0.1Ni alloy presents the best cycling stability with a high discharge capacity of 210 mA·h/g after 30 cycles. The results of LP and potential-step measurement of the Ti1.9Mg0.1Ni alloy show that the exchange current density increases from 101.1 to 203.3 mA/g and the hydrogen diffusion coefficient increases from 3.20×10?11 to 2.70×10?10 cm2/s after the heat treatment, indicating that the heat treatment facilitates both the charge-transfer and hydrogen diffusion processes, resulting in an improvement in electrochemical hydrogen storage properties of Ti2?xMgxNi (x=0?0.3) alloys.

PC技术内幕系列专题——热插拔的“硬”道理

热插拔操作给电脑应用带来便捷，但前提必须是软、硬件都支持。就软件而言，牵涉到BIOS和操作系统，如果它们不支持热插拔，就意味着插入和移除硬件都不能被系统察觉。一旦系统与这些设备交换数据，将进入漫长的等待而导致死机。《微型计算机》2003年第18期的《发现新硬件的前前后后》中已详细介绍过热插拔在软件方面的解决方案，而本文在此将向您讲解热插拔的“硬”道理。

Exchange Reaction Characteristics of Anion Exchange Resin for Diclofenac Sodium

Aim To study the exchange reaction characteristics of anion exchange resin for diclofenac sodium. Methods The drug-resin complexes were prepared by a batch method with diclofenac sodium as the model drug and the strong anion exchange resin (201 × 7) as the carrier. The effects of different forms (OH~ - and Cl~ - ) of the strong anion exchange resin, the particle size of the resin, and the reaction temperature on the exchange behavior were described. The exchange kinetic profiles were fitted. The related exc...

New atom movement mechanism for tracking path on disordering AuCuI(A_8^(Au)A_4^(Cu)) compound

Taking experimental path on disordering AuCuI（AAuCu8A4）composed of A Au8 and ACu4 stem alloy genes as an example, three discoveries and a method were presented. The ability of Au Cu I（AAu Cu8 A4）to keep structure stabilization against changing temperature is attributed to the fact that the AAu8 and ACu4 potential well depths greatly surpass their vibration energies, which leads to the subequilibrium of experimental path. A new atom movement mechanism of AuCuI（AAuACu84）to change structure for suiting variation in temperature is the resonance activating-synchro alternating of alloy genes, which leads to heterogeneous and successive subequilibrium transitions. There exists jumping order degree, which leads to the existence of jumping Tj-temperature and an unexpected so-called ＂retro-effect＂ about jumping temperature retrograde shift to lower temperatures upon the increasing heating rate. A set of subequilibrium holographic network path charts were obtained by the experimental mixed enthalpy path method.

Study on Multi-stream Heat Exchanger Network Synthesis with Parallel Genetic/Simulated Annealing Algorithm

The multi-stream heat exchanger network synthesis (HENS) problem can be formulated as a mixed integer nonlinear programming model according to Yee et al. Its nonconvexity nature leads to existence of more than one optimum and computational difficulty for traditional algorithms to find the global optimum. Compared with deterministic algorithms, evolutionary computation provides a promising approach to tackle this problem. In this paper, a mathematical model of multi-stream heat exchangers network synthesis problem is setup. Different from the assumption of isothermal mixing of stream splits and thus linearity constraints of Yee et al., non-isothermal mixing is supported. As a consequence, nonlinear constraints are resulted and nonconvexity of the objective function is added. To solve the mathematical model, an algorithm named GA/SA (parallel genetic/simulated annealing algorithm) is detailed for application to the multi-stream heat exchanger network synthesis problem. The performance of the proposed approach is demonstrated with three examples and the obtained solutions indicate the presented approach is effective for multi-stream HENS.

Heat Transfer and Friction Factor Studies in a Circular Tube Fitted with Twisted Tape Consisting of Wire-nails

This paper deals with the experimental investigation on Nusselt number,friction factor and thermal en-hancement factor of a double pipe heat exchanger equipped with twisted tape consisting wire nails(WN-TT) and plain twisted tapes(P-TT) with three different twist ratios of y 2.0,4.4 and 6.0. Test runs are conducted using the water as the working fluid with Reynolds number range between 2000 and 12000 for WN-TT and P-TT. It is found that Nusselt number,friction factor and thermal enhancement factor in the tube equipped with WN-TT appreciably higher than those in the tube fitted with P-TT and plain tube. Over the range considered Nusselt number,friction factor and thermal enhancement factor in a tube with WN-TT are respectively,1.08 to 1.31,1.1 to 1.75 and 1.05 to 1.13 times of those in tube with P-TT. The better performance of WN-TT is due to combined effects of the follow-ing factors:(1) common swirling flow generated by P-TT,(2) additional turbulence offered by the wire nails. Em-pirical correlations for Nusselt number,friction factor and thermal enhancement factor are also formulated from the experimental results of WN-TT and P-TT.

Thermohydraulics of Turbulent Flow Through Heat Exchanger Tubes Fitted with Circular-rings and Twisted Tapes

The influences of circular-ring turbulators （CRT） and twisted tape （TT） swirl generators on the heat transfer enhancement, pressure drop and thermal performance factor characteristics in a round tube are reported. The circular-ring turbulators were individually employed and together with the twisted tape swirl generators in the heated section of the tube. Three different pitch ratios （I/D = 1.0, 1.5, and 2.0） of the CRT and three different twist ratios （y/W= 3, 4, and 5） of the TT were introduced. The experiments were conducted using air as the working fluid under a uniform wall heat flux condition, for the Reynolds number between 6000 and 20000. The experimental results reveal that the heat transfer rate, friction factor and thermal performance factor of the combined CRT and qT are considerably higher than those of CRT alone. For the range examined, the Sncreases of mean Nusselt number, friction factor and thermal performance, in the tube equipped with combined devices, respectively, are 25.8%, 82.8% and 6.3% over those in the tube with the CRT alone. The highest thermal performance factor of 1.42 is found for the combined device consisting of the CRT with l/D = 1.0 and TT with y/W= 3. The correlations of the Nusselt number, friction factor and thermal performance factor of the tubes with combined devices are also developed in terms of Reynolds number, Prandtl number, twist ratio and pitch ratio.

Experimental Research on Flow Maldistribution in Plate-Fin Heat Exchangers

The flow maldistribution and the effect of different inlet configuration on the flow distribution in platefin heat exchangers were studied experimentally. It is found that the flow maldistribution is serious because of the defects of inlet configurations, while the inlet configuration and Reynolds number are the main factors affecting the flow distribution. The improved inlet configurations, which are the header with a two-stage distributing configuration and the guide vane with a fluid complementary cavity were proposed and tested in this paper. The experimental results show that the improved inlet configurations can effectively improve the performance of flow distribution in heat exchangers.

Design of heat exchanger network based on entransy theory

The heat exchanger network(HEN) synthesis problem based on entransy theory is analyzed. According to the characteristics of entransy representation of thermal potential energy, the entransy dissipation represents the irreversibility of the heat transfer process, the temperature difference determines the entransy dissipation, and four HEN design steps based on entransy theory are put forward. The present study shows how it is possible to set energy targets based on entransy and achieve them with a network of heat exchangers by an example of heat exchanger network design for four streams. In order to verify the correctness of the heat exchanger networks design method based on entransy theory, the synthesis of the HEN for the diesel hydrogenation unit is studied. Using the heat exchange networks design method based on entransy theory, the HEN obtained is consistent with energy targets. The entransy transfer efficiency of HEN based on entransy theory is 92.29%, higher than the entransy transfer efficiency of the maximum heat recovery network based on pinch technology.

An Explicit Solution for Thermal Calculation and Synthesis of Super-structure Heat Exchanger Networks

For the optimal design of a heat exchanger network,the inlet and outlet stream temperatures of each heat exchanger in the network should be known.An explicit analytical solution of stream temperatures of an arbi-trary connected heat exchanger network was introduced,which is suitable for the thermal calculation of heat ex-changer networks.For the heat exchanger network synthesis,this solution was further developed and coupled with the stage-wise superstructure heat exchanger networks.The new calculation procedure reduced the computer mem-ory requirement dramatically.On the basis of this solution,a mathematical model for synthesis of heat exchanger networks with genetic algorithm was formulated,which is always feasible and no iteration is needed.Two examples were calculated with the proposed approach and better results were obtained.

Theoretical and Experimental Study on Ground Coupled Heat Pump with Vertical Spiral Coil

The numeric al simulation study on the temperature distribution of underground field for the ground coupled heat pump (GCHP) with vertical spira l coil was carried out by using finite element. The distribution and recovery of undergroun d field temperature under different operation ratio and the optimal operation ratio were simulated.The performance parameters, i.e. inlet and outlet temperature of the ground spiral coil in heating and cooling modes were tested, the heat extracted or emitted by the heat pump to the ground was calculated, and the coefficients of performance (COP) of GCHP at heat ing and cooling modes were analyzed.

Heat transfer enhancement of finned shell and tube heat exchanger using Fe_(2)O_(3)/water nanofluid

Heat transfer mechanisms and their thermal performances need to be comprehensively studied in order to optimize efficiency and minimize energy losses.Different nanoparticles in the base fluid are investigated to upgrade the thermal performance of heat exchangers.In this numerical study,a finned shell and tube heat exchanger has been designed and different volume concentrations of nanofluid were tested to determine the effect of utilizing nanofluid on heat transfer.Fe_(2)O_(3)/water nanofluids with volume concentration of 1%,1.5% and 2% were utilized as heat transfer fluid in the heat exchanger and the obtained results were compared with pure water.ANSYS Fluent software as a CFD method was employed in order to simulate the mentioned problem.Numerical simulation results indicated the successful utilization of nanofluid in the heat exchanger.Also,increasing the ratio of Fe_(2)O_(3) nanoparticles caused more increment in thermal energy without important pressure drop.Moreover,it was revealed that the highest heat transfer rate enhancement of 19.1% can be obtained by using nanofluid Fe_(2)O_(3)/water with volume fraction of 2%.

The Current Situation of the Study on Twisted Tape Inserts in Pipe Exchangers

Heat transfer enhancement is used in many applications including heat exchangers, air conditioning, and refrigeration systems; hence many researchers have conducted experimental and numerical researches on heat transfer enhancement and have developed various techniques and methods. As a passive heat transfer technique, twisted tapes are widely used in various industries for their cost savings, lower maintenance requirements and the fact that they are easily set up. This paper introduces the principle of heat transfer enhancement of twisted tapes and reviews some of the experimental works done by researchers on this technique in recent years. The variously modified twisted tape inserts are widely researched and used to enhance heat transfer efficiency for heat exchangers. Twisted tapes perform better in low Re conditions and in square tubes. However, they could also cause higher pressure drops. Twisted tapes have great potential and profound implications if they can be used in traditional heat exchangers. Besides this, some correlations between the Nusselt number and friction factors are presented in this paper.

Variabilities of Surface Current in the Tropical Pacific Ocean

The Simple Ocean Data Assimilation (SODA) package is used to better understand the variabilities of surface current transport in the Tropical Pacific Ocean from 1950 to 1999. Seasonal variation, interannual and decadal variability analyses are conducted on the three major surface currents of the Tropical Pacific Ocean: the North Equatorial Current (NEC), the North Equatorial Countercurrent (NECC), and the South Equatorial Current (SEC). The transport of SEC is quite larger than those of NEC and NECC. The SEC has two maximums in February and August. The NEC has a small annual variation. The NECC has a maximum in October and is very weak in March and April. All currents have remarkable interannual and decadal variabilities. The variabilities of the NEC and the SEC relate to the winds over them well, but the relationship between the NECC and the wind over it is not close. Analysis related to El Nio-Southern Oscillation (ENSO) suggests that before El Nio (La Nia) the SEC is weaker (stronger) and the NECC is stronger (weaker), after El Nio (La Nia) the SEC is stronger (weaker) and the SEC is weaker (stronger). There is no notable relationship between the NEC and ENSO.

Arrangement Strategy of Ground Heat Exchanger with Groundwater

The orientation strategy of side pipe and the heat transfer performance of six ground heat exchangers(GHEs) were optimized by numerical simulation,with soil being treated as a porous medium.An experiment on the heat transfer of four GHEs was carried out in 2010.Results indicate that the velocity field is disturbed by GHEs.The optimal orientation strategy of side pipe is that the upward pipe is located upstream and the downward pipe downstream.The space between GHEs should be appropriately adjusted,depending on the direction and flow velocity.Groups of GHEs should be installed perpendicular to the mainstream in a single row,but if the acreage does not meet the requirements,GHEs should be installed in staggered multiple rows.Fewer GHEs parallel to the mainstream strengthen the heat transfer.Moreover,numerical results agree well with the test data,with the maximum relative error being less than 7.7%.

Optimizing Low-Temperature Heat Recovery in a Refinery Fluid Catalytic Cracking Unit Based on Pinch Analysis

In this paper, the research was focused on optimizing low-temperature heat recovery to adopt multi-effect distil- lation （MED） in desalination by pinch technology. And further analysis indicated that phase changes occurred during the heat recovery process. In such case, the feed stream was divided into two streams： the liquid feed stream and the gaseous feed stream. Through calculation, the optimal ATmin was established at 26℃, and the total cost of heat exchange process was only $1.098× 106. By using the Problem Table Algorithm for pinch analysis, the temperature of the hot and the cold steams was 119℃ and 93 ℃, respectively. At a temperature higher than 119 ℃, all heat of the hot stream could not be cooled by the condenser, and the minimum heat load of utility （QH.min） was 440457.64 kW; and at a temperature below 93 ℃, all heat of the cold stream could not be provided by the heater, and the minimum cold load of utility （QC.min） was 1965993.85 kW. Finally, the synthesis of heat exchanger network was established through integrating two heat exchanger networks.

Optimal design of the separate type heat pipe heat exchanger

Separate type heat pipe heat exchangers are often used for large-scale heat exchanging. The arrangement of such a heat exchanger conveniently allows heat input to and output from the heat exchanger at remote locations. The traditional method of designing an ordinary HPHE (heat pipe heat exchanger) is commonly applied in the separate type exchanger design, but the calculations have to be carried out separately, which makes it very complicated. In this work, the ε-NTU (effectiveness-Number of Transfer Units) method was applied for optimization analysis of single- or multi-level separate type heat pipe heat exchangers. An optimizing formula for single-level separate type heat pipe heat exchangers was obtained. The optimizing principles of effec- tiveness-NTU and heat transfer rate by the equal distribution method for multi-level separate type heat pipe heat exchanger are presented. The design of separate type heat pipe heat exchangers by the optimizing method is more convenient and faster than by the traditional method.

Feasibility of Intermediate Fluid Vaporizer with Spiral Wound Tubes

A novel intermediate fluid vaporization (IFV) technology for LNG re-gasification process with spiral-wound heat exchanging tubes is proposed. The new IFV project combines the advantage of running the shell and tube heat exchangers at high pressure with the advantage of compact space of heat exchangers. Thermal analysis on the two processes of forced convection and vaporization type heat transfer in the spiral wound tubes and vapor condensation /re-boiling type of heat transfer via intermediate fluid in shell side shows the feasibility of this promising technology.

Key Issues on Cryospheric Changes,Trends and Their Impacts

On the basis of analyzing the importance of cryospheric researches in China and current status of cryospheric sciences in the world, this paper addresses key issues and main contents of present cryospheric sciences in China. The key issues currently addressed are： i） mechanisms of different types of glaciers in response to climate change and the scale-conversion in water resources assessments; ii） modeling of water and heat exchanges between frozen soil and vegetation; iii） parameterization of physical processes in cryosphere as well as coupling with climate models. To gain full clarification of these key issues, works of the following three aspects should be highlighted, i.e., cryospheric processes and responses to climate change, influences of cryospheric changes, and adaptation strategies for cryospheric changes.

Numerical simulation on heat transfer performance of vertical U-tube with different borehole fill materials

Heat exchange performance of vertical U-tube heat exchanger was studied with two different borehole fill materials and CFD software. Borehole surface temperature and water temperature distribution were simulated on the condition of continuous operation for 8 h in winter with inlet water temperature being 10℃. The results show that there is no obvious difference on heat exchanger performance between the two different borehole fill materials.