To investigate the process optimizationof Cu-en/AP composite microspheres preparation via electrostatic spraying,and to reveal the effects of droplet properties and flow rate variations on the experimental results dur...To investigate the process optimizationof Cu-en/AP composite microspheres preparation via electrostatic spraying,and to reveal the effects of droplet properties and flow rate variations on the experimental results during the electrostatic spraying process,the prepared process parameters of Cu-en/AP composite microspheres by electrostatic spray method under the orthogonal experimental design simulated by ANSYS(Fluent).The influence of flow rate,solvent ratio,and solid mass on the experimental results is examined using a controlled variable method.The results indicate that under the conditions of a flow rate of 2.67×10^(-3)kg/s an acetone-to-deionized water ratio of 1.5∶1.0,and a solid mass of 200 mg,the theoretical particle size of the composite microspheres can reach e nanoscale.Droplet trajectories in the electric field remain stable without significant deviation.The simulation results show that particle diameter decreases with increasing flow rate,with the trend leveling off around a flow rate of 1×10^(-3)kg/s.As the solvent ratio increases(with higher acetone content),particle diameter initially decreases,reaching a minimum around a ratio of 1.5∶1.0 before gradually increasing.Increasing the solid mass also reduces the particle diameter,with a linear increase in diameter observed at around 220 mg.Cu-en/AP composite microspheres with nanoscale dimensions were confirmed under these conditions by the final SEM images.展开更多
A study was conducted to analyze the deformation mechanism of strongly weathered quartz schist in the Daliangshan Tunnel,located in the western Transverse Mountain area.A large deformation problem was experienced duri...A study was conducted to analyze the deformation mechanism of strongly weathered quartz schist in the Daliangshan Tunnel,located in the western Transverse Mountain area.A large deformation problem was experienced during the tunnel construction.To mitigate this problem,a support system was designed incorporating negative Poisson ratio(NPR)anchor cables with negative Poisson ratio effect.Physical model experiments,field experiments,and numerical simulation experiments were conducted to investigate the compensation mechanical behavior of NPR anchor cables.The large deformations of soft rocks in the Daliangshan Tunnel are caused by a high ground stress,a high degree of joint fracture development,and a high degree of surrounding rock fragmentation.A compensation mechanics support system combining long and short NPR anchor cables was suggested to provide sufficient counter-support force(approximately 350 kN)for the surrounding rock inside the tunnel.Comparing the NPR anchor cable support system with the original support system used in the Daliangshan tunnel showed that an NPR anchor cable support system,combining cables of 6.3 m and 10.3 m in length,effectively prevented convergence of surrounding rock deformation,and the integrated settlement convergence value remained below 300 mm.This study provides an effective scientific basis for resolving large deformation problems in deeply buried soft rocks in western transverse mountain areas.展开更多
The dynamic monitoring of landslides in engineering geology has focused on the correlation among landslide stability,rainwater infiltration,and subsurface hydrogeology.However,the understanding of this complicated cor...The dynamic monitoring of landslides in engineering geology has focused on the correlation among landslide stability,rainwater infiltration,and subsurface hydrogeology.However,the understanding of this complicated correlation is still poor and inadequate.Thus,in this study,we investigated a typical landslide in southwestern China via time-lapse electrical resistivity tomography(TLERT) in November 2013 and August 2014.We studied landslide mechanisms based on the spatiotemporal characteristics of surface water infiltration and flow within the landslide body.Combined with borehole data,inverted resistivity models accurately defined the interface between Quaternary sediments and bedrock.Preferential flow pathways attributed to fracture zones and fissures were also delineated.In addition,we found that surface water permeates through these pathways into the slipping mass and drains away as fissure water in the fractured bedrock,probably causing the weakly weathered layer to gradually soften and erode,eventually leading to a landslide.Clearly,TLERT dynamic monitoring can provide precursory information of critical sliding and can be used in landslide stability analysis and prediction.展开更多
To simultaneously take into account the Biot-flow mechanism, the squirt-flow mechanism, and the frame-viscoelasticity mechanism, a generalized viscoelastic BISQ (Biot/squirt) model is developed for wave propagation ...To simultaneously take into account the Biot-flow mechanism, the squirt-flow mechanism, and the frame-viscoelasticity mechanism, a generalized viscoelastic BISQ (Biot/squirt) model is developed for wave propagation in clay-bearing sandstones based on Dvorkin's elastic BISQ model. The present model is extended to a wide range of permeabilities (k 〉 0.05 mD) by introducing a dimensionless correction factor for viscoelastic parameters, defined as a function of the permeability and the clay content. We describe the frame's stress-strain relationship of the clay-bearing sandstones by the differential constitutive equations of generalized viscoelasticity and then derive the viscoelastic-wave dynamic equations. With the assumption of a plane-wave solution, we finally yield the phase velocities and the attenuation coefficients by solving the dynamic wave equations in the frequency and wave number domain. The comparison of numerical results and experimental data shows that the generalized viscoelastic BISQ model is applicable for modeling the wave propagation in most of the sandstones mainly bearing kaolinite clay.展开更多
Based on a detailed analysis of differences between seismic data and well logs, we discuss the problem of matching seismic traces and well logs and present a new matching method based on event search in instantaneous ...Based on a detailed analysis of differences between seismic data and well logs, we discuss the problem of matching seismic traces and well logs and present a new matching method based on event search in instantaneous phase which greatly improves seismic resolution. The method is based on flattening events in instantaneous phase to compare the seismic traces to the well log traces with the same phase. We calculate the coefficients using the singular value decomposition method to extrapolate the well logs. As a result, the events in the seismic profile are continuous and match well with well logs. We apply this method to the Mao-2 well in Daqing Oilfield with good results.展开更多
Unlike previous theories with velocity and/or elastic modulus averaging, we use a three-phase porous rock physics model developed by Santos for analyzing the seismic response of two immiscible fluids in saturated poro...Unlike previous theories with velocity and/or elastic modulus averaging, we use a three-phase porous rock physics model developed by Santos for analyzing the seismic response of two immiscible fluids in saturated porous media. Considering reservoir reference pressure and coupling drag of two fluids in pores, the effects of frequency, porosity, and gas saturation on the phase velocities of the P-and S-waves are discussed in detail under field conditions. The effects of porosity and gas saturation on Vp/Vs are also provided. The data for our numerical experiments are from a sample of deep volcanic rock from Daqing. The numerical results show that the frequency dispersion effect can be ignored for deep volcanic rocks with low porosity and low permeability. It is concluded that for deep volcanic rocks the effect of gas content in pores on Vp/Vs is negligible but the effect of porosity is significant when there is a certain amount of water contained in the pores. The accurate estimate of lithology and porosity in this case is relatively more important.展开更多
Based on Kuo and Dai's vectorial wave-field extrapolation equations, we derive new Kirchhoff migration equations by introducing unit vectors which represent the ray directions at the imaging points of the reflected P...Based on Kuo and Dai's vectorial wave-field extrapolation equations, we derive new Kirchhoff migration equations by introducing unit vectors which represent the ray directions at the imaging points of the reflected P- and PS converted-waves. Furthermore, using the slope of the events on shot records and a ray racing procedure, mirror-image reflection points are found and the reflection data are smeared along the Fresnel zone. The migration method proposed in this paper solves two troublesome imaging problems caused by limited receiving aperture and migration artifacts resulting from wave propagation at the velocities of non original wave type. The migration method is applied successfully with model data, demonstrating that the new method is effective and correct.展开更多
The catalytic wet air oxidation of aniline over Ru catalysts supported on modified Ti 2 (Ti 2, Ti0.9Ce0.1O2, Ti0.9Zr0.1O2) is investigated. A series of characterization techniques are conducted to deter...The catalytic wet air oxidation of aniline over Ru catalysts supported on modified Ti 2 (Ti 2, Ti0.9Ce0.1O2, Ti0.9Zr0.1O2) is investigated. A series of characterization techniques are conducted to determine the relationship between the physico-chemical properties and the catalytic performance. As a result of the good metal dispersion and large number of surface oxygen species, the Ru/Ti0.9 Zr0.1O2 catalyst presents the best catalytic activity among the tested samples. The effects of the operating conditions on the reaction are investigated and the optimal reaction conditions are determined. Based on the relationship between the by-products concentration and the reaction time, the reaction path for the catalytic oxidation of aniline is established. Carbonaceous deposits on the surface of the support are known to be the main reason for catalyst deactivation. The catalysts maintain a constant activity even after three consecutive cycles.展开更多
Based on the sensitivity of geophysical response to gas hydrates contained in sediments, we studied the prediction of gas hydrates with seismic techniques, including seismic attributes analysis, AVO, inverted velocity...Based on the sensitivity of geophysical response to gas hydrates contained in sediments, we studied the prediction of gas hydrates with seismic techniques, including seismic attributes analysis, AVO, inverted velocity field construction for dipping formations, and pseudo-well constrained impedance inversion. We used an optimal integration of geophysical techniques results in a set of reliable and effective workflows to predict gas hydrates. The results show that the integrated analysis of the combination of reflectivity amplitude, instantaneous phase, interval velocity, relative impedance, absolute impedance, and AVO intercept is a valid combination of techniques for identifying the BSR (Bottom Simulated Reflector) from the lower boundary of the gas hydrates. Integration of seismic sections, relative and absolute impedance sections, and interval velocity sections can improve the validity of gas hydrates determination. The combination of instantaneous frequency, energy half attenuation time, interval velocity, AVO intercept, AVO product, and AVO fluid factor accurately locates the escaped gas beneath the BSR. With these conclusions, the combined techniques have been used to successfully predict the gas hydrates in the Dongsha Sea area.展开更多
Based on the empirical Gardner equation describing the relationship between density and compressional wave velocity, the converted wave reflection coefficient extrema attributes for AVO analysis are proposed and the r...Based on the empirical Gardner equation describing the relationship between density and compressional wave velocity, the converted wave reflection coefficient extrema attributes for AVO analysis are proposed and the relations between the extrema position and amplitude, average velocity ratio across the interface, and shear wave reflection coefficient are derived. The extrema position is a monotonically decreasing function of average velocity ratio, and the extrema amplitude is a function of average velocity ratio and shear wave reflection coefficient. For theoretical models, the average velocity ratio and shear wave reflection coefficient are inverted from the extrema position and amplitude obtained from fitting a power function to converted wave AVO curves. Shear wave reflection coefficient sections have clearer physical meaning than conventional converted wave stacked sections and establish the theoretical foundation for geological structural interpretation and event correlation. "The method of inverting average velocity ratio and shear wave reflection coefficient from the extrema position and amplitude obtained from fitting a power function is applied to real CCP gathers. The inverted average velocity ratios are consistent with those computed from compressional and shear wave well logs.展开更多
We present a forward-modeling investigation of time-dependent ground magnetometric resistivity (MMR) anomalies associated with transient leachate transport in groundwater systems. Numerical geo-electrical models are...We present a forward-modeling investigation of time-dependent ground magnetometric resistivity (MMR) anomalies associated with transient leachate transport in groundwater systems. Numerical geo-electrical models are constructed based on the hydrological simulation results of leachate plumes from a highly conceptualized landfill system and the resultant MMR responses are computed using a modified finite difference software MMR2DFD. Three transmitter configurations (i.e., single source, MMR-TE, and MMR-TM modes) and two hydrological models (i.e., uniform and faulted porous media) are considered. Our forward modeling results for the uniform porous medium indicates that the magnetic field components perpendicular to the dominant current flow contain the most information of the underground targets and the MMR-TE mode is an appropriate configuration for detecting contaminant plumes. The modeling experiments for the faulted porous medium also confirm that the MMR method is capable of mapping and monitoring the extent of contaminant plumes in aroundwater systems.展开更多
Coral sand is a unique material developed in the tropical ocean environment, which is mainly composed of coral and other marine organism debris, with the CaCO3 content up to 96 %. It has special physical and mechanica...Coral sand is a unique material developed in the tropical ocean environment, which is mainly composed of coral and other marine organism debris, with the CaCO3 content up to 96 %. It has special physical and mechanical properties due to its composition, structure and sedimentary environment. In this contribution, we discuss its specific gravity, porosity ratio compressibility, crushing, shearing and intensity for coral sand samples from the Nansha islands based on laboratory mechanical tests. Our results show distinct high porosity ratio, high friction angle and low intensity as compared with the quartz sand. We believe that grain crushing is the main factor that influences the deformation and strength of coral sand. Comprehensive study on the physical and mechanical properties of coral sands is significant in providing reliable scientific parameters to construction on coral islet, and thus avoids accidents in construction.展开更多
Aim To investigate novel bioactive and structural metabolites from marineorganisms. Methods Column chromatography in association with semi-preparative HPLC were used for theisolation of compounds. 1D and 2D NMR, IR, U...Aim To investigate novel bioactive and structural metabolites from marineorganisms. Methods Column chromatography in association with semi-preparative HPLC were used for theisolation of compounds. 1D and 2D NMR, IR, UV, and MS were employed for structure elucidation.Results From the butanol fraction of the 95% EtOH extract of the starfish Asterias rollestoni, a newcompound N^7 -2'-deoxypseudoxanthosine (1), along with sixteen known compounds, 2'-0-methyl-inosine(2), 2'-deoxyinosine (3), 2'-0-methylguanosine (4), inosine (5); thymine (6), uracil (7), thymidine(8), deoxyuridine (9), 2'-0-methyluridine (10), ( ― )-(1S, 3S)-1-methyl-1, 2, 3,4-terrahydro-β-carboline-3-carboxyl-ic acid (11), ( ― )-(1R, 3S)-1-methyl-1, 2, 3,4-tetrahydro-β-carboline-3-carboxylic acid (12) , ( ― )-(3S)- 1, 2, 3,4-tetrahydro-β-carboline-3-carboxylic acid (13), L-tryptophan (14), L-phenylalanine (15), 3-carboxyindole (16), and p-hydroxybenzoic acid (17) , have been isolated. Conclusion Compound 1 is a newnatural product, and compounds 8, 9 and 10 are isolated from natural sources for the first time, andthe known compounds except 14 and 15 are first reported from starfish Asterias rollestoni.展开更多
A structure relaxation model based on the empirical electron theory of solids and molecules is developed to compute the diffusion active energies of C, N in γFe. First, adding a restriction, the lattice maintains rig...A structure relaxation model based on the empirical electron theory of solids and molecules is developed to compute the diffusion active energies of C, N in γFe. First, adding a restriction, the lattice maintains rigidity when solute atom migrates to the saddle point. In this step, the hybridization classes of every atom do not change. Then, the restriction is loosed and the atoms are relaxed under the coulomb repulsive forces. It is supposed that the energy needed in the first step would be compensated partly by the second step. In this way, the diffusion active energies of C, N in γFe are computed. Compared with the experiment data, the relative errors are less than 5%, which are good results in the computation of activation energy of diffusion.展开更多
Aluminum tri-polyphosphate was synthesized from bauxite tailings and phosphoric acid with a P/A1 molar ratio of 3. This is highly advantageous from a waste recycling perspective as bauxite railings are generally regar...Aluminum tri-polyphosphate was synthesized from bauxite tailings and phosphoric acid with a P/A1 molar ratio of 3. This is highly advantageous from a waste recycling perspective as bauxite railings are generally regarded as unusable waste. The acidity, whiteness and mean particle size of prepared aluminum tri-polyphosphate are all improved after modification. The possibility of using modified aluminum tri-polyphosphate as an anticorrosive pigment was also investigated by electrochemical impedance spectroscopy. The resistance of the coatings with modified aluminum tri-polyphosphate is 7×10^7Ω for 40 d of immersion, which is superior or at least comparable to that of coatings containing APW-2, which exhibits a resistance of 5.7×10^7Ω.展开更多
The NiCoCrAl alloy sheet was fabricated by electron beam physical vapor deposition technique and the effects of the heat treatment on the microstructure and tensile strength of the NiCoCrAl alloy sheet were investigat...The NiCoCrAl alloy sheet was fabricated by electron beam physical vapor deposition technique and the effects of the heat treatment on the microstructure and tensile strength of the NiCoCrAl alloy sheet were investigated. The heat treatment at 1050 °C is favorable to improve the interface bonding between the columnar structures due to the disappearance of the intergranular gaps. Comparing with the thin NiCoCrAl alloy sheet before heat treatment, the Ni3Al phase appears in the NiCoCrAl alloy sheet after heat treatment, which is favorable to improve the interface bonding between the columnar structures. The increase in the tensile strength and elongation is attributed to the improvement of the interface bonding between the columnar structures. The residual stress in the NiCoCrAl alloy sheet after heat treatment is reduced significantly, which also confirms that the interface bonding is improved by the heat treatment.展开更多
Diurnal and semi-diurnal tides in the Taiwan Strait and its adjacent areas are calculated by using a two-dimensional finite-difference model. Compared with data of more than 20 observation stations around the Taiwan S...Diurnal and semi-diurnal tides in the Taiwan Strait and its adjacent areas are calculated by using a two-dimensional finite-difference model. Compared with data of more than 20 observation stations around the Taiwan Strait, the model-produced results agree quite well with those of previous researches using observational data from coastal tidal gauge stations. According to the results, the co-tidal and co-range charts are given. Furthermore, the characteristics of 8 major tidal constituents have been uminated respectively. The result shows that: (1) The tide motion can be attributed to the interaction between the degenerative rotary tidal system in the north and the progressive tidal system in the south. (2) The southward and northward tidal waves of semi-diurnal tide converge in the middle of the Taiwan Strait while the diurnal tidal waves propagate southwestward through the Taiwan Strait and the Luzon Strait. (3) The maximum amplitude of semi-diurnal tides exists at the area between the Meizhou Bay and Xinghua Bay, and that of diurnal tides appears in the region to the east of the Leizhou Peninsula, (4) The patterns of co-tidal and co-range charts of N2, K2 and P1, Q1 tidal constituents are similar to those of M2, S2 and K1 O1 tidat constituents, respectively展开更多
基金National Natural Science Foundation of China(No.2275150)。
文摘To investigate the process optimizationof Cu-en/AP composite microspheres preparation via electrostatic spraying,and to reveal the effects of droplet properties and flow rate variations on the experimental results during the electrostatic spraying process,the prepared process parameters of Cu-en/AP composite microspheres by electrostatic spray method under the orthogonal experimental design simulated by ANSYS(Fluent).The influence of flow rate,solvent ratio,and solid mass on the experimental results is examined using a controlled variable method.The results indicate that under the conditions of a flow rate of 2.67×10^(-3)kg/s an acetone-to-deionized water ratio of 1.5∶1.0,and a solid mass of 200 mg,the theoretical particle size of the composite microspheres can reach e nanoscale.Droplet trajectories in the electric field remain stable without significant deviation.The simulation results show that particle diameter decreases with increasing flow rate,with the trend leveling off around a flow rate of 1×10^(-3)kg/s.As the solvent ratio increases(with higher acetone content),particle diameter initially decreases,reaching a minimum around a ratio of 1.5∶1.0 before gradually increasing.Increasing the solid mass also reduces the particle diameter,with a linear increase in diameter observed at around 220 mg.Cu-en/AP composite microspheres with nanoscale dimensions were confirmed under these conditions by the final SEM images.
基金Project(41941018)supported by the National Natural Science Foundation of China for the Special Project FundingProject(22-JKCF-08)supported by the Study on in-situ Stress Database and 3D in-situ Stress Inversion Technology of Highway Tunnel in Shanxi Province,China+1 种基金Project(2022-JKKJ-6)supported by the Study on Disaster Mechanism and NPR Anchor Cable Prevention and Control of Coal Mining Caving Subsidence in Operating Tunnel in Mountainous Area,ChinaProject(BBJ2024032)supported by the Fundamental Research Funds for the Central Universities(PhD Top Innovative Talents Fund of CUMTB),China。
文摘A study was conducted to analyze the deformation mechanism of strongly weathered quartz schist in the Daliangshan Tunnel,located in the western Transverse Mountain area.A large deformation problem was experienced during the tunnel construction.To mitigate this problem,a support system was designed incorporating negative Poisson ratio(NPR)anchor cables with negative Poisson ratio effect.Physical model experiments,field experiments,and numerical simulation experiments were conducted to investigate the compensation mechanical behavior of NPR anchor cables.The large deformations of soft rocks in the Daliangshan Tunnel are caused by a high ground stress,a high degree of joint fracture development,and a high degree of surrounding rock fragmentation.A compensation mechanics support system combining long and short NPR anchor cables was suggested to provide sufficient counter-support force(approximately 350 kN)for the surrounding rock inside the tunnel.Comparing the NPR anchor cable support system with the original support system used in the Daliangshan tunnel showed that an NPR anchor cable support system,combining cables of 6.3 m and 10.3 m in length,effectively prevented convergence of surrounding rock deformation,and the integrated settlement convergence value remained below 300 mm.This study provides an effective scientific basis for resolving large deformation problems in deeply buried soft rocks in western transverse mountain areas.
基金funded by the National Basic Research Program of China(973 Program)(No.2013CB733203)the National Natural Science Foundation of China(No.41474055)
文摘The dynamic monitoring of landslides in engineering geology has focused on the correlation among landslide stability,rainwater infiltration,and subsurface hydrogeology.However,the understanding of this complicated correlation is still poor and inadequate.Thus,in this study,we investigated a typical landslide in southwestern China via time-lapse electrical resistivity tomography(TLERT) in November 2013 and August 2014.We studied landslide mechanisms based on the spatiotemporal characteristics of surface water infiltration and flow within the landslide body.Combined with borehole data,inverted resistivity models accurately defined the interface between Quaternary sediments and bedrock.Preferential flow pathways attributed to fracture zones and fissures were also delineated.In addition,we found that surface water permeates through these pathways into the slipping mass and drains away as fissure water in the fractured bedrock,probably causing the weakly weathered layer to gradually soften and erode,eventually leading to a landslide.Clearly,TLERT dynamic monitoring can provide precursory information of critical sliding and can be used in landslide stability analysis and prediction.
基金supported by the National Science Fund for Distinguished Young Scholars of China (Grant No. 40725012)the National Hi-tech Research and Development Program of China(863 Program) (Grant No. 2006AA06Z240)the National Basic Research Program of China (973 program)(Grant No. 2007CB209505).
文摘To simultaneously take into account the Biot-flow mechanism, the squirt-flow mechanism, and the frame-viscoelasticity mechanism, a generalized viscoelastic BISQ (Biot/squirt) model is developed for wave propagation in clay-bearing sandstones based on Dvorkin's elastic BISQ model. The present model is extended to a wide range of permeabilities (k 〉 0.05 mD) by introducing a dimensionless correction factor for viscoelastic parameters, defined as a function of the permeability and the clay content. We describe the frame's stress-strain relationship of the clay-bearing sandstones by the differential constitutive equations of generalized viscoelasticity and then derive the viscoelastic-wave dynamic equations. With the assumption of a plane-wave solution, we finally yield the phase velocities and the attenuation coefficients by solving the dynamic wave equations in the frequency and wave number domain. The comparison of numerical results and experimental data shows that the generalized viscoelastic BISQ model is applicable for modeling the wave propagation in most of the sandstones mainly bearing kaolinite clay.
基金supported by National Natural Science Foundation of China (Grant No. 40674072)National Hi-techResearch and Development Program of China (863 Program) (Grant No. 2006AA09A102-08)+1 种基金National Basic ResearchProgram of China (the 973 Program. Grant No. 007CB209603) the Opening fund of State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences (GPMR200633)
文摘Based on a detailed analysis of differences between seismic data and well logs, we discuss the problem of matching seismic traces and well logs and present a new matching method based on event search in instantaneous phase which greatly improves seismic resolution. The method is based on flattening events in instantaneous phase to compare the seismic traces to the well log traces with the same phase. We calculate the coefficients using the singular value decomposition method to extrapolate the well logs. As a result, the events in the seismic profile are continuous and match well with well logs. We apply this method to the Mao-2 well in Daqing Oilfield with good results.
文摘Unlike previous theories with velocity and/or elastic modulus averaging, we use a three-phase porous rock physics model developed by Santos for analyzing the seismic response of two immiscible fluids in saturated porous media. Considering reservoir reference pressure and coupling drag of two fluids in pores, the effects of frequency, porosity, and gas saturation on the phase velocities of the P-and S-waves are discussed in detail under field conditions. The effects of porosity and gas saturation on Vp/Vs are also provided. The data for our numerical experiments are from a sample of deep volcanic rock from Daqing. The numerical results show that the frequency dispersion effect can be ignored for deep volcanic rocks with low porosity and low permeability. It is concluded that for deep volcanic rocks the effect of gas content in pores on Vp/Vs is negligible but the effect of porosity is significant when there is a certain amount of water contained in the pores. The accurate estimate of lithology and porosity in this case is relatively more important.
基金supported by National High-Tech Research and Development Program of China (Grant No. 2006AA06Z202)Open Fund of the Key Laboratory of Geophysical Exploration of CNPC (Grant No. GPKL0802)+2 种基金CNPC Young Innovation Fund (Grant No. 05E7028) graduate student Innovation Fund of China University of Petroleum(East China) (Grant No. S2008-1)the Program for New Century Excellent Talents in University (Grant No. NCET-07-0845).
文摘Based on Kuo and Dai's vectorial wave-field extrapolation equations, we derive new Kirchhoff migration equations by introducing unit vectors which represent the ray directions at the imaging points of the reflected P- and PS converted-waves. Furthermore, using the slope of the events on shot records and a ray racing procedure, mirror-image reflection points are found and the reflection data are smeared along the Fresnel zone. The migration method proposed in this paper solves two troublesome imaging problems caused by limited receiving aperture and migration artifacts resulting from wave propagation at the velocities of non original wave type. The migration method is applied successfully with model data, demonstrating that the new method is effective and correct.
基金supported by the National Natural Science Foundation of China(21333003,21577034)National Basic Research Program of China(2013CB933200)+1 种基金National High Technology Research and Development Program of China(2015AA034603)the Fundamental Research Funds for the Central Universities(WJ1514020)~~
文摘The catalytic wet air oxidation of aniline over Ru catalysts supported on modified Ti 2 (Ti 2, Ti0.9Ce0.1O2, Ti0.9Zr0.1O2) is investigated. A series of characterization techniques are conducted to determine the relationship between the physico-chemical properties and the catalytic performance. As a result of the good metal dispersion and large number of surface oxygen species, the Ru/Ti0.9 Zr0.1O2 catalyst presents the best catalytic activity among the tested samples. The effects of the operating conditions on the reaction are investigated and the optimal reaction conditions are determined. Based on the relationship between the by-products concentration and the reaction time, the reaction path for the catalytic oxidation of aniline is established. Carbonaceous deposits on the surface of the support are known to be the main reason for catalyst deactivation. The catalysts maintain a constant activity even after three consecutive cycles.
基金National Gas Hydrates Integral Appraisal Project (GZH200200203-05).
文摘Based on the sensitivity of geophysical response to gas hydrates contained in sediments, we studied the prediction of gas hydrates with seismic techniques, including seismic attributes analysis, AVO, inverted velocity field construction for dipping formations, and pseudo-well constrained impedance inversion. We used an optimal integration of geophysical techniques results in a set of reliable and effective workflows to predict gas hydrates. The results show that the integrated analysis of the combination of reflectivity amplitude, instantaneous phase, interval velocity, relative impedance, absolute impedance, and AVO intercept is a valid combination of techniques for identifying the BSR (Bottom Simulated Reflector) from the lower boundary of the gas hydrates. Integration of seismic sections, relative and absolute impedance sections, and interval velocity sections can improve the validity of gas hydrates determination. The combination of instantaneous frequency, energy half attenuation time, interval velocity, AVO intercept, AVO product, and AVO fluid factor accurately locates the escaped gas beneath the BSR. With these conclusions, the combined techniques have been used to successfully predict the gas hydrates in the Dongsha Sea area.
基金National 973 Key Basic Research Development Program (No.2005CB422104)SINOPEC's Scientific and Technological Development Program (No.P05063)
文摘Based on the empirical Gardner equation describing the relationship between density and compressional wave velocity, the converted wave reflection coefficient extrema attributes for AVO analysis are proposed and the relations between the extrema position and amplitude, average velocity ratio across the interface, and shear wave reflection coefficient are derived. The extrema position is a monotonically decreasing function of average velocity ratio, and the extrema amplitude is a function of average velocity ratio and shear wave reflection coefficient. For theoretical models, the average velocity ratio and shear wave reflection coefficient are inverted from the extrema position and amplitude obtained from fitting a power function to converted wave AVO curves. Shear wave reflection coefficient sections have clearer physical meaning than conventional converted wave stacked sections and establish the theoretical foundation for geological structural interpretation and event correlation. "The method of inverting average velocity ratio and shear wave reflection coefficient from the extrema position and amplitude obtained from fitting a power function is applied to real CCP gathers. The inverted average velocity ratios are consistent with those computed from compressional and shear wave well logs.
基金Supported by the Program to Sponsor Teams for Innovation in the Construction of Talent Highlands in Guangxi Institutions of Higher Learning (Grant No. 200508)Sponsored by the Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry (Grant No. 200889016).
文摘We present a forward-modeling investigation of time-dependent ground magnetometric resistivity (MMR) anomalies associated with transient leachate transport in groundwater systems. Numerical geo-electrical models are constructed based on the hydrological simulation results of leachate plumes from a highly conceptualized landfill system and the resultant MMR responses are computed using a modified finite difference software MMR2DFD. Three transmitter configurations (i.e., single source, MMR-TE, and MMR-TM modes) and two hydrological models (i.e., uniform and faulted porous media) are considered. Our forward modeling results for the uniform porous medium indicates that the magnetic field components perpendicular to the dominant current flow contain the most information of the underground targets and the MMR-TE mode is an appropriate configuration for detecting contaminant plumes. The modeling experiments for the faulted porous medium also confirm that the MMR method is capable of mapping and monitoring the extent of contaminant plumes in aroundwater systems.
文摘Coral sand is a unique material developed in the tropical ocean environment, which is mainly composed of coral and other marine organism debris, with the CaCO3 content up to 96 %. It has special physical and mechanical properties due to its composition, structure and sedimentary environment. In this contribution, we discuss its specific gravity, porosity ratio compressibility, crushing, shearing and intensity for coral sand samples from the Nansha islands based on laboratory mechanical tests. Our results show distinct high porosity ratio, high friction angle and low intensity as compared with the quartz sand. We believe that grain crushing is the main factor that influences the deformation and strength of coral sand. Comprehensive study on the physical and mechanical properties of coral sands is significant in providing reliable scientific parameters to construction on coral islet, and thus avoids accidents in construction.
文摘Aim To investigate novel bioactive and structural metabolites from marineorganisms. Methods Column chromatography in association with semi-preparative HPLC were used for theisolation of compounds. 1D and 2D NMR, IR, UV, and MS were employed for structure elucidation.Results From the butanol fraction of the 95% EtOH extract of the starfish Asterias rollestoni, a newcompound N^7 -2'-deoxypseudoxanthosine (1), along with sixteen known compounds, 2'-0-methyl-inosine(2), 2'-deoxyinosine (3), 2'-0-methylguanosine (4), inosine (5); thymine (6), uracil (7), thymidine(8), deoxyuridine (9), 2'-0-methyluridine (10), ( ― )-(1S, 3S)-1-methyl-1, 2, 3,4-terrahydro-β-carboline-3-carboxyl-ic acid (11), ( ― )-(1R, 3S)-1-methyl-1, 2, 3,4-tetrahydro-β-carboline-3-carboxylic acid (12) , ( ― )-(3S)- 1, 2, 3,4-tetrahydro-β-carboline-3-carboxylic acid (13), L-tryptophan (14), L-phenylalanine (15), 3-carboxyindole (16), and p-hydroxybenzoic acid (17) , have been isolated. Conclusion Compound 1 is a newnatural product, and compounds 8, 9 and 10 are isolated from natural sources for the first time, andthe known compounds except 14 and 15 are first reported from starfish Asterias rollestoni.
文摘A structure relaxation model based on the empirical electron theory of solids and molecules is developed to compute the diffusion active energies of C, N in γFe. First, adding a restriction, the lattice maintains rigidity when solute atom migrates to the saddle point. In this step, the hybridization classes of every atom do not change. Then, the restriction is loosed and the atoms are relaxed under the coulomb repulsive forces. It is supposed that the energy needed in the first step would be compensated partly by the second step. In this way, the diffusion active energies of C, N in γFe are computed. Compared with the experiment data, the relative errors are less than 5%, which are good results in the computation of activation energy of diffusion.
基金Project (2005CB623701) supported by the National Basic Research Program of China
文摘Aluminum tri-polyphosphate was synthesized from bauxite tailings and phosphoric acid with a P/A1 molar ratio of 3. This is highly advantageous from a waste recycling perspective as bauxite railings are generally regarded as unusable waste. The acidity, whiteness and mean particle size of prepared aluminum tri-polyphosphate are all improved after modification. The possibility of using modified aluminum tri-polyphosphate as an anticorrosive pigment was also investigated by electrochemical impedance spectroscopy. The resistance of the coatings with modified aluminum tri-polyphosphate is 7×10^7Ω for 40 d of immersion, which is superior or at least comparable to that of coatings containing APW-2, which exhibits a resistance of 5.7×10^7Ω.
基金Projects(51002019,91016024,51102031)supported by the National Natural Science Foundation of China
文摘The NiCoCrAl alloy sheet was fabricated by electron beam physical vapor deposition technique and the effects of the heat treatment on the microstructure and tensile strength of the NiCoCrAl alloy sheet were investigated. The heat treatment at 1050 °C is favorable to improve the interface bonding between the columnar structures due to the disappearance of the intergranular gaps. Comparing with the thin NiCoCrAl alloy sheet before heat treatment, the Ni3Al phase appears in the NiCoCrAl alloy sheet after heat treatment, which is favorable to improve the interface bonding between the columnar structures. The increase in the tensile strength and elongation is attributed to the improvement of the interface bonding between the columnar structures. The residual stress in the NiCoCrAl alloy sheet after heat treatment is reduced significantly, which also confirms that the interface bonding is improved by the heat treatment.
基金supported by the National Natural Science Foundation of China under contract Nos. 40576015, 40810069004 and 40821063by the key research project of Fujian Province under contract No. 2004N203by the Fujian demonstrating region of the "863" Project of the Ministry of Science and Technology of China
文摘Diurnal and semi-diurnal tides in the Taiwan Strait and its adjacent areas are calculated by using a two-dimensional finite-difference model. Compared with data of more than 20 observation stations around the Taiwan Strait, the model-produced results agree quite well with those of previous researches using observational data from coastal tidal gauge stations. According to the results, the co-tidal and co-range charts are given. Furthermore, the characteristics of 8 major tidal constituents have been uminated respectively. The result shows that: (1) The tide motion can be attributed to the interaction between the degenerative rotary tidal system in the north and the progressive tidal system in the south. (2) The southward and northward tidal waves of semi-diurnal tide converge in the middle of the Taiwan Strait while the diurnal tidal waves propagate southwestward through the Taiwan Strait and the Luzon Strait. (3) The maximum amplitude of semi-diurnal tides exists at the area between the Meizhou Bay and Xinghua Bay, and that of diurnal tides appears in the region to the east of the Leizhou Peninsula, (4) The patterns of co-tidal and co-range charts of N2, K2 and P1, Q1 tidal constituents are similar to those of M2, S2 and K1 O1 tidat constituents, respectively