浅议“肝体阴而用阳”

"肝体阴而用阳"出自清代叶天士的《临证指南医案》,"体阴"与"用阳"概括了肝主疏泄,喜条达而恶抑郁,主动、主升以及肝位于膈下,属阴脏,贮藏血液,调节血量等生理特点,"体阴"与"用阳"相互为用。

Cation effects in electrocatalytic reduction reactions:Recent advances

Electrocatalytic reduction reactions,powered by clean energy sources such as solar energy and wind,offer a sustainable method for converting inexpensive feedstocks(e.g.,CO_(2),N2/NOx,organics,and O_(2))into high-value-added chemicals or fuels.The design and modification of electrocatalysts have been widely implemented to improve their performance in these reactions.However,bottle-necks are encountered,making it challenging to further improve performance through catalyst development alone.Recently,cations in the electrolyte have emerged as critical factors for tuning both the activity and product selectivity of reduction reactions.This review summarizes recent advances in understanding the role of cation effects in electrocatalytic reduction reactions.First,we introduce the mechanisms underlying cation effects.We then provide a comprehensive overview of their application in electroreduction reactions.Characterization techniques and theoretical calcula-tion methods for studying cation effects are also discussed.Finally,we address remaining challeng-es and future perspectives in this field.We hope that this review offers fundamental insights and design guidance for utilizing cation effects,thereby advancing their development.

False Positives Caused by Single Primer in DDRT Analysis of Soybean

[Objective] The aim was to explore the reasons of false positives in Different Display Reverse Transcription（DDRT）analysis.[Method] Soybean varieties ＂Jilin 30＂ and ＂Tongnong 13＂ were used as materials to carry out analysis on false positives in DDRT analysis.[Result] An important origin of false positives appeared in DDRT analysis was the non-specific amplification caused by the combination of single primer and cDNA.The parallel PCR test of single primer should be set so as to verify whether the obtained fragments were the false positives or the PCR productions combined with single primer.[Conclusion] This study had provided basis for improving the success rate of DDRT experiment.

Effect of impurities in recycling water on Pb-Ag anode passivation in zinc electrowinning process

Effect of impurities in recycling water on Pb-Ag anode passivation in zinc electrowinning process was investigated by linear scan voltammetry.Results show that passivation process would be affected in the presence of Cl^-and F-in recycling water.It was highly advantageous to take H2SO4 concentration as 180g/L,Mn^2＋ concentration as 3-5 g/L and F-less than 42mg/L.However,passivation process would not be affected when Cl^-concentration was less than 13mg/L without any other ions,or when mass ratio of Mn^2＋ to Cl^-existing in electrolyte was 8,where Cl^-concentration could reach up to 625mg/L.

POWER GENERATION POTENTIAL OF BIPV APPLICATION IN CHINA

This paper discusses the potential and prospect of building-integrated photovoltaics (BIPV) for solar electrical power generation in China.The BIPV technology has been identified as the most economical renewable energy resource to contribute to world electrical energy demand for protecting environment from reduced fossil fuel consumption.The available solar energy resource of 14 cities and the potential power generation from PV claddings in buildings in China were estimated.The economical analysis of BIPV application is discussed.It is found that the potential is significant and the government should play an important role in its development.

Effect of Potassium Oleate on Rheological Behavior of Cationic Guar in Aqueous Solution with Varying Temperatures

The rheology of the cationic guar （CG） solution was measured and the effects of potassium oleate （KOA） upon the rheological properties of CG solution were studied. The steady shear viscosity measurement has shown that the viscosity of CG solution increased dramatically in the presence of KOA. The viscosity enhancement of KOA upon CG solution can be approximate three orders in magnitude. The gel-like formation of CG solution is observed at the high concentration of KOA. The excess addition of KOA results in the phase separation of CG solution. The oscillatory rheological measurement has shown that the crossover modulus Gc （corresponding to either storage modulus G＇ or loss modulus G＇＇ at the frequency wc where G＇ equals G＇＇） for CG solution, decreases with the increasing the concentration of KOA in solution. On the other hand, the apparent relaxation time 7-app （=1/wc） increases with increasing the concentration of KOA in solution. Our experimental results suggest that for surfaetant such as KOA which has a stronger tendency to form micelles in solution, the cooperative hydrophobic interaction of polymer bound to surfactants is less necessary to the formation of aggregates in solution, especially at the high concentration of surfactants. In fact, with the increase of the concentration of KOA, the number of the aggregates which associate polymer together decreases whereas the intensity of these aggregates increases. The effect of temperature upon the aggregation is also significant. With the increase of temperature, the number of the aggregates increases whereas the intensity of these aggregates decreases, probably because the ionization of KOA increases at high temperature.

Theoretical and Practical Progress of New Heliostat by Chen et al.

Recently, Chen and his team were active in the theoretical and practical study of a new heliostat for the use of solar energy. This work represents the first innovation in the area of heliostats after many years of little progress. The mathematical development of the tracking and concentration optics principles, and the practical implementation and demonstration of the technology, are both very interesting advances in this field. Many applications are possible for this technology such as generation of solar electricity and solar industrial process heat.

Adsorption of Metsulfuron and Bensulfuron on a Cationic Surfactant-Modified Paddy Soil

Adsorption isotherms of metsulfuron and bensulfuron on a hexadecyltrimethylammonium （HDTMA） bromide-modified paddy soil under different ionic strengths, with divalent cation Cu^2＋, or having different pH were studied to describe their adsorptive behavior, and to try to explain the adsorption process of a sulfonylurea compound with a carbamoylsulfamoyl group in the modified soil environment. All the adsorption isotherms fitted the Freundlich equation well, and the HDTMA treatment of paddy soil dramatically enhanced adsorption capacity of metsulfuron or bensulfuron. Also, an increase of ionic strength and the addition of divalent heavy metal cation Cu^2＋ on the HDTMA-modified paddy soil increased the adsorption of metsulfuron or bensulfuron. Additionally, for metsulfuron and bensulfuron in the aqueous phase, adsorption capacity of the HDTMA-modified paddy soft gradually increased with decreasing pH.

Micromorphology of landslide soil Case study on the Jibazi landslide in Yunyang in the Three Gorges Region, China

Abstract： Landslide is one of natural catastrophes affecting national economy and people＇s livelihood. There are many reports on the forming mechanism and control of landslide, but the studies on micromorphology of landslide soil are few. There are many potential landslides in the Three Gorges Region in China. In this paper, the micromorphologic features of the Jibazi landslide soil in Yunyang in the Three Gorges Region of the Yangtze River were studied using routine methods, that is, soil micromorphology, X-ray diffraetometer and scanning electron microscope. The main conclusions are as follow： （1） The basic micromorphologic characteristics of the landslide soil are that the fine soil particles are commonly cohesive matrix, finer and lower content of skeleton grains, the microstructures are mainly types of phenocrystal gelatinization, densely chap and fissure structure. As a result, these micromorphologic features affect the discharging of soil water, favor the movement of landslide body and provide an internal basis of materials for the formation of landslide. （2） The concept on the forming material of landslide was proposed, and types of optical beamed clay aggregates, Fe-Mn isolates and glassy material were found in landslide-belt soil, which were remarkably different from the natural soil formation, and had some scientific significance in analyzing the forming mechanism of landslide and distinguishing me landslide-belt soil. （3） Some special micromorphologic and sub-micromorphologic characteristics, such as fingerprint microstructure, clay beamed bedding microstructure, oppressive microstructure, moulage microstructure and extending hole microstncture, could bring useful micromorphologic evidences for the observation and forecasting of landslide. The results mentioned above will bring helpful micromorphologic evidences for distinguishing slide soil, analyzing the formation mechanism of landslide, and monitoring and forecasting the occurrence of landslide.

Latest progress in hydrogen production from solar water splitting via photocatalysis,photoelectrochemical,and photovoltaic-photoelectrochemical solutions

Hydrogen production via solar water splitting is regarded as one of the most promising ways to utilize solar energy and has attracted more and more attention. Great progress has been made on photocatalytic water splitting for hydrogen production in the past few years. This review summarizesthe very recent progress (mainly in the last 2–3 years) on three major types of solar hydrogenproduction systems: particulate photocatalysis (PC) systems, photoelectrochemical (PEC) systems,and photovoltaic‐photoelectrochemical (PV‐PEC) hybrid systems. The solar‐to‐hydrogen (STH)conversion efficiency of PC systems has recently exceeded 1.0% using a SrTiO3:La,Rh/Au/BiVO4:Mophotocatalyst, 2.5% for PEC water splitting on a tantalum nitride photoanode, and reached 22.4%for PV‐PEC water splitting using a multi‐junction GaInP/GaAs/Ge cell and Ni electrode hybrid system.The advantages and disadvantages of these systems for hydrogen production via solar watersplitting, especially for their potential demonstration and application in the future, are briefly describedand discussed. Finally, the challenges and opportunities for solar water splitting solutions are also forecasted.

Energy efficiency performance of multi-energy district heating and hot water supply system

A district heating and hot water supply system is presented which synthetically utilizes geothermal energy,solar thermal energy and natural gas thermal energy.The multi-energy utilization system has been set at the new campus of Tianjin Polytechnic University(TPU),A couple of deep geothermal wells which are 2 300 m in depth were dug,Deep geothermal energy cascade utilization is achieved by two stages of plate heat exchangers(PHE) and two stages of water source heat pumps(WSHP).Shallow geothermal energy is used in assistant heating by two ground coupled heat pumps(GCHPs) with 580 vertical ground wells which are 120 m in depth.Solar thermal energy collected by vacuum tube arrays(VTAs) and geothermal energy are complementarily utilized to make domestic hot water.Superfluous solar energy can be stored in shallow soil for the GCHP utilization.The system can use fossil fuel thermal energy by two natural gas boilers(NGB) to assist in heating and making hot water.The heating energy efficiency was measured in the winter of 2010-2011.The coefficients of performance(COP) under different heating conditions are discussed.The performance of hot water production is tested in a local typical winter day and the solar thermal energy utilization factor is presented.The rusults show that the average system COP is 5.75 or 4.96 under different working conditions,and the typical solar energy utilization factor is 0.324.

Study on synthesis and flocculation property of cation-polyacrylamide

On the basis of flocculating settling experimentation on flotation waste coal in Wangfenggang coal preparation plant,influence of medical dosage and cationization (CD) of CPAM samples on coal slurry's flocculating effect was studied,difference of flocculating effect on coal slurry among different categories of polyacrylamide was discussed.Experi- mental results show that when the dosage of flocculant reaches 2-4 g/m^3 flotation waste, and the CD of CPAM is 5%,flocculating effect is the best,light transmittance of super- natant liquor reaches 93%.Taking 3types of sample CPAM,PAM and PHP,which formula weight vary a little,to deal with the same concn of coal slurry,when medicine dosage is 3 g/m^3,flocculating effect of CPAM is the best,light transmittance of supernatant liquor reaches 92%.

Hybrid intelligent PID control design for PEMFC anode system

Control design is important for proton exchange membrane fuel cell (PEMFC) generator. This work researched the anode system of a 60-kW PEMFC generator. Both anode pressure and humidity must be maintained at ideal levels during steady operation. In view of characteristics and requirements of the system, a hybrid intelligent PID controller is designed specifically based on dynamic simulation. A single neuron PI controller is used for anode humidity by adjusting the water injection to the hydrogen cell. Another incremental PID controller, based on the diagonal recurrent neural network (DRNN) dynamic identification, is used to control anode pressure to be more stable and exact by adjusting the hydrogen flow rate. This control strategy can avoid the coupling problem of the PEMFC and achieve a more adaptive ability. Simulation results showed that the control strategy can maintain both anode humidity and pressure at ideal levels regardless of variable load, nonlinear dynamic and coupling characteristics of the system. This work will give some guides for further control design and applications of the total PEMFC generator.

Single‐atom catalysts on metal‐based supports for solar photoreduction catalysis

Metal atoms atomically dispersed on an inorganic metal‐based support compose a unique category of single atom catalysts(SACs)and have important applications in catalytic photoreduction reactions,including H_(2) evolution reaction,CO_(2) reduction reaction,and N_(2) reduction reaction.In this minreview,we summarized the typical metal‐support interaction(M‐SI)patterns for successful anchoring of single‐atom metals on metallic compound supports.Subsequently,the contribution of the dispersed single metal atoms and M‐SI to photocatalytic reactions with improved activity,selectivity,and stability are highlighted,such as by accelerating charge transfer,regulating band structure of the support,acting as the reductive sites,and/or increasing catalytic selectivity.Finally,some challenges and perspectives of future development are proposed.We anticipate that this minireview will be a beneficial supplement for a comprehensive perception of metal‐based material supported SACs and their application in heterogeneous photo‐reductive catalysis.

Role of transition-metal electrocatalysts for oxygen evolution with Si-based photoanodes

A comprehensive understanding of the role of the electrocatalyst in photoelectrochemical(PEC)water splitting is central to improving its performance.Herein,taking the Si-based photoanodes(n^(+)p-Si/SiO_(x)/Fe/FeOx/MOOH,M=Fe,Co,Ni)as a model system,we investigate the effect of the transition-metal electrocatalysts on the oxygen evolution reaction(OER).Among the photoanodes with the three different electrocatalysts,the best OER activity,with a low-onset potential of∼1.01 VRHE,a high photocurrent density of 24.10 mA cm^(-2)at 1.23 VRHE,and a remarkable saturation photocurrent density of 38.82 mA cm^(-2),was obtained with the NiOOH overlayer under AM 1.5G simulated sunlight(100 mW cm^(-2))in 1 M KOH electrolyte.The optimal interfacial engineering for electrocatalysts plays a key role for achieving high performance because it promotes interfacial charge transport,provides a larger number of surface active sites,and results in higher OER activity,compared to other electrocatalysts.This study provides insights into how electrocatalysts function in water-splitting devices to guide future studies of solar energy conversion.

Utilizing Solar Thermal Energy for Post-Combustion C02 Capture

Post-combustion amine absorption and stripping can remove 90% of the CO2 from power plant flue gas, but systems can reduce electrical output by approximately 30% due to energy requirements for stripping CO2 from solvent and CO2 compression. The CO2 capture energy penalty can be reduced while developing renewable energy technologies by meeting CO2 capture energy requirements with a solar thermal energy system, particularly when electricity demand and prices are the highest. This study presents an initial review of solar thermal technologies for supplying CO2 capture energy, with a focus on high temperature systems. Parabolic troughs and central receivers are technically able to provide energy for CO2 capture. However, the solar system＇s capital costs would be roughly half that of the base coal-fired plant with CO2 capture, and high electricity prices are required to offset the costs of operating the solar thermal system. For high temperature solar thermal systems, direct electricity generation is likely a more efficient way to use solar energy to replace output lost to CO2 capture energy. However, low temperature solar thermal systems might integrate better with solvent stripping equipment, and more rigorous analysis is required to definitively assess the feasibility of using solar energy for CO2 capture.

A Review of Applied Methods of Using Solar Energy in Iranian Buildings

Solar energy is the radiant light and heat from the Sun that has been harnessed by human since ancient times. Also secondary solar resources such as wind and wave power, hydroelectric power and biomass account for most of the available renewable energy on Earth, which can be used by human. Architects since alacient times have used various methods to hamesse and employ the solar energy for lighting, cooling and heating and etc. Meanwhile, Iran＇s ancient architecture, as an adaptive one, which consists of various climatic reigns, is filled with abounding examples of using sun energy in buildings. But, unfortunately despite these ancient methods, our modern architects mostly tend to provide energy of buildings with fossil fuels. This increases energy costs of the building＇s and also pollutes the environment. In this article it is intended to consider the ancient ways of using solar energy in Iran, and then suggest new methods for applying in modem buildings. The results of consideration show that among Solar technologies, passive and active methods, Iran＇s ancient architects have used passive methods, for example in mass and space, orientation and settlement of building. The idea of passive methods can be used in new shapes in current buildings, for instance by using solar space, central yard and etc. The suggestive method in this paper is combining the passive methods with the active ones.

Functional principle of the synergistic effect of co-loaded Co-Pi and FeOOH on Fe2O3 photoanodes for photoelectrochemical water oxidation

The establishment of multi-component catalytic systems on Fe2O3 photoanodes presents considerable potential for significantly enhancing the performance of photoelectrochemical water splitting systems. In this study, we hydrothermally synthesized a Fe2O3 photoanode. In addition, d-Fe OOH synthesized via dip-coating and hydrothermally prepared h-FeOOH were used as cocatalysts and their synergistic combinations with cobalt phosphate(Co-Pi) were investigated. The synergy between h-FeOOH and Co-Pi was remarkable, whereas that between d-Fe OOH and Co-Pi was negligible. For example, the onset potentials of the Co-Pi/h-FeOOH and Co-Pi/d-FeOOH dual catalysts, were cathodically shifted by 270 and 170 m V, respectively. Moreover, the photocurrent density of the Co-Pi/h-FeOOH/Fe2O3 anode was significantly higher than that of the Co-Pi/d-FeOOH/Fe2O3 one. The synergistic effect of Co-Pi and h-FeOOH could be attributed to the significantly inhibited recombination of surface charges owing to the formation of a p-n junction between β-FeOOH and Fe2O3 and the large contact area between the granular h-FeOOH and Co-Pi. However, the thin amorphous FeOOH layer of the Co-Pi/d-FeOOH/Fe2O3 anode acted as a hole-transfer medium, and weakly promoted the kinetics of the charge transfer process.

Intensified solar thermochemical CO_(2) splitting over iron-based redox materials via perovskite-mediated dealloying-exsolution cycles

Solar thermochemical CO_(2)-splitting(STCS)is a promising solution for solar energy harvesting and storage.However,practical solar fuel production by utilizing earth-abundant iron/iron oxides remains a great challenge because of the formation of passivation layers,resulting in slow reaction kinetics and limited CO_(2)conversion.Here,we report a novel material consisting of an iron-nickel alloy embedded in a perovskite substrate for intensified CO production via a two-step STCS process.The novel material achieved an unprecedented CO production rate of 381 mL g^(-1)min^(-1)with 99%CO_(2)conversion at 850℃,outperforming state-of-the-art materials.In situ structural analyses and density functional theory calculations show that the alloy/substrate interface is the main active site for CO_(2)splitting.Preferential oxidation of the FeNi alloy at the interface(as opposed to forming an FeO_(x)passivation shell encapsulating bare metallic iron)and rapid stabilization of the iron oxide species by the robust perovskite matrix significantly promoted the conversion of CO_(2)to CO.Facile regeneration of the alloy/perovskite interfaces was realized by isothermal methane reduction with simultaneous production of syngas(H_(2)/CO=2,syngas yield>96%).Overall,the novel perovskite-mediated dealloying-exsolution redox system facilitates highly efficient solar fuel production,with a theoretical solar-to-fuel efficiency of up to 58%,in the absence of any heat integration.

Analysis on the Application of Electrical New Technology of in Electromechanical Integration

The electrical new technology is a new frontier science.This kind of technology, with the development and progress of society, makes the continuous development and innovation.It is the future development trend of electrical engineering system,which plays a very important role in technological innovation.The principle and theoretical support for the development of electrical new technology includes Bio- electro magnetics, plasma physics, electromagnetic fluid mechanics and gas discharge physics etc.In addition, under the application of permanent magnetic materials and other new materials, the electrical new technology and obtained further development also promote the development and application of electronic power supply, strong magnetic field technology, solar photovoltaic power generation, and superconducting power technology.This paper mainly analyzes the application of electrical new technology in electromechanical integration.