The beginning of the Japanese Upper Paleolithic has mainly been examined using two major models:the Middle Paleolithic evolutionary model within the archipelago and the continental Upper Paleolithic diffusion/migratio...The beginning of the Japanese Upper Paleolithic has mainly been examined using two major models:the Middle Paleolithic evolutionary model within the archipelago and the continental Upper Paleolithic diffusion/migration model.However,recent archeological data from Japan and nearby countries are challenging such simple models.This paper critically reviews previous chronology of the Japanese Paleolithic,including possible Lower and Middle Paleolithic(LP/MP),and attempts to show an alternative model of the beginning of the Japanese Upper Paleolithic.This paper suggests several possible specimens of LP/MP and recommends further geoarchaeological investigation to understand the reliability and cultural relationship between possible LP/MP specimens and the Early Upper Paleolithic(EUP).The start of the Japanese EUP is presently characterized by a flake industry with trapezoids and denticulates around 39-37 kaBP cal on Paleo-Honshu Island,which has partial resemblance with contemporary assemblages in China and the Korean Peninsula,although trapezoids are endemic only to the Japanese EUP and may have derived from the ancestral lithic tradition.Blade technology appeared earliest on Central Paleo-Honshu Island,about 1000 years later than the earliest flake technology.Although blade technology may have originated from the elongated flake technology of the previous period,the sudden simultaneous emergence implies that it diffused from the Korean Peninsula.This paper proposes that blade technology from the Korean Peninsula arrived on the northeastern Paleo-Honshu Island,including the Japan Sea coastal region of western Honshu,rather than the southwest,where flake technology long prospered,due to differences in ecological settings and adaptation strategies between the two regions.展开更多
Similarities play an important role in the reconstruction of human physical,cultural and technological evolution.The two sites presented in this paper,the Middle Palaeolithic site Lingjing in China Layer 10 and 11 and...Similarities play an important role in the reconstruction of human physical,cultural and technological evolution.The two sites presented in this paper,the Middle Palaeolithic site Lingjing in China Layer 10 and 11 and the Lower Palaeolithic site Schöningen 13Ⅱ-4,the socalled Schöningen Spear Horizon in Germany,show striking similarities.The archaeological record of both sites includes lithic artifacts as well as a very large assemblage of fossil bones.The preservation of the material at both sites is excellent and the faunas encountered at both sites show many similarities.The faunal lists of both sites include a diverse carnivore guild,an elephant species,two different rhinoceros species,two different equids,different cervids and large bovids.Both sites also yielded bone retouchers as well as a unique record of bone hammers that show identical,unusual flaking and percussion damage.These similarities are remarkable if one takes into account the difference in age(ca 200 kaBP)and the geographical distance between the two sites of ca 8000 km.Therefore,we do not assume a close cultural link between the hominin populations active at both sites.The authors assume that the observed similarities show more or less identical,opportunistic hominin behaviour at both sites located in a comparable environment with more or less similar taphonomic conditions.展开更多
Here,we consider earlier Upper Paleolithic sites in the Selenga River Basin,the main fluvial input of Lake Baikal that flows through northern Mongolia and the southwestern Transbaikal region of Russia.Lithic industrie...Here,we consider earlier Upper Paleolithic sites in the Selenga River Basin,the main fluvial input of Lake Baikal that flows through northern Mongolia and the southwestern Transbaikal region of Russia.Lithic industries from these sites can be attributed to the laminar Initial Upper Paleolithic(IUP)technocomplex,widespread in southern Siberia and Central Asia.IUP industries appear in the Selenga Basin about 45 kaBP cal.Aspects of regional typological variability and the transport of exotic raw materials over long distances indicate that these populations participated in developed exchange networks and employed high mobility targeting the acquisition of necessary raw materials.Two site types are present:quarry-workshops in northern Mongolia and generalized activity settlements in the southwestern Transbaikal.Although faunal data are limited,we interpret available information as indicating a specialization on hunting,focusing on migrating steppe game species.The distribution of sites in the mid-altitudes and landscapes of the Selenga-Orkhon geographical region and the geomorphological homogeneity of this territory also supported interregional human moves during the IUP.展开更多
Manganese ferrite(MnFe_(2)O_(4))has the advantages of simple preparation,high resistivity,and high crystal symmetry.Herein,we have developed an electrochemical sensor utilizing graphene and MnFe_(2)O_(4) nanocomposite...Manganese ferrite(MnFe_(2)O_(4))has the advantages of simple preparation,high resistivity,and high crystal symmetry.Herein,we have developed an electrochemical sensor utilizing graphene and MnFe_(2)O_(4) nanocomposites modified glassy carbon electrode(GCE),which is very efficient and sensitive to detect bisphenol A(BPA).MnFe_(2)O_(4)/graphene(GR)was synthesized by immobilizing the MnFe_(2)O_(4) microspheres on the graphene nanosheets via a simple one-pot solvothermal method.The morphology and structure of the MnFe_(2)O_(4)/GR nanocomposite have been characterized through scanning electron microscopy(SEM),Fourier transform infrared spectroscopy(FT-IR),X-ray diffraction(XRD)and X-ray photoelectron spectroscopy(XPS).In addition,electrochemical properties of the modified materials are comparably explored by means of cyclic voltammetry(CV),electrochemical impedance spectroscopy(EIS)and differential pulse voltammetry(DPV).Under the optimal conditions,the proposed electrochemical sensor for the detection of BPA has a linear range of 0.8-400μmol/L and a detection limit of 0.0235μmol/L(S/N=3)with high sensitivity,good selectivity and high stability.In addition,the proposed sensor was used to measure the content of BPA in real water samples with a recovery rate of 97.94%-104.56%.At present,the synthesis of MnFe_(2)O_(4)/GR provides more opportunities for the electrochemical detection of BPA in practical applications.展开更多
In the mining industry,precise forecasting of rock fragmentation is critical for optimising blasting processes.In this study,we address the challenge of enhancing rock fragmentation assessment by developing a novel hy...In the mining industry,precise forecasting of rock fragmentation is critical for optimising blasting processes.In this study,we address the challenge of enhancing rock fragmentation assessment by developing a novel hybrid predictive model named GWO-RF.This model combines the grey wolf optimization(GWO)algorithm with the random forest(RF)technique to predict the D_(80)value,a critical parameter in evaluating rock fragmentation quality.The study is conducted using a dataset from Sarcheshmeh Copper Mine,employing six different swarm sizes for the GWO-RF hybrid model construction.The GWO-RF model’s hyperparameters are systematically optimized within established bounds,and its performance is rigorously evaluated using multiple evaluation metrics.The results show that the GWO-RF hybrid model has higher predictive skills,exceeding traditional models in terms of accuracy.Furthermore,the interpretability of the GWO-RF model is enhanced through the utilization of SHapley Additive exPlanations(SHAP)values.The insights gained from this research contribute to optimizing blasting operations and rock fragmentation outcomes in the mining industry.展开更多
Aimed at the poor performance of conventional geophones in exploration for deeper and complex targets, we present the principle and theoretical design of a new geophone based on the optical fiber Bragg grating (FBG)...Aimed at the poor performance of conventional geophones in exploration for deeper and complex targets, we present the principle and theoretical design of a new geophone based on the optical fiber Bragg grating (FBG) sensing technology. The important parameters such as response functions are calculated theoretically. Because of the advantages of FBG sensing technology, the new FBG geophone has a high dynamic range of 94dB at (10-200 Hz). This new generation of geophones will have wide use in seismic prospecting due to its higher sensitivity, lighter weight, and lower cost.展开更多
The experimental results of flue gas desulphurization with caustic lime andhydrated lime activated by water spraying in a desulphurization reactor are presented. The effectsof Ca/S molar ratio, approach to saturation ...The experimental results of flue gas desulphurization with caustic lime andhydrated lime activated by water spraying in a desulphurization reactor are presented. The effectsof Ca/S molar ratio, approach to saturation of flue gas, SO_2 concentration and gas velocity onsulfur retention efficiency and calcium utilization rate are investigated. Desulphurizationcharacteristics of the two sorbents are compared. The mechanism of improving desulphurizationefficiency by water spraying is analyzed. The results show that the activities of two sorbents areimproved obviously by humidification with water spray and the caustic lime has better applicationprospect because of cheaper cost.展开更多
Electrophoretic deposition in conjunction with electrochemical reduction was used to make flexible free-standing graphene-like films. Firstly, graphene oxide (GO) film was deposited on graphite substrate by electrop...Electrophoretic deposition in conjunction with electrochemical reduction was used to make flexible free-standing graphene-like films. Firstly, graphene oxide (GO) film was deposited on graphite substrate by electrophoretic deposition method, and then reduced by subsequent electrochemical reduction of GO to obtain reduced GO (ERGO) film with high electrochemical performance. The morphology, structure and electrochemical performance of the prepared graphene-like film were confirmed by SEM, XRD and FT-IR. These unique materials were found to provide high specific capacitance and good cycling stability. The high specific capacitance of 254 F/g was obtained from cyclic voltammetry measurement at a scan rate of 10 mV/s. When the current density increased to 83.3 A/g, the specific capacitance values still remained 132 F/g. Meanwhile, the high powder density of 39.1 kW/kg was measured at energy density of 11.8 W-h/kg in 1 mol/L H2SO4 solution. Furthermore, at a constant scan rate of 50 mV/s, 97.02% of its capacitance was retained for 1000 cycles. These promising results were attributed to the unique assembly structure of graphene film and low contact resistance, which indicated their potential application to electrochemical capacitors.展开更多
A diamond-like carbon (DLC) film is deposited as an electron injection layer between the polymer light-emitting layer(MEH-PPV) and aluminum (Al) cathode electrode in polymer electroluminescence devices (PLEDs)...A diamond-like carbon (DLC) film is deposited as an electron injection layer between the polymer light-emitting layer(MEH-PPV) and aluminum (Al) cathode electrode in polymer electroluminescence devices (PLEDs) using a radio frequency plasma deposition system. The source material of the DLC is n-butylamine. The devices consist of indium tin oxide (ITO)/MEH-PPV/DLC/Al. Electron injection properties are investigated through I-V characteristics,and the mechanism of electron injection enhancement due to a thin DLC layer has been studied. It is found that: (1) a DLC layer thinner than 1.0nm leads to a higher turn-on voltage and decreased electroluminescent (EL) efficiency; (2) a 5.0nm DLC layer significantly enhances the electron injection and results in the lowest turn-on voltage and the highest EL efficiency; (3) DLC layer that exceeds 5.0nm results in poor device performance;and(4) EL emission can hardly be detected when the layer exceeds 10.0nm. The properties of ITO/MEH-PPV/DLC/Al and ITO/MEH-PPV/LiF/Al are investigated comparatively.展开更多
The grain size and palinology of sediment and the frequency of ^14C dada provide an integrated reconstruction of the Holocene warm-humid phases of the North China Plain. Two clear intense and long-lasting warm-humid p...The grain size and palinology of sediment and the frequency of ^14C dada provide an integrated reconstruction of the Holocene warm-humid phases of the North China Plain. Two clear intense and long-lasting warm-humid phases were identified by comprehensive research in this region. The first phase was dated back to the early Holocene (9 000-7 000 a BP), and the second was centered at 5 000-3 000 a BP. The warm-humid episode between 9 000 and 7 000 a BP was also recognized at other sites showing global climatic trends rather than local events. Compared with the concern to the warm-humid phase of the early Holocene, the second one was not paid enough attention in the last few decades. The compilation of the Holocene paleoclimate data suggests that perhaps the second warm-humid phase was pervasive in monsoon region of China. In perspective of environmental archaeology, much attention should be devoted to it, because the flourish and adaptation of the Neolithic cultures and the building up of the first state seem to corresponding to the general warm-humid climatic conditions of this period. In addition, a warm-humid interval at 7 20045 500 a BP was recognized by the grain size data from three sites. However, this warm-humid event was not shown in pollen assemblage and temporal distribution of ^14C data. Perhaps, the resolution for climatic reconstruction from pollen and temporal distribution of ^14C data cited here is relatively low and small-amplitude and short-period climatic events cannot be well reflected by the data. Due to the difference in locality and elevation of sampling site, as well as in resolution of proxy records, it is difficult to make precise correlation. Further work is needed in the future.展开更多
There are about 19 Neolithic Age sites and 120 Shang-Zhou dynasties sites in the western lakeshore of Chaohu Lake,Anhui Province,China.Based on sites data,topographic data,drainage maps,administrative maps and SPOT5 r...There are about 19 Neolithic Age sites and 120 Shang-Zhou dynasties sites in the western lakeshore of Chaohu Lake,Anhui Province,China.Based on sites data,topographic data,drainage maps,administrative maps and SPOT5 remote sensing data,spatial analysis methods were introduced into the archaeology of Chaohu Lake Basin with Geographic Information System(GIS).The spatial analysis methods include:1) Point Density Analysis with density model to acquire the shift of the sites;2) Distance Analysis to reveal the spatial structure of the sites;3) 3D Analysis based on Digital Elevation Model to get micro-geomorphologic features of the sites;and 4) Buffer Analysis to discover the relationship between the sites and rivers.The results indicate that the archaeological sites spread from the western lakeshore of Chaohu Lake gradually to the northwest,later to the south,and then symmetrically spread.Controlled by productive forces and other factors,ancient people preferred to reside in those places near water,or in plain and fertile land,which resulted in linear and decentralized distribution of the sites,and presented such disciplines as river valley directivity,terrace directivity and soil directivity.This paper indicates that the distribution of archaeological sites was influenced earlier by natural elements and later by human elements in the study period.The research is important for the integration of GIS and archaeology.展开更多
Chaviano's Fables of an Extraterrestrial Grandmother is a pioneering Cuban science fiction novel with four interconnected plots that manifest their separate worlds--the Havana of Ana, the protagonist writer, the Neol...Chaviano's Fables of an Extraterrestrial Grandmother is a pioneering Cuban science fiction novel with four interconnected plots that manifest their separate worlds--the Havana of Ana, the protagonist writer, the Neolithic Celtic world of Merlin and Stonehenge, Faidir, the planet of Ijj e and the winged psyches with three eyes, and Rybel, the world of Ana's character Arlena, the "jumen" on the run in an alien planet after being wrecked in a space ship---through Ana's writing. Ana uses mental exercises and automatic writing to temporarily regress to a pre-rational state of consciousness where these parallel universes interpenetrate and cross in the locus of her subconscious. Writing for her is a form of possession that withdraws her fi'om her immediate reality into a visionary state resembling that of a shaman. She is a writer being invented and written by her own characters. Her stories are not fictions, but already existing realities, and she is a channel by which they are able to manifest their existence through her writing. This science fiction vision of worlds within worlds suggests another origin of science fiction in the ancient literary genre of Menippean satire, a type of fiction that appeals to highly cosmopolitan, alienated readers who seek to renew contact with the sources of consciousness from which technological and social change have alienated them.展开更多
In recent years,flexible pressure sensors have attracted much attention owing to their potential applications in motion detection and wearable electronics.As a result,important innovations have been reported in both c...In recent years,flexible pressure sensors have attracted much attention owing to their potential applications in motion detection and wearable electronics.As a result,important innovations have been reported in both conductive materials and the underlying substrates,which are the two crucial components of a pressure sensor.1D materials like nanowires are being widely used as the conductive materials in flexible pressure sensors,but such sensors usually exhibit low performances mainly due to the lack of strong interfacial interactions between the substrates and 1D materials.In this paper,we report the use of graphene/graphene scrolls hybrid multilayers films as the conductive material and a microstructured polydimethylsiloxane substrate using Epipremnum aureum leaf as the template to fabricate highly sensitive pressure sensors.The 2D structure of graphene allows to strongly anchor the scrolls to ensure the improved adhesion between the highly conductive hybrid films and the patterned substrate.We attribute the increased sensitivity(3.5 k Pa^-1),fast response time(<50 ms),and the good reproducibility during 1000 loading-unloading cycles of the pressure sensor to the synergistic effect between the 1D scrolls and 2D graphene films.Test results demonstrate that these sensors are promising for electronic skins and motion detection applications.展开更多
Chronic radiation proctopathy occurs in 5%-20% of patients following pelvic radiotherapy. Although many cases resolve spontaneously,some lead to chronic symptoms including diarrhea,tenesmus,urgency and persistent rect...Chronic radiation proctopathy occurs in 5%-20% of patients following pelvic radiotherapy. Although many cases resolve spontaneously,some lead to chronic symptoms including diarrhea,tenesmus,urgency and persistent rectal bleeding with iron deficiency anemia requiring blood transfusions. Treatments for chronic radiation proctitis remain unsatisfactory and the basis of evidence for various therapies is generally insuff icient. There are very few controlled or prospective trials,and comparisons between therapies are limited because of different evaluation methods. Medical treatments,including formalin,topical sucralfate,5-amino salicylic acid enemas,and short chain fatty acids have been used with limited success.Surgical management is associated with high morbidity and mortality. Endoscopic therapy using modalities such as the heater probe,neodymium:yttrium-aluminium-garnet laser,potassium titanyl phosphate laser and bipolar electrocoagulation has been reported to be of some benef it,but with frequent complications.Argon plasma coagulation is touted to be the preferred endoscopic therapy due to its eff icacy and safety profile.Newer methods of endoscopic ablation such as radiofrequency ablation and cryotherapy have been recently described which may afford broader areas of treatment per application,with lower rate of complications.This review will focus on endoscopic ablation therapies,including such newer modalities,for chronic radiation proctitis.展开更多
The vaporization ratios of the slurry at various temperature and partial pressure were calculated with the group-contribution method,and then the phase state of the slurry in the residue fluid catalytic cracking(RFCC)...The vaporization ratios of the slurry at various temperature and partial pressure were calculated with the group-contribution method,and then the phase state of the slurry in the residue fluid catalytic cracking(RFCC) disengager was determined.This research could provide some advices on how to select the technological conditions to decrease the coking in the RFCC disengager.The oil gas temperature and the slurry partial pressure had signifi- cant effects on the vaporization ratio of the slurry.Increasing the oil gas temperature and reducing the slurry partial pressure could effectively slow down the coking speed in the RFCC disengager.According to the calculation results, a correlation was established to predict the vaporization ratio of the slurry under different operating conditions.展开更多
Percussive-rotary drilling technology was considered many years ago as one of the best approaches for hard rock drilling. It is a key for popularizing this technology on a large scale to design and make an impactor wi...Percussive-rotary drilling technology was considered many years ago as one of the best approaches for hard rock drilling. It is a key for popularizing this technology on a large scale to design and make an impactor with excellent performance. This paper presents a suit of method to design the percussive parameters for the oil or gas field by introducing the working principle of back-pressurod impactor, dividing the working periods of impaetor into three phases and establishing the computer emuiational model of percussive parameters. It draws a comparison between the results of model calenlation and experiment on the basis of analyzing the experiment results of impactor. The conclude provides credible foundation for designing and further ameliorating the impactor.展开更多
Owing to its photonic band gap(PBG)and slow light effects,aniline black(AB)-poly(vinylidene fluoride)(PVDF)inverse opal(IO)photonic crystal(PC)was constructed to promote the utility of light and realize photothermal s...Owing to its photonic band gap(PBG)and slow light effects,aniline black(AB)-poly(vinylidene fluoride)(PVDF)inverse opal(IO)photonic crystal(PC)was constructed to promote the utility of light and realize photothermal synergetic catalysis.As a highly efficient reaction platform with the capability of restricting heat,a microreactor was introduced to further amplify the photothermal effects of near infrared(NIR)radiation.The photocatalytic efficiency of ZnO/0.5AB-PVDF IO(Z0.5A)increases 1.63-fold compared to that of pure ZnO film under a full solar spectrum,indicating the effectiveness of synergetic promotion by slow light and photothermal effects.Moreover,a 5.85-fold increase is achieved by combining Z0.5A with a microreactor compared to the film in a beaker.The photon localization effect of PVDF IO was further exemplified by finite-difference time-domain(FDTD)calculations.In conclusion,photonic crystal-microreactor enhanced photothermal catalysis has immense potential for alleviating the deteriorating water environment.展开更多
基金JSPS KAKENHI Grant Numbers 18H03596(PI:Yosuke Kaifu)JP19H01336(PI:Hiroyuki Sato)21H00608(PI:Kazuki Morisaki)。
文摘The beginning of the Japanese Upper Paleolithic has mainly been examined using two major models:the Middle Paleolithic evolutionary model within the archipelago and the continental Upper Paleolithic diffusion/migration model.However,recent archeological data from Japan and nearby countries are challenging such simple models.This paper critically reviews previous chronology of the Japanese Paleolithic,including possible Lower and Middle Paleolithic(LP/MP),and attempts to show an alternative model of the beginning of the Japanese Upper Paleolithic.This paper suggests several possible specimens of LP/MP and recommends further geoarchaeological investigation to understand the reliability and cultural relationship between possible LP/MP specimens and the Early Upper Paleolithic(EUP).The start of the Japanese EUP is presently characterized by a flake industry with trapezoids and denticulates around 39-37 kaBP cal on Paleo-Honshu Island,which has partial resemblance with contemporary assemblages in China and the Korean Peninsula,although trapezoids are endemic only to the Japanese EUP and may have derived from the ancestral lithic tradition.Blade technology appeared earliest on Central Paleo-Honshu Island,about 1000 years later than the earliest flake technology.Although blade technology may have originated from the elongated flake technology of the previous period,the sudden simultaneous emergence implies that it diffused from the Korean Peninsula.This paper proposes that blade technology from the Korean Peninsula arrived on the northeastern Paleo-Honshu Island,including the Japan Sea coastal region of western Honshu,rather than the southwest,where flake technology long prospered,due to differences in ecological settings and adaptation strategies between the two regions.
文摘Similarities play an important role in the reconstruction of human physical,cultural and technological evolution.The two sites presented in this paper,the Middle Palaeolithic site Lingjing in China Layer 10 and 11 and the Lower Palaeolithic site Schöningen 13Ⅱ-4,the socalled Schöningen Spear Horizon in Germany,show striking similarities.The archaeological record of both sites includes lithic artifacts as well as a very large assemblage of fossil bones.The preservation of the material at both sites is excellent and the faunas encountered at both sites show many similarities.The faunal lists of both sites include a diverse carnivore guild,an elephant species,two different rhinoceros species,two different equids,different cervids and large bovids.Both sites also yielded bone retouchers as well as a unique record of bone hammers that show identical,unusual flaking and percussion damage.These similarities are remarkable if one takes into account the difference in age(ca 200 kaBP)and the geographical distance between the two sites of ca 8000 km.Therefore,we do not assume a close cultural link between the hominin populations active at both sites.The authors assume that the observed similarities show more or less identical,opportunistic hominin behaviour at both sites located in a comparable environment with more or less similar taphonomic conditions.
文摘Here,we consider earlier Upper Paleolithic sites in the Selenga River Basin,the main fluvial input of Lake Baikal that flows through northern Mongolia and the southwestern Transbaikal region of Russia.Lithic industries from these sites can be attributed to the laminar Initial Upper Paleolithic(IUP)technocomplex,widespread in southern Siberia and Central Asia.IUP industries appear in the Selenga Basin about 45 kaBP cal.Aspects of regional typological variability and the transport of exotic raw materials over long distances indicate that these populations participated in developed exchange networks and employed high mobility targeting the acquisition of necessary raw materials.Two site types are present:quarry-workshops in northern Mongolia and generalized activity settlements in the southwestern Transbaikal.Although faunal data are limited,we interpret available information as indicating a specialization on hunting,focusing on migrating steppe game species.The distribution of sites in the mid-altitudes and landscapes of the Selenga-Orkhon geographical region and the geomorphological homogeneity of this territory also supported interregional human moves during the IUP.
基金Project(2108085ME184)supported by the Natural Science Foundation of Anhui Province,ChinaProject(2022AH010019)supported by the Innovation Team Project of Anhui Provincial Department of Education,China+1 种基金Project(GXXT-2021-057)supported by the Collaborative Innovation Project of Anhui Provincial Department of Education,ChinaProject(2020QDZ36)supported by the Doctoral Scientific Research Startup Foundation of Anhui Jianzhu University,China。
文摘Manganese ferrite(MnFe_(2)O_(4))has the advantages of simple preparation,high resistivity,and high crystal symmetry.Herein,we have developed an electrochemical sensor utilizing graphene and MnFe_(2)O_(4) nanocomposites modified glassy carbon electrode(GCE),which is very efficient and sensitive to detect bisphenol A(BPA).MnFe_(2)O_(4)/graphene(GR)was synthesized by immobilizing the MnFe_(2)O_(4) microspheres on the graphene nanosheets via a simple one-pot solvothermal method.The morphology and structure of the MnFe_(2)O_(4)/GR nanocomposite have been characterized through scanning electron microscopy(SEM),Fourier transform infrared spectroscopy(FT-IR),X-ray diffraction(XRD)and X-ray photoelectron spectroscopy(XPS).In addition,electrochemical properties of the modified materials are comparably explored by means of cyclic voltammetry(CV),electrochemical impedance spectroscopy(EIS)and differential pulse voltammetry(DPV).Under the optimal conditions,the proposed electrochemical sensor for the detection of BPA has a linear range of 0.8-400μmol/L and a detection limit of 0.0235μmol/L(S/N=3)with high sensitivity,good selectivity and high stability.In addition,the proposed sensor was used to measure the content of BPA in real water samples with a recovery rate of 97.94%-104.56%.At present,the synthesis of MnFe_(2)O_(4)/GR provides more opportunities for the electrochemical detection of BPA in practical applications.
基金Projects(42177164,52474121)supported by the National Science Foundation of ChinaProject(PBSKL2023A12)supported by the State Key Laboratory of Precision Blasting and Hubei Key Laboratory of Blasting Engineering,China。
文摘In the mining industry,precise forecasting of rock fragmentation is critical for optimising blasting processes.In this study,we address the challenge of enhancing rock fragmentation assessment by developing a novel hybrid predictive model named GWO-RF.This model combines the grey wolf optimization(GWO)algorithm with the random forest(RF)technique to predict the D_(80)value,a critical parameter in evaluating rock fragmentation quality.The study is conducted using a dataset from Sarcheshmeh Copper Mine,employing six different swarm sizes for the GWO-RF hybrid model construction.The GWO-RF model’s hyperparameters are systematically optimized within established bounds,and its performance is rigorously evaluated using multiple evaluation metrics.The results show that the GWO-RF hybrid model has higher predictive skills,exceeding traditional models in terms of accuracy.Furthermore,the interpretability of the GWO-RF model is enhanced through the utilization of SHapley Additive exPlanations(SHAP)values.The insights gained from this research contribute to optimizing blasting operations and rock fragmentation outcomes in the mining industry.
基金sponsored by the National 863 Program(Grant No.2006AA06Z207&2006AA06Z213)the National Natural Science Foundation of China(Grant No.50674098)the National 973 Program(Grant No.2007CB209601)
文摘Aimed at the poor performance of conventional geophones in exploration for deeper and complex targets, we present the principle and theoretical design of a new geophone based on the optical fiber Bragg grating (FBG) sensing technology. The important parameters such as response functions are calculated theoretically. Because of the advantages of FBG sensing technology, the new FBG geophone has a high dynamic range of 94dB at (10-200 Hz). This new generation of geophones will have wide use in seismic prospecting due to its higher sensitivity, lighter weight, and lower cost.
文摘The experimental results of flue gas desulphurization with caustic lime andhydrated lime activated by water spraying in a desulphurization reactor are presented. The effectsof Ca/S molar ratio, approach to saturation of flue gas, SO_2 concentration and gas velocity onsulfur retention efficiency and calcium utilization rate are investigated. Desulphurizationcharacteristics of the two sorbents are compared. The mechanism of improving desulphurizationefficiency by water spraying is analyzed. The results show that the activities of two sorbents areimproved obviously by humidification with water spray and the caustic lime has better applicationprospect because of cheaper cost.
基金Projects(21361020,21061012)supported by the National Natural Science Foundation of ChinaProject(NZ12156)supported by the Natural Science Foundation of Ningxia,ChinaProject(N-09-13)supported by Project of State Key Laboratory of Catalysis,Dalian Institute of Chemical Physics of the Chinese Academy of Sciences
文摘Electrophoretic deposition in conjunction with electrochemical reduction was used to make flexible free-standing graphene-like films. Firstly, graphene oxide (GO) film was deposited on graphite substrate by electrophoretic deposition method, and then reduced by subsequent electrochemical reduction of GO to obtain reduced GO (ERGO) film with high electrochemical performance. The morphology, structure and electrochemical performance of the prepared graphene-like film were confirmed by SEM, XRD and FT-IR. These unique materials were found to provide high specific capacitance and good cycling stability. The high specific capacitance of 254 F/g was obtained from cyclic voltammetry measurement at a scan rate of 10 mV/s. When the current density increased to 83.3 A/g, the specific capacitance values still remained 132 F/g. Meanwhile, the high powder density of 39.1 kW/kg was measured at energy density of 11.8 W-h/kg in 1 mol/L H2SO4 solution. Furthermore, at a constant scan rate of 50 mV/s, 97.02% of its capacitance was retained for 1000 cycles. These promising results were attributed to the unique assembly structure of graphene film and low contact resistance, which indicated their potential application to electrochemical capacitors.
文摘A diamond-like carbon (DLC) film is deposited as an electron injection layer between the polymer light-emitting layer(MEH-PPV) and aluminum (Al) cathode electrode in polymer electroluminescence devices (PLEDs) using a radio frequency plasma deposition system. The source material of the DLC is n-butylamine. The devices consist of indium tin oxide (ITO)/MEH-PPV/DLC/Al. Electron injection properties are investigated through I-V characteristics,and the mechanism of electron injection enhancement due to a thin DLC layer has been studied. It is found that: (1) a DLC layer thinner than 1.0nm leads to a higher turn-on voltage and decreased electroluminescent (EL) efficiency; (2) a 5.0nm DLC layer significantly enhances the electron injection and results in the lowest turn-on voltage and the highest EL efficiency; (3) DLC layer that exceeds 5.0nm results in poor device performance;and(4) EL emission can hardly be detected when the layer exceeds 10.0nm. The properties of ITO/MEH-PPV/DLC/Al and ITO/MEH-PPV/LiF/Al are investigated comparatively.
基金Supported by the Humanity and Social Sciences Research of Ministry of Education, China (No. 06JC780001)the Major Program of the National Natural Science Foundation of China (No. 40599420)
文摘The grain size and palinology of sediment and the frequency of ^14C dada provide an integrated reconstruction of the Holocene warm-humid phases of the North China Plain. Two clear intense and long-lasting warm-humid phases were identified by comprehensive research in this region. The first phase was dated back to the early Holocene (9 000-7 000 a BP), and the second was centered at 5 000-3 000 a BP. The warm-humid episode between 9 000 and 7 000 a BP was also recognized at other sites showing global climatic trends rather than local events. Compared with the concern to the warm-humid phase of the early Holocene, the second one was not paid enough attention in the last few decades. The compilation of the Holocene paleoclimate data suggests that perhaps the second warm-humid phase was pervasive in monsoon region of China. In perspective of environmental archaeology, much attention should be devoted to it, because the flourish and adaptation of the Neolithic cultures and the building up of the first state seem to corresponding to the general warm-humid climatic conditions of this period. In addition, a warm-humid interval at 7 20045 500 a BP was recognized by the grain size data from three sites. However, this warm-humid event was not shown in pollen assemblage and temporal distribution of ^14C data. Perhaps, the resolution for climatic reconstruction from pollen and temporal distribution of ^14C data cited here is relatively low and small-amplitude and short-period climatic events cannot be well reflected by the data. Due to the difference in locality and elevation of sampling site, as well as in resolution of proxy records, it is difficult to make precise correlation. Further work is needed in the future.
基金Under the auspices of National Natural Science Foundation of China (No 40571162)Education Department of Anhui Province Foundation (No 2007sk097)Natural Science Foundation of Anhui (No 090415212),Program for Innovative Research Team in Anhui Normal University
文摘There are about 19 Neolithic Age sites and 120 Shang-Zhou dynasties sites in the western lakeshore of Chaohu Lake,Anhui Province,China.Based on sites data,topographic data,drainage maps,administrative maps and SPOT5 remote sensing data,spatial analysis methods were introduced into the archaeology of Chaohu Lake Basin with Geographic Information System(GIS).The spatial analysis methods include:1) Point Density Analysis with density model to acquire the shift of the sites;2) Distance Analysis to reveal the spatial structure of the sites;3) 3D Analysis based on Digital Elevation Model to get micro-geomorphologic features of the sites;and 4) Buffer Analysis to discover the relationship between the sites and rivers.The results indicate that the archaeological sites spread from the western lakeshore of Chaohu Lake gradually to the northwest,later to the south,and then symmetrically spread.Controlled by productive forces and other factors,ancient people preferred to reside in those places near water,or in plain and fertile land,which resulted in linear and decentralized distribution of the sites,and presented such disciplines as river valley directivity,terrace directivity and soil directivity.This paper indicates that the distribution of archaeological sites was influenced earlier by natural elements and later by human elements in the study period.The research is important for the integration of GIS and archaeology.
文摘Chaviano's Fables of an Extraterrestrial Grandmother is a pioneering Cuban science fiction novel with four interconnected plots that manifest their separate worlds--the Havana of Ana, the protagonist writer, the Neolithic Celtic world of Merlin and Stonehenge, Faidir, the planet of Ijj e and the winged psyches with three eyes, and Rybel, the world of Ana's character Arlena, the "jumen" on the run in an alien planet after being wrecked in a space ship---through Ana's writing. Ana uses mental exercises and automatic writing to temporarily regress to a pre-rational state of consciousness where these parallel universes interpenetrate and cross in the locus of her subconscious. Writing for her is a form of possession that withdraws her fi'om her immediate reality into a visionary state resembling that of a shaman. She is a writer being invented and written by her own characters. Her stories are not fictions, but already existing realities, and she is a channel by which they are able to manifest their existence through her writing. This science fiction vision of worlds within worlds suggests another origin of science fiction in the ancient literary genre of Menippean satire, a type of fiction that appeals to highly cosmopolitan, alienated readers who seek to renew contact with the sources of consciousness from which technological and social change have alienated them.
基金supported by the National Natural Science Foundation of China(No.21503064)Anhui Provincial Natural Science Foundation(No.1508085QE103)the 100 Talents Program of the Chinese Academy of Sciences。
文摘In recent years,flexible pressure sensors have attracted much attention owing to their potential applications in motion detection and wearable electronics.As a result,important innovations have been reported in both conductive materials and the underlying substrates,which are the two crucial components of a pressure sensor.1D materials like nanowires are being widely used as the conductive materials in flexible pressure sensors,but such sensors usually exhibit low performances mainly due to the lack of strong interfacial interactions between the substrates and 1D materials.In this paper,we report the use of graphene/graphene scrolls hybrid multilayers films as the conductive material and a microstructured polydimethylsiloxane substrate using Epipremnum aureum leaf as the template to fabricate highly sensitive pressure sensors.The 2D structure of graphene allows to strongly anchor the scrolls to ensure the improved adhesion between the highly conductive hybrid films and the patterned substrate.We attribute the increased sensitivity(3.5 k Pa^-1),fast response time(<50 ms),and the good reproducibility during 1000 loading-unloading cycles of the pressure sensor to the synergistic effect between the 1D scrolls and 2D graphene films.Test results demonstrate that these sensors are promising for electronic skins and motion detection applications.
文摘Chronic radiation proctopathy occurs in 5%-20% of patients following pelvic radiotherapy. Although many cases resolve spontaneously,some lead to chronic symptoms including diarrhea,tenesmus,urgency and persistent rectal bleeding with iron deficiency anemia requiring blood transfusions. Treatments for chronic radiation proctitis remain unsatisfactory and the basis of evidence for various therapies is generally insuff icient. There are very few controlled or prospective trials,and comparisons between therapies are limited because of different evaluation methods. Medical treatments,including formalin,topical sucralfate,5-amino salicylic acid enemas,and short chain fatty acids have been used with limited success.Surgical management is associated with high morbidity and mortality. Endoscopic therapy using modalities such as the heater probe,neodymium:yttrium-aluminium-garnet laser,potassium titanyl phosphate laser and bipolar electrocoagulation has been reported to be of some benef it,but with frequent complications.Argon plasma coagulation is touted to be the preferred endoscopic therapy due to its eff icacy and safety profile.Newer methods of endoscopic ablation such as radiofrequency ablation and cryotherapy have been recently described which may afford broader areas of treatment per application,with lower rate of complications.This review will focus on endoscopic ablation therapies,including such newer modalities,for chronic radiation proctitis.
基金Supported by the National-Natural Science Foundation of China (No.20406013) and Program for New Century Excellent Talents in University (No.NCET-04-0107).
文摘The vaporization ratios of the slurry at various temperature and partial pressure were calculated with the group-contribution method,and then the phase state of the slurry in the residue fluid catalytic cracking(RFCC) disengager was determined.This research could provide some advices on how to select the technological conditions to decrease the coking in the RFCC disengager.The oil gas temperature and the slurry partial pressure had signifi- cant effects on the vaporization ratio of the slurry.Increasing the oil gas temperature and reducing the slurry partial pressure could effectively slow down the coking speed in the RFCC disengager.According to the calculation results, a correlation was established to predict the vaporization ratio of the slurry under different operating conditions.
基金Supported by the Science Foundation of China National Petroleum Corporation (990407 - 06 - 02)
文摘Percussive-rotary drilling technology was considered many years ago as one of the best approaches for hard rock drilling. It is a key for popularizing this technology on a large scale to design and make an impactor with excellent performance. This paper presents a suit of method to design the percussive parameters for the oil or gas field by introducing the working principle of back-pressurod impactor, dividing the working periods of impaetor into three phases and establishing the computer emuiational model of percussive parameters. It draws a comparison between the results of model calenlation and experiment on the basis of analyzing the experiment results of impactor. The conclude provides credible foundation for designing and further ameliorating the impactor.
文摘Owing to its photonic band gap(PBG)and slow light effects,aniline black(AB)-poly(vinylidene fluoride)(PVDF)inverse opal(IO)photonic crystal(PC)was constructed to promote the utility of light and realize photothermal synergetic catalysis.As a highly efficient reaction platform with the capability of restricting heat,a microreactor was introduced to further amplify the photothermal effects of near infrared(NIR)radiation.The photocatalytic efficiency of ZnO/0.5AB-PVDF IO(Z0.5A)increases 1.63-fold compared to that of pure ZnO film under a full solar spectrum,indicating the effectiveness of synergetic promotion by slow light and photothermal effects.Moreover,a 5.85-fold increase is achieved by combining Z0.5A with a microreactor compared to the film in a beaker.The photon localization effect of PVDF IO was further exemplified by finite-difference time-domain(FDTD)calculations.In conclusion,photonic crystal-microreactor enhanced photothermal catalysis has immense potential for alleviating the deteriorating water environment.