Determination of Five Organic Acids in Radix Isatidis by Column Partition Chromatography and Capillary Zone Electrophoresis柱分配色谱-毛细管区带电泳联用分析板蓝根中五种微量有机酸(英文)

Aim To determine five organic acids in Radix Isatidis . Method The extraction method and the column partition chromatographic conditions were studied. Then a capillary zone electrophoretic method was set up for the determination. Results The linear ranges of quinazolinone acid, n anthranilic acid, benzoic acid, salicylic acid, and syringic acid were 5 52-92 0 μg·mL -1 , 5 12-102 μg·mL -1 , 2 28-84 4 μg·mL-1 , 4 78-159 μg·mL -1 , and 1 74-87 0 μg·mL -1 respectively. Conclusion The established method is accurate and simple.

Determination of Dichlofluanid Residue in Soybean by Capillary Collumns Gas Chromatography

A method for the determination of dichlofluanid residue by Capillary Collumns Gas Chromatography was established in this study.Samples were extracted with acetone and subjected to through liquid-liquid extraction with N-hexane,and then they were cleanup with column that filled with florisil,subsequently separated by Capillary Column Gas Chromatography,and the electron capture detector （ECD） was used for detection.The detection limit of this method was 0.005 mg/kg （S/N=3）,and this method was rapid,sensitive and accurate,and was applied in the determination of dichlofluanid residue in soybean.

结构与空间的建构性整合

从结构空间化的角度,对不同建筑师创作的三个建筑进行了结构上的分析,展示了建筑师在创作过程中空间与结构的建构性整合,指出了创作构思与结构创新之间的相互促进关系。

Application of Multicapillary Column to High Speed GC Separation of Industrial Chemicals

Two multicapillary coluumns(SE 30 and Carbowax 20M)were used for high speed GC separation of positional isomers of industrial chemicals The performances of the two multicapillary columns were also evaluated,such as the effects of carrier velocity,column temperature and sample capacity Two typical explosive isomers(DNT and TNT)were well separated on SE 30 multicapillary column,while some important chemicals(e g xylenes,xylenols)were separated on Carbowax 20M multicapillary column at high speed The multimulticapillary column shows the feature of fast analysis,relatively lower column temperature and larger sample capacity

Behavior of concrete and concrete-filled circular steel tubular stub columns at constant high temperatures

Based on reanalyzing test results of uniaxial compressive behavior of concrete at constant high temperatures in China, with the compressive cube strength of concrete from 20 to 80 MPa, unified formulas for uniaxial compressive strength, elastic modulus, strain at peak uniaxial compression and mathematical expression for unaxial compressive stress-strain relations for the concrete at constant high temperatures were studied. Furthermore, the axial stress-axial strain relations between laterally confined concrete under axial compression and multiaxial stress-strain relations for steel at constant high temperatures were studied. Finally, based on continuum mechanics, the mechanics model for concentric cylinders of circular steel tube with concrete core of entire section loaded at constant high temperatures was established. Applying elasto-plastic analysis method, a FORTRAN program was developed, and the concrete-filled circular steel tubular （CFST） stub colunms at constant high temperatures were analyzed. The analysis results are in agreement with the experiment ones from references.

Novel hybrid FRP tubular columns for sustainable mining infrastructure:Recent research at University of Wollongong

This paper introduces, for applications in the mining industry, an innovative hybrid column form which consists of an inner steel tube, an outer fibre-reinforced polymer(FRP) tube and an annular concrete infill between them. The two tubes may be concentrically placed to produce a section form more suitable for columns, or eccentrically placed to produce a section form more suitable for beams. The FRP is combined with steel and concrete in these hybrid structural members in such a way that the advantages of FRP are appropriately exploited while its disadvantages are minimized. As a result, these hybrid members possess excellent corrosion resistance as well as excellent ductility and seismic resistance. This paper summarizes existing research on this new form of structural members, and discusses their potential applications in mining infrastructure before presenting a summary of the recent and current studies at University of Wollongong(UOW) on their structural behaviour and design.

Local Flow Regime Transition Criteria of Gas-Liquid Two-phase Flow in Vertical Upward Tube with a Horizontal Rod

The upward multiphase cross flow and heat transfer in the vertical tube may occur in oil production and chemical facilities. In this study, the local flow patterns of an upward gas-water two phase cross flow in a vertical tube with a horizontal rod have been investigated with an optical probe and the digital high speed video system. The local flow patterns are defined as the bubble, slug, churn and annular flow patterns. Optical probe signals are ana- lyzed in terms of probability density function, and it is proved that the local flow patterns can be recognized by this method. The transition mechanisms between the different flow patterns have been analyzed and the corresponding transitional models are proposed. Finally, local flow pattern maps of the upward gas-water two-phase flow in the vertical tube with a horizontal rod are constructed.

Joint member angle limits of composite beams and CFT square columns

This work aims to understand the relationship between the member angle limit and the energy ratio for 24 test samples of composite beams and CFT square steel tube columns. This work also compares the formula applicability for member angle limit with the previous test result to provide the basic data for the design of composite beam-CFT column. The evaluation of the member angle limit was performed with concrete compressive strength (fC =22.16 MPa, 30.49 MPa), breadth-to-thickness ratio (B/t=25.0, 33.3, 43.5), and axial capacity ratio (N/N0=0, 0.3, 0.4, 0.5) as the main variables of the test samples. For the relationship between the member angle limit (Ru) and the energy ratio (ES/EC ), the test result shows that the energy ratio becomes lower as the axial capacity ratio and the breadth-to-thickness ratio increase. The energy ratio is lower for the Type B test sample compared with that of Types A and C. For the formula suggested by SATO, the test samples are distributed evenly for comparison between test values and the member angle limit; however, other formulas indicate a deviation. Specifically, for the comparison between R u,cal and R u (Test), Maeda's formula shows severe deviation.

Influence of earth gravity on reaction engineering of tubular reactor for high concentration tungsten ion-exchange

The influence of gravity on the reaction engineering of tubular reactor is studied by analyzing the residence time distribution curves.The results show that upflow-feeding mode is more beneficial compared with downflow-feeding mode,since the flow pattern of the fluid in the reactor is closer to plug flow.The result of dynamic experiment conducted in ion-exchange of tungsten metallurgy is as good as that in reaction engineering of ion-exchange column.Whether downflow-feeding or upflow-feeding mode is adopted,breakthrough time decreases when solution concentration increases.Upflow-feeding mode has longer breakthrough time and greater improvement in adsorption capacity especially with high WO3 concentration in ion-exchange.

Analysis and Calculation of the Flow Pressure in the Multipoint Steam Injection String of a Horizontal Well

The multipoint steam injection string of the horizontal well is a commonly used downhole component for high efficiency steam injection of the thermal recovery horizontal well. A reasonable layout of the valves to ensure an even steam output of each point is still not well designed. At present, a general design method which is urgently necessary isn＇ t applied by each factory. According to the balance relationship of the momentum, the energy and the mass of the fluid flowing in the string, the pressure distribution equation of the fluid flowing in the multipoint steam injection string is built. On the basis of this equation, the design calculation method of the multipoint steam injection string is come up with. A specific example is given in the paper. Study shows that, with the equation built in this paper, the string can be designed with each axial valve having the same output, so that the technical demand of an even steam injection of the horizontal well section can be met.

Local Tensile Strength of Connection Between H-Steel Beam Flange and Concrete-Filled Circular Column Tube with Through Diaphragm

This paper focused on investigating local tensile strength of connection between steel beam flange and concrete-filled circular column tube with through diaphragm. Three specimens were designed and tested to failure, and the structure behavior was studied by experiment and FEM analysis. On the basis of the results obtained, an estimation for local plastic and ultimate strengths of the connections using yield line theory was attempted, which results in a good prediction.

Numerical and experimental study on seismic behavior of concrete-filled T-section steel tubular columns and steel beam planar frames

The seismic behavior of planar frames with concrete-filled T-section columns to steel beam was experimentally and numerically studied. A finite element analysis （FEA） model was developed to investigate the engineering properties of the planar frames. Two 1：2.5 reduced-scale specimens of T-section concrete-filled steel tubular column and steel beam of single-story and single-bay plane frames were designed and fabricated based on the design principles of strong-column, weak-beam and stronger-joint. One three-dimensional entity model of the investigated frame structure was built using a large-scale nonlinear finite-element analysis software ABAQUS. Experimental results show that the axial compression ratio has no effect on the failure mode of the structure, while with the increase of axial compression ratio and the dissipated energy ability increasing, the structural ductility decreased. The results from both experiments and simulations agree with each other, which verifies the validity and accuracy of the developed finite element model. Furthermore, the developed finite element model helps to reflect the detailed stress status of the investigated frame at different time and different positions.

Research and Realization of the Role-Based System Access Control Management

The systematical structure of the role-based access control was analyzed,giving a full description of the definitions of user,user access,and the relation between post role and access. It puts forward a role-based access control management which is relatively independent in the applied system. This management achieves the control on user's access by distribution and cancel of role-play,which is a better solution to the problems of the access control management for the applied system. Besides,a complete scheme for the realization of this access control was provided.

Finite element modeling for analysis of cracked cylindrical pipes

The characteristic properties of shell element with similar shapes are used to generate a so-called super element for the analysis of the crack problems for cylindrical pressure vessels. The formulation is processed by matrix condensation without the involvement of special treatment. This method can deal with various singularity problems and it also presents excellent results to crack problems for cylindrical shell. Especially,the knowledge of the kind of singular order is not necessary in super element generation; it is very economical in terms of computer memory and programming. This method also exhibits versatility to solve the problem of kinked crack at cylindrical shell.

Pico–nano bubble column flotation using static mixer-venturi tube for Pittsburgh No.8 coal seam

The flotation process is a particle-hydrophobic surface-based separation technique. To improve the essential flotation steps of collision and attachment probabilities, and reduce the step of detachment probabilities between air bubbles and hydrophobic particles, a selectively designed cavitation venturi tube combined with a static mixer can be used to generate very high numbers of pico and nano bubbles in a flotation column. Fully embraced by those high numbers of tiny bubbles, hydrophobic particles readily attract the tiny bubbles to their surfaces. The results of column flotation of Pittsburgh No. 8 seam coal are obtained in a 5.08 cm ID and 162 cm height flotation column equipped with a static mixer and cavitation venturi tube, using kerosene as collector and MIBC as frother. Design of the experimental procedure is combined with a statistical two-stepwise analysis to determine the optimal operating conditions for maximum recovery at a specified grade. The effect of independent variables on the responses has been explained. Combustible material recovery of 85–90% at clean coal product of 10–11% ash is obtained from feed of 29.6% ash, with a much-reduced amount of frother and collector than that used in conventional column flotation. The column flotation process utilizing pico and nano bubbles can also be extended to the lower limit and upper limit of particle size ranges, minus 75 lm and 300–600 lm, respectively, for better recovery.

Management of Pregnancy with Ankylosing Spondylitis

Objective To discuss the interaction between pregnancy and ankylosing spondylitis, and the management of pregnancy with ankylosing spondylitis. Methods Twelve cases of pregnancy with ankylosing spondylitis in Peking Union Medical College Hospital from September 2004 to July 2011 were analyzed retrospectively, focusing on the arteritis condition, pregnancy complications, and outcomes. Results All the 12 patients had full-term pregnancy. Five cases gave birth naturally, and 7 cases received cesarean section for maternity factors. No adverse pregnancy outcomes were encountered. Waist pain appeared in 2 cases in the second trimester, for both of which medication failed. One of the 2 cases had natural childbirth, while the other maintained pregnancy smoothly to cesarean section. Conclusions Pregnancy monitoring can help obtain favorable pregnancy outcomes. Attention should be paid to postpartum change of the illness.

Mechanosynthesis of Boron Nitride Nanotubes

Boron nitride nanotubes （BN-NTs） with pure hexagonal BN phase have been synthesized by heating ball-milled boron powders in flowing ammonia gas at a temperature of 1200℃. The as-synthesized products were characterized by X-ray powder diffraction, transmission electron microscopy, high-resolution transmission electron microscopy, and electron energy loss spectroscopy （EELS）. The diameters of nanotubes are in the rage of 40-120nm and the lengths are more than 10μm. EELS result identifies that the ratio of boron and nitrogen is almost 1：1 The growth temperature is a crucial growth parameter in controlling the structure and crystalline of BN-NTs. The nanotubes grown at 1100℃ possesses of a bamboo-like structure, while as the temperature increased to 1200℃, most of the nanotubes exhibited a cylindrical structure. In addition, changing the heating time can control the size of the nanotubes. The gas atmosphere has influence on the yield of BN-NTs during heating process. When heating atmosphere was replaced by nitrogen, the yield of nanotubes was remarkably decreased.

Experimental investigation of axially loaded steel fiber reinforced high strength concrete-filled steel tube columns

An experimental study on the compressive behavior of steel fiber reinforced concrete-filled steel tube columns is presented. Specimens were tested to investigate the effects of the concrete strength, the thickness of steel tube and the steel fiber volume fraction on the ultimate strength and the ductility. The experimental results indicate that the addition of steel fibers in concrete can significantly improve the ductility and the energy dissipation capacity of the concrete-filled steel tube columns and delay the local buckling of the steel tube, but has no obvious effect on the failure mode. It has also been found that the addition of steel fibers is a more effective method than using thicker steel tube in enhancing the ductility, and more advantageous in the case of higher strength concrete. An analytical model to estimate the load capacity is proposed for steel tube columns filled with both plain concrete and steel fiber reinforced concrete. The predicted results are in good agreement with the experimental ones obtained in this work and literatures.

Chemical fingerprinting of Su-He-Xiang-Wan and attribution of major characteristic peaks for its quality control by GC-MS

A simple and facile gas chromatography-mass spectrometer （GC-MS） fingerprint of Su-He-Xiang-Wan （SHXW） was developed, the similarity analysis was conducted, and attribution of the major characteristic peaks was identified for SHXW quality control. GC-MS analysis was performed on a QP2010 instrument （Shimadzu, Japan） equipped with a capillary column of RTX-5MS. The column temperature was initiated at 50℃, held for 5 min, increased at the rate of 3 ℃/min to 120 ℃, held for 2 min, and then increased at the rate of 4 ℃/min to 220℃, held for 10 min. Helium carrier gas was used at a constant flow rate of 1.3 mL/min. Mass conditions were ionization voltage, 70 eV; injector temperature, 250℃; ion source temperature, 250 ℃; splitting ratio, 30：1; full scan mode in the 40-500 Da mass ranges with rate of 0.2 s per scan. Attribution of the major characteristic peaks was identified for SHXW by comparing the chemical standards, references of Chinese herbal medicines and the negative controls of prescription samples （NC） of SHXW. With the help of the temperature-programmed retention indices （PTRIs） used together with mass spectra and chemical standards, 25 major characteristic peaks have been identified. Nine volatile medicinal materials were identified in the prescription of SHXW by attributing to the 27 major characteristic peaks. The results demonstrate that the proposed method is a powerful approach to quality control of complex herbal medicines.

Application of Compactness Detection to Complicated Concrete-Filled Steel Tube by Ultrasonic Method

An example of using ultrasonic method to detect the compactness of complicated concrete-filled steel tube in certain high-rise building was discussed in this study.Because of the particularity of the complicated concrete-filled steel tubular column,the plane detection method and embedded sounding pipe method were adopted in the process of effectively detecting the column.According to the results of the plane detection method and embedded sounding pipe method,the cementing status of steel tube and concrete can be concluded,which cannot be judged by the hammering method in the rectangular steel tube-reinforced concrete.