Green and efficient epoxidation of methyl oleate over hierarchical TS-1

The epoxidation of methyl oleate(MO)was conducted in the presence of aqueous H2O2 as the oxidant and hierarchical TS-1(HTS-1)as the catalyst;the catalyst was synthesized using polyquaternium-6 as the mesopore template.The effects of various parameters,i.e.,H2O2/C=C molar ratio,oxidant concentration,amount of the catalyst,reaction temperature,and time,were systematically studied.Furthermore,response surface methodology(RSM)was used to optimize the conditions to maximize the yield of epoxy MO and to evaluate the significance and interplay of the factors affecting the epoxy MO production.The H2O2/C=C molar ratio and catalyst amount were the determining factors for MO epoxidation,wherein the maximum yield of epoxy MO reached 94.9%over HTS-1 under the optimal conditions.

Energy-Efficient Transceiver Design for Multi-Pair Two-Way Relay Systems

In this paper, we focus on energy-efficient transceiver and relay beamforming design for multi-pair two-way relay system. The multi-antenna users and the multi-antenna relay are considered in this work. Different from the existing works, the proposed algorithm is energy-efficient which is more applicable to the future green network. It considers both the sum-MSE problem and the power consumption problem for the users under the relay power constraint. Based on the optimal condition decomposition(OCD) method, the energy-efficient precoders at the users can be designed separately with limited information exchanged. The proposed relay beamforming algorithm is based on the alternative direction method of multipliers(ADMM) which has simpler iterative solution and enjoys good convergence. Simulation results demonstrate the performance of the proposed algorithms in terms of power consumption and MSE performance.

A Case Study on Optimization of Urban Design Base on Wind Environment Simulation

Wind environment simulation of a commercial district in Baise city of Guangxi Province, China, is carried out in the design phase. The results are analyzed and based on the evaluation standard for greening building of China. The simulation method is discussed in detail, and some suggestions for wind environment optimization are put forward, which might be helpful for similar research.

The Application of Computer Simulation Technology in Building Design

From the simulation software selection, meteorological data collection, model, boundary conditions, calculation setting and evaluation indicators, the paper summarize simulation method of wind, light and sound, summarize three kinds of environmental. The paper study on optimization analysis method of green building from four aspects of building orientation, architectural form, architectural layout and indoor environment, and puts forward the optimization scheme of the typical simulation analysis of simple questions; provide guidance for optimizing the design of green building. Finally, ECOTECT can adapt to the current domestic engineering design and consulting on green building simulation and design requirements, and has a broad application prospect.

A green method of staining DNA in polyacrylamide gel electrophoresis based on fluorescent copper nanoclusters synthesized in situ

The safety of nucleic acid staining dyes has long been recognized to be a problem. Extensive efforts have been made to search for alternatives to the most popular but toxic staining dye, ethidium bromide （EtBr）. However, so far no staining method that can be guaranteed to be suffidently safe has been developed. In this paper, we report a green staining method of DNA in polyacrylamide gel electrophoresis, where in situ synthesis of DNA-templated fluorescent copper nanoclusters （CuNCs） in the gel is achieved to make the DNA bands visible under UV light. Moreover, a comprehensive study of the performance of this staining method has been conducted and the experimental results show that it has favorable sensitivity, stability, and usability. Meanwhile, in our animal experiments, the two reagents （copper sulfate and ascorbic acid） as well as the synthesized CuNCs have been proven to be non-toxic in contact with skin. In addition, all the reagents employed in this work are readily available and low cost, and the procedure is simple to carry out. Therefore, this novel staining method based on the in situ synthesis DNA-templated fluorescent CuNCs has many potential applications.

Surface-gel-conversion synthesis of submicron-thick MFI zeolite membranes to expedite shape-selective separation of hexane isomers

Ultrathin zeolite membranes are of paramount importance in accelerating gas transport during membrane separation,and lowering down their membrane thicknesses to submicron scale is deemed to be very challenging.Herein,we develop an advanced approach of surface gel conversion for synthesis of submicron-thick pure silica MFI(silicalite-1)zeolite membranes.Viscous gel is prepared by finely adjusting the precursor composition,enabling its reduced wettability.The unfavorable wetting of the support surface can effectively prevent gel penetration into alumina support voids.Aided by the seeds,the surface gel is directly and fully crystallized into an MFI zeolite membrane with minimal water steam.A membrane with a thickness of 500 nm is successfully acquired and it is free of visible cracks.Additionally,the as-synthesized membranes exhibit rapid and selective separation of hexane isomers by virtue of unprecedentedly high n-hexane permeance of 24.5×10^−7 mol m^−2 s^−1 Pa^−1 and impressive separation factors of 13.3-22.6 for n-hexane over its isomers.This developed approach is of practical interest for sustainable synthesis of high-quality zeolite membranes.

Wetting transition energy curves for a droplet on a square-post patterned surface

Due to the property of water repellence, biomimetic superhydrophobic surfaces have been widely applied to green technologies, in turn inducing wider and deeper investigations on superhydrophobic surfaces. Theoretical, experimental and numerical studies on wetting transitions have been carried out by researchers, but the mechanism of wetting transitions between Cassie-Baxter state and Wenzel state, which is crucial to develop a stable superhydrophobic surface, is still not fully understood. In this paper, the flee energy curves based on the transition processes are presented and discussed in detail. The exis- tence of energy barriers with or without consideration of the gravity effect, and the irreversibility of wet- ting transition are discussed based on the presented energy curves. The energy curves show that different routes of the Cassie-to-Wenzel transition and the reverse transition are the main reason for the irre- versibility. Numerical simulations are implemented via a phase field lattice Boltzmann method of large density ratio, and the simulation results show good consistency with the theoretical analysis.

The Current Status, Problems and Prospects of Researches on the Carrying Capacities of Ecological Environment in China

Determining the carrying capacity of ecological resources is the key to finding contradictions between human activities and the environment,as well as the links between economic growth,environmental protection and social development.In recent years,the carrying capacity of the ecological environment has been extensively studied at home and abroad.Through extensive literature research and analysis,this paper discusses the current status and main problems of recent research on the carrying capacity of the ecological environment in China.For example,two of the main problems are that:1)the concepts and connotations are not clear enough,and 2)the research content is not systematic enough.This is followed by a summary of the evaluation index system and main calculation methods.Finally,according to the research status and development trends at home and abroad,the possible direction for the development of this research field in the future is proposed.

Landscape design method for a green community based on green building design theory

Landscape design for a green community should be favorable for the ambient ecological environment and for enhancement of both the local climate of a residential area and the environmental quality of life. This paper presents optimization methods for plant landscape design that take account of results of comparisons of noise reduction effects, heat island temperature decreases and effects on ventilation. These methods are based on different plant configurations and various luminous environments, such as exterior sunshine and shaded areas after the simulation of exterior luminous, acoustic and thermal environments of a residential area using the analytic software ECOTECT, CADNA/A, and PHEONICS. Three different types of residential buildings are simulated including a faculty apartment in the Xixi Campus of Zhejiang University, the Huaqing Villa and the Gangwan Jiayuan faculty apartment of Zhejiang University, China, based on green building design theory. In addition, the methods and process flow of landscape design of green residential areas are also described for the improvement of the exterior physical living environment.