Geopolymer-lightweight aggregate refractory concrete (GLARC) was prepared with geopolymer and lightweight aggregate. The mechanical property and heat-resistance (950 ℃) of GLARC were investigated. The effects of size...Geopolymer-lightweight aggregate refractory concrete (GLARC) was prepared with geopolymer and lightweight aggregate. The mechanical property and heat-resistance (950 ℃) of GLARC were investigated. The effects of size of aggregate and mass ratio of geopolymer to aggregate on mechanical and thermal properties were also studied. The results show that the highest compressive strength of the heated refractory concrete is 43.3 MPa,and the strength loss is only 42%. The mechanical property and heat-resistance are influenced by the thickness of geopolymer covered with aggregate,which can be expressed as the quantity of geopolymer on per surface area of aggregate. In order to show the relationship between the thickness of geopolymer covered with aggregate and the thermal property of concrete,equal thickness model is presented,which provides a reference for the mix design of GLARC. For the haydite sand with size of 1.18-4.75 mm,the best amount of geopolymer per surface area of aggregate should be in the range of 0.300-0.500 mg/mm2.展开更多
The stability of soil aggregates and the fractal characteristics of four typical land use types(farmland,grassland,woodland,and bare land) in the Jiangjiagou Ravine(Yunnan,China),a frequent debris flow occurring area,...The stability of soil aggregates and the fractal characteristics of four typical land use types(farmland,grassland,woodland,and bare land) in the Jiangjiagou Ravine(Yunnan,China),a frequent debris flow occurring area,were studied according to the normal mean mass diameter and fractal theory.The present research showed that the stability of the soil aggregates was different for the different land use types.When the soil depth was 0-30 cm,farmland soil formed more aggregates with diameters greater than 0.25 mm,i.e.,the farmland soil was more stable than that of the other three land uses.When the soil depth was 30-45 cm,the order of stability of the soil aggregates was woodland > grassland > farmland > bare land.The fractal dimensions had a significant linear positive correlation with the amount of soil particles with diameters of <0.25 mm,and a significant negative linear correlation with the amount of soil particles with diameters of 0.25-0.5 mm,0.5-1 mm and 1-2 mm.Smaller fractal dimensions of the soil particles correlated with more stable soil aggregates.The fractal dimensions had a positive linear correlation with the soil bulk density and a negative correlation with the concentration of organic matter.These results showed that soil aggregates can be used as a parameter for characterizing the soil structures and properties.According to these results,the soil particle fractal dimensions could not only objectively characterize the stability of the soil structure but also could be used to indicate soil structure and properties.In addition,these results have great significance for the discussion of the comprehensive evaluation of soil.展开更多
Soil and water conservation is essential for sustaining food production and for preserving the environment in arid and semi arid lands (ASALs) where conditions for agriculture and other land use systems are often ha...Soil and water conservation is essential for sustaining food production and for preserving the environment in arid and semi arid lands (ASALs) where conditions for agriculture and other land use systems are often harsh and unpredictable. The ASALs of Algeria are an important source of a variety of non wood forest products like Stipa tenacissima L. plant (esparto grass). This research was conducted to determine the effects of different low concentration (〈 I%) polyacrylaJnide, Stipa tenacissima L. fiber (esparto grass fibers) and its mixtures with the polymer at water retention in arid and semi arid soil. All samples are characterized by infrared spectroscopy, X-ray Diffractometry, thermal analysis TG DSC and scanning electron micrographs (SEM). The results showed that polymer blend in soil could improve better soil physical proprieties decreased evaporation and increase water retention in arid soils compared with application of any other blend at the same concentration. The use of Polyacrylamide-Cellulose blend appears to promise for reducing the labor cost of irrigation at arid and semi-arid soils, and offers safe and environmentally friendly inexpensive materials. The importance of Polyacrylamide-Cellulose blends to alleviate poor physical properties and retain water in these arid regions to sustain plant growth.展开更多
One approach to apply precision agriculture to optimize crop production and environmental quality is identifying management zones. In this paper,the variables of soil electrical conductivity (EC) data,cotton yield dat...One approach to apply precision agriculture to optimize crop production and environmental quality is identifying management zones. In this paper,the variables of soil electrical conductivity (EC) data,cotton yield data and normalized differ-ence vegetation index (NDVI) data in an about 15 ha field in a coastal saline land were selected as data resources,and their spatial variabilities were firstly analyzed and spatial distribution maps constructed with geostatistics technique. Then fuzzy c-means clustering algorithm was used to define management zones,fuzzy performance index (FPI) and normalized classification entropy (NCE) were used to determine the optimal cluster numbers. Finally one-way variance analysis was performed on 224 georefer-enced soil and yield sampling points to assess how well the defined management zones reflected the soil properties and produc-tivity level. The results reveal that the optimal number of management zones for the present study area was 3 and the defined management zones provided a better description of soil properties and yield variation. Statistical analyses indicate significant differences between the chemical properties of soil samples and crop yield in each management zone,and management zone 3 presented the highest nutrient level and potential crop productivity,whereas management zone 1 the lowest. Based on these findings,we conclude that fuzzy c-means clustering approach can be used to delineate management zones by using the given three variables in the coastal saline soils,and the defined management zones form an objective basis for targeting soil samples for nutrient analysis and development of site-specific application strategies.展开更多
Reuse of concrete waste, especially in large quantity, can save not only material but also cost for its disposal. This paper presents experiment results on the use of fine and coarse aggregates from concrete waste in ...Reuse of concrete waste, especially in large quantity, can save not only material but also cost for its disposal. This paper presents experiment results on the use of fine and coarse aggregates from concrete waste in geopolymer mortars and concretes. Geopolymeric cement is an inorganic compounds of aluminosilicates synthesized from precursors with high content of silica and alumina activated by alkali silicate solutions. Geopolymer in this experiment was synthesized from fly ash as the precursor and sodium silicate solution as the activator. Hardening of geopolymers was performed by heating the casted paste in an oven at -60~Cfor 3 to 36 hours. Compressive strength of geopolymer pastes and mortars using either fresh or waste fine aggregates were in the range of 19-26 MPa. Hardening time of 3 hours at 60~C followed by leaving the test pieces at room temperature for 7 day before testing results in similar strength to that of mortars cured for 36 hours at 60~C followed by leaving the samples at room temperature for 3 days. It suggests that optimum strength can be achieved by combination of heating time and rest period before testing, i.e the specimens age. Applying mix design with a target strength of 40 MPa, conventional Portland cement concretes using fresh aggregates reached 70% of its target strength at day-7. Compressive strength of geopolymer concretes with waste aggregates was -25 MPa at day-3 while geopolymer concretes with fresh aggregates achieved -39 MPa at day-3. It can be concluded that geopolymer concretes can achieve the target strength in only 3 days. However, the expected reinforcing effect of coarse aggregates in concrete was ineffective if waste coarse aggregates were used as the strength of the concretes did not increase significantly from that of the mortars. On the other hand, waste fine aggregates can be reused for making geopolymer mortars having the same strength as the geopolymer mortars using fresh aggregates.展开更多
In many regions both urban expansion and rural development take place simultaneously, and for the purpose of understanding the dynamic process of land use/cover change (LUCC) in such large areas, this study develops...In many regions both urban expansion and rural development take place simultaneously, and for the purpose of understanding the dynamic process of land use/cover change (LUCC) in such large areas, this study develops a multi-agent based land use model. Taking the Poyang Lake area of China as a typical case, this study applies the mechanism of diffusion-limited aggregation to simulate the behavior of urban agents, while rural land use is illustrated with a bottom-up based model consisting of agent and environment layers. In the agent layer, each household agent makes its own decisions on land use, and at each time interval a government agent takes control of land use by implementing policies. According to incomes and the rate of migrant workers, household agents are divided into six categories, among which different decision rules are followed. For complex LUCC in the Poyang Lake area of China from 1985 to 2005, the artificial society model developed in this study yields results highly consistent with observations. Importantly, it is shown that governmental policies can impose significant effects on the decisions of individual household agents on land use and the multi-agent-based land use model developed in this study provides a robust means for assessing the effectiveness of governmental policies.展开更多
Promoting soil carbon sequestration in agricultural land is one of the viable strategies to decelerate the observed climate changes. However, soil physical disturbances have aggravated the soil degradation process by ...Promoting soil carbon sequestration in agricultural land is one of the viable strategies to decelerate the observed climate changes. However, soil physical disturbances have aggravated the soil degradation process by accelerating erosion. Thus, reducing the magnitude and intensity of soil physical disturbance through appropriate farming/agricultural systems is essential to management of soil carbon sink capacity of agricultural lands. Four sites of different land use types/tillage practices, i) no-till (NT) corn (Zea mays L.) (NTC), ii) conventional till (CT) corn (CTC), iii) pastureland (PL), and iv) native forest (NF), were selected at the North Appalachian Experimental Watershed Station, Ohio, USA to assess the impact of NT farming on soil aggregate indices including water-stable aggregation, mean weight diameter (MWD) and geometric mean diameter (GMD), and soil organic carbon and total nitrogen contents. The NTC plots received cow manure additions (about 15 t ha-1) every other year. The CTC plots involved disking and chisel ploughing and liquid fertilizer application (110 L ha-l). The results showed that both water-stable aggregation and MWD were greater in soil for NTC than for CTC. In the 0-10 cm soil layer, the 〉 4.75-mm size fraction dominated NTC and was 46% more than that for CTC, whereas the 〈 0.25-mm size fraction was 380% more for CTC than for NTC. The values of both MWD and GMD in soil for NTC (2.17 mm and 1.19 mm, respectively) were higher than those for CTC (1.47 and 0.72 mm, respectively) in the 0-10 cm soil layer. Macroaggregates contained 6%-42% and 13%-43% higher organic carbon and total nitrogen contents, respectively, than microaggregates in soil for all sites. Macroaggregates in soil for NTC contained 40% more organic carbon and total nitrogen over microaggregates in soil for CTC. Therefore, a higher proportion of microaggregates with lower organic carbon contents created a carbon-depleted environment for CTC. In contrast, soil for NTC had more aggregation and contained higher organic carbon content within water-stable aggregates. The soil organic carbon and total nitrogen stocks (Mg ha-1) among the different sites followed the trend of NF 〉 PL 〉 NTC 〉 CTC, being 35%-46% more for NTC over CTC. The NT practice enhanced soil organic carbon content over the CT practice and thus was an important strategy of carbon sequestration in cropland soils.展开更多
The size distribution of water-stable aggregates and the variability of organic C,N and P contents over aggregate size fractions were studied for orchard,upland,paddy,and grassland soils with high,medium,and low ferti...The size distribution of water-stable aggregates and the variability of organic C,N and P contents over aggregate size fractions were studied for orchard,upland,paddy,and grassland soils with high,medium,and low fertility levels.The results showed that > 5 mm aggregates in the cultivated upland and paddy soils were 44.0% and 32.0%,respectively,less than those in the un-tilled orchard soil.Organic C and soil N in different size aggregate fractions in orchard soil with high fertility were significantly higher than those of other land uses.However,the contents of soil P in different size aggregates were significantly greater in the paddy soil as compared to the other land uses.Soil organic C,N and P contents were higher in larger aggregates than those in smaller ones.The amount of water-stable aggregates was positively correlated to their contribution to soil organic C,N and P.For orchard and grassland soils,the > 5 mm aggregates made the greatest contribution to soil nutrients,while for upland soil,the 0.25-0.053 mm aggregates contributed the most to soil nutrients.Therefore,the land use with minimum disturbance was beneficial for the formation of a better soil structure.The dominant soil aggregates in different land use types determined the distribution of soil nutrients.Utilization efficiency of soil P could be improved by converting other land uses to the paddy soil.展开更多
High-resolution and detailed regional soil spatial distribution information is increasingly needed for ecological modeling and land resource management. For areas with no point data, regional soil mapping includes two...High-resolution and detailed regional soil spatial distribution information is increasingly needed for ecological modeling and land resource management. For areas with no point data, regional soil mapping includes two steps: soil sampling and soil mapping. Because sampling over a large area is costly, efficient sampling strategies are required. A multi-grade representative sampling strategy, which designs a small number of representative samples with different representative grades to depict soil spatial variations at different scales, could be a potentially efficient sampling strategy for regional soil mapping. Additionally, a suitable soil mapping approach is needed to map regional soil variations based on a small number of samples. In this study, the multi-grade representative sampling strategy was applied and a fuzzy membership-weighted soil mapping approach was developed to map soil sand percentage and soil organic carbon (SOC) at 0-20 and 20-40 cm depths in a study area of 5 900 km2 in Anhui Province of China. First, geographical sub-areas were delineated using a parent lithology data layer. Next, fuzzy c-means clustering was applied to two climate and four terrain variables in each stratum. The clustering results (environmental cluster chains) were used to locate representative samples. Evaluations based on an independent validation sample set showed that the addition of samples with lower representativeness generally led to a decrease of root mean square error (RMSE). The declining rates of RMSE with the addition of samples slowed down for 20-40 cm depth, but fluctuated for 0-20 cm depth. The predicted SOC maps based on the representative samples exhibited higher accuracy, especially for soil depth 20-40 cm, as compared to those based on legacy soil data. Multi-grade representative sampling could be an effective sampling strategy at a regional scale. This sampling strategy, combined with the fuzzy membership-based mapping approach, could be an optional effective framework for regional soil property mapping. A more detailed and accurate soft parent material map and the addition of environmental variables representing human activities would improve mapping accuracy.展开更多
Soil aggregation and organic matter of soils from the pre-Pyrenean range in Catalonia (NE Spain) were studied,in order to assess their quality as carbon sinks and also to select the best soil management practices to p...Soil aggregation and organic matter of soils from the pre-Pyrenean range in Catalonia (NE Spain) were studied,in order to assess their quality as carbon sinks and also to select the best soil management practices to preserve their quality.Aggregate stability,organic carbon and micromorphology were investigated.The highest amount of organic carbon was found in alluvial,deep soils (228 Mg C ha -1 ),and the lowest was in a shallow,stony soil with a low plant cover (78 Mg C ha -1 ).Subsurface horizons of degraded soils under pastures were the ones with smaller and less-stable aggregates.Fresh residues of organic matter (OM) were found mostly in interaggregate spaces.Within the aggregates there were some organic remains that were beginning to decompose,and also impregnative nodules of amorphous OM.Although OM was evenly distributed among the aggregate fractions,the larger blocky peds had more specific surface,contained less decomposed OM and had a lower organic/mineral interphase than smaller crumb aggregates,which were also more stable.Soil carbon storage was affected primarily by the OM inputs in the surface horizons.In order to store organic carbon over the mid- and long-term periods,the mechanisms favouring structuration through biological activity and creating small aggregates with intrapedal stable microporosities seemed to be the most effective.展开更多
The use of landscape covariates to variability of soil properties in similar estimate soil properties is not suitable topographic and vegetation conditions. for the areas of low relief due to the high A new method wa...The use of landscape covariates to variability of soil properties in similar estimate soil properties is not suitable topographic and vegetation conditions. for the areas of low relief due to the high A new method was implemented to map regional soil texture (in terms of sand, silt and clay contents) by hypothesizing that the change in the land surface diurnal temperature difference (DTD) is related to soil texture in case of a relatively homogeneous rainfall input. To examine this hypothesis, the DTDs from moderate resolution imagine spectroradiometer (MODIS) during a selected time period, i.e., after a heavy rainfall between autumn harvest and autumn sowing, were classified using fuzzy-c-means (FCM) clustering. Six classes were generated, and for each class, the sand (〉 0.05 mm), silt (0.002-0.05 mm) and clay (〈 0.002 mm) contents at the location of maximum membership value were considered as the typical values of that class. A weighted average model was then used to digitally map soil texture. The results showed that the predicted map quite accurately reflected the regional soil variation. A validation dataset produced estimates of error for the predicted maps of sand, silt and clay contents at root mean of squared error values of 8.4%, 7.8% and 2.3%, respectively, which is satisfactory in a practical context. This study thus provided a methodology that can help improve the accuracy and efficiency of soil texture mapping in plain areas using easily available data sources.展开更多
There is a certain degree of ambiguity associated with remote sensing as a means of performing earth observations.Using interval-valued data to describe clustering prototype features may be more suitable for handling ...There is a certain degree of ambiguity associated with remote sensing as a means of performing earth observations.Using interval-valued data to describe clustering prototype features may be more suitable for handling the fuzzy nature of remote sensing data,which is caused by the uncertainty and heterogeneity in the surface spectral reflectance of ground objects.After constructing a multi-spectral interval-valued model of source data and defining a distance measure to achieve the maximum dissimilarity between intervals,an interval-valued fuzzy c-means(FCM)clustering algorithm that considers both the functional characteristics of fuzzy clustering algorithms and the interregional features of ground object spectral reflectance was applied in this study.Such a process can significantly improve the clustering effect;specifically,the process can reduce the synonym spectrum phenomenon and the misclassification caused by the overlap of spectral features between classes of clustering results.Clustering analysis experiments aimed at land cover classification using remote sensing imagery from the SPOT-5 satellite sensor for the Pearl River Delta region,China,and the TM sensor for Yushu,Qinghai,China,were conducted,as well as experiments involving the conventional FCM algorithm,the results of which were used for comparative analysis.Next,a supervised classification method was used to validate the clustering results.The final results indicate that the proposed interval-valued FCM clustering is more effective than the conventional FCM clustering method for land cover classification using multi-spectral remote sensing imagery.展开更多
Remote sensing based land cover mapping at large scale is time consuming when using either supervised or unsupervised clas- sification approaches. This article used a fast clustering method---Clustering by Eigen Space...Remote sensing based land cover mapping at large scale is time consuming when using either supervised or unsupervised clas- sification approaches. This article used a fast clustering method---Clustering by Eigen Space Transformation (CBEST) to pro- duce a land cover map for China. Firstly, 508 Landsat TM scenes were collected and processed. Then, TM images were clus- tered by combining CBEST and K-means in each pre-defined ecological zone (50 in total for China). Finally, the obtained clusters were visually interpreted as land cover types to complete a land cover map. Accuracy evaluation using 2159 test sam- pies indicates an overall accuracy of 71.7% and a Kappa coefficient of 0.64. Comparisons with two global land cover products (i.e., Finer Resolution Observation and Monitoring of Global Land Cover (FROM-GLC) and GlobCover 2009) also indicate that our land cover result using CBEST is superior in both land cover area estimation and visual effect for different land cover types.展开更多
Geopolymer is produced through the polymerization of active aluminosilicate material with an alkaline activator,leading to the formation of a green,inorganic polymer binder.Geopolymer concrete(GPC)has become a promisi...Geopolymer is produced through the polymerization of active aluminosilicate material with an alkaline activator,leading to the formation of a green,inorganic polymer binder.Geopolymer concrete(GPC)has become a promising low-carbon alternative to traditional Portland cement-based concrete(OPC).GPC-bonded reinforcing bars offer a promising alternative for concrete structures,boasting excellent geopolymer binder/reinforcement bonding and superior corrosion and high-temperature resistance compared to Portland cement.However,due to differences in the production process of GPC,there are distinct engineering property variations,including bonding characteristics.This literature review provides an examination of the manufacturing procedures of GPC,encompassing source materials,mix design,curing regimes,and other factors directly influencing concrete properties.Additionally,it delves into the bond mechanism,bond tests,and corresponding results that represent the bond characteristics.The main conclusions are that GPC generally has superior mechanical properties and bond performance compared to ordinary Portland cement concrete(OPC).However,proper standardization is needed for its production and performance tests to limit the contradictory results in the lab and on site.展开更多
This study evaluated the morphological characteristics and dynamic variation in characteristics of soil crust and iden-tified the relationships between soil crust and splash erosion under simulated rainfall.The effect...This study evaluated the morphological characteristics and dynamic variation in characteristics of soil crust and iden-tified the relationships between soil crust and splash erosion under simulated rainfall.The effect of polyacrylamide (PAM) on soil aggregate stabilization and crust formation was also investigated.A laboratory rainfall simulation experiment was carried out using soil sample slices.The slices were examined under a polarized light microscopy and a scanning electron microscope (SEM).The results revealed that the soil crusts were thin and were characterized by a greater density,higher shear strength,finer porosity,and lower saturated hydraulic conductivity than the underlying soil.Two types of crusts,i.e.,structural and depositional crusts,were observed.Soil texture was determined to be the most important soil variable influ-encing surface crust formation;depositional crust formation was primarily related to the skeleton characteristics of the soil and happened when the soil contained a high level of medium and large aggregates.The crust formation processes observed were as follows:1) The fine particles on the soil surface became spattered,leached,and then rough in response to raindrop impact and 2) the fine particles were washed into the subsoil pores while a compact dense layer concurrently formed at soil surface due to the continual compaction by the raindrops.Therefore,the factors that influenced structural crust formation were a large amount of fine particles in the soil surface,continual impact of raindrops,dispersion of aggregates into fine particles,and the formation of a compact dense layer concurrently at the soil surface.It was concluded that the most important factor in the formation of soil crusts was raindrop impact.When polyacrylamide (PAM) was applied,it restored the soil structure and greatly increased soil aggregate stabilization.This effectively prevented crust formation.However,this function of PAM was not continuously effective and the crust reformed with long-term rainfall.In conclusion,this study showed that soil micromorphological studies were a useful method for evaluating soil crust formation.展开更多
Soil harbors remarkably stabilize bacterial communities at the phylum level. However, no two soils have exactly the same structure of bacterial phyla. The structure of microbial community is strongly influenced by the...Soil harbors remarkably stabilize bacterial communities at the phylum level. However, no two soils have exactly the same structure of bacterial phyla. The structure of microbial community is strongly influenced by the type of land-use through changes in soil attributes. Using high-throughput pyrosequencing and quantitative polymerase chain reaction techniques, soil microbial community structures were investigated along a land-use gradient of 100- and 27-year farmlands, a 33-year Pinus forest, a 28-year poplar forest, and a 21-year shrubland, as well as a native desert from which all cultivated systems were converted. The results revealed that the dominant phylotypes in the native soil comprised primarily of Alphaproteobacteria, Actinobacteria, Bacteroidetes, and Firmicutes, accounting for 〉 71.4% of the total bacterial 16S rRNA sequence reads. Changes in land-use led to a significant decrease in these dominant phylotypes down to 33.4%. In contrast, the phylotypes with low abundance, such as Acidobaeteria, Chloroflexi, Nitrospira, and Gammaproteobaeteria, increased sharply from 4.5%-5.9% in the native soil to 20.9% 30.2% of the total 16S rRNA gene sequences in the cultivated soils except for the soil from the shrubland. These contrasting changes in the major taxa appear to be correlated with the changes in soil attributes. For instance, bacterial and archaeal amoA genes were found to be 960- and 3 800-fold more abundant in the soil from the 100-year farmland than the native soil. The changes in numerically less dominant nitrifying phylotypes are consistent with soil inorganic nitrogen dynamics. Quantification of the 16S rRNA genes demonstrated that bacteria and archaea were about two to three orders of magnitude more abundant in the cultivated soil than in the native soil. Hence, land-use type affects the soil bacterial community structure, which has profound consequences on ecosystem function.展开更多
The Taihu Lake region in East China has become prone to soil acidification, which changes heavy metals such as copper(Cu) in soil into water-soluble species and increases the mobility and contamination risks of heavy ...The Taihu Lake region in East China has become prone to soil acidification, which changes heavy metals such as copper(Cu) in soil into water-soluble species and increases the mobility and contamination risks of heavy metals in the biological environment. In this study, the kinetics of Cu2+sorption by the bulk soil and the aggregate size fractions of an acidic paddy soil collected from the Taihu Lake region, the effects of temperature on Cu2+sorption, and the p H changes of the solution were investigated by static sorption and magnetic stirring. The aggregate size fractions were prepared by low-energy ultrasonic dispersing and freeze-drying. The total sorption amounts of the bulk soil and the aggregate size fractions for Cu2+followed a descending order of clay > coarse sand > bulk soil > silt> sand, corresponding to those of organic matter content, free iron oxide content, free aluminum oxide content, and cation exchange capacity. The kinetic sorption curves of Cu2+by the bulk soil and the aggregates, which were divided into two stages(rapid and slow sequentially), were well fitted by the first-order equation, the diffusion equation, and the Elovich equation, showing significant correlations(P < 0.05). Specific and non-specific sorption dominated in the fast and slow stages, respectively, and the former was predominant throughout the sorption process. The specific sorption accelerated and the non-specific sorption decelerated with rising temperature. The p H of the solution decreased significantly during the specific sorption and remained unchanged or increased slightly during the non-specific sorption. When the specific sorption terminated, the p H of the solution was minimized nearly simultaneously.The sorption progress of Cu2+by the bulk soil significantly preceded that by the aggregates. Therefore, heavy metal contamination may be another factor reducing soil p H and metal sorption forms should be taken into consideration in studies of mitigating soil heavy metal pollution or determining environmental capacity of heavy metal in soil.展开更多
基金Project(2009CB623201) supported by the National Basic Research Program of ChinaProject(G0510) supported by the Key Laboratory for Refractories and High-temperature Ceramics of Hubei Province, China
文摘Geopolymer-lightweight aggregate refractory concrete (GLARC) was prepared with geopolymer and lightweight aggregate. The mechanical property and heat-resistance (950 ℃) of GLARC were investigated. The effects of size of aggregate and mass ratio of geopolymer to aggregate on mechanical and thermal properties were also studied. The results show that the highest compressive strength of the heated refractory concrete is 43.3 MPa,and the strength loss is only 42%. The mechanical property and heat-resistance are influenced by the thickness of geopolymer covered with aggregate,which can be expressed as the quantity of geopolymer on per surface area of aggregate. In order to show the relationship between the thickness of geopolymer covered with aggregate and the thermal property of concrete,equal thickness model is presented,which provides a reference for the mix design of GLARC. For the haydite sand with size of 1.18-4.75 mm,the best amount of geopolymer per surface area of aggregate should be in the range of 0.300-0.500 mg/mm2.
基金supported by the Research Fund for Commonweal Trades Meteorology (Grant No. GYHY201006039)the Starting fund fordoctoral research of Neijiang Normal University(Grant No.09249)
文摘The stability of soil aggregates and the fractal characteristics of four typical land use types(farmland,grassland,woodland,and bare land) in the Jiangjiagou Ravine(Yunnan,China),a frequent debris flow occurring area,were studied according to the normal mean mass diameter and fractal theory.The present research showed that the stability of the soil aggregates was different for the different land use types.When the soil depth was 0-30 cm,farmland soil formed more aggregates with diameters greater than 0.25 mm,i.e.,the farmland soil was more stable than that of the other three land uses.When the soil depth was 30-45 cm,the order of stability of the soil aggregates was woodland > grassland > farmland > bare land.The fractal dimensions had a significant linear positive correlation with the amount of soil particles with diameters of <0.25 mm,and a significant negative linear correlation with the amount of soil particles with diameters of 0.25-0.5 mm,0.5-1 mm and 1-2 mm.Smaller fractal dimensions of the soil particles correlated with more stable soil aggregates.The fractal dimensions had a positive linear correlation with the soil bulk density and a negative correlation with the concentration of organic matter.These results showed that soil aggregates can be used as a parameter for characterizing the soil structures and properties.According to these results,the soil particle fractal dimensions could not only objectively characterize the stability of the soil structure but also could be used to indicate soil structure and properties.In addition,these results have great significance for the discussion of the comprehensive evaluation of soil.
文摘Soil and water conservation is essential for sustaining food production and for preserving the environment in arid and semi arid lands (ASALs) where conditions for agriculture and other land use systems are often harsh and unpredictable. The ASALs of Algeria are an important source of a variety of non wood forest products like Stipa tenacissima L. plant (esparto grass). This research was conducted to determine the effects of different low concentration (〈 I%) polyacrylaJnide, Stipa tenacissima L. fiber (esparto grass fibers) and its mixtures with the polymer at water retention in arid and semi arid soil. All samples are characterized by infrared spectroscopy, X-ray Diffractometry, thermal analysis TG DSC and scanning electron micrographs (SEM). The results showed that polymer blend in soil could improve better soil physical proprieties decreased evaporation and increase water retention in arid soils compared with application of any other blend at the same concentration. The use of Polyacrylamide-Cellulose blend appears to promise for reducing the labor cost of irrigation at arid and semi-arid soils, and offers safe and environmentally friendly inexpensive materials. The importance of Polyacrylamide-Cellulose blends to alleviate poor physical properties and retain water in these arid regions to sustain plant growth.
基金Project supported by the National Natural Science Foundation of China (Nos. 40701007 and 40571066)the Postdoctoral Science Foundation of China (No. 20060401048)
文摘One approach to apply precision agriculture to optimize crop production and environmental quality is identifying management zones. In this paper,the variables of soil electrical conductivity (EC) data,cotton yield data and normalized differ-ence vegetation index (NDVI) data in an about 15 ha field in a coastal saline land were selected as data resources,and their spatial variabilities were firstly analyzed and spatial distribution maps constructed with geostatistics technique. Then fuzzy c-means clustering algorithm was used to define management zones,fuzzy performance index (FPI) and normalized classification entropy (NCE) were used to determine the optimal cluster numbers. Finally one-way variance analysis was performed on 224 georefer-enced soil and yield sampling points to assess how well the defined management zones reflected the soil properties and produc-tivity level. The results reveal that the optimal number of management zones for the present study area was 3 and the defined management zones provided a better description of soil properties and yield variation. Statistical analyses indicate significant differences between the chemical properties of soil samples and crop yield in each management zone,and management zone 3 presented the highest nutrient level and potential crop productivity,whereas management zone 1 the lowest. Based on these findings,we conclude that fuzzy c-means clustering approach can be used to delineate management zones by using the given three variables in the coastal saline soils,and the defined management zones form an objective basis for targeting soil samples for nutrient analysis and development of site-specific application strategies.
文摘Reuse of concrete waste, especially in large quantity, can save not only material but also cost for its disposal. This paper presents experiment results on the use of fine and coarse aggregates from concrete waste in geopolymer mortars and concretes. Geopolymeric cement is an inorganic compounds of aluminosilicates synthesized from precursors with high content of silica and alumina activated by alkali silicate solutions. Geopolymer in this experiment was synthesized from fly ash as the precursor and sodium silicate solution as the activator. Hardening of geopolymers was performed by heating the casted paste in an oven at -60~Cfor 3 to 36 hours. Compressive strength of geopolymer pastes and mortars using either fresh or waste fine aggregates were in the range of 19-26 MPa. Hardening time of 3 hours at 60~C followed by leaving the test pieces at room temperature for 7 day before testing results in similar strength to that of mortars cured for 36 hours at 60~C followed by leaving the samples at room temperature for 3 days. It suggests that optimum strength can be achieved by combination of heating time and rest period before testing, i.e the specimens age. Applying mix design with a target strength of 40 MPa, conventional Portland cement concretes using fresh aggregates reached 70% of its target strength at day-7. Compressive strength of geopolymer concretes with waste aggregates was -25 MPa at day-3 while geopolymer concretes with fresh aggregates achieved -39 MPa at day-3. It can be concluded that geopolymer concretes can achieve the target strength in only 3 days. However, the expected reinforcing effect of coarse aggregates in concrete was ineffective if waste coarse aggregates were used as the strength of the concretes did not increase significantly from that of the mortars. On the other hand, waste fine aggregates can be reused for making geopolymer mortars having the same strength as the geopolymer mortars using fresh aggregates.
基金Chinese R&D Program of "Development of a comprehensive monitoring and evaluation system for ecological compensation of typical ecologically vulnerable regions of China (2006BAC08B06)"National Science Fund for Distinguished Young Scholars (40788001)One Hundred Talents Program of the Chinese Academy of Sciences
文摘In many regions both urban expansion and rural development take place simultaneously, and for the purpose of understanding the dynamic process of land use/cover change (LUCC) in such large areas, this study develops a multi-agent based land use model. Taking the Poyang Lake area of China as a typical case, this study applies the mechanism of diffusion-limited aggregation to simulate the behavior of urban agents, while rural land use is illustrated with a bottom-up based model consisting of agent and environment layers. In the agent layer, each household agent makes its own decisions on land use, and at each time interval a government agent takes control of land use by implementing policies. According to incomes and the rate of migrant workers, household agents are divided into six categories, among which different decision rules are followed. For complex LUCC in the Poyang Lake area of China from 1985 to 2005, the artificial society model developed in this study yields results highly consistent with observations. Importantly, it is shown that governmental policies can impose significant effects on the decisions of individual household agents on land use and the multi-agent-based land use model developed in this study provides a robust means for assessing the effectiveness of governmental policies.
基金the research fellowship granted by the Department of Biotechnology,Government of India,in the form of Overseas Associateship(No. BT/20/NE/2011/2014)
文摘Promoting soil carbon sequestration in agricultural land is one of the viable strategies to decelerate the observed climate changes. However, soil physical disturbances have aggravated the soil degradation process by accelerating erosion. Thus, reducing the magnitude and intensity of soil physical disturbance through appropriate farming/agricultural systems is essential to management of soil carbon sink capacity of agricultural lands. Four sites of different land use types/tillage practices, i) no-till (NT) corn (Zea mays L.) (NTC), ii) conventional till (CT) corn (CTC), iii) pastureland (PL), and iv) native forest (NF), were selected at the North Appalachian Experimental Watershed Station, Ohio, USA to assess the impact of NT farming on soil aggregate indices including water-stable aggregation, mean weight diameter (MWD) and geometric mean diameter (GMD), and soil organic carbon and total nitrogen contents. The NTC plots received cow manure additions (about 15 t ha-1) every other year. The CTC plots involved disking and chisel ploughing and liquid fertilizer application (110 L ha-l). The results showed that both water-stable aggregation and MWD were greater in soil for NTC than for CTC. In the 0-10 cm soil layer, the 〉 4.75-mm size fraction dominated NTC and was 46% more than that for CTC, whereas the 〈 0.25-mm size fraction was 380% more for CTC than for NTC. The values of both MWD and GMD in soil for NTC (2.17 mm and 1.19 mm, respectively) were higher than those for CTC (1.47 and 0.72 mm, respectively) in the 0-10 cm soil layer. Macroaggregates contained 6%-42% and 13%-43% higher organic carbon and total nitrogen contents, respectively, than microaggregates in soil for all sites. Macroaggregates in soil for NTC contained 40% more organic carbon and total nitrogen over microaggregates in soil for CTC. Therefore, a higher proportion of microaggregates with lower organic carbon contents created a carbon-depleted environment for CTC. In contrast, soil for NTC had more aggregation and contained higher organic carbon content within water-stable aggregates. The soil organic carbon and total nitrogen stocks (Mg ha-1) among the different sites followed the trend of NF 〉 PL 〉 NTC 〉 CTC, being 35%-46% more for NTC over CTC. The NT practice enhanced soil organic carbon content over the CT practice and thus was an important strategy of carbon sequestration in cropland soils.
基金Supported by the National Natural Science Foundation of China(No.30971869)
文摘The size distribution of water-stable aggregates and the variability of organic C,N and P contents over aggregate size fractions were studied for orchard,upland,paddy,and grassland soils with high,medium,and low fertility levels.The results showed that > 5 mm aggregates in the cultivated upland and paddy soils were 44.0% and 32.0%,respectively,less than those in the un-tilled orchard soil.Organic C and soil N in different size aggregate fractions in orchard soil with high fertility were significantly higher than those of other land uses.However,the contents of soil P in different size aggregates were significantly greater in the paddy soil as compared to the other land uses.Soil organic C,N and P contents were higher in larger aggregates than those in smaller ones.The amount of water-stable aggregates was positively correlated to their contribution to soil organic C,N and P.For orchard and grassland soils,the > 5 mm aggregates made the greatest contribution to soil nutrients,while for upland soil,the 0.25-0.053 mm aggregates contributed the most to soil nutrients.Therefore,the land use with minimum disturbance was beneficial for the formation of a better soil structure.The dominant soil aggregates in different land use types determined the distribution of soil nutrients.Utilization efficiency of soil P could be improved by converting other land uses to the paddy soil.
基金supported by the National Natural Science Foundation of China (Nos. 41471178, 41530749, and 41431177)the State Key Laboratory of Soil and Sustainable Agriculture, China (No. Y052010002)+2 种基金the Natural Science Research Program of Jiangsu, China (No. 14KJA170001)the National Key Technology Innovation Project for Water Pollution Control and Remediation, China (No. 2013ZX07103006)the National Basic Research Program (973 Program) of China (No. 2015CB954102)
文摘High-resolution and detailed regional soil spatial distribution information is increasingly needed for ecological modeling and land resource management. For areas with no point data, regional soil mapping includes two steps: soil sampling and soil mapping. Because sampling over a large area is costly, efficient sampling strategies are required. A multi-grade representative sampling strategy, which designs a small number of representative samples with different representative grades to depict soil spatial variations at different scales, could be a potentially efficient sampling strategy for regional soil mapping. Additionally, a suitable soil mapping approach is needed to map regional soil variations based on a small number of samples. In this study, the multi-grade representative sampling strategy was applied and a fuzzy membership-weighted soil mapping approach was developed to map soil sand percentage and soil organic carbon (SOC) at 0-20 and 20-40 cm depths in a study area of 5 900 km2 in Anhui Province of China. First, geographical sub-areas were delineated using a parent lithology data layer. Next, fuzzy c-means clustering was applied to two climate and four terrain variables in each stratum. The clustering results (environmental cluster chains) were used to locate representative samples. Evaluations based on an independent validation sample set showed that the addition of samples with lower representativeness generally led to a decrease of root mean square error (RMSE). The declining rates of RMSE with the addition of samples slowed down for 20-40 cm depth, but fluctuated for 0-20 cm depth. The predicted SOC maps based on the representative samples exhibited higher accuracy, especially for soil depth 20-40 cm, as compared to those based on legacy soil data. Multi-grade representative sampling could be an effective sampling strategy at a regional scale. This sampling strategy, combined with the fuzzy membership-based mapping approach, could be an optional effective framework for regional soil property mapping. A more detailed and accurate soft parent material map and the addition of environmental variables representing human activities would improve mapping accuracy.
基金Supported by the Ministry of Education and Science of Spain (No. SUM2006-00029-C02)
文摘Soil aggregation and organic matter of soils from the pre-Pyrenean range in Catalonia (NE Spain) were studied,in order to assess their quality as carbon sinks and also to select the best soil management practices to preserve their quality.Aggregate stability,organic carbon and micromorphology were investigated.The highest amount of organic carbon was found in alluvial,deep soils (228 Mg C ha -1 ),and the lowest was in a shallow,stony soil with a low plant cover (78 Mg C ha -1 ).Subsurface horizons of degraded soils under pastures were the ones with smaller and less-stable aggregates.Fresh residues of organic matter (OM) were found mostly in interaggregate spaces.Within the aggregates there were some organic remains that were beginning to decompose,and also impregnative nodules of amorphous OM.Although OM was evenly distributed among the aggregate fractions,the larger blocky peds had more specific surface,contained less decomposed OM and had a lower organic/mineral interphase than smaller crumb aggregates,which were also more stable.Soil carbon storage was affected primarily by the OM inputs in the surface horizons.In order to store organic carbon over the mid- and long-term periods,the mechanisms favouring structuration through biological activity and creating small aggregates with intrapedal stable microporosities seemed to be the most effective.
基金Supported by the Basic Research Program of Jiangsu Province,China (No. BK2008058)the Knowledge Innovation Program of Chinese Academy of Sciences (No. KZCX2-YW-409)
文摘The use of landscape covariates to variability of soil properties in similar estimate soil properties is not suitable topographic and vegetation conditions. for the areas of low relief due to the high A new method was implemented to map regional soil texture (in terms of sand, silt and clay contents) by hypothesizing that the change in the land surface diurnal temperature difference (DTD) is related to soil texture in case of a relatively homogeneous rainfall input. To examine this hypothesis, the DTDs from moderate resolution imagine spectroradiometer (MODIS) during a selected time period, i.e., after a heavy rainfall between autumn harvest and autumn sowing, were classified using fuzzy-c-means (FCM) clustering. Six classes were generated, and for each class, the sand (〉 0.05 mm), silt (0.002-0.05 mm) and clay (〈 0.002 mm) contents at the location of maximum membership value were considered as the typical values of that class. A weighted average model was then used to digitally map soil texture. The results showed that the predicted map quite accurately reflected the regional soil variation. A validation dataset produced estimates of error for the predicted maps of sand, silt and clay contents at root mean of squared error values of 8.4%, 7.8% and 2.3%, respectively, which is satisfactory in a practical context. This study thus provided a methodology that can help improve the accuracy and efficiency of soil texture mapping in plain areas using easily available data sources.
基金supported by the National Natural Science Foundation of China(Grant Nos.41272359&11001019)the Specialized Research Fund for the Doctoral Program of Higher Education(SRFDP)the Fundamental Research Funds for the Central Universities
文摘There is a certain degree of ambiguity associated with remote sensing as a means of performing earth observations.Using interval-valued data to describe clustering prototype features may be more suitable for handling the fuzzy nature of remote sensing data,which is caused by the uncertainty and heterogeneity in the surface spectral reflectance of ground objects.After constructing a multi-spectral interval-valued model of source data and defining a distance measure to achieve the maximum dissimilarity between intervals,an interval-valued fuzzy c-means(FCM)clustering algorithm that considers both the functional characteristics of fuzzy clustering algorithms and the interregional features of ground object spectral reflectance was applied in this study.Such a process can significantly improve the clustering effect;specifically,the process can reduce the synonym spectrum phenomenon and the misclassification caused by the overlap of spectral features between classes of clustering results.Clustering analysis experiments aimed at land cover classification using remote sensing imagery from the SPOT-5 satellite sensor for the Pearl River Delta region,China,and the TM sensor for Yushu,Qinghai,China,were conducted,as well as experiments involving the conventional FCM algorithm,the results of which were used for comparative analysis.Next,a supervised classification method was used to validate the clustering results.The final results indicate that the proposed interval-valued FCM clustering is more effective than the conventional FCM clustering method for land cover classification using multi-spectral remote sensing imagery.
基金partially supported by the National High-tech R&D Program of China(Grant No.2009AA12200101)a research grant from Tsinghua University(Grant No.2012Z02287)
文摘Remote sensing based land cover mapping at large scale is time consuming when using either supervised or unsupervised clas- sification approaches. This article used a fast clustering method---Clustering by Eigen Space Transformation (CBEST) to pro- duce a land cover map for China. Firstly, 508 Landsat TM scenes were collected and processed. Then, TM images were clus- tered by combining CBEST and K-means in each pre-defined ecological zone (50 in total for China). Finally, the obtained clusters were visually interpreted as land cover types to complete a land cover map. Accuracy evaluation using 2159 test sam- pies indicates an overall accuracy of 71.7% and a Kappa coefficient of 0.64. Comparisons with two global land cover products (i.e., Finer Resolution Observation and Monitoring of Global Land Cover (FROM-GLC) and GlobCover 2009) also indicate that our land cover result using CBEST is superior in both land cover area estimation and visual effect for different land cover types.
基金supported by the ongoing projects provided by the National Key Research and Development Program(2021YFB2600704)the National Natural Science Foundation of China(52108223,U22A20244)+3 种基金the Outstanding Youth Fund of Shandong Province(ZR2021JQ17)the Natural Science Foundation of Shandong Province(ZR2020QE249)the 111 Project(D16006)the First-Class Discipline Project funded by the Education Department of Shandong Province are gratefully acknowledged.
文摘Geopolymer is produced through the polymerization of active aluminosilicate material with an alkaline activator,leading to the formation of a green,inorganic polymer binder.Geopolymer concrete(GPC)has become a promising low-carbon alternative to traditional Portland cement-based concrete(OPC).GPC-bonded reinforcing bars offer a promising alternative for concrete structures,boasting excellent geopolymer binder/reinforcement bonding and superior corrosion and high-temperature resistance compared to Portland cement.However,due to differences in the production process of GPC,there are distinct engineering property variations,including bonding characteristics.This literature review provides an examination of the manufacturing procedures of GPC,encompassing source materials,mix design,curing regimes,and other factors directly influencing concrete properties.Additionally,it delves into the bond mechanism,bond tests,and corresponding results that represent the bond characteristics.The main conclusions are that GPC generally has superior mechanical properties and bond performance compared to ordinary Portland cement concrete(OPC).However,proper standardization is needed for its production and performance tests to limit the contradictory results in the lab and on site.
基金Supported by the National Natural Science Foundation of China (NSFC) (No. 41101019)the Fundamental Research Funds for the Central Universities of Chinathe State Key Laboratory of Earth Surface Processes and Resource Ecology of China (No. 2011-KF-09)
文摘This study evaluated the morphological characteristics and dynamic variation in characteristics of soil crust and iden-tified the relationships between soil crust and splash erosion under simulated rainfall.The effect of polyacrylamide (PAM) on soil aggregate stabilization and crust formation was also investigated.A laboratory rainfall simulation experiment was carried out using soil sample slices.The slices were examined under a polarized light microscopy and a scanning electron microscope (SEM).The results revealed that the soil crusts were thin and were characterized by a greater density,higher shear strength,finer porosity,and lower saturated hydraulic conductivity than the underlying soil.Two types of crusts,i.e.,structural and depositional crusts,were observed.Soil texture was determined to be the most important soil variable influ-encing surface crust formation;depositional crust formation was primarily related to the skeleton characteristics of the soil and happened when the soil contained a high level of medium and large aggregates.The crust formation processes observed were as follows:1) The fine particles on the soil surface became spattered,leached,and then rough in response to raindrop impact and 2) the fine particles were washed into the subsoil pores while a compact dense layer concurrently formed at soil surface due to the continual compaction by the raindrops.Therefore,the factors that influenced structural crust formation were a large amount of fine particles in the soil surface,continual impact of raindrops,dispersion of aggregates into fine particles,and the formation of a compact dense layer concurrently at the soil surface.It was concluded that the most important factor in the formation of soil crusts was raindrop impact.When polyacrylamide (PAM) was applied,it restored the soil structure and greatly increased soil aggregate stabilization.This effectively prevented crust formation.However,this function of PAM was not continuously effective and the crust reformed with long-term rainfall.In conclusion,this study showed that soil micromorphological studies were a useful method for evaluating soil crust formation.
基金Supported by the National Natural Science Foundation of China (No.91025021)the Knowledge Innovation Programs of the Chinese Academy of Sciences (Nos.KSCX2-EW-G-16-02 and KSCX2-YW-G-074-02)the E-Science Program of the Chinese Academy of Sciences (No.INFO-115-D01-Z006)
文摘Soil harbors remarkably stabilize bacterial communities at the phylum level. However, no two soils have exactly the same structure of bacterial phyla. The structure of microbial community is strongly influenced by the type of land-use through changes in soil attributes. Using high-throughput pyrosequencing and quantitative polymerase chain reaction techniques, soil microbial community structures were investigated along a land-use gradient of 100- and 27-year farmlands, a 33-year Pinus forest, a 28-year poplar forest, and a 21-year shrubland, as well as a native desert from which all cultivated systems were converted. The results revealed that the dominant phylotypes in the native soil comprised primarily of Alphaproteobacteria, Actinobacteria, Bacteroidetes, and Firmicutes, accounting for 〉 71.4% of the total bacterial 16S rRNA sequence reads. Changes in land-use led to a significant decrease in these dominant phylotypes down to 33.4%. In contrast, the phylotypes with low abundance, such as Acidobaeteria, Chloroflexi, Nitrospira, and Gammaproteobaeteria, increased sharply from 4.5%-5.9% in the native soil to 20.9% 30.2% of the total 16S rRNA gene sequences in the cultivated soils except for the soil from the shrubland. These contrasting changes in the major taxa appear to be correlated with the changes in soil attributes. For instance, bacterial and archaeal amoA genes were found to be 960- and 3 800-fold more abundant in the soil from the 100-year farmland than the native soil. The changes in numerically less dominant nitrifying phylotypes are consistent with soil inorganic nitrogen dynamics. Quantification of the 16S rRNA genes demonstrated that bacteria and archaea were about two to three orders of magnitude more abundant in the cultivated soil than in the native soil. Hence, land-use type affects the soil bacterial community structure, which has profound consequences on ecosystem function.
基金the Science and Technology Support Project of Jiangsu Province(Project No.BE2013711)for financially supporting this study
文摘The Taihu Lake region in East China has become prone to soil acidification, which changes heavy metals such as copper(Cu) in soil into water-soluble species and increases the mobility and contamination risks of heavy metals in the biological environment. In this study, the kinetics of Cu2+sorption by the bulk soil and the aggregate size fractions of an acidic paddy soil collected from the Taihu Lake region, the effects of temperature on Cu2+sorption, and the p H changes of the solution were investigated by static sorption and magnetic stirring. The aggregate size fractions were prepared by low-energy ultrasonic dispersing and freeze-drying. The total sorption amounts of the bulk soil and the aggregate size fractions for Cu2+followed a descending order of clay > coarse sand > bulk soil > silt> sand, corresponding to those of organic matter content, free iron oxide content, free aluminum oxide content, and cation exchange capacity. The kinetic sorption curves of Cu2+by the bulk soil and the aggregates, which were divided into two stages(rapid and slow sequentially), were well fitted by the first-order equation, the diffusion equation, and the Elovich equation, showing significant correlations(P < 0.05). Specific and non-specific sorption dominated in the fast and slow stages, respectively, and the former was predominant throughout the sorption process. The specific sorption accelerated and the non-specific sorption decelerated with rising temperature. The p H of the solution decreased significantly during the specific sorption and remained unchanged or increased slightly during the non-specific sorption. When the specific sorption terminated, the p H of the solution was minimized nearly simultaneously.The sorption progress of Cu2+by the bulk soil significantly preceded that by the aggregates. Therefore, heavy metal contamination may be another factor reducing soil p H and metal sorption forms should be taken into consideration in studies of mitigating soil heavy metal pollution or determining environmental capacity of heavy metal in soil.