迟到131年的证明:普适时间反演不变性禁止任何可逆性

指出并纠正了物理学中关于时间反演的科学观念问题上的错误。根据物理学中的时间反演的定义,经过严格数学逻辑推理证明并应用了图示加以说明;证明了任何物理过程的时间反演过程是原过程的空间图像本身。还证明了所有物理理论都具有时间反演不变性,即在物理学中,时间反演不变性是普适的。物理理论的时间反演不变性不表示以往理论所认为的是过程的可逆性。同时指出,历来把物理过程的时间反演过程看作原过程的逆过程,并解释为原过程电影的倒映是错误的。历来把时间反演不变性看作过程的可逆性也是完全错误的。物理学中不存在由时间反演导致的可逆性。由此消除了物理学中如"可逆佯谬"这样的矛盾,使物理学变得完美和统一。最后解释了时间反演的物理图像,指出了时间反演变换的物理意义。

第二语言学习过程的认知研究

第二语言学习是有关外语学习的一个重要理论,也是语言学界反复深入讨论的一个热门话题。在这个问题上出现了许多不同的理论,其中比较流行的有"整体论假说"和"补缺假说"。这两个假说对第二语言学习有很好的指导意义,但也不够完善。由于第二语言学习涉及到一种文化系统进入另一种文化系统的问题,所以第二语言学习的过程是儿童学习母语过程的"逆过程"。

Inverse procedure for determining model parameter of soils using real-coded genetic algorithm

The hybrid genetic algorithm is utilized to facilitate model parameter estimation.The tri-dimensional compression tests of soil are performed to supply experimental data for identifying nonlinear constitutive model of soil.In order to save computing time during parameter inversion,a new procedure to compute the calculated strains is presented by multi-linear simplification approach instead of finite element method(FEM).The real-coded hybrid genetic algorithm is developed by combining normal genetic algorithm with gradient-based optimization algorithm.The numerical and experimental results for conditioned soil are compared.The forecast strains based on identified nonlinear constitutive model of soil agree well with observed ones.The effectiveness and accuracy of proposed parameter estimation approach are validated.

Component content distribution profile control in rare earth countercurrent extraction process

Considering that the on-line measurement and automatic control of element component content(ECC) are difficult to perform in rare earth cascade extraction process, the ECC distribution profile is dynamically regulated at all stages to assess the effect of product purity control. Focusing on the theory of countercurrent extraction, the technology parameters and pre-setting flow-rates during the extract process are designed. Under varying process parameters, a novel step by step model is also proposed for each stage to analyze the impact on the distribution profile change. Combining the mass balance model and ECC changing trend at the monitoring stage, the ECC distribution profile can be automatically regulated by dynamically compensating the related extract or scrubbing liquid flow-rate. To this end, the required product purity at the two outlets is achieved. Based on Wincc and Matlab dynamic simulators, a specific Pr/Nd cascade extraction process is used to illustrate and demonstrate the application of the present approach.

A novel method based on entransy theory for setting energy targets of heat exchanger network

A T-Q diagram based on entransy theory is applied to graphically and quantitatively describe the irreversibility of the heat transfer processes.The hot and cold composite curves can be obtained in the T-Q diagram.The entransy recovery and entransy dissipation that are affected by temperature differences can be obtained through the shaded area under the composite curves.The method for setting the energy target of the HENs in T-Q diagram based on entransy theory is proposed.A case study of the diesel oil hydrogenation unit is used to illustrate the application of the method.The results show that three different heat transfer temperature differences is 10 K,15 K and 20 K,and the entransy recovery is 5.498×10~7k W·K,5.377×10~7k W·K,5.257×10~7k W·K,respectively.And the entransy transfer efficiency is 92.29%,91.63%,90.99%.Thus,the energy-saving potential of the HENs is obtained by setting the energy target based on the entransy transfer efficiency.

Application of orthogonal experimental design and Tikhonov regularization method for the identification of parameters in the casting solidification process

The inverse heat conduction method is one of methods to identify the casting simulation parameters. A new inverse method was presented according to the Tikhonov regularization theory. One appropriate regularized functional was established, and the functional was solved by the sensitivity coefficient and Newtonaphson iteration method. Moreover, the orthogonal experimental design was used to estimate the appropriate initial value and variation domain of each variable to decrease the number of iteration and improve the identification accuracy and efficiency. It illustrated a detailed case of AlSiTMg sand mold casting and the temperature measurement experiment was done. The physical properties of sand mold and the interracial heat transfer coefficient were identified at the meantime. The results indicated that the new regularization method was efficient in overcoming the ill-posedness of the inverse heat conduction problem and improving the stability and accuracy of the solutions.

Estimation of Separation of Electrolytes and Organic Compounds by Nanofiltration Membranes Using an Irreversible Thermodynamic Modei

Nanofiltration separation has become a popular technique for removing largeorganic molecules and inorganic substances from water. It is achieved by a combination of threemechanisms: electrostatic repulsion, sieving and diffusion. In the present work, a model based onirreversible thermodynamics is extended and used to estimate rejection of inorganic salts andorganic substances. Binary systems are modeled, where the feed contains an ion that is much lesspermeable to the membrane as compared with the other ion. The two model parameters are estimated byfitting the model to the experimental data. Variation of these parameters with the composition ofthe feed is described by an empirical correlation. This work attempts to describe transport throughthe nanofiltration membranes by a simple model.

The Saturation Model and Its Application on Partition Equilibria for Main Types of Heterogeneous Systems

Within the model, a definition of novel saturation and dilution degree is presented. A novel expression of equilibrium constant is derived by including interactions between components to reversible processes running between the components particles under a dynamic equilibrium. For partition equilibria, three types of basic processes are proposed and corresponding partition isotherms were derived. The isotherms are applied to the components partition between two phases for main heterogenous systems types. For construction and prediction ternary phase diagrams, a new method, the Component Binding by Saturation Model （CBSM） method, is proposed. Applying the partition isotherms derived, new extraction, evaporation and adsorption isotherms are expressed. Directly, or after an approximation, from the new adsorption isotherms, well-known adsorption isotherms are obtained.

Converse Result on Szász-Type Operators

Szasz-type operators can be constructed by a Poisson process. The purpose of this paper is to derive the converse result in connection with Szasz-type operators by Steckin-Marchaud-type inequalities and new Ditzian modulus of continuity. The degree of approximation on deterministic signals is also given.

Multi-objective Optimization of Controller for Process with Reverse Response and Dead Time

Due to the difficulty of controlling the process with inverse response and dead time,a Multi-objective Optimization based on Genetic Algorithm (MOGA) method for tuning of proportional-integral-derivative (PID) controller is proposed. The settings of the controller are valued by two criteria,the error between output and reference signals and control moves. An appropriate set of Pareto optimal setting of the PID controller is founded by analyzing the results of Pareto optimal surfaces for balancing the two criteria. A high order process with inverse response and dead time is used to illustrate the results of the proposed method. And the efficiency and robustness of the tuning method are evident compared with methods in recent literature.

Embodied coefficient of energy carriers and its calculation method

To quantify the energy consumption in the process of production, transportation and processing of energy carriers, the life cycle of building energy used can be divided into two phases： on-site phase and embodied phase. As for the embodied phase, with the data in existing statistic yearbook, the consumption items of energy production and transportation were investigated. And based on the life cycle theory, an embodied coefficient of energy carriers was proposed to quantify the embodied energy consumption. Moreover, a calculation method for the embodied coefficient of energy carriers was deduced using Leontief inverse matrix based on the existing data sources. With relevant data of 2005-2007 in China, the embodied coefficients in 2005-2007 were obtained, in which the values for natural gas and thermal power are around 1.3 and 3. l, respectively; while they are 1.03-1.08 for other selected energy carriers. In addition, it is also found that the consumption in the production and processing accounts for more than 75%.

Cu_2O nanowires as anode materials for Li-ion rechargeable batteries

Li-ion batteries are a key technology for multiple clean energy applications.In this study,Cu2O nanowires were obtained by the reduction of cupric acetate with pyrrole.The resulting Cu2O nanowires exhibited excellent reversible capacities of 470mAh g-1 at rate of 1 C after 100 cycles.The results show that the Cu2O nanowires had more capacity than materials previously reported.No fading was observed over 100 cycles of charging and discharging.The compound metal Cu and incorporation of the conducting polymer polypyrrole(PPy)improved the conductivity of Cu2O and enhanced the stability of the electrode during cycling.The results from this study imply that Cu2O nanowires with high capacity and good cycle retention could be excellent candidates as anode materials for Li-ion rechargeable batteries.

Work entransy and its applications

The entransy theory has been applied to the analyses of heat-work conversion systems. The physical meaning and the applications of work entransy are analyzed and discussed in this paper. Work entransy, which is clarified to be a process dependent quantity, is not the entransy of work, but the system entransy change accompanying work transfer. The relationship between the work entransy and the output work is set up. When the application preconditions are satisfied, larger work entransy leads to larger output work. Entransy loss, which was proposed and applied to heat work conversion processes with irreversible heat transfer, is the net entransy flow into the system and the summation of work entransy and entransy dissipation. The application preconditions of entransy loss are also discussed.

Combustion Irreversibilities: Numerical Simulation and Analysis

An exergy analysis was performed considering the combustion of methane and agro-industrial residues produced in Portugal (forest residues and vines pruning). Regarding that the irreversibilities of a thermodynamic process are path dependent, the combustion process was considering as resulting from different hypothetical paths each one characterized by four main sub-processes: reactant mixing, fuel oxidation, internal thermal energy exchange (heat transfer), and product mixing. The exergetic efficiency was computed using a zero dimensional model developed by using a Visual Basic home code. It was concluded that the exergy losses were mainly due to the internal thermal energy exchange sub-process. The exergy losses from this sub-process are higher when the reactants are preheated up to the ignition temperature without previous fuel oxidation. On the other hand, the global exergy destruction can be minored increasing the pressure, the reactants temperature and the oxygen content on the oxidant stream. This methodology allows the identification of the phenomena and processes that have larger exergy losses, the understanding of why these losses occur and how the exergy changes with the parameters associated to each system which is crucial to implement the syngas combustion from biomass products as a competitive technology.