人大代表直接选举“间接化”问题的生成与矫治方略——基于县乡人大代表换届选举实践的分析

县乡人大代表直接选举"间接化"现象,在近年来的基层人大代表选举中愈益增多,其主要表现为委托投票失范且不断增加、不当投票数和弃权票增加趋势明显。这导致了选举基本原则无法充分落实、无法充分表达民意、加剧选民的政治冷漠症、助长不良风气、影响选举的合法性,使选举结果有失公平。为有效遏制直接选举"间接化"现象,必须注重提升选民权利意识,完善法律法规,健全竞争机制,并运用先进技术使选举活动健康高效进行。

Synthesis of nitrocarbazole compounds and their electrocatalytic oxidation of alcohol

Three compounds with nitrocarbazole frameworks were synthesized and their electrochemical reversibility as organic electrocatalysts was studied by cyclic voltammetry. The electrochemical reversibility and oxidation‐reduction potential of the compounds were greatly affected by their substituents. The oxidation‐reduction potential of the compound with an electron‐donating group was negative, while that of the compound with an electron‐withdrawing group on the carbazole framework was positive. The electrocatalytic oxidation activities of the nitrocarbazole compounds were investigated through cyclic voltammetry and controlled potential electrolysis at room tem‐perature. The electrocatalysts showed excellent selectivity for p‐methoxybenzyl alcohol, converting it to the corresponding aldehyde through electro‐oxidation with just 2.5 mol%of the electrocata‐lysts presented. The electrocatalysts maintained their excellent electroredox activity following re‐cycling.

Effect of immersion Ni plating on interface microstructure and mechanical properties of Al/Cu bimetal

A nickel-based coating was deposited on the pure Al substrate by immersion plating,and the Al/Cu bimetals were prepared by diffusion bonding in the temperature range of 450-550 ℃.The interce microstructure and fracture surface of Al/Cu joints were studied by scanning electron microscopy（SEM） and X-ray diffraction（XRD）.The mechanical properties of the Al/Cu bimetals were measured by tensile shear and microhardness tests.The results show that the Ni interiayer can effectively eliminate the formation of Al-Cu intermetallic compounds.The Al/Ni interface consists of the Al3Ni and Al3Ni2 phases,while it is Ni-Cu solid solution at the Ni/Cu interce.The tensile shear strength of the joints is improved by the addition of Ni interiayer.The joint with Ni interiayer annealed at 500 ℃ exhibits a maximum value of tensile shear strength of 34.7 MPa.

Influence of electron-beam superposition welding on intermetallic layer of Cu/Ti joint

QCr0.8 was electron-beam welded to TC4 and the effect of the intermetallic layer （IMC-layer） on the mechanical properties of the joint was investigated. The IMC-layers are joint weaknesses at the Cu fusion line in centered welding and at the Ti fusion line when the beam is deviated towards Cu. A new method referred to as electron-beam superposition welding was presented, and the optimal welding sequence was considered. The IMC-layer produced by centered welding was fragmented and remelted during Cu-side non-centered welding, giving a finely structured compound layer and improved mechanical properties of the joint. The tensile strength of joint is 276.0 MPa, 76.7% that of the base metal.

Microstructures and properties of welded joint of aluminum alloy to galvanized steel by Nd:YAG laser + MIG arc hybrid brazing-fusion welding

According to the differences in melting point between aluminum alloy and steel, 6013-T4 aluminum alloy was joined to galvanized steel by large spot Nd：YAG laser ＋ MIG arc hybrid brazing-fusion welding with ER4043（AlSi5） filler wire. The microstructures and mechanical properties of the brazed-fusion welded joint were investigated. The joint is divided into two parts of fusion weld and brazed seam. There is a zinc-rich zone at fusion weld toe, which consists of α（Al）-Zn solid solution and Al-Zn eutectic. The brazed seam is the Fe-Al intermetallic compounds （IMCs） layer of 2-4μm in thickness, and the IMCs include FeAl2, Fe2Al5 and Fe4Al13. FeAl2 and Fe2Al5 are located in the compact reaction layer near the steel side, and Fe4Al13 with tongue shape or sawtooth shape grows towards the fusion weld. The tensile strength of the joint firstly increases and then decreases as the welding current and laser power increase, the highest tensile strength can be up to 247.3 MPa, and the fracture usually occurs at fusion zone of the fusion weld. The hardness is the highest at the brazed seam because of hard Fe-Al IMCs, and gradually decreases along the fusion weld and galvanized steel, respectively.

A Study of ISA in Chinese Cultural Communication

The paper tentatively studies the function of the indirect speech act in Chinese cultural communication, namely, domestic communication. Two aspects are shown in this paper： communication between people of different social status, genders and casual relationships, and communication between people of same social status, genders and close relationships. Therefore, the study result can be concluded like this： whether the use of indirect speech act is successful or not always influences people＇s communication significantly.

Capillary Zone Electrophoresis of Native Amino Acids with Indirect Ultraviolet Detection

Aim To strdy the separation of native amino acids using capillary zone electro- pboresis (CZE) with indirect ultraviolet detecition. Methods 13 native amino acids were sepa- rated by capillary electrophoresis with indirect detection . The experiments were carried out with homemade CE apparatus under the following operating conditior conditions: a fused-silica capillary col- umn of 50.0cm effect length and of 75m i.d. was used. 7 organic acids were used as BGAE, and a positive potential of separation in CZE with indirect detection. After optimizing for l3 native amino acids were established. Conclusion The choice of BGAe is an important factor influencing the efficiency of separation in CZE with indiect detection .After optimizing the separation conditions a baseline separation for 13 native amino acids is obtained.

Indirect Electrochemical Reduction of Indanthrene Brilliant Green FFB

The indirect electrochemical reduction of Indanthrene Brilliant Green FFB （IBG） was investigated in detail by cyclic voltammetry and electrolytic experiments.Triethanolamine （TEA） was used as ligand to form elec-trochemically active Fe（III）-complexes in alkaline solution.The effects of operating parameters including reaction temperature,current density,concentration of NaOH and Fe（III）-TEA mediator had been studied by orthogonal ex-periments and the mechanism of radicals on electrochemical reduction was discussed.The cyclic voltammetry ex-perimental results show that Fe（III）-TEA complexes are well suited for the indirect electrochemical reduction of IBG.The electrolytic experiments show that high current efficiency （49.9%） can be successfully achieved under op-timized conditions and the current density is found to be the main influence factor.

Effect of postweld heat treatment on interface microstructure and metallurgical properties of explosively welded bronze–carbon steel

The effects of postweld heat treatment on the microstructure and metallurgical properties of a bronze–carbon steel(st37)explosively bonded interface were studied.Explosive welding was done under 1.5-and 2-mm standoff distances and different conditions of explosive charge.Samples were postweld heat treated for 4 and 16 h in the furnace at 250°C and 500°C and then air cooled.Laboratory studies using optical microscopy,scanning electron microscopy,and microhardness testing were used to evaluate the welded samples.Microstructural examinations showed that by increasing the standoff distance and the explosive charge,the interface of bronze to steel became wavier.The microhardness test result showed that the hardness of the samples was higher near the joint interface compared with other areas because of the intensive plastic deformation,which was caused by the explosion force.The results show that increasing the heat treatment temperature and time caused the intermetallic compounds’layer thickness to increase,and,because of the higher diffusion of copper and tin,the iron amount in the intermetallic compounds decreased.Also,because of the increase in heat treatment temperature and time,internal stresses were released,and the interface hardness decreased.

Diffusion bonding of Al 7075 and Mg AZ31 alloys:Process parameters, microstructural analysis and mechanical properties

Al 7075 and Mg AZ31 alloys were joined by diffusion bonding method. Joining process was performed in pressure range of 10-35 MPa at temperatures of 430-450 ℃ for 60 min under a vacuum of 13.3 MPa. The microstructure evaluation, phase analysis and distribution of elements at the interface were done using scanning electron microscopy （SEM）, energy-dispersive X-ray spectroscopy （EDS） and X-ray diffraction （XRD）. The pressure of 25 MPa was determined as the optimum pressure in which the minimum amount of plastic deformation takes place at the joint. Different reaction layers containing intermetallic compounds, such as Al12Mg17, Al3Mg2 andα（Al） solid solution, were observed, in interfacial transition zone （ITZ）. Thickness of layers was increased with increasing the operating temperature. According to the results, diffusion of aluminum atoms into magnesium alloy was more and the interface movement towards the Al alloy was observed. The maximum bond strength of 38 MPa was achieved at the temperature of 440 ℃ and pressure of 25 MPa. Fractography studies indicated that the brittle fracture originated from Al3Mg2 phase.

Corrosion evaluation of friction stir welded lap joints of AA6061-T6 aluminum alloy

Corrosion behavior of friction stir lap welded AA6061-T6 aluminum alloy was investigated by immersion tests in sodium chloride + hydrogen peroxide solution. Electrochemical measurement by cyclic potentiodynamic polarization, scanning electron microscopy, and energy dispersive spectroscopy were employed to characterize corrosion morphology and to realize corrosion mechanism of weld regions as opposed to the parent alloy. The microstructure and shear strength of welded joint were fully investigated. The results indicate that, compared with the parent alloy, the weld regions are susceptible to intergranular and pitting attacks in the test solution during immersion time. The obtained results of lap shear testing disclose that tensile shear strength of the welds is 128 MPa which is more than 60% of the strength of parent alloy in lap shear testing. Electrochemical results show that the protection potentials of the WNZ and HAZ regions are more negative than the pitting potential. This means that the WNZ and HAZ regions do not show more tendencies to pitting corrosion. Corrosion resistance of parent alloy is higher than that for the weldments, and the lowest corrosion resistance is related to the heat affected zone. The pitting attacks originate from the edge of intermetallic particles as the cathode compared with the Al matrix due to their high self-corrosion potential. It is supposed that by increasing intermetallic particle distributed throughout the matrix of weld regions, the galvanic corrosion couples are increased, and hence decrease the corrosion resistance of weld regions.

Effect of Mg and Si on intermetallic formation and fracture behavior of pure aluminum-galvanized carbon-steel joints made by weld-brazing

Commercial pure aluminum and galvanized carbon steel were lap-welded using the weld-brazing(WB)technique.Three types of aluminum filler materials(4043,4047,and 5356) were used for WB.The joint strength and intermetallic compounds at the interface of three series of samples were analyzed and compared.Depending on the Si content,a variety of ternary Al-Fe-Si intermetallic compounds(IMCs) such as Fe_(4)(Al,Si)_(13),Fe_(2) Al_(8) Si(τ_(5)),and Fe_(2) Al_(9) Si_(2)(τ_(6)) were formed at the interface.Mg element in 5356 filler material cannot contribute to the formation of Al-Fe intermetallic phases due to the positive mixing enthalpy of Mg-Fe.The presence of Mg enhances the hot cracking phenomenon near the Al-Fe intermetallic compound at the interface.Zn coating does not participate in intermetallic formation due to its evaporation during WB.It was concluded that the softening of the base metal in the heat-affected zone rather than the IMCs determines the joint efficiency.

Microstructural characterization and mechanical properties of aluminum 6061-T6 plates welded with copper insert plate(Al/Cu/Al) using friction stir welding

Friction stir welding was used to join two aluminum 6061-T6 plates with an insert of a pure copper plate(Al/Cu/Al),and then the influence of the copper insert on the joint performance was studied.The dissimilar welding results were also compared with AA 6061 friction stir welds produced without copper insert(Al/Al).Optical and scanning electron microscopes were used for the microstructural observations of the welded samples.X-ray diffraction analysis was used to analyze phase component of the Al/Cu/Al specimen.A defect-free joint was observed for the Al/Cu/Al joint at a rotational speed of 950 r/min and a welding speed of 50 mm/min.Microstructural observation of the weld nugget zone(WNZ)demonstrates the formation of composite-like structure which promotes metallurgical bonding of aluminum and copper.XRD results show the formation of intermetallic compounds(IMCs),such as Al4Cu9 and Al2Cu.Furthermore,it was observed that the hardness of the weld with the Cu insert plate is higher than that of other samples due to more dislocation density and a distinct rise in hardness values was observed due to the presence of IMCs.The ultimate tensile strength of the joint with copper insert plate is higher than that of the other sample due to the strong metallurgical bonding between Al and Cu.

Friction stir welding of aluminum to copper—An overview

Components made by joining different materials are required in various engineering applications.Fabrication of suchcomponents is a challenging task due to the vast difference in mechanical,thermal and electrical properties of the materials beingused.Friction stir welding(FSW)is capable of joining dissimilar materials such as aluminum(Al)and copper(Cu)and thereforeresearchers have used this novel process for dissimilar joining.Consequently,several works pertaining to dissimilar joining,specifically Al?Cu,are available in the literature but they are scattered in different sources,which makes the task of gatheringinformation about dissimilar FSW of Al?Cu cumbersome.This work has been written with an aim to provide all pertinentinformation related to dissimilar FSW of Al?Cu at one place to ease the problems of researchers.It comprehensively covers andsummarizes the topics such as the effect of tool design and geometry,FSW process parameters,FSW strategies on mechanicalproperties,microstructure and formation of defects during dissimilar FSW of Al?Cu.In addition,it also presents and discussesseveral variants of dissimilar FSW of Al?Cu.Finally,this work not only puts forth major findings of the previous researchers but alsosuggests future recommendations for dissimilar FSW of Al?Cu.

Spectra analysis and O_2 evolution for TiO_2 photocatalyst compounded with indirect transition semiconductors

The photo absorbing, photo transmitting and photoluminescence performances of WiO2 photocatalysts compounded with V2O5 or WO3 were investigated by UV-Vis spectra, transmitting spectra, and PL spectra, respectively. The energy band structures of TiO2 photocatalysts were analyzed. The photocatalytic activities of the TiO2 photocatalysts were investigated by splitting of water for 02 evolution. The results indicate that the band gaps of WO3 and V205 are about 2.8 and 2.14 eV, respectively, and the band gap of rutile TiO2 is about 3.08 eV. Speeds of water splitting for 2%WO3-TiO2 and 8%V2O5-TiO2 photocatalysts are 420 and 110 μmol/（L.h）, respectively, under UV light irradiation. V2O5 and WO3 compounded with suitable concentration can improve the photocatalytic activity of TiO2 with Fe3＋ as electron acceptor.

Optimization Design and Comprehensive Evaluation of Screw Contact of Space Battery Based on ANSYS

In order to improve the safety of the battery of satellite side mounting,and prevent the screw from producing excess due to frequent assembly and disassembly,the YS-20 material replacement and structure optimization design of the screw body are carried out under the premise of not changing the original tooling.The double⁃shear test of YS-20 bar is carried out,and the ANSYS optimization design module is used to design 7×7×6,a total of 294,calculation cases of D1,D2,T,the three important dimension parameters of screw structure.The actual bearing state of screw composite structure is accurately simulated by using asymmetric contact model.Three comprehensive evaluations are established,and the calculation examples satisfying the conditions are evaluated comprehensively.The final results are T=12.2 mm,D1=16 mm,D2=2 mm.The stress verification and contact analysis are carried out for the final scheme and the bearing state and contact state optimized screw structure are obtained.

TIG welding-brazing joint of aluminum to stainless steel with hot wire

TIG welding-brazing process with high frequency induction hot wire technology was presented to create joints between 5A06 aluminum alloy and SUS32! stainless steel using ER1100 filler wire with different temperature. The joints were evaluated by mechanical test and microstructural analyses. The welding procedure using hot fiUer wire （400 ℃ ） significantly increases strength stability by 71% and average value of tensile strength by 30. 8 % of the joints, compared with cold wire. The research of microstructures in interfaces and welded seams reveals that using 400 ℃ hot filler wire can decrease the thickness of intermetallic compounds （ IMCs ） from 6 to 3.5 txm approximately, which is the main reason of mechanical property improvement.

Swelling Characteristics of Saudi Tayma Shale and Consequential Impact on Light Structures

Expansive soils in Saudi Arabia have received wide attention in recent decades, following the rapid urbanization of rural and agricultural parts of the country. Tayma expansive shale inflicted serious damages to light structures, roads and boundary walls. This research is aimed at studying the engineering characteristics of the shale at this area including the basic geotechnical parameters as well as swelling behavior under oedometric loading conditions. The engineering properties were determined and compared to the local and international characterization charts. Mineralogy study using x-ray diffraction was conducted to investigate clay minerals present. The swell percent and the swelling pressure of the shale were investigated for samples prepared at different initial moisture contents and various dry densities. A close-up view of damages caused by the expansive shale in the town is highlighted and measures to reduce the risk of potential swelling distress for future constructions are presented.

Analyzing and Pondering on the Regulation of Urban Construction Land Expansion

Along with the economic development and the acceleration of urbanization,urban construction land expands rapidly in China,and has resulted in a series of socio-economic problems.This article summarized the major points of controlling the unchecked and rash expansion of construction land in the academic circle,and analyzed the problems of regulating the expansion of construction land from three aspects.First,this article analyzed the relationships between socio-economic development and urbanization from the historical viewpoints,and pointed out that the expansion of construction land is a historical phenomenon which will be surely appeared in the development of human race.Second,the authors utilized two-sector model to analyze the importance of urbanization in the socio-economic development from the academic angles.At last,the authors utilize four-quadrant model and bidrent curve model to analyze the influence that brought by the strict control of construction land expansion.Through analysis,this article drew some conclusions.First,the expansion of construction land is a phenomenon which will surely appear in the social development.It is impossible to accomplish the national modernization on the basis of dualistic structure between urban and rural areas.Second,under the function of rent gradient gap,strict control of construction land expansion will not only obtain the anticipated effects,but also cause a series of socio-economic problems,such as land-levying contradiction,the appearance of limited property right house,and being dependant on lease instead of expropriation.Third,unreasonable policies and governmental behaviors are the roots of the unchecked and rash expansion of urban construction land.Based on these conclusions,this article proposed that three transformations should be realized to regulate the unchecked and rash expansion of construction land:transfers from quantity regulation to quality regulation,from direct regulation to indirect regulation,and from single-measure regulation to multi-measures regulation.

Deep removal of copper from cobalt sulfate electrolyte by ion-exchange

SP-C was applied for the removal of Cu^2＋ from simulated cobalt sulfate electrolyte containing Co2＋ 50 g/L and Cu2＋ 0.5-2.0 g/L. Experimental conditions included pH of 2-4, temperature of 20-60℃ and contact time of 10-40 min. The investigation demonstrated that SP-C had recommendable efficiency in adsorbing Cu2＋ from the electrolyte with 25- to 100-fold of Co2＋ The optimal adsorption conditions of SP-C were pH of 4, contact time of 30 min and ambient temperature. The study also showed that the loaded resin could be effectively eluted with 2.0 mol/L H2SO4 solution at a contact time of 40 min; the peak concentration of Cu2＋ in the eluate was about 35 g/L. The sorption characteristics of Cu2＋ by SP-C could be described by Langrnuir isotherm and the pseudo second-order kinetic equation. Infrared spectra showed that nitrogen atoms in the functional group coordinated with Cu2＋ to form coordination bands.