To further improve the utilization efficiency of solar energy and the performance of solar heat pump heating systems,a new heating mode of a solar air-source heat pump（SASHP）is proposed,and the characteristics and p...To further improve the utilization efficiency of solar energy and the performance of solar heat pump heating systems,a new heating mode of a solar air-source heat pump（SASHP）is proposed,and the characteristics and performance of the heat pump part of this new heating system are studied.Based on a SASHP with 10 kW,the mathematical model of this system is built,and the characteristics and performance are concluded from the simulation analysis at different environmental temperatures and output water temperatures.The results show that the performance of heat pumps can be greatly improved based on the new SASHP.When the environmental temperature is 7 ℃,the coefficient of performance（COP）of the air-source heat pump（ASHP）can be increased by 26% at most.This paper sets up a base for further study on the heating system with this new SASHP in the heating season.展开更多
A novel SnO2-based gas anode was developed for aluminum electrolysis in molten cryolite at 850 ＆#176;C to reduce energy consumption and decrease CO2 emissions. Hydrogen was introduced into the anode, participating in...A novel SnO2-based gas anode was developed for aluminum electrolysis in molten cryolite at 850 ＆#176;C to reduce energy consumption and decrease CO2 emissions. Hydrogen was introduced into the anode, participating in the anode reaction. Carbon and aluminum were used as the cathode and reference electrodes, respectively. Cyclic voltammetry was applied in the cell to investigate the electrochemical behavior of oxygen ion on platinum and SnO2-based materials. The potential for oxygen evolution on these electrode materials was determined. Then, galvanostatic electrolysis was performed on the gas anode, showing a significant depolarization effect （a decrease of ~0.8 V of the anode potential） after the introduction of hydrogen, compared with no gas introduction or the introduction of argon. The results indicate the involvement of hydrogen in the anode reaction （three-phase-boundary reaction including gas, electrolyte and electrode） and give the possibility for the utilization of reducing gas anodes for aluminum electrolysis.展开更多
A method to investigate the effect of gas bubble on cell voltage oscillations was established. The whole aluminum electrolysis cell was treated as a resistance circuit, and the dynamic simulation of the cell equivalen...A method to investigate the effect of gas bubble on cell voltage oscillations was established. The whole aluminum electrolysis cell was treated as a resistance circuit, and the dynamic simulation of the cell equivalent circuit was modeled with Matlab/Simulink simulation software. The time-series signals of cell voltage and anode current were obtained under different bubble conditions, and analyzed by spectral and statistical analysis methods. The simulation results show that higher bubble release frequency has a significant effect on the cell voltage oscillations. When the bubble coverage of one anode block exceeds 80%, the cell voltage may exceed its normal fluctuation amplitude. The simulation also proves that the anode effect detected by computer in actual production is mainly the whole cell anode effect.展开更多
Based on the commercial computational fluid dynamics software CFX-4.3, electrolyte flow fields in a 156 kA pre-baked anode aluminum electrolysis cell were investigated in three different cases where the electrolyte me...Based on the commercial computational fluid dynamics software CFX-4.3, electrolyte flow fields in a 156 kA pre-baked anode aluminum electrolysis cell were investigated in three different cases where the electrolyte melt was driven by different kinds of force, i.e. electromagnetic force only, the anode gas drag force only and both of the former two forces. The results show that when electromagnetic force was introduced only, most of the electrolyte moves horizontally; when anode gas drag force was introduced only, the electrolyte flows mainly around each anode with small circulation; when electromagnetic force and anode gas drag force were both introduced together, the structure of the electrolyte flow fields and the velocity of electrolyte are similar to that of the case where only anode gas drag force is used. The electrolyte flow fields are mainly determined by the anode gas drag force.展开更多
A transient three-dimensional（3 D） model was established to understand the bubble motion in an industrial electrolytic process. An anode with a new design was tested. It incorporates two slots that allow an efficien...A transient three-dimensional（3 D） model was established to understand the bubble motion in an industrial electrolytic process. An anode with a new design was tested. It incorporates two slots that allow an efficient removal of gas bubbles. The electromagnetic fields were described by solving Maxwell＇s equations. The bubble movement was studied with two-way coupling Euler-Lagrange approach. The interplay of current density and bubble nucleation rate was included. The collision and coalescence of bubbles were considered. Random walk module was invoked for involving the chaotic effect of the turbulence. The numerical results were validated by experimental measurements. The results indicate that the current distribution and the bubble nucleation periodically change. Due to the slot, the bubble elimination heavily increases. The contribution of the slot to the bubble removal exceeds 50% in the case of three currents, and the promotion of the slot decays with increasing the current.展开更多
The bubble behavior is one of the key factors for the design and the process of aluminum reduction cell using inert anode.A see-through cell is constructed to investigate the bubble flow behavior and the electrolyte f...The bubble behavior is one of the key factors for the design and the process of aluminum reduction cell using inert anode.A see-through cell is constructed to investigate the bubble flow behavior and the electrolyte flow pattern induced by bubbles.The test results show that the electrolyte is driven by the bubble to move around the cathode,and also some vortices occur in local areas.The bubble generated at the anode bottom undergoes the processes of formation,growth,sliding,detachment and coalescence.However,the bubble generated at the middle of anode detaches rapidly from the anode surface and moves upward and collides with other bubbles,which results in coalescence or break-up.Most bubbles are released into the atmosphere at the liquid surface,while some other bubbles taken by the electrolyte flush to the height higher than the mean horizontal level of the liquid and then drop down and move horizontally and they are released finally.Some bubbles are kept unbroken and are sliding on the electrolyte surface.The diameter of bubble generated at inert anode is smaller than that of bubble generated at graphite anode.Moreover,the bubbles on inert anode are spherical,which was different from those in tubular or disk form on graphite anode.展开更多
Climatic characteristics of broadband solarradiation (Rs) in Chinese arid and semi-arid areas are reported in this study. The annual average daily Rs in thearid and semi-arid areas is 16.3 ± 5.77 and 15.3 ± ...Climatic characteristics of broadband solarradiation (Rs) in Chinese arid and semi-arid areas are reported in this study. The annual average daily Rs in thearid and semi-arid areas is 16.3 ± 5.77 and 15.3 ± 5.16 MJm-2 d-1, respectively. The highest value (17.2 ± 5.84 MJm-2 d-1) appears in an arid area at Linze. The lowest valueappears in the semi-arid area of Ansai. Pronounced seasonal variation of Rs is observed with the highest value insummer and the lowest in winter. The clearness indexshowed similar seasonal pattern at most sites, with theminimum observed in the summer and the highest valuesin winter at both arid and semi-arid areas. The seasonalvariation of the ratio of Rs to its extraterrestrial value Kt inthe arid area is more significant than that observed in thesemi-arid region, and it is caused by the different range ofvariation of water vapor between arid and semi-arid areasThe seasonal fluctuations in Rs and Kt are mainly controlled by the water vapor content in these areas. Theaerosol particles have significant influence on Rs and Kt atstations with higher aerosol burden.展开更多
基金The National Natural Science Foundation of China(No.50676018)the National Key Technology R&D Program of China during the 11th Five-Year Plan Period(No.2008BAJ12B02)
文摘To further improve the utilization efficiency of solar energy and the performance of solar heat pump heating systems,a new heating mode of a solar air-source heat pump（SASHP）is proposed,and the characteristics and performance of the heat pump part of this new heating system are studied.Based on a SASHP with 10 kW,the mathematical model of this system is built,and the characteristics and performance are concluded from the simulation analysis at different environmental temperatures and output water temperatures.The results show that the performance of heat pumps can be greatly improved based on the new SASHP.When the environmental temperature is 7 ℃,the coefficient of performance（COP）of the air-source heat pump（ASHP）can be increased by 26% at most.This paper sets up a base for further study on the heating system with this new SASHP in the heating season.
基金Project(51404001)supported by the National Natural Science Foundation of ChinaProject([2014]1685)supported by the Scientific Research Foundation for the Returned Overseas Chinese Scholars,Ministry of Education,China
文摘A novel SnO2-based gas anode was developed for aluminum electrolysis in molten cryolite at 850 ＆#176;C to reduce energy consumption and decrease CO2 emissions. Hydrogen was introduced into the anode, participating in the anode reaction. Carbon and aluminum were used as the cathode and reference electrodes, respectively. Cyclic voltammetry was applied in the cell to investigate the electrochemical behavior of oxygen ion on platinum and SnO2-based materials. The potential for oxygen evolution on these electrode materials was determined. Then, galvanostatic electrolysis was performed on the gas anode, showing a significant depolarization effect （a decrease of ~0.8 V of the anode potential） after the introduction of hydrogen, compared with no gas introduction or the introduction of argon. The results indicate the involvement of hydrogen in the anode reaction （three-phase-boundary reaction including gas, electrolyte and electrode） and give the possibility for the utilization of reducing gas anodes for aluminum electrolysis.
基金Project(2012BAE08B09)supported by the National Key Technology R&D Program of China
文摘A method to investigate the effect of gas bubble on cell voltage oscillations was established. The whole aluminum electrolysis cell was treated as a resistance circuit, and the dynamic simulation of the cell equivalent circuit was modeled with Matlab/Simulink simulation software. The time-series signals of cell voltage and anode current were obtained under different bubble conditions, and analyzed by spectral and statistical analysis methods. The simulation results show that higher bubble release frequency has a significant effect on the cell voltage oscillations. When the bubble coverage of one anode block exceeds 80%, the cell voltage may exceed its normal fluctuation amplitude. The simulation also proves that the anode effect detected by computer in actual production is mainly the whole cell anode effect.
基金Project (G1999064903) supported by the National Key Fundamental Research and Development Programof China
文摘Based on the commercial computational fluid dynamics software CFX-4.3, electrolyte flow fields in a 156 kA pre-baked anode aluminum electrolysis cell were investigated in three different cases where the electrolyte melt was driven by different kinds of force, i.e. electromagnetic force only, the anode gas drag force only and both of the former two forces. The results show that when electromagnetic force was introduced only, most of the electrolyte moves horizontally; when anode gas drag force was introduced only, the electrolyte flows mainly around each anode with small circulation; when electromagnetic force and anode gas drag force were both introduced together, the structure of the electrolyte flow fields and the velocity of electrolyte are similar to that of the case where only anode gas drag force is used. The electrolyte flow fields are mainly determined by the anode gas drag force.
基金Project(51434005) supported by the National Natural Science Foundation of China
文摘A transient three-dimensional（3 D） model was established to understand the bubble motion in an industrial electrolytic process. An anode with a new design was tested. It incorporates two slots that allow an efficient removal of gas bubbles. The electromagnetic fields were described by solving Maxwell＇s equations. The bubble movement was studied with two-way coupling Euler-Lagrange approach. The interplay of current density and bubble nucleation rate was included. The collision and coalescence of bubbles were considered. Random walk module was invoked for involving the chaotic effect of the turbulence. The numerical results were validated by experimental measurements. The results indicate that the current distribution and the bubble nucleation periodically change. Due to the slot, the bubble elimination heavily increases. The contribution of the slot to the bubble removal exceeds 50% in the case of three currents, and the promotion of the slot decays with increasing the current.
基金Projects(51304216,51371161)supported by the National Natural Science Foundation of China
文摘The bubble behavior is one of the key factors for the design and the process of aluminum reduction cell using inert anode.A see-through cell is constructed to investigate the bubble flow behavior and the electrolyte flow pattern induced by bubbles.The test results show that the electrolyte is driven by the bubble to move around the cathode,and also some vortices occur in local areas.The bubble generated at the anode bottom undergoes the processes of formation,growth,sliding,detachment and coalescence.However,the bubble generated at the middle of anode detaches rapidly from the anode surface and moves upward and collides with other bubbles,which results in coalescence or break-up.Most bubbles are released into the atmosphere at the liquid surface,while some other bubbles taken by the electrolyte flush to the height higher than the mean horizontal level of the liquid and then drop down and move horizontally and they are released finally.Some bubbles are kept unbroken and are sliding on the electrolyte surface.The diameter of bubble generated at inert anode is smaller than that of bubble generated at graphite anode.Moreover,the bubbles on inert anode are spherical,which was different from those in tubular or disk form on graphite anode.
基金supported by the National Basic Research Program of China (Grant No. 2006CB403702)the National High Technology Research and Development Program of China (Grant No. 2006AA06A301)
文摘Climatic characteristics of broadband solarradiation (Rs) in Chinese arid and semi-arid areas are reported in this study. The annual average daily Rs in thearid and semi-arid areas is 16.3 ± 5.77 and 15.3 ± 5.16 MJm-2 d-1, respectively. The highest value (17.2 ± 5.84 MJm-2 d-1) appears in an arid area at Linze. The lowest valueappears in the semi-arid area of Ansai. Pronounced seasonal variation of Rs is observed with the highest value insummer and the lowest in winter. The clearness indexshowed similar seasonal pattern at most sites, with theminimum observed in the summer and the highest valuesin winter at both arid and semi-arid areas. The seasonalvariation of the ratio of Rs to its extraterrestrial value Kt inthe arid area is more significant than that observed in thesemi-arid region, and it is caused by the different range ofvariation of water vapor between arid and semi-arid areasThe seasonal fluctuations in Rs and Kt are mainly controlled by the water vapor content in these areas. Theaerosol particles have significant influence on Rs and Kt atstations with higher aerosol burden.
