Accountable capability improvement based on interpretable capability evaluation using belief rule base

A new approach is proposed in this study for accountable capability improvement based on interpretable capability evaluation using the belief rule base(BRB).Firstly,a capability evaluation model is constructed and optimized.Then,the key sub-capabilities are identified by quantitatively calculating the contributions made by each sub-capability to the overall capability.Finally,the overall capability is improved by optimizing the identified key sub-capabilities.The theoretical contributions of the proposed approach are as follows.(i)An interpretable capability evaluation model is constructed by employing BRB which can provide complete access to decision-makers.(ii)Key sub-capabilities are identified according to the quantitative contribution analysis results.(iii)Accountable capability improvement is carried out by only optimizing the identified key sub-capabilities.Case study results show that“Surveillance”,“Positioning”,and“Identification”are identified as key sub-capabilities with a summed contribution of 75.55%in an analytical and deducible fashion based on the interpretable capability evaluation model.As a result,the overall capability is improved by optimizing only the identified key sub-capabilities.The overall capability can be greatly improved from 59.20%to 81.80%with a minimum cost of 397.Furthermore,this paper also investigates how optimizing the BRB with more collected data would affect the evaluation results:only optimizing“Surveillance”and“Positioning”can also improve the overall capability to 81.34%with a cost of 370,which thus validates the efficiency of the proposed approach.

Ballistic Testing and Thermal Behavior of Cast Double-base Propellant Containing BuNENA

Preparation of cast double-propellant grains depends on the ability of nitrocellulose powder to swell and coalesce into a coherent mass when treated with a suitable solvent.The cast double-base process has been developed into a highly versatile technique for manufacturing solid rocket charges.Propellants manufactured by this process provide a wide range of energies and burning rates.Successful preparation of cast double-base propellant grains has been performed using compatible casting liquid with the casting powder.BuNENA was used as an energetic plasticizer for manufacturing of casting powder.Burning rate measurements have been performed using closed bomb SV-2to investigate the burning behavior along a wide range of operating pressure.Plateau burning had been detected in pressure range(50-70)×105 Pa for the composition included BuNENA.DTA and TGA thermal analysis were conducted to evaluate the thermal behavior of the prepared cast double-base propellants.Results from DTA were used to calculate the apparent activation energy.

Solid base catalysts derived from Ca-M-Al(M = Mg, La, Ce, Y) layered double hydroxides for dimethyl carbonate synthesis by transesterification of methanol with propylene carbonate

Composite solid base catalysts derived from Ca‐M‐Al(M=Mg,La,Ce,Y)layered double hydroxides(LDH)were synthesized,characterized and applied to the transesterification of methanol with propylene carbonate.X‐ray diffraction analyses of the catalysts show that all of the catalysts were in the form of composite oxides.Compared with the Ca‐Al LDH catalyst,the specific surface areas and pore volumes of the catalysts were increased with the introduction of Mg,La or Ce.The catalytic performance of these catalysts increases in the order of Ca‐Y‐Al<Ca‐Al<Ca‐Ce‐Al<Ca‐La‐Al<Ca‐Mg‐Al,which is consistent with the total surface basic amounts of these materials and the formation of especially strong basic sites following modification with Mg and La.The Ca‐Mg‐Al catalyst shows the highest(Ca+Mg):Al atomic ratio,indicating that it likely contains more unsaturated O2?ions,providing it with the highest concentration of very strong basic sites.The recyclability of these catalysts is improved following the addition of Mg,La,Ce or Y,with the Ca‐Mg‐Al maintaining a high level of activity after ten recycling trials.X‐ray diffraction analyses of fresh and used Ca‐Mg‐Al demonstrate that this catalyst is exceptionally stable,which could be of value in practical applications related to heterogeneous catalysis.

Attack on Optical Double Random Phase Encryption Based on the Principle of Ptychographical Imaging

The principle of ptychography is applied in known plain text attack on the double random phase encoding （DRPE） system. We find that with several pairs of plain texts and cipher texts, the model of attack on DRPE can be converted to the model of ptyehographical imaging. Owing to the inherent merits of the ptyehographical imaging, the DRPE system can be breached totally in a fast and nearly perfect way, which is unavailable for currently existing attack methods. Further, since the decryption keys can be seen as an object to be imaged from the perspective of imaging, the ptychographical technique may be a kind of new direction to further analysis of the security of other encryption systems based on double random keys.

Simulation of the plasticizing behavior of composite modified doublebase(CMDB)propellant in grooved calendar based on adaptive grid technology

The frequent occurrence of safety accidents during the calendering process is caused by the flammable and explosive properties of composite modified double-base(CMDB)propellant.Optimization of process parameters with the aid of fluid simulation technology could effectively ensure the safety of the calendering process.To improve the accuracy of the simulation results,material parameters and model structure were corrected based on actual conditions,and adaptive grid technology was applied in the local mesh refinement.In addition,the rheological behavior,motion trajectories and heat transfer mechanisms of CMDB propellant slurry were studied with different gaps,rotational rates and temperatures of two rollers.The results indicated that the refined mesh could significantly improve the contour clarity of boundaries and simulate the characteristics of CMDB propellant slurry reflux movement caused by the convergent flow near the outlet.Compared with the gap,the increased rotational rate of roller could promote the reflux movement and intensify the shear flow of slurry inside the flow region by viscous shear dragging.Meanwhile,under the synergistic effect of contact heat transfer as well as convective heat exchange,heat accumulated near the outlet and diffused along the reflux movement,which led to the countercurrent heat dissipation behavior of CMDB propellant slurry.The plasticizing mechanism of slurry and the safety of calendering under different conditions were explored,which provided theoretical guidance and reference data for the optimization of calendering process conditions.Based on the simulation results,the safety of the CMDB propellant calendering process could be significantly improved with a few tests conducted during a short research and development cycle.

Common Base Four-Finger InGaAs/InP Double Heterojunction Bipolar Transistor with Maximum Oscillation Frequency 535 GHz

A common base four-finger InOaAs/InP double heterojunction bipolar transistor with 535 OHz fmax by using the 0.5 μm emitter technology is fabricated. Multi-finger design is used to increase the input current. Common base configuration is compared with common emitter configuration, and shows a smaller K factor at high frequency span, indicating a larger breakpoint frequency of maximum stable gain/maximum available gain （MSG/MAG） and thus a higher gain near the cut-off frequency, which is useful in THz amplifier design.

Novel aspects for thermal stability studies and shelf life assessment of modified double-base propellants

Modified DB propellants, based on energetic nitramine(RDX) were manufactured by solventless extrusion process. Thermal stability and shelf life assessment of modified DB propellant were investigated. Shelf life assessment was evaluated using Van’t Hoff’s formula and artificial aging at 70℃ up to120 days. Quantification of total heat released and heat flow with aging time was conducted using differential scanning calorimetry(DSC) and thermal activity monitoring(TAMIII) respectively. Modified DB formulation based on 20 wt % RDX demonstrated enhanced thermal stability in terms of controlled heat flow, and slow decomposition reactions at elevated temperature. This formulation demonstrated extended service life up to 56 years compared with reference formulation. These novel finding was ascribed to the high thermal stability of RDX and its compatibility with DB constituents. This manuscript shaded the light on novel and effective approach for thermal stability via monitoring thermal activity with aging.

Chemical stability, thermal behavior, and shelf life assessment of extruded modified double-base propellants

Double base propellant suffers from lack of chemical stability; this could result in self ignition during storing. Modified double base(MDB) propellant based on stoichiometric binary mixture of oxidizermetal fuel(Ammonium perchlorate/Aluminum), and energetic nitramines(HMX) offered enhanced thrust as well as combustion characteristics. This study is devoted to evaluate the impact of such energetic additives on thermal behavior, chemical stability, and shelf life. Extruded MDB formulations were manufactured by extrusion process. Artificial aging at 80℃ for 28 days was conducted. Shelf life assessment was performed using Van't Hoff's equation. Quantification of evolved NOxgases with aging time was performed using quantitative stability tests. MDB formulation based on HMX demonstrated extended service life of 16 years compared with(AP/Al)-MDB which demonstrated 9 years. This finding was ascribed to the reactivity of AP with nitroglycerin with the formation of perchloric acid. Thermal behavior of aged MDB, exhibited an increase in heat released with time; this was ascribed to the autocatalytic thermal degradation during artificial aging. The increase in released heat by 31% was found to be equivalent to evolved NOx gases of 6.2 cm^3/5 g and 2.5 cm^3/1 g for Bergmann-Junk test, and Vacuum stability test respectively. This manuscript shaded the light on a novel approach to quantify evolved NOx gases to heat released with aging time. MDB based on HMX offered balanced ballistic performance,chemical stability, and service life.

Non-ideal effect in 4H-SiC bipolar junction transistor with double Gaussian-doped base

The non-ideal effect of 4H-SiC bipolar junction transistor （BJT） with a double Gaussian-doped base is characterized and simulated in this paper. By adding a specific interface model between SiC and SiO2, the simulation results are in good agreement with the experiment data. An obvious early effect is found from the output characteristic. As the temperature rises, the early voltage increases, while the current gain gradually decreases, which is totally different from the scenario of silicon BJT. With the same effective Gummet number in the base region, the double Gaussian-doped base structure can realize higher current gain than the single base BJT due to the built-in electric field, whereas the early effect will be more salient. Besides, the emitter current crowding effect is also analyzed. Due to the low sheet resistance in the first highly- doped base epilayer, the 4H-BJT with a double base has more uniform emitter current density across the base-emitter junction, leading to better thermal stability.

Injection modulation of p^+-n emitter junction in 4H-SiC light triggered thyristor by double-deck thin n-base

To overcome hole-injection limitation of p^＋-n emitter junction in 4H-SiC light triggered thyristor, a novel high- voltage 4H-SiC light triggered thyristor with double-deck thin n-base structure is proposed and demonstrated by two- dimensional numerical simulations. In this new structure, the conventional thin n-base is split to double-deck. The hole- injection of p^＋-n emitter junction is modulated by modulating the doping concentration and thickness of upper-deck thin n- base. With double-deck thin n-base, the current gain coefficient of the top pnp transistor in 4H-SiC light triggered thyristor is enhanced. As a result, the triggering light intensity and the turn-on delay time of 4H-SiC light triggered thyristor are both reduced. The simulation results show that the proposed 10-kV 4H-SiC light triggered thyristor is able to be triggered on by 500-mW/cm^2 ultraviolet light pulse. Meanwhile, the turn-on delay time of the proposed thyristor is reduced to 337 ns.

Novel approach to quantify the chemical stability and shelf life of modified double-base propellants

Double-base(DB) propellant is vulnerable to auto-catalytic decomposition reactions during storing with the evolution of nitrogen oxides. Modified DB propellant based on energetic nitramines(RDX) can offer enhanced thrust and action time. This study is devoted to evaluate the impact of RDX on chemical stability and shelf life of DB propellant. Extruded modified DB propellant based on RDX was manufactured by solventless extrusion process. Shelf life assessment was performed using an artificial aging at70 ℃ up to 120 days and employing Van't Hoffs formula. Quantification of evolved NOx gases and stabilizer depletion with aging time was conducted using Bergmann-Junk test and HPLC respectively.Modified DB formulation based on RDX 20 wt % demonstrated enhanced chemical stability and extended service life up to 46 years compared with reference formulation. This finding was ascribed to the high chemical and thermal stability of RDX as well as its compatibility with DB constituents; no side chemical reactions could take place during storing. This manuscript shaded the light on RDX as effective energetic constituent that offered DB propellants with enhanced performance, good chemical stability, and extended service life.

An Improved Double r-iteration IOD Method for GEO UCTs Based on SBSS System

The purpose of initial orbit determination,especially in the case of angles-only data for observation,is to obtain an initial estimate that is close enough to the true orbit to enable subsequent precision orbit determination processing to be successful.However,the classical angles-only initial orbit determination methods cannot deal with the observation data whose Earth-central angle is larger than 360°.In this paper,an improved double r-iteration initial orbit determination method to deal with the above case is presented to monitor geosynchronous Earth orbit objects for a spacebased surveillance system.Simulation results indicate that the improved double r-iteration method is feasible,and the accuracy of the obtained initial orbit meets the requirements of re-acquiring the object.

Theoretical study on the mechanism for the excited-state double proton transfer process of an asymmetric Schiff base ligand

Excited-state double proton transfer(ESDPT)in the 1-[(2-hydroxy-3-methoxy-benzylidene)-hydrazonomethyl]-naphthalen-2-ol(HYDRAVH_(2))ligand was studied by the density functional theory and time-dependent density functional theory method.The analysis of frontier molecular orbitals,infrared spectra,and non-covalent interactions have crossvalidated that the asymmetric structure has an influence on the proton transfer,which makes the proton transfer ability of the two hydrogen protons different.The potential energy surfaces in both S_(0)and S_1 states were scanned with varying O-H bond lengths.The results of potential energy surface analysis adequately proved that the HYDRAVH_(2)can undergo the ESDPT process in the S_1 state and the double proton transfer process is a stepwise proton transfer mechanism.Our work can pave the way towards the design and synthesis of new molecules.

Existence and uniqueness for a class of double pyramidal central configurations with a concave pentagonal base

Based on some necessary conditions for double pyramidal central configurations with a concave pentagonal base, for any given ratio of masses, the existence and uniqueness of a class of double pyramidal central configurations with a concave pentagonal base in 7-body problems are proved and the range of the ratio between radius and half-height is obtained, within which the 7 bodies involved form a central configuration or form uniquely a central configuration.

A Study of Estimating the Safe Storage Life, Self-accelerating Decomposition Temperature and Critical Temperature of Thermal Explosion of Double-base Propellant Using Isothermal and Non-isothermal Decomposition Behaviours

A method of estimating the safe storage life （τ）, self-accelerating decomposition temperature （TsADT） and critical temperature of thermal explosion （Tb） of double-base propellant using isothermal and non-isothermal decomposition behaviours is presented. For double-base propellant composed of 56±1wt% of nitrocellulose （NC）, 27±0.5wt% of nitroglycerine （NG）, 8.15±0.15wt% of dinitrotoluene （DNT）, 2.5±0.1wt% of methyl centralite, 5.0±0.15wt% of catalyst and 1.0±0.1wt% of other, the values of r of 49.4 years at 40℃, of TSAOT of 151.35℃ and of Tb of 163.01℃ were obtained.

Synthesis and Properties of Double Calix[4]arene Derivatives Linked by Schiff-base in the Lower Rim

25,27-bis-(2-aminoethoxy)-p-tert-butylcalix[4]arene was linked to double calix[4]arene derivatives by the Schiff-base moiety in its lower rim. They behave strong ability to complex with Ph2+, Cu2+ and Co2+.

Combustion Properties of Metal Particles as Components of Modified Double-Base Propellants

Metal particles such as aluminum（ Al）,magnesium（ Mg）,boron（ B） and nickel（ Ni）,as well as Mg/Al alloy（ Mg/Al = 3/4） are currently the most widely used ingredients in modified doublebase propellants. In this contribution,the combustion properties of the metal species are studied by means of the high-speed photography technique and the non-contact wavelet-based measurement of flame temperature distribution. The combustion process of the Al,Mg and Mg/Al samples shows both gas phase reaction and surface oxidation,which yield volatile and nonvolatile products,corresponding to the oxide and suboxide respectively. However,the combustion of B and Ni shows only gas phase reaction,due to their high melting point as well as high enthalpy of vaporization. In addition to the experiments,a hypothetical combustion model has been proposed to clarify the combustion characteristics of metal species in modified double-base propellants.

Secondary Activation of Commercial Activated Carbon and its Application in Electric Double Layer Capacitor

The cheap commercial activated carbon (AC) was improved through the secondary activation under steam in the presence of FeCl2 catalyst in the temperature range of 800-950℃ and its application in electric double layer capacitors (EDLCs) with organic electrolyte was studied. The re-activation of AC results in the increases in both specific capacitance and high rate capability of EDLCs. For AC treated under optimized conditions, its discharge specific capacitance increases up to 55.65 F/g, an increase of about 33% as compared to the original AC, and the high rate capability was increased significantly. The good performances of EDLC with improved AC were correlated to the increasing mesoporous ratio.

Optimal precursors of double-gyre regime transitions with an adjoint-free method

In this paper, we find the optimal precursors which can cause double-gyre regime transitions based on conditional nonlinear optimal perturbation (CNOP) method with Regional Ocean Modeling System (ROMS). Firstly, we simulate the multiple-equilibria regimes of double-gyre circulation under different viscosity coefficient and obtain the bifurcation diagram, then choose two equilibrium states (called jet-up state and jet-down state) as reference states respectively, propose Principal Component Analysis-based Simulated Annealing (PCASA) algorithm to solve CNOP-type initial perturbations which can induce double-gyre regime transitions between jet-up state and jet-down state. PCASA algorithm is an adjoint-free method which searches optimal solution randomly in the whole solution space. In addition, we investigate CNOP-type initial perturbations how to evolve with time. The results show:(1) the CNOP-type perturbations present a two-cell structure, and gradually evolves into a three-cell structure at predictive time;(2) by superimposing CNOP-type perturbations on the jet-up state and integrating ROMS, double-gyre circulation transfers from jet-up state to jet-down state, and vice versa, and random initial perturbations don't cause the transitions, which means CNOP-type perturbations are the optimal precursors of double-gyre regime transitions;(3) by analyzing the transition process of double-gyre regime transitions, we find that CNOP-type initial perturbations obtain energy from the background state through both barotropic and baroclinic instabilities, and barotropic instability contributes more significantly to the fast-growth of the perturbations. The optimal precursors and the dynamic mechanism of double-gyre regime transitions revealed in this paper have an important significance to enhance the predictability of double-gyre circulation.

新课标中核心素养对“双基”“三维目标”的继承与超越

继承与超越是把握核心素养与“双基”“三维目标”关系的两个关键词。素养导向的新课标承认知识在教育中的基础性地位,各学科着重培育的核心素养普遍以中国学生发展核心素养为统率,以各学科知识和技能为基础。“三维目标”在拓展教育目标的全面性等方面超越“双基”,核心素养在将知识、技能、方法、情感等课程教学目标看作有机整体等方面进一步超越“双基”和“三维目标”,核心素养语境中的知识观和技能观在强调基于真实情境的应用与生成等方面较以往有了很大进步。聚焦核心素养,新时代课程教学改革应该在继承基础上超越,构建兼容“双基”与“三维目标”的核心素养结构模型,直观呈现三者的内在统一关系;合理定位聚焦核心素养的单元和课时教学目标,抓准教学设计的“牛鼻子”;基于多种教学方式的相辅相成培育核心素养,丰富课堂教学组织形式。