The pathways to achieving carbon neutrality at the city level are diverse due to varying energy supply and demand conditions.Shanghai faces obstacles such as limited land resources,high costs of renewable energy techn...The pathways to achieving carbon neutrality at the city level are diverse due to varying energy supply and demand conditions.Shanghai faces obstacles such as limited land resources,high costs of renewable energy technologies,and instability of renewable energy.These challenges hinder the city’s efforts to achieve carbon peak and carbon neutrality(dual carbon).Therefore,Shanghai must identify and optimize its development path for renewable energy under the dual carbon goal.We employed the Low Emissions Analysis Platform Shanghai(LEAP-SH)model to simulate the impact of policies,such as industrial upgrading,energy efficiency improvement,energy structure optimization,increased technical innovation on energy,and ecological restoration,on the carbon emission pathways from 2022 to 2060 using five different scenarios.Our results indicate that Shanghai has the potential to achieve carbon neutrality in 2059 by promoting carbon reduction,pollution control,and green expansion.Moreover,we determined that the manufacturing industry;power generation industry;and transportation,storage,and mail services are the three major sectors for emission reduction under the dual carbon goal.Furthermore,the capacity and output of coal-fired power plants will be gradually replaced by offshore wind power in the dual carbon pathway.Finally,this study proposes countermeasures and suggestions for Shanghai to attain the dual carbon goal and high-quality development.展开更多
Fatigue properties play a crucial role as they are vital to ensuring the durability and integrity of components subjected to repeated loading conditions over long periods.The main objective of this work is to investig...Fatigue properties play a crucial role as they are vital to ensuring the durability and integrity of components subjected to repeated loading conditions over long periods.The main objective of this work is to investigate the fatigue behavior of dual phase low-carbon steels used in automotive applications using a rotating bending fatigue machine.Heat treatments were carried out to analyze the microstructure's effect on the fatigue properties,including quenching low-carbon steel samples at 800℃ and 900℃.Hardness and tensile tests were performed,and the microstructure was inspected to examine the constitute phases.With the assistance of a scanning electron microscope,fractographic analyses were carried out to reveal the fracture features of the samples at different lifetime ranges.The results show that various failure mechanisms occur depending on the stress levels.Additionally,the specimens quenched at 900℃ exhibited higher fatigue strength.展开更多
With the increasingly severe global climate change problem,the“dual carbon”goals(peak carbon emissions and carbon neutrality)have become a common focus of international attention.The report of the 20th National Cong...With the increasingly severe global climate change problem,the“dual carbon”goals(peak carbon emissions and carbon neutrality)have become a common focus of international attention.The report of the 20th National Congress of the Communist Party of China clearly emphasizes the need to accelerate the green transformation of development models,implement comprehensive strategies for frugal development,support the growth of green and low-carbon industries,and promote the concept of green consumption.At the same time,“Made in China 2025”also elaborates on the strategic concept of innovation-driven and green development centered,and strives for breakthroughs in key industries such as new energy vehicles.In such a macro environment,adopting green innovation measures by enterprises not only contributes to ecological protection but also has an undeniable impact on their economic performance and overall value.This article takes BYD Group as a case study to explore in detail the positive effects of green innovation on its economic performance.We first systematically organized and analyzed BYD’s specific practices in green innovation;Then,by examining three key financial indicators,BYD’s current financial situation was analyzed in depth;On this basis,combined with research data,the positive impact of green innovation on BYD’s financial performance was revealed;Finally,based on the analysis results,relevant suggestions are proposed to provide reference for the sustainable development of enterprises in the context of“dual carbon.”展开更多
Against the backdrop of global climate change and China’s“dual carbon”goals,the green transformation of the construction industry is imperative,and completing the transformation requires many dual carbon talents to...Against the backdrop of global climate change and China’s“dual carbon”goals,the green transformation of the construction industry is imperative,and completing the transformation requires many dual carbon talents to support it.This article focuses on the construction engineering technology major in higher vocational education.It explores in depth the specific requirements for construction engineering technology talents in terms of professional knowledge,vocational skills,and literacy under the dual carbon mode.Based on this,corresponding dual carbon talent training courses are proposed,aiming to provide theoretical support and practical guidance for cultivating high-quality dual carbon talents that meet the needs of the new era.展开更多
In responding to the“dual carbon”strategy,intelligent networked new energy vehicle technology plays a crucial role.This type of vehicle combines the advantages of new energy technology and intelligent network techno...In responding to the“dual carbon”strategy,intelligent networked new energy vehicle technology plays a crucial role.This type of vehicle combines the advantages of new energy technology and intelligent network technology,effectively reduces carbon emissions in the transportation sector,improves energy utilization efficiency,and contributes to the green transportation system through intelligent transportation management and collaborative work between vehicles,making significant contributions.This article aims to explore the development of intelligent network-connected new energy vehicle technology and applications under the dual-carbon strategy and lay the foundation for the future development direction of the automotive industry.展开更多
A dual wavelength differential first derivative spectrophotometric method has been developed to standardize the concentration of a saturated aqueous solution of carbon monoxide (CO) as the standard and to identify and...A dual wavelength differential first derivative spectrophotometric method has been developed to standardize the concentration of a saturated aqueous solution of carbon monoxide (CO) as the standard and to identify and to determine CO formed during the microsomal metabolism of xenobiotics in vitro. The method can significantly eliminate the background interference in the assay media and increase the quantitative accuracy and the sensitivity. There is a good linear relationship between CO concentration in the range of 2~10 μmol·L 1 CO and the distance D between the first derivative peak at 415 nm amd valley at 426 nm with r=0.9999(n=5),the regression equation being C (mmol·L 1 )=17.6D 0.4, the detection limit lower than 0.1 μmol·L 1 CO. The average recoveries of CO from the assay system and the sample were 102.1%, RSD=2.9% (n=7) and 79.7%, RSD=6.8% (n=12),respectively. The RSD of within day was 4.4%(n=18),and the RSD of day to day was 6.1%(n=16). By this method, four trihaloanilines and one trihalobenzene were tested, the results showed that only 2,4,5 trifluoroaniline could be converted to CO by the incubation with rat hepatic microsomes, NADPH and oxygen, the ability of phenobarbital or dexamethasone to induce rat hepatic microsomes to catalyze CO formation was 3 or 8 times higher than that of the control.展开更多
Cave carbonate formations are characterized by heterogeneity, which makes electrical log prediction difficult. It is currently important to know how to use the dual laterolog to accurately identify and quantitatively ...Cave carbonate formations are characterized by heterogeneity, which makes electrical log prediction difficult. It is currently important to know how to use the dual laterolog to accurately identify and quantitatively evaluate caves. Using numerical simulation to calculate electrical log responses can provide a theoretical basis for cave identification and evaluation. In this paper, based on the dual laterolog principles, we first study different size spherical cave models using the finite element method (FEM), determine a relation between resistivity and cave filling after comprehensively studying the log responses of cave models with different filling material, and finally study the dual laterolog responses on caves filled with shale, limestone, conglomerate, and thin laminated formation of sand and shale. The numerical results provide a theoretical basis for identification and evaluation of carbonate cave reservoirs.展开更多
We demonstrated a simple and effective dual-templating approach for the synthesis of hierarchically mesocellular carbon foams by using nonionic surfactant of sorbitan monooleate and silica colloid particles as sacrifi...We demonstrated a simple and effective dual-templating approach for the synthesis of hierarchically mesocellular carbon foams by using nonionic surfactant of sorbitan monooleate and silica colloid particles as sacrificial templates, and resorcinol/ formaldehyde as carbon source. The representative carbon foam has dual mesopore sizes of 4 and 10 nm, and possesses the specific surface area of 580 m^2/g and the total pore volume of 0.80 cm^3/g.展开更多
Goal oriented( GO) methodology is a kind of success oriented system reliability analysis method and has been used widely.The repairable system with dual input closed-loop feedback link( DICLFL) considering shutdown co...Goal oriented( GO) methodology is a kind of success oriented system reliability analysis method and has been used widely.The repairable system with dual input closed-loop feedback link( DICLFL) considering shutdown correlation didn't make reliability analysis accurately based on existing GO methodology. So, a reliability analysis method used to deal with DICLFL considering shutdown correlation is provided based on GO methodology.Firstly, a new operator, which is used to describe DICLFL considering shutdown correlation,whose number is 1,is created and named as Type 9C operator. And then,the formulas of type 9C operator are derived based on Markov process theory. Finally,the new method presented in this paper is adopted to conduct the reliability analysis of an electro-hydraulic servo speed control system. The analysis result is compared with those of Monte Carlo simulation and fault tree analysis( FTA). The comparison results show that this new reliability analysis method based on GO methodology is feasible and meaningful for reliability analysis of repairable systems with DICLFL considering shutdown correlation.Meantime,it will be useful for more other applications.展开更多
The key to construct high-energy supercapacitors is to maximize the capacitance of electrode and the voltage of the device. Realizing this purpose by utilizing sustainable and low-cost resources is still a big challen...The key to construct high-energy supercapacitors is to maximize the capacitance of electrode and the voltage of the device. Realizing this purpose by utilizing sustainable and low-cost resources is still a big challenge. Herein, N, B co-doped carbon nanosheets are obtained through the proposed dual-template assisted approach by using methyl cellulose as the precursor. Due to the synergistic effects form the high surface area with the hierarchical porous structure, N/B dual doping, and a high degree of graphitization, the resultant carbon electrode exhibits a high capacitance of 572 F g^(-1)at 0.5 A g^(-1)and retains 281 F g^(-1)at 50 A g^(-1)in an acidic electrolyte. Furthermore, the symmetric device assembled using bacterial cellulose-based gel polymer electrolyte can deliver high energy density of 43 W h kg^(-1)and excellent cyclability with 97.8% capacity retention after 20 000 cycles in “water in salt” electrolyte. This work successfully realizes the fabrication of high-performance allcellulose-based quasi-solid-state supercapacitors, which brings a cost-effective insight into jointly designing electrodes and electrolytes for supporting highly efficient energy storage.展开更多
The electronic and functional synergies between the twin metal centers make dual single-atom catalysts(DACs) attractive for oxygen electrocatalysis. The catalytic activities of DACs are largely decided by their surrou...The electronic and functional synergies between the twin metal centers make dual single-atom catalysts(DACs) attractive for oxygen electrocatalysis. The catalytic activities of DACs are largely decided by their surrounding micro-environment and supporting substrates. Modulating the micro-environment as well as engineering the efficient support is challenging tasks. Moreover, both are critical to optimizing the performance of DACs. Herein, a novel bio-cooperative strategy is developed to synthesize Fe Ni-DAC wherein Fe-Ni dual-atom sites are embedded in the N, P codoped tyre shaped carbon matrix. The configuration matching of Fe-Ni dual centers together with the local electronic engineering of N, P heteroatoms synergistically boost the catalytic activity on the oxygen reaction. Furthermore, the central-hollow highlyporous carbon matrix not only gives rise to a large amount of active sites, but also facilitates fast kinetics.Taking advantage of both the DAC and the substrate, the Fe Ni-NPC hollow tyre(HT) catalyst scores high in both oxygen reduction and evolution reactions, which exhibits the narrow potential difference and excellent durability. The aqueous Zn-air full battery(ZAB) integrating the Fe Ni-NPC HT air cathode has a high power density and a good stability over long-term cycling. Moreover, the flexible solid-state ZAB assembled with the polymer electrolyte obtains the high reliability over a wide range of temperatures or under diverse outside deformations. Therefore, this work offers a new green approach to prepare highly efficient DACs with built-in modulated micro-environment and tailor-made substrates. Moreover,it also paves a new way to develop highly-pliable power source for flexible electronics.展开更多
The estimation of fractures is key to evaluating fractured carbonate reservoirs. It is difficult to evaluate this kind of reservoir because of its heterogeneously distributed fractures and anisotropy, A three-dimensio...The estimation of fractures is key to evaluating fractured carbonate reservoirs. It is difficult to evaluate this kind of reservoir because of its heterogeneously distributed fractures and anisotropy, A three-dimensional numerical model was used to simulate the responses of the dual laterolog (DLL) in a fractured formation based on a macro-isotropic anisotropic model, Accordingly, a fast fracture computing method was developed. First, the apparent conductivity of the DLL is linearly related to the porosity of the fracture and the conductivity of pore fluid. Second, the amplitude difference of the deep and shallow apparent resistivity logs is mainly dependent on the dip angle of the fracture. Then the response of the DLL to a formation with dip angle fractures is approximately depicted as a function of the bulk resistivity of the rock, the porosity of the fractures and the conductivity of fracture fluid. This function can be used to compute the porosity of fracture quickly. The actual data show that the fracture parameters determined by the DLL closely coincide with the formation micro imager log.展开更多
CdS nanosheets(NSs)photocatalysts modified with dual earth‐abundant co‐catalysts of metallic carbon black(CB)and NiS2were synthesized by a two‐step solvothermal/impregnation method.Allthe experiment results demonst...CdS nanosheets(NSs)photocatalysts modified with dual earth‐abundant co‐catalysts of metallic carbon black(CB)and NiS2were synthesized by a two‐step solvothermal/impregnation method.Allthe experiment results demonstrated that the co‐loading of CB and NiS2could significantly enhance the photocatalytic H2‐evolution activity of CdS NSs.The photocatalytic performance of the as‐prepared CdS/CB/NiS2samples was tested under visible light(λ≥420nm)by using an aqueous solution containing0.25mol L–1Na2S‐Na2SO3as the sacrifice agent.The CdS‐0.5%CB‐1.0%NiS2composite photocatalysts exhibited the highest H2‐evolution rate of166.7μmol h?1,which was approximately5.16and1.87times higher than those of pure CdS NSs and CdS‐1.0%NiS2,respectively.The possible mechanism for the enhanced H2‐evolution activity of CdS/CB/NiS2composite photocatalysts was proposed.The results showed that the enhanced photocatalytic H2‐evolution activities could be ascribed to the co‐loading of metallic CB and NiS2as co‐catalysts onto the surface of CdS NSs.The excellent synergetic effect between the CB and NiS2could obviously improve visible light absorption,promote separation of photogenerated electron‐hole pairs and boost the H2‐evolution kinetics,thus leading to an enhanced activity for H2evolution.More interestingly,the metallic CB could not only act as a cocatalyst for H2evolution,but also serve as a conductive electron bridge to promote the charge migration.This work not only demonstrates that loading CB as a co‐catalyst is a promising strategy to further boost the photocatalytic activity of CdS/NiS2composites,but also offers a new mechanistic insight into the construction of highly efficient and stable CdS NSs‐based hybrid photocatalysts with dual earth‐abundant co‐catalysts for photocatalytic applications.展开更多
The electrochemical carbon dioxide reduction reaction(CO_(2)RR)for highvalue-added products is a promising strategy to tackle excessive CO_(2) emissions.However,the activity of and selectivity for catalysts for CO_(2)...The electrochemical carbon dioxide reduction reaction(CO_(2)RR)for highvalue-added products is a promising strategy to tackle excessive CO_(2) emissions.However,the activity of and selectivity for catalysts for CO_(2)RR still need to be improved because of the competing reaction(hydrogen evolution reaction).In this study,for the first time,we have demonstrated dual atomic catalytic sites for CO_(2)RR from a core-shell hybrid of the covalent-organic framework and the metal-organic framework.Due to abundant dual atomic sites(with CoN_(4)O and ZnN_(4) of 2.47 and 11.05 wt.%,respectively)on hollow carbon,the catalyst promoted catalysis of CO_(2)RR,with the highest Faradic efficiency for CO of 92.6%at-0.8 V and a turnover frequency value of 1370.24 h^(-1) at-1.0 V.More importantly,the activity and selectivity of the catalyst were well retained for 30 h.The theoretical calculation further revealed that CoN_(4)O was the main site for CO_(2)RR,and the activity of and selectivity for Zn sites were also improved because of the synergetic roles.展开更多
We develop a dual porous (DP) TiO2 film for the electron transporting layer (ETL) in carbon cathode based perovskite solar cells (C-PSCs). The DP TiO2 film was synthesized via a facile PS-templated method with t...We develop a dual porous (DP) TiO2 film for the electron transporting layer (ETL) in carbon cathode based perovskite solar cells (C-PSCs). The DP TiO2 film was synthesized via a facile PS-templated method with the thickness being controlled by the spin-coating speed. It was found that there is an optimum DP TiO2 film thickness for achieving an effective ETL, a suitable perovskite]TiO2 interface, an efficient light harvester and thus a high performance C-PSC. In particular, such a DP TiO2 film can act as a scaffold for complete-filling of the pores with perovskite and for forming high-quality perovskite crystals that are seamlessly interfaced with Ti02 to enhance interracial charge injection. Leveraging the unique advantages of DP TiO2 ETL, together with a dense-packed and pinhole-free TiO2 compact layer, PCE of the C-PSCs has reached 9.81% with good stability.展开更多
In dual-ion batteries (DIBs), energy storage is achieved by intercalation/de-intercalation of both cations and anions. Due to the mismatch between ion diameter and layer space of active materials, however, volume expa...In dual-ion batteries (DIBs), energy storage is achieved by intercalation/de-intercalation of both cations and anions. Due to the mismatch between ion diameter and layer space of active materials, however, volume expansion and exfoliation always occur for electrode materials. Herein, an integrated electrode Co3O4/carbon fiber paper (CFP) is prepared as the anode of DIB. As the Co3O4 nanosheets grow on CFP substrate vertically, it promotes the immersion of electrolyte and shortens the pathway for ionic transport. Besides, the strong interaction between Co3O4 and CFP substrate reduces the possibility of sheet exfoliation. An integrated-electrode-based DIB is therefore packaged using Co3O4/CFP as anode and graphite as cathode. As a result, a high energy density of 72 Wh/kg is achieved at a power density of 150 W/kg. The design of integrated electrode provides a new route for the development of high-performance DIBs.展开更多
A novel carbon foam with microporous structure(CFMS),with the advantages of a simple fabrication process,low energy consumption,large specific surface area and high conductivity,has been prepared by a facile one-step ...A novel carbon foam with microporous structure(CFMS),with the advantages of a simple fabrication process,low energy consumption,large specific surface area and high conductivity,has been prepared by a facile one-step carbonization.In addition,the carbon foam possesses suitable interlayer spacing in short range which is flexible to accommodate the deformation of carbon layer caused by the ion insertion and deinsertion at the charge and discharge state.Furthermore,a low cost carbon-based symmetric potassium dual-ion capacitor(PDIC),which integrates the virtues of potassium ion capacitors and dual-ion batteries,is successfully established with CFMS as both the battery-type cathode and the capacitor-type anode.PDIC displays a superior rate performance,an ultra-long cycle life(90%retention after 10000 cycles),and a high power density of 7800 W kg^-1 at an energy density of 39Whkg^-1.The PDIC also exhibits excellent ultrafast charge and slow discharge properties,with a full charge in just 60 s and a discharge time of more than 3000 s.展开更多
Lithium-ion hybrid supercapacitors(Li-HSCs) and dual-ion batteries(DIBs) are two types of energy storage devices that have attracted extensive research interest in recent years. Li-HSCs and DIBs have similarities in d...Lithium-ion hybrid supercapacitors(Li-HSCs) and dual-ion batteries(DIBs) are two types of energy storage devices that have attracted extensive research interest in recent years. Li-HSCs and DIBs have similarities in device structure, tendency for ion migration, and energy storage mechanisms at the negative electrode. However, these devices have differences in energy storage mechanisms and working potentials at the positive electrode. Here, we first realize the integration of a Li-HSC and a DIB to form a dual-ion hybrid supercapacitor(DIHSC), by employing mesocarbon microbead(MCMB)-based porous graphitic carbon(PGC) with a partially graphitized structure and porous structure as a positive electrode material. The MCMB-PGC-based DIHSC exhibits a novel dual-ion battery-capacitor hybrid mechanism: it exhibits excellent electronic double-layer capacitor(EDLC) behavior like a Li-HSC in the low-middle wide potential range and anion intercalation/de-intercalation behavior like a DIB in the high-potential range. Two types of mechanisms are observed in the electrochemical characterization process, and the energy density of the new DIHSC is significantly increased.展开更多
基金supported by the National Social Science Fund of China[Grant No.21FJYB058].
文摘The pathways to achieving carbon neutrality at the city level are diverse due to varying energy supply and demand conditions.Shanghai faces obstacles such as limited land resources,high costs of renewable energy technologies,and instability of renewable energy.These challenges hinder the city’s efforts to achieve carbon peak and carbon neutrality(dual carbon).Therefore,Shanghai must identify and optimize its development path for renewable energy under the dual carbon goal.We employed the Low Emissions Analysis Platform Shanghai(LEAP-SH)model to simulate the impact of policies,such as industrial upgrading,energy efficiency improvement,energy structure optimization,increased technical innovation on energy,and ecological restoration,on the carbon emission pathways from 2022 to 2060 using five different scenarios.Our results indicate that Shanghai has the potential to achieve carbon neutrality in 2059 by promoting carbon reduction,pollution control,and green expansion.Moreover,we determined that the manufacturing industry;power generation industry;and transportation,storage,and mail services are the three major sectors for emission reduction under the dual carbon goal.Furthermore,the capacity and output of coal-fired power plants will be gradually replaced by offshore wind power in the dual carbon pathway.Finally,this study proposes countermeasures and suggestions for Shanghai to attain the dual carbon goal and high-quality development.
基金the AL-Mustaqbal Universitythe University of Technology-Iraq for their support。
文摘Fatigue properties play a crucial role as they are vital to ensuring the durability and integrity of components subjected to repeated loading conditions over long periods.The main objective of this work is to investigate the fatigue behavior of dual phase low-carbon steels used in automotive applications using a rotating bending fatigue machine.Heat treatments were carried out to analyze the microstructure's effect on the fatigue properties,including quenching low-carbon steel samples at 800℃ and 900℃.Hardness and tensile tests were performed,and the microstructure was inspected to examine the constitute phases.With the assistance of a scanning electron microscope,fractographic analyses were carried out to reveal the fracture features of the samples at different lifetime ranges.The results show that various failure mechanisms occur depending on the stress levels.Additionally,the specimens quenched at 900℃ exhibited higher fatigue strength.
基金Interim Achievements of the 2023 Internationalization Special Projects 2023ZX13 and 2023ZX14 of Zhejiang Financial College。
文摘With the increasingly severe global climate change problem,the“dual carbon”goals(peak carbon emissions and carbon neutrality)have become a common focus of international attention.The report of the 20th National Congress of the Communist Party of China clearly emphasizes the need to accelerate the green transformation of development models,implement comprehensive strategies for frugal development,support the growth of green and low-carbon industries,and promote the concept of green consumption.At the same time,“Made in China 2025”also elaborates on the strategic concept of innovation-driven and green development centered,and strives for breakthroughs in key industries such as new energy vehicles.In such a macro environment,adopting green innovation measures by enterprises not only contributes to ecological protection but also has an undeniable impact on their economic performance and overall value.This article takes BYD Group as a case study to explore in detail the positive effects of green innovation on its economic performance.We first systematically organized and analyzed BYD’s specific practices in green innovation;Then,by examining three key financial indicators,BYD’s current financial situation was analyzed in depth;On this basis,combined with research data,the positive impact of green innovation on BYD’s financial performance was revealed;Finally,based on the analysis results,relevant suggestions are proposed to provide reference for the sustainable development of enterprises in the context of“dual carbon.”
基金Reform and Practice of Talent Training Mode for Construction Engineering Technology Majors Serving the National Dual Carbon Strategy(Project No.Z233314)。
文摘Against the backdrop of global climate change and China’s“dual carbon”goals,the green transformation of the construction industry is imperative,and completing the transformation requires many dual carbon talents to support it.This article focuses on the construction engineering technology major in higher vocational education.It explores in depth the specific requirements for construction engineering technology talents in terms of professional knowledge,vocational skills,and literacy under the dual carbon mode.Based on this,corresponding dual carbon talent training courses are proposed,aiming to provide theoretical support and practical guidance for cultivating high-quality dual carbon talents that meet the needs of the new era.
文摘In responding to the“dual carbon”strategy,intelligent networked new energy vehicle technology plays a crucial role.This type of vehicle combines the advantages of new energy technology and intelligent network technology,effectively reduces carbon emissions in the transportation sector,improves energy utilization efficiency,and contributes to the green transportation system through intelligent transportation management and collaborative work between vehicles,making significant contributions.This article aims to explore the development of intelligent network-connected new energy vehicle technology and applications under the dual-carbon strategy and lay the foundation for the future development direction of the automotive industry.
文摘A dual wavelength differential first derivative spectrophotometric method has been developed to standardize the concentration of a saturated aqueous solution of carbon monoxide (CO) as the standard and to identify and to determine CO formed during the microsomal metabolism of xenobiotics in vitro. The method can significantly eliminate the background interference in the assay media and increase the quantitative accuracy and the sensitivity. There is a good linear relationship between CO concentration in the range of 2~10 μmol·L 1 CO and the distance D between the first derivative peak at 415 nm amd valley at 426 nm with r=0.9999(n=5),the regression equation being C (mmol·L 1 )=17.6D 0.4, the detection limit lower than 0.1 μmol·L 1 CO. The average recoveries of CO from the assay system and the sample were 102.1%, RSD=2.9% (n=7) and 79.7%, RSD=6.8% (n=12),respectively. The RSD of within day was 4.4%(n=18),and the RSD of day to day was 6.1%(n=16). By this method, four trihaloanilines and one trihalobenzene were tested, the results showed that only 2,4,5 trifluoroaniline could be converted to CO by the incubation with rat hepatic microsomes, NADPH and oxygen, the ability of phenobarbital or dexamethasone to induce rat hepatic microsomes to catalyze CO formation was 3 or 8 times higher than that of the control.
基金supported by State Key Laboratory of Petroleum Resources and Prospecting (Grant No. 2009009)Basic Scientific Research Special Fund of Central Colleges (Grant No. 2010ZY28)National Major Projects (Grant No.2008ZX05023-005 and 2008ZX05035-002)
文摘Cave carbonate formations are characterized by heterogeneity, which makes electrical log prediction difficult. It is currently important to know how to use the dual laterolog to accurately identify and quantitatively evaluate caves. Using numerical simulation to calculate electrical log responses can provide a theoretical basis for cave identification and evaluation. In this paper, based on the dual laterolog principles, we first study different size spherical cave models using the finite element method (FEM), determine a relation between resistivity and cave filling after comprehensively studying the log responses of cave models with different filling material, and finally study the dual laterolog responses on caves filled with shale, limestone, conglomerate, and thin laminated formation of sand and shale. The numerical results provide a theoretical basis for identification and evaluation of carbonate cave reservoirs.
基金supported by the National Natural Science Foundation of China(Nos.20473057 and 20673076)Shanghai Nanotechnology Promotion Center(Nos.0652nm030 and 0752nm006).
文摘We demonstrated a simple and effective dual-templating approach for the synthesis of hierarchically mesocellular carbon foams by using nonionic surfactant of sorbitan monooleate and silica colloid particles as sacrificial templates, and resorcinol/ formaldehyde as carbon source. The representative carbon foam has dual mesopore sizes of 4 and 10 nm, and possesses the specific surface area of 580 m^2/g and the total pore volume of 0.80 cm^3/g.
基金Technical Basis Projects of China's MIIT(Nos.ZQ092012B003,2012090003)
文摘Goal oriented( GO) methodology is a kind of success oriented system reliability analysis method and has been used widely.The repairable system with dual input closed-loop feedback link( DICLFL) considering shutdown correlation didn't make reliability analysis accurately based on existing GO methodology. So, a reliability analysis method used to deal with DICLFL considering shutdown correlation is provided based on GO methodology.Firstly, a new operator, which is used to describe DICLFL considering shutdown correlation,whose number is 1,is created and named as Type 9C operator. And then,the formulas of type 9C operator are derived based on Markov process theory. Finally,the new method presented in this paper is adopted to conduct the reliability analysis of an electro-hydraulic servo speed control system. The analysis result is compared with those of Monte Carlo simulation and fault tree analysis( FTA). The comparison results show that this new reliability analysis method based on GO methodology is feasible and meaningful for reliability analysis of repairable systems with DICLFL considering shutdown correlation.Meantime,it will be useful for more other applications.
基金supported by the National Natural Science Foundation of China (No.22179123 and 21471139)the Shandong Provincial Natural Science Foundation,China (ZR2020ME038)+2 种基金the Fundamental Research Funds for the Central Universities (No.201941010)the Shandong Provincial Key R&D Plan and the Public Welfare Special Program,China (2019GGX102038)the Qingdao City Programs for Science and Technology Plan Projects (19-6-2-77-cg)。
文摘The key to construct high-energy supercapacitors is to maximize the capacitance of electrode and the voltage of the device. Realizing this purpose by utilizing sustainable and low-cost resources is still a big challenge. Herein, N, B co-doped carbon nanosheets are obtained through the proposed dual-template assisted approach by using methyl cellulose as the precursor. Due to the synergistic effects form the high surface area with the hierarchical porous structure, N/B dual doping, and a high degree of graphitization, the resultant carbon electrode exhibits a high capacitance of 572 F g^(-1)at 0.5 A g^(-1)and retains 281 F g^(-1)at 50 A g^(-1)in an acidic electrolyte. Furthermore, the symmetric device assembled using bacterial cellulose-based gel polymer electrolyte can deliver high energy density of 43 W h kg^(-1)and excellent cyclability with 97.8% capacity retention after 20 000 cycles in “water in salt” electrolyte. This work successfully realizes the fabrication of high-performance allcellulose-based quasi-solid-state supercapacitors, which brings a cost-effective insight into jointly designing electrodes and electrolytes for supporting highly efficient energy storage.
基金supported by the Innovation Foundation of Graduate Student of Harbin Normal University (HSDSSCX2022-111)the Natural Science Foundation of Heilongjiang Province of China(TD2020B001)the Opening Project of State Key Laboratory of Advanced Chemical Power Sources (SKL-ACPS-C-25)。
文摘The electronic and functional synergies between the twin metal centers make dual single-atom catalysts(DACs) attractive for oxygen electrocatalysis. The catalytic activities of DACs are largely decided by their surrounding micro-environment and supporting substrates. Modulating the micro-environment as well as engineering the efficient support is challenging tasks. Moreover, both are critical to optimizing the performance of DACs. Herein, a novel bio-cooperative strategy is developed to synthesize Fe Ni-DAC wherein Fe-Ni dual-atom sites are embedded in the N, P codoped tyre shaped carbon matrix. The configuration matching of Fe-Ni dual centers together with the local electronic engineering of N, P heteroatoms synergistically boost the catalytic activity on the oxygen reaction. Furthermore, the central-hollow highlyporous carbon matrix not only gives rise to a large amount of active sites, but also facilitates fast kinetics.Taking advantage of both the DAC and the substrate, the Fe Ni-NPC hollow tyre(HT) catalyst scores high in both oxygen reduction and evolution reactions, which exhibits the narrow potential difference and excellent durability. The aqueous Zn-air full battery(ZAB) integrating the Fe Ni-NPC HT air cathode has a high power density and a good stability over long-term cycling. Moreover, the flexible solid-state ZAB assembled with the polymer electrolyte obtains the high reliability over a wide range of temperatures or under diverse outside deformations. Therefore, this work offers a new green approach to prepare highly efficient DACs with built-in modulated micro-environment and tailor-made substrates. Moreover,it also paves a new way to develop highly-pliable power source for flexible electronics.
基金This paper is supported by the National High Technology Research andDevelopment Programof China (No .863-306-ZT01-02-3) .
文摘The estimation of fractures is key to evaluating fractured carbonate reservoirs. It is difficult to evaluate this kind of reservoir because of its heterogeneously distributed fractures and anisotropy, A three-dimensional numerical model was used to simulate the responses of the dual laterolog (DLL) in a fractured formation based on a macro-isotropic anisotropic model, Accordingly, a fast fracture computing method was developed. First, the apparent conductivity of the DLL is linearly related to the porosity of the fracture and the conductivity of pore fluid. Second, the amplitude difference of the deep and shallow apparent resistivity logs is mainly dependent on the dip angle of the fracture. Then the response of the DLL to a formation with dip angle fractures is approximately depicted as a function of the bulk resistivity of the rock, the porosity of the fractures and the conductivity of fracture fluid. This function can be used to compute the porosity of fracture quickly. The actual data show that the fracture parameters determined by the DLL closely coincide with the formation micro imager log.
基金supported by the National Natural Science Foundation of China(51672089)the Science and Technology Planning Project of Guangdong Province(2015B020215011)the State Key Laboratory of Advanced Technology for Material Synthesis and Processing(Wuhan University of Technology)(2015-KF-7)~~
文摘CdS nanosheets(NSs)photocatalysts modified with dual earth‐abundant co‐catalysts of metallic carbon black(CB)and NiS2were synthesized by a two‐step solvothermal/impregnation method.Allthe experiment results demonstrated that the co‐loading of CB and NiS2could significantly enhance the photocatalytic H2‐evolution activity of CdS NSs.The photocatalytic performance of the as‐prepared CdS/CB/NiS2samples was tested under visible light(λ≥420nm)by using an aqueous solution containing0.25mol L–1Na2S‐Na2SO3as the sacrifice agent.The CdS‐0.5%CB‐1.0%NiS2composite photocatalysts exhibited the highest H2‐evolution rate of166.7μmol h?1,which was approximately5.16and1.87times higher than those of pure CdS NSs and CdS‐1.0%NiS2,respectively.The possible mechanism for the enhanced H2‐evolution activity of CdS/CB/NiS2composite photocatalysts was proposed.The results showed that the enhanced photocatalytic H2‐evolution activities could be ascribed to the co‐loading of metallic CB and NiS2as co‐catalysts onto the surface of CdS NSs.The excellent synergetic effect between the CB and NiS2could obviously improve visible light absorption,promote separation of photogenerated electron‐hole pairs and boost the H2‐evolution kinetics,thus leading to an enhanced activity for H2evolution.More interestingly,the metallic CB could not only act as a cocatalyst for H2evolution,but also serve as a conductive electron bridge to promote the charge migration.This work not only demonstrates that loading CB as a co‐catalyst is a promising strategy to further boost the photocatalytic activity of CdS/NiS2composites,but also offers a new mechanistic insight into the construction of highly efficient and stable CdS NSs‐based hybrid photocatalysts with dual earth‐abundant co‐catalysts for photocatalytic applications.
基金Q.Xu acknowledges financial support from the Natural Science Foundation of Shanghai(20ZR1464000)G.Zeng is grateful for the support from the National Natural Science Foundation of China(21878322,22075309)the Science and Technology Commission of Shanghai(19ZR1479200).The authors also thank the Shanghai Synchrotron Radiation Facility for XAFS measurements at Beamline BL14w1.
文摘The electrochemical carbon dioxide reduction reaction(CO_(2)RR)for highvalue-added products is a promising strategy to tackle excessive CO_(2) emissions.However,the activity of and selectivity for catalysts for CO_(2)RR still need to be improved because of the competing reaction(hydrogen evolution reaction).In this study,for the first time,we have demonstrated dual atomic catalytic sites for CO_(2)RR from a core-shell hybrid of the covalent-organic framework and the metal-organic framework.Due to abundant dual atomic sites(with CoN_(4)O and ZnN_(4) of 2.47 and 11.05 wt.%,respectively)on hollow carbon,the catalyst promoted catalysis of CO_(2)RR,with the highest Faradic efficiency for CO of 92.6%at-0.8 V and a turnover frequency value of 1370.24 h^(-1) at-1.0 V.More importantly,the activity and selectivity of the catalyst were well retained for 30 h.The theoretical calculation further revealed that CoN_(4)O was the main site for CO_(2)RR,and the activity of and selectivity for Zn sites were also improved because of the synergetic roles.
基金supported by the HK Innovation and Technology Fund (ITS/004/14)the HK-RGC General Research Funds (GRE No. HKUST 606511)
文摘We develop a dual porous (DP) TiO2 film for the electron transporting layer (ETL) in carbon cathode based perovskite solar cells (C-PSCs). The DP TiO2 film was synthesized via a facile PS-templated method with the thickness being controlled by the spin-coating speed. It was found that there is an optimum DP TiO2 film thickness for achieving an effective ETL, a suitable perovskite]TiO2 interface, an efficient light harvester and thus a high performance C-PSC. In particular, such a DP TiO2 film can act as a scaffold for complete-filling of the pores with perovskite and for forming high-quality perovskite crystals that are seamlessly interfaced with Ti02 to enhance interracial charge injection. Leveraging the unique advantages of DP TiO2 ETL, together with a dense-packed and pinhole-free TiO2 compact layer, PCE of the C-PSCs has reached 9.81% with good stability.
基金Supports from the National Natural Science Foundation of China (51872115 and 51802110)the National Key R&D Program of China (2016YFA0200400)+2 种基金the Jilin Province/Jilin University Co-construction Project-Funds for New Materials (SXGJSF20173, Branch-2/440050316A36)the Program for JLU Science and Technology Innovative Research Team (JLUSTIRT, 2017TD-09)“Double-First Class” Discipline for Materials Science & Engineering, are greatly acknowledged
文摘In dual-ion batteries (DIBs), energy storage is achieved by intercalation/de-intercalation of both cations and anions. Due to the mismatch between ion diameter and layer space of active materials, however, volume expansion and exfoliation always occur for electrode materials. Herein, an integrated electrode Co3O4/carbon fiber paper (CFP) is prepared as the anode of DIB. As the Co3O4 nanosheets grow on CFP substrate vertically, it promotes the immersion of electrolyte and shortens the pathway for ionic transport. Besides, the strong interaction between Co3O4 and CFP substrate reduces the possibility of sheet exfoliation. An integrated-electrode-based DIB is therefore packaged using Co3O4/CFP as anode and graphite as cathode. As a result, a high energy density of 72 Wh/kg is achieved at a power density of 150 W/kg. The design of integrated electrode provides a new route for the development of high-performance DIBs.
基金financially supported by the National Natural Science Foundation of China(Nos.51672078 and 21473052)Hunan University State Key Laboratory of Advanced Design and Manufacturing for Vehicle Body Independent Research Project(No.71675004)+2 种基金the Fundamental Research Funds for the Central UniversitiesHunan Natural Science Foundation(2019JJ40031)Foundation of State Key Laboratory of Coal Conversion(Grant J1718-903)。
文摘A novel carbon foam with microporous structure(CFMS),with the advantages of a simple fabrication process,low energy consumption,large specific surface area and high conductivity,has been prepared by a facile one-step carbonization.In addition,the carbon foam possesses suitable interlayer spacing in short range which is flexible to accommodate the deformation of carbon layer caused by the ion insertion and deinsertion at the charge and discharge state.Furthermore,a low cost carbon-based symmetric potassium dual-ion capacitor(PDIC),which integrates the virtues of potassium ion capacitors and dual-ion batteries,is successfully established with CFMS as both the battery-type cathode and the capacitor-type anode.PDIC displays a superior rate performance,an ultra-long cycle life(90%retention after 10000 cycles),and a high power density of 7800 W kg^-1 at an energy density of 39Whkg^-1.The PDIC also exhibits excellent ultrafast charge and slow discharge properties,with a full charge in just 60 s and a discharge time of more than 3000 s.
基金supported by the National Natural Science Foundation of China (grant no. 51672151).
文摘Lithium-ion hybrid supercapacitors(Li-HSCs) and dual-ion batteries(DIBs) are two types of energy storage devices that have attracted extensive research interest in recent years. Li-HSCs and DIBs have similarities in device structure, tendency for ion migration, and energy storage mechanisms at the negative electrode. However, these devices have differences in energy storage mechanisms and working potentials at the positive electrode. Here, we first realize the integration of a Li-HSC and a DIB to form a dual-ion hybrid supercapacitor(DIHSC), by employing mesocarbon microbead(MCMB)-based porous graphitic carbon(PGC) with a partially graphitized structure and porous structure as a positive electrode material. The MCMB-PGC-based DIHSC exhibits a novel dual-ion battery-capacitor hybrid mechanism: it exhibits excellent electronic double-layer capacitor(EDLC) behavior like a Li-HSC in the low-middle wide potential range and anion intercalation/de-intercalation behavior like a DIB in the high-potential range. Two types of mechanisms are observed in the electrochemical characterization process, and the energy density of the new DIHSC is significantly increased.