Cellulose, the most abundant organic polymer on Earth, is a sustainable source of carbon to use as a negative electrode for sodium ion batteries. Here, hard carbons(HC) prepared by cellulose pyrolysis were investigate...Cellulose, the most abundant organic polymer on Earth, is a sustainable source of carbon to use as a negative electrode for sodium ion batteries. Here, hard carbons(HC) prepared by cellulose pyrolysis were investigated with varying pyrolysis temperature from 700 °C to 1600 °C. Characterisation methods such as Small Angle X-ray Scattering(SAXS) measurements and N2adsorption were performed to analyse porosity differences between the samples. The graphene sheet arrangements were observed by transmission electron microscopy(TEM): an ordering of the graphene sheets is observed at temperatures above 1150 °C and small crystalline domains appear over 1400 °C. As the graphene sheets start to align, the BET surface area decreases and the micropore size increases. To correlate hard carbon structures and electrochemical performances, different tests in Na//HC cells with 1 M NaPF6ethylene carbonate/dimethyl carbonate(EC/DMC) were performed. Samples pyrolysed from 1300 °C to 1600 °C showed a 300 m Ah/g reversible capacity at C/10 rate(where C = 372 mA/g) with an excellent stability in cycling and a very good initial Coulombic efficiency of up to 84%. Furthermore, hard carbons showed an excellent rate capability where sodium extraction rate varies from C/10 to 5C. At 5C more than 80% of reversible capacity remains stable for hard carbons synthesized from 1000 °C to 1600 °C.展开更多
The microstructure of a Cu-Zn alloy treated under different high pressures was investigated by means of metallographic, scanning electron microscope （SEM）, energy dispersive spectrometer （EDS）, and X-ray diffracti...The microstructure of a Cu-Zn alloy treated under different high pressures was investigated by means of metallographic, scanning electron microscope （SEM）, energy dispersive spectrometer （EDS）, and X-ray diffraction （XRD）, and the hardness of the Cu-Zn alloy was also measured. The results show that the ct phase with a smaller grain size, different shapes, and random distribution appears in the Cu-Zn alloy during the solid-state phase transformation generation in the temperature range of 25-750℃ and the pressure range of 0-6 GPa. The amount of residual α phase in the microstructure decreases and then increases with increasing pressure. Under a high pressure of 3 GPa, the least volume fraction of residual a phase was obtained, and under a high pressure of 6 GPa, the changes of the microstructure of the Cu-Zn alloy were not obvious. In addition, high pressure can increase the hardness of the Cu-Zn alloy, but it cannot generate any new phase.展开更多
Concerning the issue of mine pressure behaviors occurred in fully mechanized caving mining of thick coal seams beneath hard stratum in Datong Mining Area, combined with thin and thick plate theory, the paper utilizes ...Concerning the issue of mine pressure behaviors occurred in fully mechanized caving mining of thick coal seams beneath hard stratum in Datong Mining Area, combined with thin and thick plate theory, the paper utilizes theoretical analysis, similar experiments, numerical simulations and field tests to study the influence of remaining coal pillars in Jurassic system goaf on hard stratum fractures, as well as mine pressure behaviors under their coupling effects. The paper concludes the solution formula of initial fault displacement in hard stratum caused by remaining coal pillars. Experiments prove that coupling effects can enhance mine pressure behaviors on working faces. When inter-layer inferior key strata fractures, mine pressure phenomenon such as significant roof weighting steps and increasing resistance in support.When inter-layer superior key strata fractures, the scope of overlying strata extends to Jurassic system goaf, dual-system stopes cut through, and remaining coal pillars lose stability. As a result, the bottom inferior key strata also lose stability. It causes huge impacts on working face, and the second mine pressure behaviors. These phenomena provide evidence for research on other similar mine strata pressure behaviors occurred in dual-system mines with remaining coal pillars.展开更多
This paper discusses experimental results of turnin g experiments on GCr15 bearing steel hardened to 60～64 HRC. The objective was to d etermine the effect of the cutting parameters on cutting force, chip morphology a...This paper discusses experimental results of turnin g experiments on GCr15 bearing steel hardened to 60～64 HRC. The objective was to d etermine the effect of the cutting parameters on cutting force, chip morphology and resultant workpiece surface quality, more specifically surface texture, micr ostructure alterations, changes in microhardness and residual stresses distribut ion. The changing rules of the main cutting force was shown in this paper which feature a increasing tendency with the improvement of the workpiece hardness wit hin the cutting parameter scope. The rule of cutting force changing with the wor kpiece hardness is accord to the traditional metal cutting theory. Stress value decrease with increasing cutting speed and workpiece hardness. The comparison of the machined surface roughness and harden layer depth of machined surface for d ifferent hardness is shown in Fig.1. The machined surface roughness is the worst when the workpiece hardness is around 50HRC. When the workpiece hardness is ove r 50HRC, the surface roughness value shows a descending tendency with the additi on hardness. The machined superficial harden layer depth shows an increasing ten dency with the improvement of the workpiece hardness. When the workpiece hardnes s is 50HRC the machined superficial harden layer depth is tiptop. When the workp iece hardness is over 50HRC the depth changes little with the addition of workpi ece hardness. The remnant stress status of the machined surface is shown in Fig. 2, which is press stress status both in surface and in base for less cutting par ameters under two kinds of cutting condition. But experiment results show that t ensile stress can be produced under uncomfortable cutting conditions. The deform ation created by the chip formation is reduced whereduce with [TPP126A,+35mm77mm,Z,PY#]Depth from surface (μm) ■ v=200m/min,f=0.24mm/r,ap=0.8mm,60HRC ● v=200m/min,f=0.15mm/r,ap=0.5mm,60HRC Fig.1 The subsurface residual stress between the two experimentsHardness (HRC) Fig.2 The surface finish vs. workpiece hardness the workpiece hardness is improved.展开更多
In order to explore the pressure relief and structure stability mechanism of lateral cantilever structure in the stope under the direct coverage of thick hard roof and its impact on the gob-side entry retaining, a lat...In order to explore the pressure relief and structure stability mechanism of lateral cantilever structure in the stope under the direct coverage of thick hard roof and its impact on the gob-side entry retaining, a lateral cantilever fractured structural mechanical model was established on the basis of clarification for the stress environment of gob-side entry retaining, and the equation of roof given deformation and the balance judgment for fracture block were obtained. The optimal cantilever length was proposed based on the comparison of roof structural characteristics and the stress, deformation law of surrounding rocks under six different cantilever lengths by numerical simulation method. Double stress peaks exist on the sides of gob-side entry retaining and the entry located in the low stress area. The pressure of gob-side entry retaining can be relieved by reducing the cantilever length. However, due to the impact of arch structure of rock beam, unduly short cantilever would result in insufficient pressure relief and unduly long cantilever would bring larger roof stress which results in intense deformation. Therefore, there is optimal cantilever length, which was 7-8 m in this project that enables to achieve the minimum deformation and the most stabilized rock structure of entry retaining. An engineering case of gob-side entry retaining with the direct coverage of 10 m thick hard limestone roof was put forward, and the measured data verified the reasonability of conclusion.展开更多
Flannery O'Connor is considered one of the outstanding female writers of the American South in the 20 th century.Her works not only reveal to readers a world of nihilism,but also describe a society of original sin...Flannery O'Connor is considered one of the outstanding female writers of the American South in the 20 th century.Her works not only reveal to readers a world of nihilism,but also describe a society of original sins.Nihilism reflected by two major characters and their fates in A Good Man Is Hard to Find demonstrate her concern about the lack of belief and emptiness of modern people's soul.展开更多
基金supported by Direction Générale de l’Armement(DGA)
文摘Cellulose, the most abundant organic polymer on Earth, is a sustainable source of carbon to use as a negative electrode for sodium ion batteries. Here, hard carbons(HC) prepared by cellulose pyrolysis were investigated with varying pyrolysis temperature from 700 °C to 1600 °C. Characterisation methods such as Small Angle X-ray Scattering(SAXS) measurements and N2adsorption were performed to analyse porosity differences between the samples. The graphene sheet arrangements were observed by transmission electron microscopy(TEM): an ordering of the graphene sheets is observed at temperatures above 1150 °C and small crystalline domains appear over 1400 °C. As the graphene sheets start to align, the BET surface area decreases and the micropore size increases. To correlate hard carbon structures and electrochemical performances, different tests in Na//HC cells with 1 M NaPF6ethylene carbonate/dimethyl carbonate(EC/DMC) were performed. Samples pyrolysed from 1300 °C to 1600 °C showed a 300 m Ah/g reversible capacity at C/10 rate(where C = 372 mA/g) with an excellent stability in cycling and a very good initial Coulombic efficiency of up to 84%. Furthermore, hard carbons showed an excellent rate capability where sodium extraction rate varies from C/10 to 5C. At 5C more than 80% of reversible capacity remains stable for hard carbons synthesized from 1000 °C to 1600 °C.
文摘The microstructure of a Cu-Zn alloy treated under different high pressures was investigated by means of metallographic, scanning electron microscope （SEM）, energy dispersive spectrometer （EDS）, and X-ray diffraction （XRD）, and the hardness of the Cu-Zn alloy was also measured. The results show that the ct phase with a smaller grain size, different shapes, and random distribution appears in the Cu-Zn alloy during the solid-state phase transformation generation in the temperature range of 25-750℃ and the pressure range of 0-6 GPa. The amount of residual α phase in the microstructure decreases and then increases with increasing pressure. Under a high pressure of 3 GPa, the least volume fraction of residual a phase was obtained, and under a high pressure of 6 GPa, the changes of the microstructure of the Cu-Zn alloy were not obvious. In addition, high pressure can increase the hardness of the Cu-Zn alloy, but it cannot generate any new phase.
基金provided by the National Natural Science Foundation of China(No.51104191)the National Natural Science Foundation of China(No.51374258)the Program for Changjiang Scholars and Innovative Research Team in University of China(No.IRT13043)
文摘Concerning the issue of mine pressure behaviors occurred in fully mechanized caving mining of thick coal seams beneath hard stratum in Datong Mining Area, combined with thin and thick plate theory, the paper utilizes theoretical analysis, similar experiments, numerical simulations and field tests to study the influence of remaining coal pillars in Jurassic system goaf on hard stratum fractures, as well as mine pressure behaviors under their coupling effects. The paper concludes the solution formula of initial fault displacement in hard stratum caused by remaining coal pillars. Experiments prove that coupling effects can enhance mine pressure behaviors on working faces. When inter-layer inferior key strata fractures, mine pressure phenomenon such as significant roof weighting steps and increasing resistance in support.When inter-layer superior key strata fractures, the scope of overlying strata extends to Jurassic system goaf, dual-system stopes cut through, and remaining coal pillars lose stability. As a result, the bottom inferior key strata also lose stability. It causes huge impacts on working face, and the second mine pressure behaviors. These phenomena provide evidence for research on other similar mine strata pressure behaviors occurred in dual-system mines with remaining coal pillars.
文摘This paper discusses experimental results of turnin g experiments on GCr15 bearing steel hardened to 60～64 HRC. The objective was to d etermine the effect of the cutting parameters on cutting force, chip morphology and resultant workpiece surface quality, more specifically surface texture, micr ostructure alterations, changes in microhardness and residual stresses distribut ion. The changing rules of the main cutting force was shown in this paper which feature a increasing tendency with the improvement of the workpiece hardness wit hin the cutting parameter scope. The rule of cutting force changing with the wor kpiece hardness is accord to the traditional metal cutting theory. Stress value decrease with increasing cutting speed and workpiece hardness. The comparison of the machined surface roughness and harden layer depth of machined surface for d ifferent hardness is shown in Fig.1. The machined surface roughness is the worst when the workpiece hardness is around 50HRC. When the workpiece hardness is ove r 50HRC, the surface roughness value shows a descending tendency with the additi on hardness. The machined superficial harden layer depth shows an increasing ten dency with the improvement of the workpiece hardness. When the workpiece hardnes s is 50HRC the machined superficial harden layer depth is tiptop. When the workp iece hardness is over 50HRC the depth changes little with the addition of workpi ece hardness. The remnant stress status of the machined surface is shown in Fig. 2, which is press stress status both in surface and in base for less cutting par ameters under two kinds of cutting condition. But experiment results show that t ensile stress can be produced under uncomfortable cutting conditions. The deform ation created by the chip formation is reduced whereduce with [TPP126A,+35mm77mm,Z,PY#]Depth from surface (μm) ■ v=200m/min,f=0.24mm/r,ap=0.8mm,60HRC ● v=200m/min,f=0.15mm/r,ap=0.5mm,60HRC Fig.1 The subsurface residual stress between the two experimentsHardness (HRC) Fig.2 The surface finish vs. workpiece hardness the workpiece hardness is improved.
基金Project(51404251)supported by the National Natural Science Foundation of ChinaProject(BK20140198)supported by the Natural Science Foundation of Jiangsu Province of China+1 种基金Project(2014XT01)supported by the Fundamental Research Funds for the Central UniversitiesChina
文摘In order to explore the pressure relief and structure stability mechanism of lateral cantilever structure in the stope under the direct coverage of thick hard roof and its impact on the gob-side entry retaining, a lateral cantilever fractured structural mechanical model was established on the basis of clarification for the stress environment of gob-side entry retaining, and the equation of roof given deformation and the balance judgment for fracture block were obtained. The optimal cantilever length was proposed based on the comparison of roof structural characteristics and the stress, deformation law of surrounding rocks under six different cantilever lengths by numerical simulation method. Double stress peaks exist on the sides of gob-side entry retaining and the entry located in the low stress area. The pressure of gob-side entry retaining can be relieved by reducing the cantilever length. However, due to the impact of arch structure of rock beam, unduly short cantilever would result in insufficient pressure relief and unduly long cantilever would bring larger roof stress which results in intense deformation. Therefore, there is optimal cantilever length, which was 7-8 m in this project that enables to achieve the minimum deformation and the most stabilized rock structure of entry retaining. An engineering case of gob-side entry retaining with the direct coverage of 10 m thick hard limestone roof was put forward, and the measured data verified the reasonability of conclusion.
文摘Flannery O'Connor is considered one of the outstanding female writers of the American South in the 20 th century.Her works not only reveal to readers a world of nihilism,but also describe a society of original sins.Nihilism reflected by two major characters and their fates in A Good Man Is Hard to Find demonstrate her concern about the lack of belief and emptiness of modern people's soul.
