Triangle zones, generally found in foreland fold-and-thrust belts, serve as favorable objects of petroleum exploration. Taking the Dabashan foreland belt as an example, we studied the formation and development of tria...Triangle zones, generally found in foreland fold-and-thrust belts, serve as favorable objects of petroleum exploration. Taking the Dabashan foreland belt as an example, we studied the formation and development of triangle zones, and investigated the effect of d^collements and the mechanical contrast of lithology by employing the method of physical modeling. Four experimental models were conducted in the work. The results showed that 'sand wedges' grew episodically, recorded by deformational length, height and slope angle. The height versus shortening rate presented an S-shape curve, and uplifting occurred successively in the direction of the foreland belt. During the formation of the triangle zone, layer-parallel shortening took place at the outset; deformation decoupling then occurred between the upper and lower brittle layers, divided by a middle-embedded silicone polymers layer. The upper brittle layers deformed mainly by folding, while the lower sand layers by thrusting. As shortening continued, the geometry of a triangle zone was altered. We consider that the triangle zone in the Dabashan foreland belt was modified from an early one based on available seismic profiles and the experimental results. In addition, dccollements and mechanical contrast impose significant influence on structural development, which can directly give rise to structural discrepancies. More d^collements and obvious mechanical contrast between brittle layers can promote the coupling between the upper and lower brittle layers. Basal d^collement controls the whole deformation and decreases the slope angle of the wedge, while roof d^collement determines whether a triangle zone can be formed.展开更多
Cast iron alloys with low production cost and quite good mechanical properties are widely used in the automotive industry.To study the mechanical behavior of a typical ductile cast iron(GJS-450)with nodular graphite,u...Cast iron alloys with low production cost and quite good mechanical properties are widely used in the automotive industry.To study the mechanical behavior of a typical ductile cast iron(GJS-450)with nodular graphite,uni-axial quasi-static and dynamic tensile tests at strain rates of 10^(-4),1,10,100,and 250 s^(-1)were carried out.In order to investigate the influence of stress state on the deformation and fracture parameters,specimens with various geometries were used in the experiments.Stress strain curves and fracture strains of the GJS-450 alloy in the strain rate range of 10^(-4)to 250 s^(-1)were obtained.A strain rate-dependent plastic flow model was proposed to describe the mechanical behavior in the corresponding strain-rate range.The available damage model was extended to take the strain rate into account and calibrated based on the analysis of local fracture strains.Simulations with the proposed plastic flow model and the damage model were conducted to observe the deformation and fracture process.The results show that the strain rate has obviously nonlinear effects on the yield stress and fracture strain of GJS-450 alloys.The predictions with the proposed plastic flow and damage models at various strain rates agree well with the experimental results,which illustrates that the rate-dependent plastic flow and damage models can be used to describe the mechanical behavior of cast iron alloys at elevated strain rates.The proposed plastic flow and damage models can be used to describe the deformation and fracture analysis of materials with similar properties.展开更多
Conductivities of lithium bis(oxalato)borate (LiBOB)-ethyl carbonate (EC)/diethyl carbonaten (DEC) electrolytes at 25℃ and 50℃ were studied. The electrolyte component with the highest conductivity at each te...Conductivities of lithium bis(oxalato)borate (LiBOB)-ethyl carbonate (EC)/diethyl carbonaten (DEC) electrolytes at 25℃ and 50℃ were studied. The electrolyte component with the highest conductivity at each temperature was obtained through changing the concentration of LiBOB and the ratio of EC/DEC. The mass triangle model was applied to calculate the conductivity of Li- BOB-EC/DEC ternary system at 25℃ and 50℃. The results show that the calculated and experimental results have reached a good agreement. Therefore, it is expected that the experimental work can be vastly reduced by introducing the mass triangle model.展开更多
目的:分析基于Triangle模型的分层分级延续护理在2型糖尿病(T2DM)病人中的应用效果。方法:纳入2021年11月—2022年11月在徐州医科大学附属宿迁医院接受治疗的120例T2DM病人,按随机数字表法分为观察组与对照组,各60例。对照组接受延续性...目的:分析基于Triangle模型的分层分级延续护理在2型糖尿病(T2DM)病人中的应用效果。方法:纳入2021年11月—2022年11月在徐州医科大学附属宿迁医院接受治疗的120例T2DM病人,按随机数字表法分为观察组与对照组,各60例。对照组接受延续性护理,观察组接受基于Triangle模型的分层分级延续性护理。于干预前、干预3个月时、干预6个月时评定病人血糖控制状况、自我管理能力、生活质量;并记录病人干预期间再住院次数。结果:干预3个月、6个月时,两组病人空腹血糖(FPG)、餐后2 h血糖(2 h PG)、糖化血红蛋白(HbA1c)水平明显低于干预前,糖尿病自我管理行为量表(SDSCA)得分高于干预前,中国糖尿病病人生存质量特异性量表(DSQL)得分低于干预前,且观察组病人各项指标改善优于对照组(P<0.05);但两组病人干预6个月时的各项指标与干预3个月时比较,差异无统计学意义(P>0.05);观察组病人再住院次数少于对照组(P<0.05)。结论:基于Triangle模型的分层分级延续性护理可提高T2DM病人的血糖控制水平、自我管理能力及生活质量,并减少再住院次数。展开更多
The utilization of iron coke provides a green pathway for low-carbon ironmaking.To uncover the influence mechanism of iron ore on the behavior and kinetics of iron coke gasification,the effect of iron ore on the micro...The utilization of iron coke provides a green pathway for low-carbon ironmaking.To uncover the influence mechanism of iron ore on the behavior and kinetics of iron coke gasification,the effect of iron ore on the microstructure of iron coke was investigated.Furthermore,a comparative study of the gasification reactions between iron coke and coke was conducted through non-isothermal thermogravimetric method.The findings indicate that compared to coke,iron coke exhibits an augmentation in micropores and specific surface area,and the micropores further extend and interconnect.This provides more adsorption sites for CO_(2) molecules during the gasification process,resulting in a reduction in the initial gasification temperature of iron coke.Accelerating the heating rate in non-isothermal gasification can enhance the reactivity of iron coke.The metallic iron reduced from iron ore is embedded in the carbon matrix,reducing the orderliness of the carbon structure,which is primarily responsible for the heightened reactivity of the carbon atoms.The kinetic study indicates that the random pore model can effectively represent the gasification process of iron coke due to its rich pore structure.Moreover,as the proportion of iron ore increases,the activation energy for the carbon gasification gradually decreases,from 246.2 kJ/mol for coke to 192.5 kJ/mol for iron coke 15wt%.展开更多
目的研究糖尿病患者采用Triangle分层分级管理结合LEARNS模式干预的护理效果。方法选择2020年10月—2023年10月东南大学附属中大医院收治的40例糖尿病患者为研究对象,以随机抽签法分为A组(20例,行Triangle分层分级管理结合LEARNS模式护...目的研究糖尿病患者采用Triangle分层分级管理结合LEARNS模式干预的护理效果。方法选择2020年10月—2023年10月东南大学附属中大医院收治的40例糖尿病患者为研究对象,以随机抽签法分为A组(20例,行Triangle分层分级管理结合LEARNS模式护理)和B组(20例,施行常规护理干预)。对比两组护理前后血糖水平、糖尿病自我管理行为量表(Summary of Diabetes Self Care Activities,SDSCA)评分及依从性。结果干预后,A组患者血糖水平显著优于B组,差异有统计学意义(P<0.05)。干预前,两组患者SDSCA评分对比,差异无统计学意义(P>0.05);干预后,A组SDSCA评分显著优于B组,差异有统计学意义(P<0.05)。A组患者依从性显著优于B组,差异有统计学意义(P<0.05)。结论给予糖尿病患者Triangle分层分级管理结合LEARNS模式进行干预,与常规护理干预对比,其能够很大程度改善患者血糖情况,提高糖尿病患者自我管理能力及依从性。展开更多
The connection is found between the star-triangle relation and the star-square relation in the Baxter-Bazhanov model which is an Interaltion-Round-a-Cube model.This gives a proof of the guess suggested by Bazhanov and...The connection is found between the star-triangle relation and the star-square relation in the Baxter-Bazhanov model which is an Interaltion-Round-a-Cube model.This gives a proof of the guess suggested by Bazhanov and Baxter.展开更多
Over the years the defense industry has become a de facto participant in the policy-making process. As in other areas dominated by big business interests, a policy sub-government of "iron triangle" has emerg...Over the years the defense industry has become a de facto participant in the policy-making process. As in other areas dominated by big business interests, a policy sub-government of "iron triangle" has emerged. In the view of some American scholars, such an "iron triangle" as a political relationship that brings together .展开更多
The article initially reviews various works describing the physical model (PM) of Michelson’s interferometric experiment (ME), represented by the race between two swimmers Sw1, Sw2 (or boats, or planes, or sound sign...The article initially reviews various works describing the physical model (PM) of Michelson’s interferometric experiment (ME), represented by the race between two swimmers Sw1, Sw2 (or boats, or planes, or sound signals, etc.). The two swimmers must each swim the same distance, but Sw1 will swim along the river flow, and Sw2 will swim perpendicularly to this direction. In all such works, it is considered that Sw2’s path will require less time and that it will reach the start point first. However, in this work, it has been determined that in order to make this possible, Sw2 must not observe the orthogonality rule of his start direction. This action would be deceitful to the arbiters and thus considered as non-fair-play towards Sw1. The article proves by swimming times calculus, that if the fair-play rules are observed, then the correct crosswise path (in water reference frame) is a right triangle instead of the isosceles triangle considered by Michelson. Consequently, the two times shall be perfectly equal and the race ends in a tie, and the myth of Sw2 as the race winner shall be debunked. Note that the same result shall also be applicable to Michelson’s interferometric experiment (ME) as well as to any similar experiment. Therefore, utilising the isosceles triangle as the transversal path in PM and also in ME is an erroneous act.展开更多
Two mono iron complexes Fe(CO)2PR3(NN) (R = Cy (3), Ph (4), NN = o-phenylenediamine dianion ligand, N2H2Ph2-) derived from the ligand substitution of Fe(CO)3hPR3 by the NN ligand were isolated and structur...Two mono iron complexes Fe(CO)2PR3(NN) (R = Cy (3), Ph (4), NN = o-phenylenediamine dianion ligand, N2H2Ph2-) derived from the ligand substitution of Fe(CO)3hPR3 by the NN ligand were isolated and structurally characterized by single crystal X-ray diffraction. They have a similar first coordination sphere and oxidation state of the iron center as the [Fe]-hydrogenase active site, and can be a model of it IR demonstrated that the effect of the NN ligand on the coordinated CO stretch- ing frequencies was due to its excellent electron donating ability. The reversible protonation/deprotonation of the NN ligand was identified by infrared spectroscopy and density functional theory computation. The NN ligand is an effective proton acceptor as the internal base of the cysteine thiolate ligand in [Fe]-hydrogenase. The electrochemical properties of complexes 3, 4 were investigated by cyclic voltammograms. Complex 3 catalyzed the transfer hydrogenation of benzoquinone to hydroquinone effectively under mild conditions.展开更多
An ore-blending optimization model for the sintering process is an intelligent system that includes iron ore characteristics, expert knowledge and material balance. In the present work, 14 indices are proposed to repr...An ore-blending optimization model for the sintering process is an intelligent system that includes iron ore characteristics, expert knowledge and material balance. In the present work, 14 indices are proposed to represent chemical composition, granulating properties and high temperature properties of iron ores. After the relationships between iron ore characteristics and sintering performance are established, the "two-step" method and the simplex method are introduced to build the model by distinguishing the calculation of optimized blending proportion of iron ores from that of other sintering materials in order to improve calculation efficiency. The ore-blending optimization model, programmed by Access and Visual Basic, is applied to practical production in steel mills and the results prove that the present model can take advantage of the available iron ore resource with stable sinter yield and quality performance but at a lower cost.展开更多
Extensive iron deposition has been observed in the midbrain substantia nigra (SN) of Parkinson's disease (PD) patients, but the mechanisms of iron deposition in the SN remain poorly understood. The present study ...Extensive iron deposition has been observed in the midbrain substantia nigra (SN) of Parkinson's disease (PD) patients, but the mechanisms of iron deposition in the SN remain poorly understood. The present study investigated the relationship between dopaminergic neuronal damage, iron content changes, and divalent metal transporter 1 (DMT1) in the midbrain SN of PD rats to explore the relationship between time of iron deposition and DMT1 expression. Frozen midbrain SN sections from model rats were stained with Perls' iron. Results showed massive loss of tyrosine hydroxylase (TH)-positive cells in the SN and increased DMT1 expression in model group rats. No obvious iron deposition was observed in the SN during early stages after damage, but significant iron deposition was detected at 8 weeks post-injury. Results demonstrate that the loss of TH-positive cells in the SN appeared simultaneously with increased DMT1 expression. Extensive iron deposition occurred at 8 weeks post injury, which could be regarded as an early time window of iron deposition.展开更多
A micro-modeling method (MM) for the quantitative prediction of the shrinkage cavity formation in SGiron castings is proposed. The mathematical models describing the volume changes during the solidification ofspheroid...A micro-modeling method (MM) for the quantitative prediction of the shrinkage cavity formation in SGiron castings is proposed. The mathematical models describing the volume changes during the solidification ofspheroidal graphite cast iron are established based on the models of solidification kinetics. The shrinkage cavityformation of T-shaped SG iron castings is calculated with MM method. The calculated results are compared with theexperimental results. It is shown that the predicted size, shape and distribution of shrinkage cavity by MM methodare in good agreement with the measured results.展开更多
Polymer-supported hydrous iron oxides(HFOs) are promising for heavy metals removal from aqueous systems.The ubiquitous inorganic ligands, e.g., sulfate, are expected to exert considerable impacts on pollutants removal...Polymer-supported hydrous iron oxides(HFOs) are promising for heavy metals removal from aqueous systems.The ubiquitous inorganic ligands, e.g., sulfate, are expected to exert considerable impacts on pollutants removal by these hybrid sorbents. Herein, we obtained a hybrid sorbent HFO-PS by encapsulating nanosized HFO into macroporous polystyrene(PS) resin. Both batch and column sorption experiments of Cu(Ⅱ) by HFO-PS were carried out in the presence of sulfate. Obviously, the presence of sulfate is favorable for Cu(Ⅱ) sorption onto HFO-PS.The performances of column Cu(Ⅱ) removal were fitted and predicted with Adams–Bohart, Clark, Thomas and BDST models. Thomas model is suggested best-fit to predict the breakthrough curves. Besides, a linear correlation is observed between breakthrough time and column length based on BDST model, which might be useful for predicting the breakthrough time for Cu(Ⅱ) removal by HFO-PS.展开更多
The aim of this article was to theoretically study diffusion and migration of chloride ions during electrochemical chloride removal. The proposed model would enable optimization of its application by predicting the op...The aim of this article was to theoretically study diffusion and migration of chloride ions during electrochemical chloride removal. The proposed model would enable optimization of its application by predicting the optimal treatment time and current combination. A mathematical model for simulating the transport behavior of chloride ions was developed by consideration of diffusion and migration of chloride ions when a constant DC current density was applied through the marine cast iron artifacts. The corresponding tests were conducted to validate the mathematical model. This model predicted the data of the extraction ratio of the chloride ion that correlated satisfactorily with the experimental values. An important issue in electrochemical chloride removal was to understand how chloride ions moved, taking account of diffusion and migration of chloride ions and the release of binding chloride ions. The effects of the treatment time, externally applied current density, chloride diffusion coefficient, and rate constant of release of binding chloride ion on chloride removal are studied. The specific quantitative details applied to one-dimensional model were discussed here. This article has proposed a mathematical model for the first time, which was showed to be a useful tool that can reveal the ionic transport mechanism and optimize the application during electrochemical chloride removal.展开更多
A new model for describing the compaction process of iron powder was proposed based on the continuum hypothesis and elliptical yield criterion.To simulate the densification behaviour,the constitutive model was impleme...A new model for describing the compaction process of iron powder was proposed based on the continuum hypothesis and elliptical yield criterion.To simulate the densification behaviour,the constitutive model was implemented in Marc computer program.For the relationship between load and displacement,different models were compared and the influence of the parameters in the constitutive equations was determined by means of simulation and experiments.The density distribution of a balancer was measured and simulated.The results show that the parameterηadopted plays a modification role for the load-displacement curve,and compared with other models the present model fits better with the experimental data in the later stage of the compaction process mainly due to the different parameters A and B.The friction on the contact surface contributes to the inhomogeneous density distribution under large deformation of the workpiece.The comparison between the simulation and experimental data indicates that this model can be used to predict the powder compact process precisely and effectively.展开更多
Rotary kiln process for iron ore oxide pellet production is hard to detect and control.Construction of one-dimensional model of temperature field in rotary kiln was described.And the results lay a solid foundation for...Rotary kiln process for iron ore oxide pellet production is hard to detect and control.Construction of one-dimensional model of temperature field in rotary kiln was described.And the results lay a solid foundation for online control.Establishment of kiln process control expert system was presented,with maximum temperature of pellet and gas temperature at the feed end as control cores,and interval estimate as control strategy.Software was developed and put into application in a pellet plant.The results show that control guidance of this system is accurate and effective.After production application for nearly one year,the compressive strength and first grade rate of pellet are increased by 86 N and 2.54%,respectively,while FeO content is 0.05% lowered.This system can reveal detailed information of real time kiln process,and provide a powerful tool for online control of pellet production.展开更多
Grate process is an important step in grate-kiln pellet production.However,as a relatively closed system,the process on grate is inaccessible to direct detection,therefore,it is hard to control.As a result,mathematica...Grate process is an important step in grate-kiln pellet production.However,as a relatively closed system,the process on grate is inaccessible to direct detection,therefore,it is hard to control.As a result,mathematical models of temperature distribution,moisture distribution and oxidation degree distribution in pellet bed,with good universality,computation speed and calculation accuracy,are presented based on analysis of heat transfer and physical-chemical reactions during grate process.And real-time visualization of temperature,moisture and oxidation degree distribution in pellet bed during grate process is realized.Model validation is displayed,and the similarity of 91% is proved.The results can reveal real time status on grate,and provide a solid foundation for the subsequent study of artificial intelligence control system of pellet production.展开更多
A simple model for estimating the rate constant between CO2-CO gas and molten slag containing iron oxides was developed using optical basicity only. In this model, the temperature dependence of the rate constant can b...A simple model for estimating the rate constant between CO2-CO gas and molten slag containing iron oxides was developed using optical basicity only. In this model, the temperature dependence of the rate constant can be described by the Arrhenius law, and the activation energy can be expressed with a linear function of the slag's optical basicity. The model was applied to some molten slag systems, such as FeO, FeO-CaO, FeO-SiO2, FeO-Na2O, FeO-CaO-SiO2, FeO-SiO2-P2O5, FeO-SiOE-Na2O, and FeO-CaO-SiOE-P2O5. A comparison between the predicted results and measured data showed that the model worked well.展开更多
文摘Triangle zones, generally found in foreland fold-and-thrust belts, serve as favorable objects of petroleum exploration. Taking the Dabashan foreland belt as an example, we studied the formation and development of triangle zones, and investigated the effect of d^collements and the mechanical contrast of lithology by employing the method of physical modeling. Four experimental models were conducted in the work. The results showed that 'sand wedges' grew episodically, recorded by deformational length, height and slope angle. The height versus shortening rate presented an S-shape curve, and uplifting occurred successively in the direction of the foreland belt. During the formation of the triangle zone, layer-parallel shortening took place at the outset; deformation decoupling then occurred between the upper and lower brittle layers, divided by a middle-embedded silicone polymers layer. The upper brittle layers deformed mainly by folding, while the lower sand layers by thrusting. As shortening continued, the geometry of a triangle zone was altered. We consider that the triangle zone in the Dabashan foreland belt was modified from an early one based on available seismic profiles and the experimental results. In addition, dccollements and mechanical contrast impose significant influence on structural development, which can directly give rise to structural discrepancies. More d^collements and obvious mechanical contrast between brittle layers can promote the coupling between the upper and lower brittle layers. Basal d^collement controls the whole deformation and decreases the slope angle of the wedge, while roof d^collement determines whether a triangle zone can be formed.
基金Supported by National Natural Science Foundation of China (Grant Nos.12202205,U1730101)the Federal Ministry of Economic Affairs and Energy (BMWi)via the German Federation of Industrial Research Associations‘Otto von Guericke’e.V. (AiF) (IGF-Nr.19567N)Forschungsvereinigung Automobiltechnik e.V. (FAT)。
文摘Cast iron alloys with low production cost and quite good mechanical properties are widely used in the automotive industry.To study the mechanical behavior of a typical ductile cast iron(GJS-450)with nodular graphite,uni-axial quasi-static and dynamic tensile tests at strain rates of 10^(-4),1,10,100,and 250 s^(-1)were carried out.In order to investigate the influence of stress state on the deformation and fracture parameters,specimens with various geometries were used in the experiments.Stress strain curves and fracture strains of the GJS-450 alloy in the strain rate range of 10^(-4)to 250 s^(-1)were obtained.A strain rate-dependent plastic flow model was proposed to describe the mechanical behavior in the corresponding strain-rate range.The available damage model was extended to take the strain rate into account and calibrated based on the analysis of local fracture strains.Simulations with the proposed plastic flow model and the damage model were conducted to observe the deformation and fracture process.The results show that the strain rate has obviously nonlinear effects on the yield stress and fracture strain of GJS-450 alloys.The predictions with the proposed plastic flow and damage models at various strain rates agree well with the experimental results,which illustrates that the rate-dependent plastic flow and damage models can be used to describe the mechanical behavior of cast iron alloys at elevated strain rates.The proposed plastic flow and damage models can be used to describe the deformation and fracture analysis of materials with similar properties.
基金supported by the National Natural Science Foundation of China(No.50472093)
文摘Conductivities of lithium bis(oxalato)borate (LiBOB)-ethyl carbonate (EC)/diethyl carbonaten (DEC) electrolytes at 25℃ and 50℃ were studied. The electrolyte component with the highest conductivity at each temperature was obtained through changing the concentration of LiBOB and the ratio of EC/DEC. The mass triangle model was applied to calculate the conductivity of Li- BOB-EC/DEC ternary system at 25℃ and 50℃. The results show that the calculated and experimental results have reached a good agreement. Therefore, it is expected that the experimental work can be vastly reduced by introducing the mass triangle model.
文摘目的:分析基于Triangle模型的分层分级延续护理在2型糖尿病(T2DM)病人中的应用效果。方法:纳入2021年11月—2022年11月在徐州医科大学附属宿迁医院接受治疗的120例T2DM病人,按随机数字表法分为观察组与对照组,各60例。对照组接受延续性护理,观察组接受基于Triangle模型的分层分级延续性护理。于干预前、干预3个月时、干预6个月时评定病人血糖控制状况、自我管理能力、生活质量;并记录病人干预期间再住院次数。结果:干预3个月、6个月时,两组病人空腹血糖(FPG)、餐后2 h血糖(2 h PG)、糖化血红蛋白(HbA1c)水平明显低于干预前,糖尿病自我管理行为量表(SDSCA)得分高于干预前,中国糖尿病病人生存质量特异性量表(DSQL)得分低于干预前,且观察组病人各项指标改善优于对照组(P<0.05);但两组病人干预6个月时的各项指标与干预3个月时比较,差异无统计学意义(P>0.05);观察组病人再住院次数少于对照组(P<0.05)。结论:基于Triangle模型的分层分级延续性护理可提高T2DM病人的血糖控制水平、自我管理能力及生活质量,并减少再住院次数。
基金financially supported by the National Science Foundation of China(Nos.51974212 and 52274316)the China Baowu Low Carbon Metallurgy Innovation Foundation(No.BWLCF202116)+1 种基金the Science and Technology Major Project of Wuhan(No.2023020302020572)the Foundation of Key Laboratory for Ferrous Metallurgy and Resources Utilization of Ministry of Education(No.FMRUlab23-04)。
文摘The utilization of iron coke provides a green pathway for low-carbon ironmaking.To uncover the influence mechanism of iron ore on the behavior and kinetics of iron coke gasification,the effect of iron ore on the microstructure of iron coke was investigated.Furthermore,a comparative study of the gasification reactions between iron coke and coke was conducted through non-isothermal thermogravimetric method.The findings indicate that compared to coke,iron coke exhibits an augmentation in micropores and specific surface area,and the micropores further extend and interconnect.This provides more adsorption sites for CO_(2) molecules during the gasification process,resulting in a reduction in the initial gasification temperature of iron coke.Accelerating the heating rate in non-isothermal gasification can enhance the reactivity of iron coke.The metallic iron reduced from iron ore is embedded in the carbon matrix,reducing the orderliness of the carbon structure,which is primarily responsible for the heightened reactivity of the carbon atoms.The kinetic study indicates that the random pore model can effectively represent the gasification process of iron coke due to its rich pore structure.Moreover,as the proportion of iron ore increases,the activation energy for the carbon gasification gradually decreases,from 246.2 kJ/mol for coke to 192.5 kJ/mol for iron coke 15wt%.
文摘目的研究糖尿病患者采用Triangle分层分级管理结合LEARNS模式干预的护理效果。方法选择2020年10月—2023年10月东南大学附属中大医院收治的40例糖尿病患者为研究对象,以随机抽签法分为A组(20例,行Triangle分层分级管理结合LEARNS模式护理)和B组(20例,施行常规护理干预)。对比两组护理前后血糖水平、糖尿病自我管理行为量表(Summary of Diabetes Self Care Activities,SDSCA)评分及依从性。结果干预后,A组患者血糖水平显著优于B组,差异有统计学意义(P<0.05)。干预前,两组患者SDSCA评分对比,差异无统计学意义(P>0.05);干预后,A组SDSCA评分显著优于B组,差异有统计学意义(P<0.05)。A组患者依从性显著优于B组,差异有统计学意义(P<0.05)。结论给予糖尿病患者Triangle分层分级管理结合LEARNS模式进行干预,与常规护理干预对比,其能够很大程度改善患者血糖情况,提高糖尿病患者自我管理能力及依从性。
文摘The connection is found between the star-triangle relation and the star-square relation in the Baxter-Bazhanov model which is an Interaltion-Round-a-Cube model.This gives a proof of the guess suggested by Bazhanov and Baxter.
文摘Over the years the defense industry has become a de facto participant in the policy-making process. As in other areas dominated by big business interests, a policy sub-government of "iron triangle" has emerged. In the view of some American scholars, such an "iron triangle" as a political relationship that brings together .
文摘The article initially reviews various works describing the physical model (PM) of Michelson’s interferometric experiment (ME), represented by the race between two swimmers Sw1, Sw2 (or boats, or planes, or sound signals, etc.). The two swimmers must each swim the same distance, but Sw1 will swim along the river flow, and Sw2 will swim perpendicularly to this direction. In all such works, it is considered that Sw2’s path will require less time and that it will reach the start point first. However, in this work, it has been determined that in order to make this possible, Sw2 must not observe the orthogonality rule of his start direction. This action would be deceitful to the arbiters and thus considered as non-fair-play towards Sw1. The article proves by swimming times calculus, that if the fair-play rules are observed, then the correct crosswise path (in water reference frame) is a right triangle instead of the isosceles triangle considered by Michelson. Consequently, the two times shall be perfectly equal and the race ends in a tie, and the myth of Sw2 as the race winner shall be debunked. Note that the same result shall also be applicable to Michelson’s interferometric experiment (ME) as well as to any similar experiment. Therefore, utilising the isosceles triangle as the transversal path in PM and also in ME is an erroneous act.
基金supported by the National Natural Science Foundation of China(21103121,21276187)Tianjin Municipal Natural Science Foundation(13JCQNJC05800)the Specialized Research Fund for the Doctoral Program of Higher Education(20121317110009)~~
文摘Two mono iron complexes Fe(CO)2PR3(NN) (R = Cy (3), Ph (4), NN = o-phenylenediamine dianion ligand, N2H2Ph2-) derived from the ligand substitution of Fe(CO)3hPR3 by the NN ligand were isolated and structurally characterized by single crystal X-ray diffraction. They have a similar first coordination sphere and oxidation state of the iron center as the [Fe]-hydrogenase active site, and can be a model of it IR demonstrated that the effect of the NN ligand on the coordinated CO stretch- ing frequencies was due to its excellent electron donating ability. The reversible protonation/deprotonation of the NN ligand was identified by infrared spectroscopy and density functional theory computation. The NN ligand is an effective proton acceptor as the internal base of the cysteine thiolate ligand in [Fe]-hydrogenase. The electrochemical properties of complexes 3, 4 were investigated by cyclic voltammograms. Complex 3 catalyzed the transfer hydrogenation of benzoquinone to hydroquinone effectively under mild conditions.
文摘An ore-blending optimization model for the sintering process is an intelligent system that includes iron ore characteristics, expert knowledge and material balance. In the present work, 14 indices are proposed to represent chemical composition, granulating properties and high temperature properties of iron ores. After the relationships between iron ore characteristics and sintering performance are established, the "two-step" method and the simplex method are introduced to build the model by distinguishing the calculation of optimized blending proportion of iron ores from that of other sintering materials in order to improve calculation efficiency. The ore-blending optimization model, programmed by Access and Visual Basic, is applied to practical production in steel mills and the results prove that the present model can take advantage of the available iron ore resource with stable sinter yield and quality performance but at a lower cost.
基金the Scientific Research Common Program of Beijing Municipal Commission of Education,No.KM200610025008
文摘Extensive iron deposition has been observed in the midbrain substantia nigra (SN) of Parkinson's disease (PD) patients, but the mechanisms of iron deposition in the SN remain poorly understood. The present study investigated the relationship between dopaminergic neuronal damage, iron content changes, and divalent metal transporter 1 (DMT1) in the midbrain SN of PD rats to explore the relationship between time of iron deposition and DMT1 expression. Frozen midbrain SN sections from model rats were stained with Perls' iron. Results showed massive loss of tyrosine hydroxylase (TH)-positive cells in the SN and increased DMT1 expression in model group rats. No obvious iron deposition was observed in the SN during early stages after damage, but significant iron deposition was detected at 8 weeks post-injury. Results demonstrate that the loss of TH-positive cells in the SN appeared simultaneously with increased DMT1 expression. Extensive iron deposition occurred at 8 weeks post injury, which could be regarded as an early time window of iron deposition.
文摘A micro-modeling method (MM) for the quantitative prediction of the shrinkage cavity formation in SGiron castings is proposed. The mathematical models describing the volume changes during the solidification ofspheroidal graphite cast iron are established based on the models of solidification kinetics. The shrinkage cavityformation of T-shaped SG iron castings is calculated with MM method. The calculated results are compared with theexperimental results. It is shown that the predicted size, shape and distribution of shrinkage cavity by MM methodare in good agreement with the measured results.
基金Supported by the National Natural Science Foundation of China(21607080)the Natural Science Foundation of Jiangsu Province(BK20160946)Jiangsu Higher Education Institution NSF(16KJB610011)
文摘Polymer-supported hydrous iron oxides(HFOs) are promising for heavy metals removal from aqueous systems.The ubiquitous inorganic ligands, e.g., sulfate, are expected to exert considerable impacts on pollutants removal by these hybrid sorbents. Herein, we obtained a hybrid sorbent HFO-PS by encapsulating nanosized HFO into macroporous polystyrene(PS) resin. Both batch and column sorption experiments of Cu(Ⅱ) by HFO-PS were carried out in the presence of sulfate. Obviously, the presence of sulfate is favorable for Cu(Ⅱ) sorption onto HFO-PS.The performances of column Cu(Ⅱ) removal were fitted and predicted with Adams–Bohart, Clark, Thomas and BDST models. Thomas model is suggested best-fit to predict the breakthrough curves. Besides, a linear correlation is observed between breakthrough time and column length based on BDST model, which might be useful for predicting the breakthrough time for Cu(Ⅱ) removal by HFO-PS.
基金the National Key Technologies R&D Program of the Tenth Five-Year Plan Period for financial support (Contract No.2001BA805B01)
文摘The aim of this article was to theoretically study diffusion and migration of chloride ions during electrochemical chloride removal. The proposed model would enable optimization of its application by predicting the optimal treatment time and current combination. A mathematical model for simulating the transport behavior of chloride ions was developed by consideration of diffusion and migration of chloride ions when a constant DC current density was applied through the marine cast iron artifacts. The corresponding tests were conducted to validate the mathematical model. This model predicted the data of the extraction ratio of the chloride ion that correlated satisfactorily with the experimental values. An important issue in electrochemical chloride removal was to understand how chloride ions moved, taking account of diffusion and migration of chloride ions and the release of binding chloride ions. The effects of the treatment time, externally applied current density, chloride diffusion coefficient, and rate constant of release of binding chloride ion on chloride removal are studied. The specific quantitative details applied to one-dimensional model were discussed here. This article has proposed a mathematical model for the first time, which was showed to be a useful tool that can reveal the ionic transport mechanism and optimize the application during electrochemical chloride removal.
基金Project(50325516) supported by the National Natural Science Foundation of ChinaProject(CG2003-GA005) supported by China Education and Research Grid(China Grid)+1 种基金Project(003019) supported by the Natural Science Foundation of Guangdong Province,ChinaProject(2009ZM0290) supported by the Fundamental Research Funds for the Central Universities,China
文摘A new model for describing the compaction process of iron powder was proposed based on the continuum hypothesis and elliptical yield criterion.To simulate the densification behaviour,the constitutive model was implemented in Marc computer program.For the relationship between load and displacement,different models were compared and the influence of the parameters in the constitutive equations was determined by means of simulation and experiments.The density distribution of a balancer was measured and simulated.The results show that the parameterηadopted plays a modification role for the load-displacement curve,and compared with other models the present model fits better with the experimental data in the later stage of the compaction process mainly due to the different parameters A and B.The friction on the contact surface contributes to the inhomogeneous density distribution under large deformation of the workpiece.The comparison between the simulation and experimental data indicates that this model can be used to predict the powder compact process precisely and effectively.
基金Project(NCET-05-0630) supported by Program for New Century Excellent Talents in University of China
文摘Rotary kiln process for iron ore oxide pellet production is hard to detect and control.Construction of one-dimensional model of temperature field in rotary kiln was described.And the results lay a solid foundation for online control.Establishment of kiln process control expert system was presented,with maximum temperature of pellet and gas temperature at the feed end as control cores,and interval estimate as control strategy.Software was developed and put into application in a pellet plant.The results show that control guidance of this system is accurate and effective.After production application for nearly one year,the compressive strength and first grade rate of pellet are increased by 86 N and 2.54%,respectively,while FeO content is 0.05% lowered.This system can reveal detailed information of real time kiln process,and provide a powerful tool for online control of pellet production.
基金Project(NCET050630) supported by Program for New Century Excellent Talents in University,China
文摘Grate process is an important step in grate-kiln pellet production.However,as a relatively closed system,the process on grate is inaccessible to direct detection,therefore,it is hard to control.As a result,mathematical models of temperature distribution,moisture distribution and oxidation degree distribution in pellet bed,with good universality,computation speed and calculation accuracy,are presented based on analysis of heat transfer and physical-chemical reactions during grate process.And real-time visualization of temperature,moisture and oxidation degree distribution in pellet bed during grate process is realized.Model validation is displayed,and the similarity of 91% is proved.The results can reveal real time status on grate,and provide a solid foundation for the subsequent study of artificial intelligence control system of pellet production.
基金supported by the National Natural Science Foundation of China (Nos. 50834007, 50874128, and 50674012)
文摘A simple model for estimating the rate constant between CO2-CO gas and molten slag containing iron oxides was developed using optical basicity only. In this model, the temperature dependence of the rate constant can be described by the Arrhenius law, and the activation energy can be expressed with a linear function of the slag's optical basicity. The model was applied to some molten slag systems, such as FeO, FeO-CaO, FeO-SiO2, FeO-Na2O, FeO-CaO-SiO2, FeO-SiO2-P2O5, FeO-SiOE-Na2O, and FeO-CaO-SiOE-P2O5. A comparison between the predicted results and measured data showed that the model worked well.