Tuning the surface electronic structure of noble metal aerogels to promote the electrocatalytic oxygen reduction

The sluggish kinetics of the oxygen reduction reaction(ORR)is the bottleneck for various electrochemical energy conversion devices.Regulating the electronic structure of electrocatalysts by ligands has received particular attention in deriving valid ORR electrocatalysts.Here,the surface electronic structure of Ptbased noble metal aerogels(NMAs)was modulated by various organic ligands,among which the electron-withdrawing ligand of 4-methylphenylene effectively boosted the ORR electrocatalysis.Theoretical calculations suggested the smaller energy barrier for the transformation of O^(*) to OH^(*) and downshift the d-band center of Pt due to the interaction between 4-methylphenylene and the surface metals,thus enhancing the ORR intrinsic activity.Both Pt3Ni and Pt Pd aerogels with 4-methylphenylene decoration performed significant enhancement in ORR activity and durability in different media.Remarkably,the 4-methylphenylene modified Pt Pd aerogel exhibited the higher halfwave potential of 0.952 V and the mass activity of 10.2 times of commercial Pt/C.This work explained the effect of electronic structure on ORR electrocatalytic properties and would promote functionalized NMAs as efficient ORR electrocatalysts.

A general synthetic strategy for N, P co-doped graphene supported metal-rich noble metal phosphides for hydrogen generation

The exploitation of electrocatalysts with high activity and durability for HER is desirable for future energy systems,but it is still a challenge.NMPs have attracted increasing attentions,but the preparation process often needs toxic regents or dangerous reaction conditions.Herein,we develop a general green method to fabricate metal-rich NMPs anchored on NPG through pyrolyzing DNA cross-linked complexes.The obtained Ru_(2) P-NPG exhibits an ultrasmall overpotential of 7 mV at 10 mA cm^(2) and ultralow Tafel slope of 33 mV dec^(-1) in 1.0 mol L?1 KOH,even better than that of commercial Pt/C.In addition,Ru 2 P-NPG also shows low overpotentials of 29 and 78 mV in 0.5 mol L^(-1) H_(2)SO_(4) and 1.0 mol L^(-1) PBS,respectively.The superior activity can be attributed to the ultrafine dispersion of Ru 2 P nanoparticles for more accessible sites,more defects formed for abundant active sites,the two-dimensional plane structure for accelerated electron transfer and mass transport,as well as the regulation of electron distribution of the catalyst.Moreover,the synthetic method can also be applied to prepare other metal-rich noble metal phosphides(Pd_(3)P-NPG and Rh_(2)P-NPG),which also exhibits high activity for HER.This work provides an effective strategy for designing NMP-based electrocatalysts.

Advances in noble metal-modified g-C_(3)N_(4) heterostructures toward enhanced photocatalytic redox ability

The photocatalytic activity of catalysts depends on the energy-harvesting ability and the separation or transport of photogenerated carriers.The light absorption capacity of graphitic carbon nitride(g-C_(3)N_(4))-based composites can be enhanced by adjusting the surface plasmon resonance(SPR)of noble metal nanoparticles(e.g.,Cu,Au,and Pd)in the entire visible region.Adjustments can be carried out by varying the nanocomponents of the materials.The SPR of noble metals can enhance the local electromagnetic field and improve interband transition,and resonant energy transfer occurs from plasmonic dipoles to electron-hole pairs via near-field electromagnetic interactions.Thus,noble metals have emerged as relevant nanocomponents for g-C_(3)N_(4) used in CO_(2) photoreduction and water splitting.Herein,recent key advances in noble metals(either in single atom,cluster,or nanoparticle forms)and composite photocatalysts based on inorganic or organic nanocomponent-incorporated g-C_(3)N_(4) nanosheets are systematically discussed,including the applications of these photocatalysts,which exhibit improved photoinduced charge mobility in CO_(2) photoconversion and H2 production.Issues related to the different types of multi-nanocomponent heterostructures(involving Schottky junctions,Z-/S-scheme heterostructures,noble metals,and additional semiconductor nanocomponents)and the adjustment of dimensionality of heterostructures(by incorporating noble metal nanoplates on g-C_(3)N_(4) forming 2D/2D heterostructures)are explored.The current prospects and possible challenges of g-C_(3)N_(4) composite photocatalysts incorporated with noble metals(e.g.,Au,Pt,Pd,and Cu),particularly in water splitting,CO_(2) reduction,pollution degradation,and chemical conversion applications,are summarized.

Reform Practice of College Students’ Employment Guidance Course under the Concept of Curriculum Ideology and Politics

Under the background of“fostering character and civic virtue,”higher education must effectively integrate ideological and political education.The concept of curriculum ideology and politics has become increasingly developed and sophisticated,which can be a guiding concept for the teaching and reform practice of college students’employment guidance courses.Based on educational observation and logical analysis,this paper elaborates on the connotation of the concept of curriculum ideology and politics,analyzes the key points of the reform of college students’employment guidance courses under this concept,and affirms the value of course reform.On this basis,this paper specifically analyzes the common problems in the reform of the employment guidance course under the new concept and makes a detailed interpretation of the performance problems such as the vague course objectives and the lack of innovation in the course teaching methods.Combined with the relevant problems,this paper proposes strategies such as building the course objective system by linking the curriculum ideology and politics,and driving the teaching innovation of the course from multiple perspectives,aiming to provide more references for the corresponding course reform.

Teaching Reform of Basic Medicine Curriculum by Integrating the Perspective of Curriculum Civics and Politics in the Context of Healthy China

Basic medicine is the foundation of basic knowledge of medical science,life science,and natural science,and is the basis for training medical talents.It can help students correctly understand the relationship between disease and health,and is of great significance under the perspective of the Healthy China strategy.However,there are still some deficiencies in the current teaching,and insufficient attention has been paid to civics and politics.Thus,it is necessary to carry out curriculum reform in order to enable students to better understand medical knowledge and master medical skills,to ensure the development of medical education,and to play an important role in basic medicine.This study combines the necessity of curriculum reform under the perspective of civics and politics and puts forward a teaching reform strategy suitable for the development of contemporary medicine to provide a direction for the educational development of basic medicine.

Teaching Reform of Veterinary Microbiology Based on the Hybrid Teaching of Ideology and Politics

The veterinary microbiology teaching team thoroughly implements the national education policy,and iteratively promotes the implementation of the teaching reform of Sanquan education.The teaching team is focused on a“student-centered”approach to education,emphasizing the foundation of“cultivating people and nurturing the root and soul of the nation.”By integrating“knowledge exploration,skill training,and value shaping”into the talent training plan,they are reshaping curriculum objectives and emphasizing ideological education in the syllabus.The teaching content system is being reconstructed,combining multiple interactions of blended teaching with the“six-in-one”ideological education model,to achieve the educational goals of the new agricultural“in-class-extracurricular”approach.This effort provides an empirical basis for the ideological and political teaching reform of the veterinary microbiology curriculum.

Teaching Pathways of Curriculum Civics and Politics in Physical Education Courses of Higher Vocational Colleges and Universities in Chongqing

This paper firstly analyses the due evaluation indexes of curriculum civics and politics in physical education of higher vocational colleges and,based on the indexes,puts forward suggestions to improve the quality of teaching curriculum civics and politics in physical education of higher vocational colleges and universities in Chongqing.It involves maintaining steadfast adherence to professional attributes,unwavering commitment to Sanquan education,and thorough exploration of professional civics and political elements.This approach also entails supplementing extracurricular civics and political resources and utilizing a variety of methods such as contextual teaching and role-modeling to the fullest extent.At the same time,we increase the opportunities for civics and political practice inside and outside the classroom and develop teaching evaluation and assessment in civics and politics.

Research on the Construction Path of New Engineering+Curriculum Ideology and Politics

With the rapid development of science and technology and the transformation and upgrading of industry,new engineering construction has become the important direction of higher engineering education reform in our country.This research focuses on the“new engineering+curriculum ideological and political new form course construction path,”in order to meet the new requirements of talent training put forward by the development of new engineering.This paper analyzes the educational value and current situation of curriculum ideology and politics under the background of new engineering,and improves the ability of curriculum ideology and politics from the perspective of strengthening the teacher training system;optimizing curriculum ideological and political design,skillfully integrating into the ideological and political elements;and strengthening the cooperation between schools,enterprises,and family associations to enrich curriculum ideological and political resources.To build a collaborative education mechanism and form an all-round education pattern,the four aspects of the new engineering+curriculum ideological and political of the new form course construction path have been preliminarily explored,hoping to provide some references and guidance.

Exploration of Curriculum Ideology and Politics Integrating Medical Humanities Cultivation Model to Enhance Medical Core Values

Purpose:To explore the application effect of the cultivation mode of Curriculum Ideology and Political Integration of Medical Humanities to enhance the core values of medicine in the clinical internship stage of medical students.Methods:Students in the clinical internship stage of the First Affiliated Hospital of Baotou Medical College were selected,and a total of 156 students in one random class in each grade were taken as the observation group and received the integration cultivation mode;148 students were taken as the control group and employed the traditional mode.The teaching effect of interns in the two groups was analyzed.Results:The teaching performance of students in both groups after clinical internship teaching was improved compared with that before admission;the teaching performance,teaching effect,teaching evaluation,and teaching satisfaction of the observation group were higher than that of the control group.Conclusion:The integration of the medical humanities training model with curriculum ideology and politics in the clinical internship of medical students is conducive to the improvement of teaching performance,teaching evaluation,teaching satisfaction of teachers and students,and the development and improvement of core values of medical students,which is of good value for teaching application.

Research on the Optimization Paths for Outstanding Agricultural Economics and Management Talents under the Background of Curriculum Ideology and Politics

The article aims to discuss how to cultivate outstanding agricultural economics and management talents to meet the needs of agricultural and rural economic development in the new era,within the context of ideological and political education.Through literature review and field research,a series of innovative talent training optimization paths are proposed,and specific suggestions are made for policymakers and educational practitioners.

Research on the Integration Path of Postgraduate Professional Courses into the Construction of Curriculum Ideology and Politics

The curriculum ideology and politics play an important role in cultivating students’correct worldview,outlook on life,and values.In recent years,universities and colleges have begun to pay attention to the cultivation of postgraduates’moral education and the construction of postgraduates’curriculum ideology and politics.This paper takes the course“Theory of Software Engineering”of Anqing Normal University as an example,discusses the paths of integrating postgraduate professional courses into the construction of curriculum ideology and politics,and puts forward the paths of feeding back from scientific research,connecting with practice and summarizing and condensing,which are aimed at improving postgraduates’comprehensive quality and innovation ability,and have positive significance for cultivating high-level applied scientific and technological talents who are both moral and talented.

Exploration of the Integration of Curriculum Ideology and Politics into the Educational Pathway of Standardized Training for General Practice Residents

In recent years,the national higher education reform has proposed the concept of curriculum ideological and political education as a major element.This integration into the standardized training of general practice residents(commonly referred to as general resident training)is an unavoidable trend in the teaching field.Based on the actual situation of our unit at The First Affiliated Hospital of Xi’an Medical University,this paper emphasizes the necessity of incorporating ideological and political education into the general resident training curriculum,despite the absence of pertinent practical experience in how to effectively incorporate such courses into comprehensive residential training.In our hospital,we must assess the ideological and political education in the curriculum of general resident training,proposing a scientific,reasonable ideological and political education concept system for general practice courses,integrating ideological and political education with general practice resident training,and strengthening the team of ideological and political education physicians to teach them to carry out such education,this would foster enthusiasm and initiative.Strengthening admission education and training for general practice resident training,as well as regularly hosting symposiums to share ideas and understand the mission of doctors can provide effective experience for ideological and political education in general resident training courses.

Advances in Noble Metal-Decorated Metal Oxide Nanomaterials for Chemiresistive Gas Sensors:Overview

Highly sensitive gas sensors with remarkably low detection limits are attractive for diverse practical application fields including real-time environmental monitoring,exhaled breath diagnosis,and food freshness analysis.Among various chemiresistive sensing materials,noble metal-decorated semiconducting metal oxides(SMOs)have currently aroused extensive attention by virtue of the unique electronic and catalytic properties of noble metals.This review highlights the research progress on the designs and applications of different noble metal-decorated SMOs with diverse nanostructures(e.g.,nanoparticles,nanowires,nanorods,nanosheets,nanoflowers,and microspheres)for high-performance gas sensors with higher response,faster response/recovery speed,lower operating temperature,and ultra-low detection limits.The key topics include Pt,Pd,Au,other noble metals(e.g.,Ag,Ru,and Rh.),and bimetals-decorated SMOs containing ZnO,SnO_(2),WO_(3),other SMOs(e.g.,In_(2)O_(3),Fe_(2)O_(3),and CuO),and heterostructured SMOs.In addition to conventional devices,the innovative applications like photo-assisted room temperature gas sensors and mechanically flexible smart wearable devices are also discussed.Moreover,the relevant mechanisms for the sensing performance improvement caused by noble metal decoration,including the electronic sensitization effect and the chemical sensitization effect,have also been summarized in detail.Finally,major challenges and future perspectives towards noble metal-decorated SMOs-based chemiresistive gas sensors are proposed.

Towards the selectivity distinction of phenol hydrogenation on noble metal catalysts

Selective hydrogenation of phenol to cyclohexanone is intriguing in chemical industry.Though a few catalysts with promising performances have been developed in recent years,the basic principle for catalyst design is still missing owing to the unclear catalytic mechanism.This work tries to unravel the mechanism of phenol hydro-genation and the reasons causing the selectivity discrepancy on noble metal catalysts under mild conditions.Results show that different reaction pathways always firstly converge to the formation of cyclohexanone under mild conditions.The selectivity discrepancy mainly depends on the activity for cyclohexanone sequential hy-drogenation,in which two factors are found to be responsible,i.e.the hydrogenation energy barrier and the competitive chemisorption between phenol and cyclohexanone,if the specific co-catalyzing effect of H 2 O on Ru is not considered.Based on the above results,a quantitative descriptor,E b(one/pl)/E a,in which E a can be further correlated to the d band center of the noble metal catalyst,is proposed by the first time to roughly evaluate and predict the selectivity to cyclohexanone for catalyst screening.

Finned Zn-MFI zeolite encapsulated noble metal nanoparticle catalysts for the oxidative dehydrogenation of propane with carbon dioxide

Oxidative dehydrogenation of propane with carbon dioxide(CO_(2)-ODP)characterizes the tandem dehydrogenation of propane to propylene with the reduction of the greenhouse gas of CO_(2)to valuable CO.However,the existing catalyst is limited due to the poor activity and stability,which hinders its industrialization.Herein,we design the finned Zn-MFI zeolite encapsulated noble metal nanoparticles(NPs)as bifunctional catalysts(NPs@Zn-MFI)for CO_(2)-ODP.Characterization results reveal that the Zn2+species are coordinated with the MFI zeolite matrix as isolated cations and the NPs of Pt,Rh,or Rh Pt are highly dispersed in the zeolite crystals.The isolated Zn2+cations are very effective for activating the propane and the small NPs are favorable for activating the CO_(2),which synergistically promote the selective transformation of propane and CO_(2)to propylene and CO.As a result,the optimal 0.25%Rh0.50%Pt@Zn-MFI catalyst shows the best propylene yield,satisfactory CO_(2)conversion,and long-term stability.Moreover,considering the tunable synergetic effects between the isolated cations and NPs,the developed approach offers a general guideline to design more efficient CO_(2)-ODP catalysts,which is validated by the improved performance of the bifunctional catalysts via simply substituting Sn4+cations for Zn2+cations in the MFI zeolite matrix.

An Innovative Study on the Path of Integrating Curriculum Ideology and Politics in College English Teaching:Taking An Overview of Chinese Culture as an Example

With the rapid development of information technology and the Internet,people can easily and quickly obtain news and information from all over the world.As the state’s requirements for the curriculum ideology and politics are being strengthened,it is necessary to adapt to the needs of the times and integrate ideology and politics into college English teaching.Integration of ideology and politics into teaching is a challenge faced by colleges and universities nowadays,which aims to make ideology and politics alive and well and more acceptable to contemporary college students.In view of this,this paper starts with the importance of the integration of ideology and politics into college English teaching,takes An Overview of Chinese Culture as an example,analyzes new approaches for integrating ideology and politics into the teaching process,and formulates the teaching design centered around these approaches,so as to promote the organic integration of ideology and politics with English teaching.

Power and Politics:The Psychology of Gender

Power,often seen as a tool for control,extends beyond individuals to encompass decisions and resources.Various groups hold varying degrees of power in society,employing tactics to gain and expand it.Politics is essentially the use of power to achieve goals,often stemming from conflicts between personal and organizational objectives.This occurs in situations marked by autocratic decision-making,unclear authority,resource scarcity,and uncertainty,when organizational politics contradict employees’interests,trust erodes,prioritizing individual concerns over collective goals.Constructive politics,however,empower and differentiate between ethical and unethical behavior.Gender,a socially constructed variable,is influenced by psychology and sociology literature,affecting power dynamics.This paper explores the interplay of power and politics in society,striving for a more equitable and progressive outcome while addressing their contribution to gender inequality.Globalization and economic restructuring impose changes,fostering discrimination and preferential treatment.We examine policy implementations in food,agriculture,health,and education,finding that despite significant changes,they often fail to benefit disadvantaged populations.

The Pathologies of Modernity:Liberalism,Nihilism,Conservatism,Postmodernism,Intersectionality/Identity Politics,and Secular Humanism

In this article,Mocombe highlights what he calls the pathological-pathogenic purposive-rationalities(liberalism,nihilism,conservatism,postmodernism,intersectionality/identity politics,and secular humanism)that emerge out of modernity as constituted by the West under American hegemony.In the place of these pathological-pathogenic responses to the vagaries of modernity,Mocombe calls for an antihumanism,associated with what he calls libertarian communism,as a panacea to the aforementioned malaises.

The Constructed Image:“China”in Gertrude Stein’s Composite Matrix of Aesthetics and Politics

As a representative modernist writer of the early 20th century,Gertrude Stein creatively established a unique experimental writing style to support her modernist expression.This paper attempts to analyze the Oriental elements,especially elements and images related to“China”in her works.Stein’s uses these elements to construct a systematic and complex matrix of aesthetics and politics.“China”in Stein’s matrix is an essential source of her so-called“the oriental peaceful penetration”and a significant lens for her ideological expression and political thoughts.Although Stein emphasizes her Oriental components in the source of identity,she always places herself in a Western position,ignoring cultural and political expressions in the real Chinese context and turning“China”into a useful tool in the collective fantasies of the West.

International Politics of Western Literary Theory:Literary Theory as Doctrine and as Discipline

European literary criticism was rapidly transformed into literary theory through the United States after Rene Wellek and Austin Warren’s textbook Theory of Literary Theory by Harcourt,Brace and Co.(1949).Within a short period of time,American new criticism,European psychoanalysis,semiotics,structuralism,hermeneutics,deconstructivism,and so on,as well as the western Marxism,feminism,new historicism,post-colonial criticism,and cultural studies,all the critical methods little referenced to postwar Western ideology and Soviet Ideology,and are even known for their profound criticism of some problems in capitalist society.These intuitively scientific or neutral literary theories flourished during the Cold War years that contained the Soviet Union.During this period,“political correctness”not only influenced the direction of social development in the West,but also directly influenced the academic pattern and the development trend of universities at that time,so that“literary criticism”,which was originally only based on personal experience,benefited and became“literary theory”in the discipline and curriculum system.As a result,the discipline of literary theory,which benefited from the Cold War pattern,is often in conflict with the specific literary theory that transcends ideology.However,the Cold War ended with the failure of the Soviet Union and its socialist realism theory system,and the western literary theory unexpectedly gained full legitimacy like Fukuyama’s“the end of history”.In the post-Cold War era,Western literary critics reasonably expanded the controversial theories and this has become the most concerned topic for 30 years.Thus,the international politics of the disguised Western literary theory was highlighted.Such Western literary theory has been generalized in China in the last 40 years,because Chinese academic yet has not understood the difference between theory as discipline and theory as doctrine,even anti-western in recent years.