Slickwater fracturing fluids have gained widespread application in the development of tight oil reservoirs. After the fracturing process, the active components present in slickwater can directly induce spontaneous imb...Slickwater fracturing fluids have gained widespread application in the development of tight oil reservoirs. After the fracturing process, the active components present in slickwater can directly induce spontaneous imbibition within the reservoir. Several variables influence the eventual recovery rate within this procedure, including slickwater composition, formation temperature, degree of reservoir fracture development, and the reservoir characteristics. Nonetheless, the underlying mechanisms governing these influences remain relatively understudied. In this investigation, using the Chang-7 block of the Changqing Oilfield as the study site, we employ EM-30 slickwater fracturing fluid to explore the effects of the drag-reducing agent concentration, imbibition temperature, core permeability, and core fracture development on spontaneous imbibition. An elevated drag-reducing agent concentration is observed to diminish the degree of medium and small pore utilization. Furthermore, higher temperatures and an augmented permeability enhance the fluid flow properties, thereby contributing to an increased utilization rate across all pore sizes. Reduced fracture development results in a lower fluid utilization across diverse pore types. This study deepens our understanding of the pivotal factors affecting spontaneous imbibition in tight reservoirs following fracturing. The findings act as theoretical, technical, and scientific foundations for optimizing fracturing strategies in tight oil reservoir transformations.展开更多
A mathematical model for the gas-water two-phase flow in tight gas reservoirs is elaborated.The model can account for the gas slip effect,stress sensitivity,and high-speed non-Darcy factors.The related equations are s...A mathematical model for the gas-water two-phase flow in tight gas reservoirs is elaborated.The model can account for the gas slip effect,stress sensitivity,and high-speed non-Darcy factors.The related equations are solved in the framework of a finite element method.The results are validated against those obtained by using the commercial software CMG(Computer Modeling Group software for advanced recovery process simulation).It is shown that the proposed method is reliable.It can capture the fracture rejection characteristics of tight gas reservoirs better than the CMG.A sensitivity analysis of various control factors(initial water saturation,reservoir parameters,and fracturing parameters)affecting the production in tight gas wells is conducted accordingly.Finally,a series of theoretical arguments are provided for a rational and effective development/exploitation of tight sandstone gas reservoirs.展开更多
To investigate the mechanism of rockburst prevention by spraying water onto the surrounding rocks,15 experiments are performed considering different water absorption levels on a single face.High-speed photography and ...To investigate the mechanism of rockburst prevention by spraying water onto the surrounding rocks,15 experiments are performed considering different water absorption levels on a single face.High-speed photography and acoustic emission(AE)system are used to monitor the rockburst process.The effect of water on sandstone rockburst and the prevention mechanism of water on sandstone rockburst are analyzed from the perspective of energy and failure mode.The results show that the higher the ab-sorption degree,the lower the intensity of the rockburst after absorbing water on single side of sand-stone.This is reflected in the fact that with the increase in the water absorption level,the ejection velocity of rockburst fragments is smaller,the depth of the rockburst pit is shallower,and the AE energy is smaller.Under the water absorption level of 100%,the magnitude of rockburst intensity changes from medium to slight.The prevention mechanism of water on sandstone rockburst is that water reduces the capacity of sandstone to store strain energy and accelerates the expansion of shear cracks,which is not conducive to the occurrence of plate cracking before rockburst,and destroys the conditions for rockburst incubation.展开更多
Active ingredients from highland barley have received considerable attention as natural products for developing treatments and dietary supplements against obesity.In practical application,the research of food combinat...Active ingredients from highland barley have received considerable attention as natural products for developing treatments and dietary supplements against obesity.In practical application,the research of food combinations is more significant than a specific food component.This study investigated the lipid-lowering effect of highland barley polyphenols via lipase assay in vitro and HepG2 cells induced by oleic acid(OA).Five indexes,triglyceride(TG),total cholesterol(T-CHO),low density lipoprotein-cholesterol(LDL-C),aspartate aminotransferase(AST),and alanine aminotransferase(ALT),were used to evaluate the lipidlowering effect of highland barley extract.We also preliminary studied the lipid-lowering mechanism by Realtime fluorescent quantitative polymerase chain reaction(q PCR).The results indicated that highland barley extract contains many components with lipid-lowering effects,such as hyperoside and scoparone.In vitro,the lipase assay showed an 18.4%lipase inhibition rate when the additive contents of highland barley extract were 100μg/m L.The intracellular lipid-lowering effect of highland barley extract was examined using 0.25 mmol/L OA-induced HepG2 cells.The results showed that intracellular TG,LDL-C,and T-CHO content decreased by 34.4%,51.2%,and 18.4%,respectively.ALT and AST decreased by 51.6%and 20.7%compared with the untreated hyperlipidemic HepG2 cells.q PCR results showed that highland barley polyphenols could up-regulation the expression of lipid metabolism-related genes such as PPARγand Fabp4.展开更多
Graphene, with its zero-bandgap electronic structure, is a highly promising ultra-broadband light absorbing material.However, the performance of graphene-based photodetectors is limited by weak absorption efficiency a...Graphene, with its zero-bandgap electronic structure, is a highly promising ultra-broadband light absorbing material.However, the performance of graphene-based photodetectors is limited by weak absorption efficiency and rapid recombination of photoexcited carriers, leading to poor photodetection performance. Here, inspired by the photogating effect, we demonstrated a highly sensitive photodetector based on graphene/WSe_(2) vertical heterostructure where the WSe_(2) layer acts as both the light absorption layer and the localized grating layer. The graphene conductive channel is induced to produce more carriers by capacitive coupling. Due to the strong light absorption and high external quantum efficiency of multilayer WSe_(2), as well as the high carrier mobility of graphene, a high photocurrent is generated in the vertical heterostructure. As a result, the photodetector exhibits ultra-high responsivity of 3.85×10~4A/W and external quantum efficiency of 1.3 × 10~7%.This finding demonstrates that photogating structures can effectively enhance the sensitivity of graphene-based photodetectors and may have great potential applications in future optoelectronic devices.展开更多
Lithium–sulfur(Li–S)batteries are supposed to be one of the most potential next-generation batteries owing to their high theoretical capacity and low cost.Nevertheless,the shuttle effect of firm multi-step two-elect...Lithium–sulfur(Li–S)batteries are supposed to be one of the most potential next-generation batteries owing to their high theoretical capacity and low cost.Nevertheless,the shuttle effect of firm multi-step two-electron reaction between sulfur and lithium in liquid electrolyte makes the capacity much smaller than the theoretical value.Many methods were proposed for inhibiting the shuttle effect of polysulfide,improving corresponding redox kinetics and enhancing the integral performance of Li–S batteries.Here,we will comprehensively and systematically summarize the strategies for inhibiting the shuttle effect from all components of Li–S batteries.First,the electrochemical principles/mechanism and origin of the shuttle effect are described in detail.Moreover,the efficient strategies,including boosting the sulfur conversion rate of sulfur,confining sulfur or lithium polysulfides(LPS)within cathode host,confining LPS in the shield layer,and preventing LPS from contacting the anode,will be discussed to suppress the shuttle effect.Then,recent advances in inhibition of shuttle effect in cathode,electrolyte,separator,and anode with the aforementioned strategies have been summarized to direct the further design of efficient materials for Li–S batteries.Finally,we present prospects for inhibition of the LPS shuttle and potential development directions in Li–S batteries.展开更多
Nanoparticles have been widely used in polymer gel systems in recent years to improve gelation performance under high-temperature reservoir conditions. However, different types of nanoparticles have different effects ...Nanoparticles have been widely used in polymer gel systems in recent years to improve gelation performance under high-temperature reservoir conditions. However, different types of nanoparticles have different effects on their gelation performance, which has been little researched. In this study, the high-temperature gelation performance, chemical structure, and microstructure of polymer gels prepared from two nanomaterials (i.e., nano-SiO_(2) and nano-TiO_(2)) were measured. The conventional HPAM/PEI polymer gel system was employed as the control sample. Results showed that the addition of nano-TiO_(2) could significantly enhance the gel strength of HPAM/PEI gel at 80 ℃. The gel strength of the enhanced HPAM/PEI gel with 0.1 wt% nano-TiO_(2) could reach grade I. The system also had excellent high-temperature stability at 150 ℃. The enhanced HPAM/PEI gel with 0.02 wt% nano-TiO_(2) reached the maximum gel strength at 150 ℃ with a storage modulus (G′) of 15 Pa, which can meet the need for efficient plugging. However, the nano-SiO_(2) enhanced HPAM/PEI polymer gel system showed weaker gel strength than that with nano-TiO_(2) at both 80 and 150 ℃ with G′ lower than 5 Pa. Microstructures showed that the nano-TiO_(2) enhanced HPAM/PEI gel had denser three-dimensional (3D) mesh structures, which makes the nano-TiO_(2) enhanced HPAM/PEI gel more firmly bound to water. The FT-IR results also confirmed that the chemical structure of the nano-TiO_(2) enhanced HPAM/PEI gel was more thermally stable than nano-SiO_(2) since there was a large amount of –OH groups on the structure surface. Therefore, nano-TiO_(2) was more suitable as the reinforcing material for HPAM/PEI gels for high-temperature petroleum reservoir conformance improvement.展开更多
Based on the global basement reservoir database and the dissection of basement reservoirs in China,the characteristics of hydrocarbon accumulation in basement reservoirs are analyzed,and the favorable conditions for h...Based on the global basement reservoir database and the dissection of basement reservoirs in China,the characteristics of hydrocarbon accumulation in basement reservoirs are analyzed,and the favorable conditions for hydrocarbon accumulation in deep basement reservoirs are investigated to highlight the exploration targets.The discovered basement reservoirs worldwide are mainly buried in the Archean and Precambrian granitic and metamorphic formations with depths less than 4500 m,and the relatively large reservoirs have been found in rift,back-arc and foreland basins in tectonic active zones of the Meso-Cenozoic plates.The hydrocarbon accumulation in basement reservoirs exhibits the characteristics in three aspects.First,the porous-fractured reservoirs with low porosity and ultra-low permeability are dominant,where extensive hydrocarbon accumulation occurred during the weathering denudation and later tectonic reworking of the basin basement.High resistance to compaction allows the physical properties of these highly heterogeneous reservoirs to be independent of the buried depth.Second,the hydrocarbons were sourced from the formations outside the basement.The source-reservoir assemblages are divided into contacted source rock-basement and separated source rock-basement patterns.Third,the abnormal high pressure in the source rock and the normal–low pressure in the basement reservoirs cause a large pressure difference between the source rock and the reservoirs,which is conducive to the pumping effect of hydrocarbons in the deep basement.The deep basement prospects are mainly evaluated by the factors such as tectonic activity of basement,source-reservoir combination,development of large deep faults(especially strike-slip faults),and regional seals.The Precambrian crystalline basements at the margin of the intracontinental rifts in cratonic basins,as well as the Paleozoic folded basements and the Meso-Cenozoic fault-block basements adjacent to the hydrocarbon generation depressions,have favorable conditions for hydrocarbon accumulation,and thus they are considered as the main targets for future exploration of deep basement reservoirs.展开更多
Exploring carbon emission effects based on the evolution of residents’ dietary structure to achieve the carbon neutrality goal and mitigate climate change is an important task.This study took China as the research ob...Exploring carbon emission effects based on the evolution of residents’ dietary structure to achieve the carbon neutrality goal and mitigate climate change is an important task.This study took China as the research object(data excluding Hong Kong,Macao and Taiwan) and used the carbon emission coefficient method to quantitatively measure the food carbon emissions from 1987–2020,then analyzed the carbon emission effects under the evolution of dietary structure.The results showed that during the study period,the Chinese dietary structure gradually changed to a high-carbon consumption pattern.The dietary structure of urban residents developed to a balanced one,while that of rural residents developed to a high-quality one.During the study period,the per capita food carbon emissions and total food consumption of Chinese showed an increasing trend.The per capita food carbon emissions of residents in urban and rural showed an overall upward trend.The total food carbon emissions in urban increased significantly,while that in rural increased first and then decreased.The influence of beef and mutton on carbon emissions is the highest in dietary structure.Compared with the balanced dietary pattern,the food carbon emissions of Chinese residents had not yet reached the peak,but were evolving to a high-carbon consumption pattern.展开更多
Thin reservoirs prediction method such as spectral inversion has drawn considerable attention in recent years. In order to avoid extracting wavelets within the whole field area purposeless and to make the filtered dat...Thin reservoirs prediction method such as spectral inversion has drawn considerable attention in recent years. In order to avoid extracting wavelets within the whole field area purposeless and to make the filtered data has preferable fidelity as well as signal-to-noise ratio, an effective structural constrained thin reservoir description method which combines spectral inversion and wide-band Ricker wavelet filtering technology has been proposed in this paper. The method given here is more credible and is suitable for the prediction of middle-deep thin reservoirs. We take LD-A structure within Bohai Bay Basin as an example to show the implement of our method. Several sets of thin sand layers which are hardly to recognize originally have been finally identified. Also, with the application of this method, a high-production thin reservoir of LD-B structure has been identified accurately, which provides credible information for subsequent fine oil exploration and development.展开更多
Through the long development processes of reservoir sedimentation and diagenesis, acidic and alkaline fluids play key roles in controlling deep reservoir development. However, the ways in which deep fluids control and...Through the long development processes of reservoir sedimentation and diagenesis, acidic and alkaline fluids play key roles in controlling deep reservoir development. However, the ways in which deep fluids control and transform the reservoir under complex fault conditions remain unclear. In this study, a 2D model was established based on a typical sub-salt to intra-salt vertical profile in the Qaidam Basin, China. Based on measured data, multiphase flow reaction and solute transport simulation technology were used to analyze fluids flow and migration in the intra-salt and sub-salt reservoirs, determine the mineral dissolution, precipitation, and transformation in the reservoir caused by the deep fluids, and calculate the changes in reservoir porosity. Results show that deep fluid migrates preferentially along dominant channels and triggers a series of fluid–rock chemical reactions. In the first stage, a large amount of anhydrite precipitated in the fault as a result of upward migration of deep saline fluid, resulting in the formation of anhydrite veins and blockage at the base of the fault. In the second stage, organic acids caused minerals dissolution and a vertical channel was opened in previously blocked area, which promoted continuous upward migration of organic acids and the formation of secondary pores. This study clarifies the transformative effects of deep alkaline and acidic fluids on the reservoir. Moreover, the important fluid transport role of faults and their effect on reservoir development were determined.展开更多
Based on the geological and geophysical data of Mesozoic oil-gas exploration in the sea area of Bohai Bay Basin and the discovered high-yield volcanic oil and gas wells since 2019,this paper methodically summarizes th...Based on the geological and geophysical data of Mesozoic oil-gas exploration in the sea area of Bohai Bay Basin and the discovered high-yield volcanic oil and gas wells since 2019,this paper methodically summarizes the formation conditions of large-and medium-sized Cretaceous volcanic oil and gas reservoirs in the Bohai Sea.Research shows that the Mesozoic large intermediate-felsic lava and intermediate-felsic composite volcanic edifices in the Bohai Sea are the material basis for the formation of large-scale volcanic reservoirs.The upper subfacies of effusive facies and cryptoexplosive breccia subfacies of volcanic conduit facies of volcanic vent-proximal facies belts are favorable for large-scale volcanic reservoir formation.Two types of efficient reservoirs,characterized by high porosity and medium to low permeability,as well as medium porosity and medium to low permeability,are the core of the formation of large-and medium-sized volcanic reservoirs.The reservoir with high porosity and medium to low permeability is formed by intermediate-felsic vesicular lava or the cryptoexplosive breccia superimposed by intensive dissolution.The reservoir with medium porosity and medium to low permeability is formed by intense tectonism superimposed by fluid dissolution.Weathering and tectonic transformation are main formation mechanisms for large and medium-sized volcanic reservoirs in the study area.The low-source“source-reservoir draping type”is the optimum source-reservoir configuration relationship for large-and medium-sized volcanic reservoirs.There exists favorable volcanic facies,efficient reservoirs and source-reservoir draping configuration relationship on the periphery of Bozhong Sag,and the large intermediate-felsic lava and intermediate-felsic composite volcanic edifices close to strike-slip faults and their branch faults are the main directions of future exploration.展开更多
The deeply buried Lower Cambrian Longwangmiao Formation and Upper Ediacaran Dengying Formation from the Sichuan Basin,China,have a total natural gas reserve up to 3×10^(12)m^(3).The complex diagenetic evolution a...The deeply buried Lower Cambrian Longwangmiao Formation and Upper Ediacaran Dengying Formation from the Sichuan Basin,China,have a total natural gas reserve up to 3×10^(12)m^(3).The complex diagenetic evolution and their impacts on the present-day reservoir quality have not been systematically elucidated,hampering the current exploration.Crucially,the integration and comparation diagenetic study on these two formations,which may be able to shed new lights on reservoir formation mechanism,are yet to be systemically evaluated.By compiling geochemistry data,including carbonate U-Pb ages and petrophysics data,coupled with new petrology,trace elements,and strontium isotope data,of various types of diagenetic carbonates,this study aims to decipher the potential links between diagenesis and reservoir development of both formations.Intriguingly,similar diagenetic sequence,which contains five distinctive dolomite phases,is established in both formations.The matrix dolomite(D1)and early dolomite cement(D2)were likely formed by reflux dolomitization,as inferred by their nearly syn-depositional U-Pb ages and elevatedδ^(18)O caused by seawater evaporation.The subsequent moderate burial dolomite cement(D3)was most plausibly the product of burial compaction as indicated by its lighterδ^(18)O and slightly younger U-Pb ages compared with D1 and D2.Whereas deep burial dolomite cements(D4 and D5)yield markedly depletedδ^(18)O,elevated ^(87)Sr/^(86)Sr,along with much younger U-Pb ages and higher precipitation temperatures,suggesting that they were likely linked to hydrothermal fluids.Despite the wide occurrence of meteoric and organic acids leaching and thermochemical sulfate reduction,they may have only played a subsidiary role on these reservoirs development.Instead,superior reservoir quality is tightly linked to tectonics as inferred by higher reservoir quality closely related to the well-developed fractures and faults filled with abundant hydrothermal minerals.Notably,good reservoirs in both formations are mainly attributed to high permeability caused by tectonics.Hence,this new contribution emphasizes the crucial role of tectonics on spatially explicit reservoir prediction of deep to ultra-deep(up to>8000 m)carbonates in the Sichuan Basin,as well as other sedimentary basin analogues in China.展开更多
In this study,we systematically investigated the effect of proton concentration on the kinetics of the oxygen reduction reaction(ORR)on Pt(111)in acidic solutions.Experimental results demonstrate a rectangular hyperbo...In this study,we systematically investigated the effect of proton concentration on the kinetics of the oxygen reduction reaction(ORR)on Pt(111)in acidic solutions.Experimental results demonstrate a rectangular hyperbolic relationship,i.e.,the ORR current excluding the effect of other variables increases with proton concentration and then tends to a constant value.We consider that this is caused by the limitation of ORR kinetics by the trace oxygen concentration in the solution,which determines the upper limit of ORR kinetics.A model of effective concentration is further proposed for rectangular hyperbolic relationships:when the reactant concentration is high enough to reach a critical saturation concentration,the effective reactant concentration will become a constant value.This could be due to the limited concentration of a certain reactant for reactions involving more than one reactant or the limited number of active sites available on the catalyst.Our study provides new insights into the kinetics of electrocatalytic reactions,and it is important for the proper evaluation of catalyst activity and the study of structureperformance relationships.展开更多
Urban shrinkage has emerged as a widespread phenomenon globally and has a significant impact on land,particularly in terms of land use and price.This study focuses on 2851 county-level cities in China in 2005–2018(ex...Urban shrinkage has emerged as a widespread phenomenon globally and has a significant impact on land,particularly in terms of land use and price.This study focuses on 2851 county-level cities in China in 2005–2018(excluding Hong Kong,Macao,Taiwan,and‘no data’areas in Qinhai-Tibet Plateau)as the fundamental units of analysis.By employing nighttime light(NTL)data to identify shrinking cities,the propensity score matching(PSM)model was used to quantitatively examine the impact of shrinking cities on land prices,and evaluate the magnitude of this influence.The findings demonstrate the following:1)there were 613 shrinking cities in China,with moderate shrinkage being the most prevalent and severe shrinkage being the least.2)Regional disparities are evident in the spatial distribution of shrinking cities,especially in areas with diverse terrain.3)The spatial pattern of land price exhibits a significant correlated to the economic and administrative levels.4)Shrinking cities significantly negatively impact on the overall land price(ATT=–0.1241,P<0.05).However,the extent of the effect varies significantly among different spatial regions.This study contributes novel insights into the investigation of land prices and shrinking cities,ultimately serving as a foundation for government efforts to promote the sustainable development of urban areas.展开更多
Emulsification is one of the important mechanisms of surfactant flooding. To improve oil recovery for low permeability reservoirs, a highly efficient emulsification oil flooding system consisting of anionic surfactant...Emulsification is one of the important mechanisms of surfactant flooding. To improve oil recovery for low permeability reservoirs, a highly efficient emulsification oil flooding system consisting of anionic surfactant sodium alkyl glucosyl hydroxypropyl sulfonate(APGSHS) and zwitterionic surfactant octadecyl betaine(BS-18) is proposed. The performance of APGSHS/BS-18 mixed surfactant system was evaluated in terms of interfacial tension, emulsification capability, emulsion size and distribution, wettability alteration, temperature-resistance and salt-resistance. The emulsification speed was used to evaluate the emulsification ability of surfactant systems, and the results show that mixed surfactant systems can completely emulsify the crude oil into emulsions droplets even under low energy conditions. Meanwhile,the system exhibits good temperature and salt resistance. Finally, the best oil recovery of 25.45% is achieved for low permeability core by the mixed surfactant system with a total concentration of 0.3 wt%while the molar ratio of APGSHS:BS-18 is 4:6. The current study indicates that the anionic/zwitterionic mixed surfactant system can improve the oil flooding efficiency and is potential candidate for application in low permeability reservoirs.展开更多
In-situ stress is a critical factor influencing the permeability of coal reservoirs and the production capacity of coalbed methane(CBM)wells.Accurate prediction of in-situ stress and investigation of its influence on ...In-situ stress is a critical factor influencing the permeability of coal reservoirs and the production capacity of coalbed methane(CBM)wells.Accurate prediction of in-situ stress and investigation of its influence on coal reservoir permeability and production capacity are significant for CBM development.This study investigated the CBM development zone in the Zhengzhuang area of the Qinshui Basin.According to the low mechanical strength of coal reservoirs,this study derived a calculation model of the in-situ stress of coal reservoirs based on the multi-loop hydraulic fracturing method and analyzed the impacts of initial fractures on the calculated results.Moreover,by combining the data such as the in-situ stress,permeability,and drainage and recovery data of CBM wells,this study revealed the spatial distribution patterns of the current in-situ stress of the coal reservoirs and discussed the impacts of the insitu stress on the permeability and production capacity.The results are as follows.(1)Under given fracturing pressure,longer initial fractures are associated with higher calculated maximum horizontal principal stress values.Therefore,ignoring the effects of the initial fractures will cause the calculated values of the in-situ stress to be less than the actual values.(2)As the burial depth increases,the fracturing pressure,closure pressure,and the maximum and minimum horizontal principal stress of the coal reservoirs in the Zhengzhuang area constantly increase.The average gradients of the maximum and minimum horizontal principal stress are 3.17 MPa/100 m and 2.05 MPa/100 m,respectively.(3)Coal reservoir permeability is significantly controlled by the magnitude and state of the current in-situ stress.The coal reservoir permeability decreases exponentially with an increase in the effective principal stress.Moreover,a low lateral pressure coefficient(less than 1)is associated with minor horizontal compressive effects and high coal reservoir permeability.(4)Under similar conditions,such as resource endowments,CBM well capacity is higher in primary structural coal regions with moderate paleotectonic stress modification,low current in-situ stress,and lateral pressure coefficient of less than 1.展开更多
Deep and ultra-deep reservoirs have gradually become the primary focus of hydrocarbon exploration as a result of a series of significant discoveries in deep hydrocarbon exploration worldwide.These reservoirs present u...Deep and ultra-deep reservoirs have gradually become the primary focus of hydrocarbon exploration as a result of a series of significant discoveries in deep hydrocarbon exploration worldwide.These reservoirs present unique challenges due to their deep burial depth(4500-8882 m),low matrix permeability,complex crustal stress conditions,high temperature and pressure(HTHP,150-200℃,105-155 MPa),coupled with high salinity of formation water.Consequently,the costs associated with their exploitation and development are exceptionally high.In deep and ultra-deep reservoirs,hydraulic fracturing is commonly used to achieve high and stable production.During hydraulic fracturing,a substantial volume of fluid is injected into the reservoir.However,statistical analysis reveals that the flowback rate is typically less than 30%,leaving the majority of the fluid trapped within the reservoir.Therefore,hydraulic fracturing in deep reservoirs not only enhances the reservoir permeability by creating artificial fractures but also damages reservoirs due to the fracturing fluids involved.The challenging“three-high”environment of a deep reservoir,characterized by high temperature,high pressure,and high salinity,exacerbates conventional forms of damage,including water sensitivity,retention of fracturing fluids,rock creep,and proppant breakage.In addition,specific damage mechanisms come into play,such as fracturing fluid decomposition at elevated temperatures and proppant diagenetic reactions at HTHP conditions.Presently,the foremost concern in deep oil and gas development lies in effectively assessing the damage inflicted on these reservoirs by hydraulic fracturing,comprehending the underlying mechanisms,and selecting appropriate solutions.It's noteworthy that the majority of existing studies on reservoir damage primarily focus on conventional reservoirs,with limited attention given to deep reservoirs and a lack of systematic summaries.In light of this,our approach entails initially summarizing the current knowledge pertaining to the types of fracturing fluids employed in deep and ultra-deep reservoirs.Subsequently,we delve into a systematic examination of the damage processes and mechanisms caused by fracturing fluids within the context of hydraulic fracturing in deep reservoirs,taking into account the unique reservoir characteristics of high temperature,high pressure,and high in-situ stress.In addition,we provide an overview of research progress related to high-temperature deep reservoir fracturing fluid and the damage of aqueous fracturing fluids to rock matrix,both artificial and natural fractures,and sand-packed fractures.We conclude by offering a summary of current research advancements and future directions,which hold significant potential for facilitating the efficient development of deep oil and gas reservoirs while effectively mitigating reservoir damage.展开更多
It is important to study the effect of hydrate production on the physical and mechanical properties of low-permeability clayey–silty reservoirs for the largescale exploitation of hydrate reservoirs in the South China...It is important to study the effect of hydrate production on the physical and mechanical properties of low-permeability clayey–silty reservoirs for the largescale exploitation of hydrate reservoirs in the South China Sea.In this study,a multiphysical-field coupling model,combined with actual exploration drilling data and the mechanical experimental data of hydrate cores in the laboratory,was established to investigate the physical and mechanical properties of low-permeability reservoirs with different slope angles during 5-year hydrate production by the depressurization method via a horizontal well.The result shows that the permeability of reservoirs severely affects gas production rate,and the maximum gas production amount of a 20-m-long horizontal well can reach186.8 m3/day during the 5-year hydrate production.Reservoirs with smaller slope angles show higher gas production rates.The depressurization propagation and hydrate dissociation mainly develop along the direction parallel to the slope.Besides,the mean effective stress of reservoirs is concentrated in the near-wellbore area with the on-going hydrate production,and gradually decreases with the increase of the slope angle.Different from the effective stress distribution law,the total reservoir settlement amount first decreases and then increases with the increase of the slope angle.The maximum settlement of reservoirs with a 0°slope angle is up to 3.4 m,and the displacement in the near-wellbore area is as high as2.2 m after 5 years of hydrate production.It is concluded that the pore pressure drop region of low-permeability reservoirs in the South China Sea is limited,and various slope angles further lead to differences in effective stress and strain of reservoirs during hydrate production,resulting in severe uneven settlement of reservoirs.展开更多
Using the typical characteristics of multi-layered marine and continental transitional gas reservoirs as a basis,a model is developed to predict the related well production rate.This model relies on the fractal theory...Using the typical characteristics of multi-layered marine and continental transitional gas reservoirs as a basis,a model is developed to predict the related well production rate.This model relies on the fractal theory of tortuous capillary bundles and can take into account multiple gas flow mechanisms at the micrometer and nanometer scales,as well as the flow characteristics in different types of thin layers(tight sandstone gas,shale gas,and coalbed gas).Moreover,a source-sink function concept and a pressure drop superposition principle are utilized to introduce a coupled flow model in the reservoir.A semi-analytical solution for the production rate is obtained using a matrix iteration method.A specific well is selected for fitting dynamic production data,and the calculation results show that the tight sandstone has the highest gas production per unit thickness compared with the other types of reservoirs.Moreover,desorption and diffusion of coalbed gas and shale gas can significantly contribute to gas production,and the daily production of these two gases decreases rapidly with decreasing reservoir pressure.Interestingly,the gas production from fractures exhibits an approximately U-shaped distribution,indicating the need to optimize the spacing between clusters during hydraulic fracturing to reduce the area of overlapping fracture control.The coal matrix water saturation significantly affects the coalbed gas production,with higher water saturation leading to lower production.展开更多
基金The authors sincerely appreciate the financial support from the National Natural Science Foundation of China(No.52074279,51874261).
文摘Slickwater fracturing fluids have gained widespread application in the development of tight oil reservoirs. After the fracturing process, the active components present in slickwater can directly induce spontaneous imbibition within the reservoir. Several variables influence the eventual recovery rate within this procedure, including slickwater composition, formation temperature, degree of reservoir fracture development, and the reservoir characteristics. Nonetheless, the underlying mechanisms governing these influences remain relatively understudied. In this investigation, using the Chang-7 block of the Changqing Oilfield as the study site, we employ EM-30 slickwater fracturing fluid to explore the effects of the drag-reducing agent concentration, imbibition temperature, core permeability, and core fracture development on spontaneous imbibition. An elevated drag-reducing agent concentration is observed to diminish the degree of medium and small pore utilization. Furthermore, higher temperatures and an augmented permeability enhance the fluid flow properties, thereby contributing to an increased utilization rate across all pore sizes. Reduced fracture development results in a lower fluid utilization across diverse pore types. This study deepens our understanding of the pivotal factors affecting spontaneous imbibition in tight reservoirs following fracturing. The findings act as theoretical, technical, and scientific foundations for optimizing fracturing strategies in tight oil reservoir transformations.
基金supported by the China Postdoctoral Science Foundation(2021M702304)and Natural Science Foundation of Shandong Province(ZR2021QE260).
文摘A mathematical model for the gas-water two-phase flow in tight gas reservoirs is elaborated.The model can account for the gas slip effect,stress sensitivity,and high-speed non-Darcy factors.The related equations are solved in the framework of a finite element method.The results are validated against those obtained by using the commercial software CMG(Computer Modeling Group software for advanced recovery process simulation).It is shown that the proposed method is reliable.It can capture the fracture rejection characteristics of tight gas reservoirs better than the CMG.A sensitivity analysis of various control factors(initial water saturation,reservoir parameters,and fracturing parameters)affecting the production in tight gas wells is conducted accordingly.Finally,a series of theoretical arguments are provided for a rational and effective development/exploitation of tight sandstone gas reservoirs.
基金The financial support from the National Natural Science Foun-dation of China(Grant Nos.52074299 and 41941018)the Fundamental Research Funds for the Central Universities of China(Grant No.2023JCCXSB02)are gratefully acknowledged.
文摘To investigate the mechanism of rockburst prevention by spraying water onto the surrounding rocks,15 experiments are performed considering different water absorption levels on a single face.High-speed photography and acoustic emission(AE)system are used to monitor the rockburst process.The effect of water on sandstone rockburst and the prevention mechanism of water on sandstone rockburst are analyzed from the perspective of energy and failure mode.The results show that the higher the ab-sorption degree,the lower the intensity of the rockburst after absorbing water on single side of sand-stone.This is reflected in the fact that with the increase in the water absorption level,the ejection velocity of rockburst fragments is smaller,the depth of the rockburst pit is shallower,and the AE energy is smaller.Under the water absorption level of 100%,the magnitude of rockburst intensity changes from medium to slight.The prevention mechanism of water on sandstone rockburst is that water reduces the capacity of sandstone to store strain energy and accelerates the expansion of shear cracks,which is not conducive to the occurrence of plate cracking before rockburst,and destroys the conditions for rockburst incubation.
基金financially supported by the National Key Research and Development Program of China(2021YFD2100904)the National Natural Science Foundation of China(31871729,32172147)+2 种基金the Modern Agriculture key Project of Jiangsu Province of China(BE2022317)the Modern Agricultural Industrial Technology System Construction Project of Jiangsu Province of China(JATS[2021]522)a project funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)。
文摘Active ingredients from highland barley have received considerable attention as natural products for developing treatments and dietary supplements against obesity.In practical application,the research of food combinations is more significant than a specific food component.This study investigated the lipid-lowering effect of highland barley polyphenols via lipase assay in vitro and HepG2 cells induced by oleic acid(OA).Five indexes,triglyceride(TG),total cholesterol(T-CHO),low density lipoprotein-cholesterol(LDL-C),aspartate aminotransferase(AST),and alanine aminotransferase(ALT),were used to evaluate the lipidlowering effect of highland barley extract.We also preliminary studied the lipid-lowering mechanism by Realtime fluorescent quantitative polymerase chain reaction(q PCR).The results indicated that highland barley extract contains many components with lipid-lowering effects,such as hyperoside and scoparone.In vitro,the lipase assay showed an 18.4%lipase inhibition rate when the additive contents of highland barley extract were 100μg/m L.The intracellular lipid-lowering effect of highland barley extract was examined using 0.25 mmol/L OA-induced HepG2 cells.The results showed that intracellular TG,LDL-C,and T-CHO content decreased by 34.4%,51.2%,and 18.4%,respectively.ALT and AST decreased by 51.6%and 20.7%compared with the untreated hyperlipidemic HepG2 cells.q PCR results showed that highland barley polyphenols could up-regulation the expression of lipid metabolism-related genes such as PPARγand Fabp4.
基金Project supported by the National Natural Science Foundation of China (Grant No.11974379)the National Key Basic Research and Development Program of China (Grant No.2021YFC2203400)Jiangsu Vocational Education Integrated Circuit Technology “Double-Qualified” Famous Teacher Studio (Grant No.2022-13)。
文摘Graphene, with its zero-bandgap electronic structure, is a highly promising ultra-broadband light absorbing material.However, the performance of graphene-based photodetectors is limited by weak absorption efficiency and rapid recombination of photoexcited carriers, leading to poor photodetection performance. Here, inspired by the photogating effect, we demonstrated a highly sensitive photodetector based on graphene/WSe_(2) vertical heterostructure where the WSe_(2) layer acts as both the light absorption layer and the localized grating layer. The graphene conductive channel is induced to produce more carriers by capacitive coupling. Due to the strong light absorption and high external quantum efficiency of multilayer WSe_(2), as well as the high carrier mobility of graphene, a high photocurrent is generated in the vertical heterostructure. As a result, the photodetector exhibits ultra-high responsivity of 3.85×10~4A/W and external quantum efficiency of 1.3 × 10~7%.This finding demonstrates that photogating structures can effectively enhance the sensitivity of graphene-based photodetectors and may have great potential applications in future optoelectronic devices.
基金support from the “Joint International Laboratory on Environmental and Energy Frontier Materials”“Innovation Research Team of High-Level Local Universities in Shanghai”support from the National Natural Science Foundation of China (22209103)
文摘Lithium–sulfur(Li–S)batteries are supposed to be one of the most potential next-generation batteries owing to their high theoretical capacity and low cost.Nevertheless,the shuttle effect of firm multi-step two-electron reaction between sulfur and lithium in liquid electrolyte makes the capacity much smaller than the theoretical value.Many methods were proposed for inhibiting the shuttle effect of polysulfide,improving corresponding redox kinetics and enhancing the integral performance of Li–S batteries.Here,we will comprehensively and systematically summarize the strategies for inhibiting the shuttle effect from all components of Li–S batteries.First,the electrochemical principles/mechanism and origin of the shuttle effect are described in detail.Moreover,the efficient strategies,including boosting the sulfur conversion rate of sulfur,confining sulfur or lithium polysulfides(LPS)within cathode host,confining LPS in the shield layer,and preventing LPS from contacting the anode,will be discussed to suppress the shuttle effect.Then,recent advances in inhibition of shuttle effect in cathode,electrolyte,separator,and anode with the aforementioned strategies have been summarized to direct the further design of efficient materials for Li–S batteries.Finally,we present prospects for inhibition of the LPS shuttle and potential development directions in Li–S batteries.
基金supported by the Natural Science Foundation of Xinjiang Uygur Autonomous Region(No.2022D01A250)the CNPC Strategic Cooperation Science and Technology Project(ZLZX2020-01-04-04).
文摘Nanoparticles have been widely used in polymer gel systems in recent years to improve gelation performance under high-temperature reservoir conditions. However, different types of nanoparticles have different effects on their gelation performance, which has been little researched. In this study, the high-temperature gelation performance, chemical structure, and microstructure of polymer gels prepared from two nanomaterials (i.e., nano-SiO_(2) and nano-TiO_(2)) were measured. The conventional HPAM/PEI polymer gel system was employed as the control sample. Results showed that the addition of nano-TiO_(2) could significantly enhance the gel strength of HPAM/PEI gel at 80 ℃. The gel strength of the enhanced HPAM/PEI gel with 0.1 wt% nano-TiO_(2) could reach grade I. The system also had excellent high-temperature stability at 150 ℃. The enhanced HPAM/PEI gel with 0.02 wt% nano-TiO_(2) reached the maximum gel strength at 150 ℃ with a storage modulus (G′) of 15 Pa, which can meet the need for efficient plugging. However, the nano-SiO_(2) enhanced HPAM/PEI polymer gel system showed weaker gel strength than that with nano-TiO_(2) at both 80 and 150 ℃ with G′ lower than 5 Pa. Microstructures showed that the nano-TiO_(2) enhanced HPAM/PEI gel had denser three-dimensional (3D) mesh structures, which makes the nano-TiO_(2) enhanced HPAM/PEI gel more firmly bound to water. The FT-IR results also confirmed that the chemical structure of the nano-TiO_(2) enhanced HPAM/PEI gel was more thermally stable than nano-SiO_(2) since there was a large amount of –OH groups on the structure surface. Therefore, nano-TiO_(2) was more suitable as the reinforcing material for HPAM/PEI gels for high-temperature petroleum reservoir conformance improvement.
基金Supported by the Science and Technology Project of China National Petroleum Corporation(2021DJ02).
文摘Based on the global basement reservoir database and the dissection of basement reservoirs in China,the characteristics of hydrocarbon accumulation in basement reservoirs are analyzed,and the favorable conditions for hydrocarbon accumulation in deep basement reservoirs are investigated to highlight the exploration targets.The discovered basement reservoirs worldwide are mainly buried in the Archean and Precambrian granitic and metamorphic formations with depths less than 4500 m,and the relatively large reservoirs have been found in rift,back-arc and foreland basins in tectonic active zones of the Meso-Cenozoic plates.The hydrocarbon accumulation in basement reservoirs exhibits the characteristics in three aspects.First,the porous-fractured reservoirs with low porosity and ultra-low permeability are dominant,where extensive hydrocarbon accumulation occurred during the weathering denudation and later tectonic reworking of the basin basement.High resistance to compaction allows the physical properties of these highly heterogeneous reservoirs to be independent of the buried depth.Second,the hydrocarbons were sourced from the formations outside the basement.The source-reservoir assemblages are divided into contacted source rock-basement and separated source rock-basement patterns.Third,the abnormal high pressure in the source rock and the normal–low pressure in the basement reservoirs cause a large pressure difference between the source rock and the reservoirs,which is conducive to the pumping effect of hydrocarbons in the deep basement.The deep basement prospects are mainly evaluated by the factors such as tectonic activity of basement,source-reservoir combination,development of large deep faults(especially strike-slip faults),and regional seals.The Precambrian crystalline basements at the margin of the intracontinental rifts in cratonic basins,as well as the Paleozoic folded basements and the Meso-Cenozoic fault-block basements adjacent to the hydrocarbon generation depressions,have favorable conditions for hydrocarbon accumulation,and thus they are considered as the main targets for future exploration of deep basement reservoirs.
基金Under the auspices of National Natural Science Foundation of China(No.42171230)。
文摘Exploring carbon emission effects based on the evolution of residents’ dietary structure to achieve the carbon neutrality goal and mitigate climate change is an important task.This study took China as the research object(data excluding Hong Kong,Macao and Taiwan) and used the carbon emission coefficient method to quantitatively measure the food carbon emissions from 1987–2020,then analyzed the carbon emission effects under the evolution of dietary structure.The results showed that during the study period,the Chinese dietary structure gradually changed to a high-carbon consumption pattern.The dietary structure of urban residents developed to a balanced one,while that of rural residents developed to a high-quality one.During the study period,the per capita food carbon emissions and total food consumption of Chinese showed an increasing trend.The per capita food carbon emissions of residents in urban and rural showed an overall upward trend.The total food carbon emissions in urban increased significantly,while that in rural increased first and then decreased.The influence of beef and mutton on carbon emissions is the highest in dietary structure.Compared with the balanced dietary pattern,the food carbon emissions of Chinese residents had not yet reached the peak,but were evolving to a high-carbon consumption pattern.
文摘Thin reservoirs prediction method such as spectral inversion has drawn considerable attention in recent years. In order to avoid extracting wavelets within the whole field area purposeless and to make the filtered data has preferable fidelity as well as signal-to-noise ratio, an effective structural constrained thin reservoir description method which combines spectral inversion and wide-band Ricker wavelet filtering technology has been proposed in this paper. The method given here is more credible and is suitable for the prediction of middle-deep thin reservoirs. We take LD-A structure within Bohai Bay Basin as an example to show the implement of our method. Several sets of thin sand layers which are hardly to recognize originally have been finally identified. Also, with the application of this method, a high-production thin reservoir of LD-B structure has been identified accurately, which provides credible information for subsequent fine oil exploration and development.
基金supported by the Natural Science Foundation of China(No.41902045,41702249)the Strategic Priority Research Program of the Chinese Academy of Sciences,Grant No.XDA14010401.
文摘Through the long development processes of reservoir sedimentation and diagenesis, acidic and alkaline fluids play key roles in controlling deep reservoir development. However, the ways in which deep fluids control and transform the reservoir under complex fault conditions remain unclear. In this study, a 2D model was established based on a typical sub-salt to intra-salt vertical profile in the Qaidam Basin, China. Based on measured data, multiphase flow reaction and solute transport simulation technology were used to analyze fluids flow and migration in the intra-salt and sub-salt reservoirs, determine the mineral dissolution, precipitation, and transformation in the reservoir caused by the deep fluids, and calculate the changes in reservoir porosity. Results show that deep fluid migrates preferentially along dominant channels and triggers a series of fluid–rock chemical reactions. In the first stage, a large amount of anhydrite precipitated in the fault as a result of upward migration of deep saline fluid, resulting in the formation of anhydrite veins and blockage at the base of the fault. In the second stage, organic acids caused minerals dissolution and a vertical channel was opened in previously blocked area, which promoted continuous upward migration of organic acids and the formation of secondary pores. This study clarifies the transformative effects of deep alkaline and acidic fluids on the reservoir. Moreover, the important fluid transport role of faults and their effect on reservoir development were determined.
基金Supported by the China National Offshore Oil Corporation Limited Project(2021-KT-YXKY-03)。
文摘Based on the geological and geophysical data of Mesozoic oil-gas exploration in the sea area of Bohai Bay Basin and the discovered high-yield volcanic oil and gas wells since 2019,this paper methodically summarizes the formation conditions of large-and medium-sized Cretaceous volcanic oil and gas reservoirs in the Bohai Sea.Research shows that the Mesozoic large intermediate-felsic lava and intermediate-felsic composite volcanic edifices in the Bohai Sea are the material basis for the formation of large-scale volcanic reservoirs.The upper subfacies of effusive facies and cryptoexplosive breccia subfacies of volcanic conduit facies of volcanic vent-proximal facies belts are favorable for large-scale volcanic reservoir formation.Two types of efficient reservoirs,characterized by high porosity and medium to low permeability,as well as medium porosity and medium to low permeability,are the core of the formation of large-and medium-sized volcanic reservoirs.The reservoir with high porosity and medium to low permeability is formed by intermediate-felsic vesicular lava or the cryptoexplosive breccia superimposed by intensive dissolution.The reservoir with medium porosity and medium to low permeability is formed by intense tectonism superimposed by fluid dissolution.Weathering and tectonic transformation are main formation mechanisms for large and medium-sized volcanic reservoirs in the study area.The low-source“source-reservoir draping type”is the optimum source-reservoir configuration relationship for large-and medium-sized volcanic reservoirs.There exists favorable volcanic facies,efficient reservoirs and source-reservoir draping configuration relationship on the periphery of Bozhong Sag,and the large intermediate-felsic lava and intermediate-felsic composite volcanic edifices close to strike-slip faults and their branch faults are the main directions of future exploration.
基金supported by grants from the National Natural Science Foundation of China(41972149,41890843).
文摘The deeply buried Lower Cambrian Longwangmiao Formation and Upper Ediacaran Dengying Formation from the Sichuan Basin,China,have a total natural gas reserve up to 3×10^(12)m^(3).The complex diagenetic evolution and their impacts on the present-day reservoir quality have not been systematically elucidated,hampering the current exploration.Crucially,the integration and comparation diagenetic study on these two formations,which may be able to shed new lights on reservoir formation mechanism,are yet to be systemically evaluated.By compiling geochemistry data,including carbonate U-Pb ages and petrophysics data,coupled with new petrology,trace elements,and strontium isotope data,of various types of diagenetic carbonates,this study aims to decipher the potential links between diagenesis and reservoir development of both formations.Intriguingly,similar diagenetic sequence,which contains five distinctive dolomite phases,is established in both formations.The matrix dolomite(D1)and early dolomite cement(D2)were likely formed by reflux dolomitization,as inferred by their nearly syn-depositional U-Pb ages and elevatedδ^(18)O caused by seawater evaporation.The subsequent moderate burial dolomite cement(D3)was most plausibly the product of burial compaction as indicated by its lighterδ^(18)O and slightly younger U-Pb ages compared with D1 and D2.Whereas deep burial dolomite cements(D4 and D5)yield markedly depletedδ^(18)O,elevated ^(87)Sr/^(86)Sr,along with much younger U-Pb ages and higher precipitation temperatures,suggesting that they were likely linked to hydrothermal fluids.Despite the wide occurrence of meteoric and organic acids leaching and thermochemical sulfate reduction,they may have only played a subsidiary role on these reservoirs development.Instead,superior reservoir quality is tightly linked to tectonics as inferred by higher reservoir quality closely related to the well-developed fractures and faults filled with abundant hydrothermal minerals.Notably,good reservoirs in both formations are mainly attributed to high permeability caused by tectonics.Hence,this new contribution emphasizes the crucial role of tectonics on spatially explicit reservoir prediction of deep to ultra-deep(up to>8000 m)carbonates in the Sichuan Basin,as well as other sedimentary basin analogues in China.
基金supported by the National Natural Science Foundation of China(21972131)。
文摘In this study,we systematically investigated the effect of proton concentration on the kinetics of the oxygen reduction reaction(ORR)on Pt(111)in acidic solutions.Experimental results demonstrate a rectangular hyperbolic relationship,i.e.,the ORR current excluding the effect of other variables increases with proton concentration and then tends to a constant value.We consider that this is caused by the limitation of ORR kinetics by the trace oxygen concentration in the solution,which determines the upper limit of ORR kinetics.A model of effective concentration is further proposed for rectangular hyperbolic relationships:when the reactant concentration is high enough to reach a critical saturation concentration,the effective reactant concentration will become a constant value.This could be due to the limited concentration of a certain reactant for reactions involving more than one reactant or the limited number of active sites available on the catalyst.Our study provides new insights into the kinetics of electrocatalytic reactions,and it is important for the proper evaluation of catalyst activity and the study of structureperformance relationships.
基金Under the auspices of National Natural Science Foundation of China(No.42071222,41771194)。
文摘Urban shrinkage has emerged as a widespread phenomenon globally and has a significant impact on land,particularly in terms of land use and price.This study focuses on 2851 county-level cities in China in 2005–2018(excluding Hong Kong,Macao,Taiwan,and‘no data’areas in Qinhai-Tibet Plateau)as the fundamental units of analysis.By employing nighttime light(NTL)data to identify shrinking cities,the propensity score matching(PSM)model was used to quantitatively examine the impact of shrinking cities on land prices,and evaluate the magnitude of this influence.The findings demonstrate the following:1)there were 613 shrinking cities in China,with moderate shrinkage being the most prevalent and severe shrinkage being the least.2)Regional disparities are evident in the spatial distribution of shrinking cities,especially in areas with diverse terrain.3)The spatial pattern of land price exhibits a significant correlated to the economic and administrative levels.4)Shrinking cities significantly negatively impact on the overall land price(ATT=–0.1241,P<0.05).However,the extent of the effect varies significantly among different spatial regions.This study contributes novel insights into the investigation of land prices and shrinking cities,ultimately serving as a foundation for government efforts to promote the sustainable development of urban areas.
基金financially supported by National Natural Science Foundation of China(No.22302229)Beijing Municipal Excellent Talent Training Funds Youth Advanced Individual Project(No.2018000020124G163)。
文摘Emulsification is one of the important mechanisms of surfactant flooding. To improve oil recovery for low permeability reservoirs, a highly efficient emulsification oil flooding system consisting of anionic surfactant sodium alkyl glucosyl hydroxypropyl sulfonate(APGSHS) and zwitterionic surfactant octadecyl betaine(BS-18) is proposed. The performance of APGSHS/BS-18 mixed surfactant system was evaluated in terms of interfacial tension, emulsification capability, emulsion size and distribution, wettability alteration, temperature-resistance and salt-resistance. The emulsification speed was used to evaluate the emulsification ability of surfactant systems, and the results show that mixed surfactant systems can completely emulsify the crude oil into emulsions droplets even under low energy conditions. Meanwhile,the system exhibits good temperature and salt resistance. Finally, the best oil recovery of 25.45% is achieved for low permeability core by the mixed surfactant system with a total concentration of 0.3 wt%while the molar ratio of APGSHS:BS-18 is 4:6. The current study indicates that the anionic/zwitterionic mixed surfactant system can improve the oil flooding efficiency and is potential candidate for application in low permeability reservoirs.
基金sponsored by the National Natural Science Foundation of China(42002181)projecta public bidding project of 2020 Shanxi Provincial Science and Technology Program(20201101002-03).
文摘In-situ stress is a critical factor influencing the permeability of coal reservoirs and the production capacity of coalbed methane(CBM)wells.Accurate prediction of in-situ stress and investigation of its influence on coal reservoir permeability and production capacity are significant for CBM development.This study investigated the CBM development zone in the Zhengzhuang area of the Qinshui Basin.According to the low mechanical strength of coal reservoirs,this study derived a calculation model of the in-situ stress of coal reservoirs based on the multi-loop hydraulic fracturing method and analyzed the impacts of initial fractures on the calculated results.Moreover,by combining the data such as the in-situ stress,permeability,and drainage and recovery data of CBM wells,this study revealed the spatial distribution patterns of the current in-situ stress of the coal reservoirs and discussed the impacts of the insitu stress on the permeability and production capacity.The results are as follows.(1)Under given fracturing pressure,longer initial fractures are associated with higher calculated maximum horizontal principal stress values.Therefore,ignoring the effects of the initial fractures will cause the calculated values of the in-situ stress to be less than the actual values.(2)As the burial depth increases,the fracturing pressure,closure pressure,and the maximum and minimum horizontal principal stress of the coal reservoirs in the Zhengzhuang area constantly increase.The average gradients of the maximum and minimum horizontal principal stress are 3.17 MPa/100 m and 2.05 MPa/100 m,respectively.(3)Coal reservoir permeability is significantly controlled by the magnitude and state of the current in-situ stress.The coal reservoir permeability decreases exponentially with an increase in the effective principal stress.Moreover,a low lateral pressure coefficient(less than 1)is associated with minor horizontal compressive effects and high coal reservoir permeability.(4)Under similar conditions,such as resource endowments,CBM well capacity is higher in primary structural coal regions with moderate paleotectonic stress modification,low current in-situ stress,and lateral pressure coefficient of less than 1.
基金Dao-Bing Wang was supported by the Beijing Natural Science Foundation Project(No.3222030)the National Natural Science Foundation of China(No.52274002)+1 种基金the PetroChina Science and Technology Innovation Foundation Project(No.2021DQ02-0201)Fu-Jian Zhou was supported by the National Natural Science Foundation of China(No.52174045).
文摘Deep and ultra-deep reservoirs have gradually become the primary focus of hydrocarbon exploration as a result of a series of significant discoveries in deep hydrocarbon exploration worldwide.These reservoirs present unique challenges due to their deep burial depth(4500-8882 m),low matrix permeability,complex crustal stress conditions,high temperature and pressure(HTHP,150-200℃,105-155 MPa),coupled with high salinity of formation water.Consequently,the costs associated with their exploitation and development are exceptionally high.In deep and ultra-deep reservoirs,hydraulic fracturing is commonly used to achieve high and stable production.During hydraulic fracturing,a substantial volume of fluid is injected into the reservoir.However,statistical analysis reveals that the flowback rate is typically less than 30%,leaving the majority of the fluid trapped within the reservoir.Therefore,hydraulic fracturing in deep reservoirs not only enhances the reservoir permeability by creating artificial fractures but also damages reservoirs due to the fracturing fluids involved.The challenging“three-high”environment of a deep reservoir,characterized by high temperature,high pressure,and high salinity,exacerbates conventional forms of damage,including water sensitivity,retention of fracturing fluids,rock creep,and proppant breakage.In addition,specific damage mechanisms come into play,such as fracturing fluid decomposition at elevated temperatures and proppant diagenetic reactions at HTHP conditions.Presently,the foremost concern in deep oil and gas development lies in effectively assessing the damage inflicted on these reservoirs by hydraulic fracturing,comprehending the underlying mechanisms,and selecting appropriate solutions.It's noteworthy that the majority of existing studies on reservoir damage primarily focus on conventional reservoirs,with limited attention given to deep reservoirs and a lack of systematic summaries.In light of this,our approach entails initially summarizing the current knowledge pertaining to the types of fracturing fluids employed in deep and ultra-deep reservoirs.Subsequently,we delve into a systematic examination of the damage processes and mechanisms caused by fracturing fluids within the context of hydraulic fracturing in deep reservoirs,taking into account the unique reservoir characteristics of high temperature,high pressure,and high in-situ stress.In addition,we provide an overview of research progress related to high-temperature deep reservoir fracturing fluid and the damage of aqueous fracturing fluids to rock matrix,both artificial and natural fractures,and sand-packed fractures.We conclude by offering a summary of current research advancements and future directions,which hold significant potential for facilitating the efficient development of deep oil and gas reservoirs while effectively mitigating reservoir damage.
基金China Postdoctoral Science Foundation,Grant/Award Number:2020M681768Natural Science Foundation of Jiangsu Province,Grant/Award Number:BK20200653+1 种基金Fundamental Research Funds for the Central Universities,Grant/Award Number:2021GJZPY15National Natural Science Foundation of China,Grant/Award Number:42106210。
文摘It is important to study the effect of hydrate production on the physical and mechanical properties of low-permeability clayey–silty reservoirs for the largescale exploitation of hydrate reservoirs in the South China Sea.In this study,a multiphysical-field coupling model,combined with actual exploration drilling data and the mechanical experimental data of hydrate cores in the laboratory,was established to investigate the physical and mechanical properties of low-permeability reservoirs with different slope angles during 5-year hydrate production by the depressurization method via a horizontal well.The result shows that the permeability of reservoirs severely affects gas production rate,and the maximum gas production amount of a 20-m-long horizontal well can reach186.8 m3/day during the 5-year hydrate production.Reservoirs with smaller slope angles show higher gas production rates.The depressurization propagation and hydrate dissociation mainly develop along the direction parallel to the slope.Besides,the mean effective stress of reservoirs is concentrated in the near-wellbore area with the on-going hydrate production,and gradually decreases with the increase of the slope angle.Different from the effective stress distribution law,the total reservoir settlement amount first decreases and then increases with the increase of the slope angle.The maximum settlement of reservoirs with a 0°slope angle is up to 3.4 m,and the displacement in the near-wellbore area is as high as2.2 m after 5 years of hydrate production.It is concluded that the pore pressure drop region of low-permeability reservoirs in the South China Sea is limited,and various slope angles further lead to differences in effective stress and strain of reservoirs during hydrate production,resulting in severe uneven settlement of reservoirs.
文摘Using the typical characteristics of multi-layered marine and continental transitional gas reservoirs as a basis,a model is developed to predict the related well production rate.This model relies on the fractal theory of tortuous capillary bundles and can take into account multiple gas flow mechanisms at the micrometer and nanometer scales,as well as the flow characteristics in different types of thin layers(tight sandstone gas,shale gas,and coalbed gas).Moreover,a source-sink function concept and a pressure drop superposition principle are utilized to introduce a coupled flow model in the reservoir.A semi-analytical solution for the production rate is obtained using a matrix iteration method.A specific well is selected for fitting dynamic production data,and the calculation results show that the tight sandstone has the highest gas production per unit thickness compared with the other types of reservoirs.Moreover,desorption and diffusion of coalbed gas and shale gas can significantly contribute to gas production,and the daily production of these two gases decreases rapidly with decreasing reservoir pressure.Interestingly,the gas production from fractures exhibits an approximately U-shaped distribution,indicating the need to optimize the spacing between clusters during hydraulic fracturing to reduce the area of overlapping fracture control.The coal matrix water saturation significantly affects the coalbed gas production,with higher water saturation leading to lower production.