It is well known that [6,6]-phenyl-C<sub><span style="font-size:12px;font-family:Verdana;">61</span></sub><span style="font-size:12px;font-family:Verdana;">-butyric ac...It is well known that [6,6]-phenyl-C<sub><span style="font-size:12px;font-family:Verdana;">61</span></sub><span style="font-size:12px;font-family:Verdana;">-butyric acid methyl ester (PCBM) is a common n-type passivation material in PSCs, usually used as an interface modification layer. However, PCBM is extremely expensive and is not suitable for future industrialization. Herein, the various concentrations of PCBM as an additive are adopted for PSCs. It not only avoids the routine process of spin coating the multi-layer films, but also reduces the PCBM material and cost. Meanwhile, PCBM can passivate the grain surface and modulate morphology of perovskite films. Furthermore, the most important optical parameters of solar cells, the current density (</span><i><span style="font-size:12px;font-family:Verdana;">J</span><sub><span style="font-size:12px;font-family:Verdana;">sc</span></sub></i><span style="font-size:12px;font-family:Verdana;">), fill factor (FF), open-circuit voltage (</span><i><span style="font-size:12px;font-family:Verdana;">V</span><sub><span style="font-size:12px;font-family:Verdana;">oc</span></sub></i><span style="font-size:12px;font-family:Verdana;">) and power conversion efficiencies (PCE) were improved. Especially, when the PCBM doping ratio in CH</span><sub><span style="font-size:12px;font-family:Verdana;">3</span></sub><span style="font-size:12px;font-family:Verdana;">NH</span><sub><span style="font-size:12px;font-family:Verdana;">3</span></sub><span style="font-size:12px;font-family:Verdana;">PbI</span><sub><span style="font-size:12px;font-family:Verdana;">3</span></sub><span style="font-size:12px;font-family:Verdana;"> (MAPbI</span><sub><span style="font-size:12px;font-family:Verdana;">3</span></sub><span style="font-size:12px;font-family:Verdana;">) precursor solution was 1</span><span><span><span style="font-family:;" "=""> </span></span></span><span><span><span style="font-family:;" "=""><span style="font-size:12px;font-family:Verdana;">wt%, the device obtained the smallest </span><i><span style="font-size:12px;font-family:Verdana;">V</span><sub><span style="font-size:12px;font-family:Verdana;">oc</span></sub></i><span style="font-size:12px;font-family:Verdana;"> decay (less than 1%) in the p-i-n type PSCs with poly</span></span></span></span><span><span><span style="font-family:;" "=""> </span></span></span><span><span><span style="font-family:;" "=""><span style="font-size:12px;font-family:Verdana;">(3,4-ethylenedioxythiophene):poly (styrene sulfonate) (PEDOT:PSS) as hole transport layer (HTL) and fullerene (C</span><sub><span style="font-size:12px;font-family:Verdana;">60</span></sub><span style="font-size:12px;font-family:Verdana;">) as electron transport layer (ETL). The PSCs </span><i><span style="font-size:12px;font-family:Verdana;">V</span><sub><span style="font-size:12px;font-family:Verdana;">oc</span></sub></i><span style="font-size:12px;font-family:Verdana;"> stability improvement is attri</span><span style="font-size:12px;font-family:Verdana;">buted to enhanced crystallinity of photoactive layer and decreased non-radiative </span><span style="font-size:12px;font-family:Verdana;">recombination by PCBM doping in the perovskites.</span></span></span></span>展开更多
文摘It is well known that [6,6]-phenyl-C<sub><span style="font-size:12px;font-family:Verdana;">61</span></sub><span style="font-size:12px;font-family:Verdana;">-butyric acid methyl ester (PCBM) is a common n-type passivation material in PSCs, usually used as an interface modification layer. However, PCBM is extremely expensive and is not suitable for future industrialization. Herein, the various concentrations of PCBM as an additive are adopted for PSCs. It not only avoids the routine process of spin coating the multi-layer films, but also reduces the PCBM material and cost. Meanwhile, PCBM can passivate the grain surface and modulate morphology of perovskite films. Furthermore, the most important optical parameters of solar cells, the current density (</span><i><span style="font-size:12px;font-family:Verdana;">J</span><sub><span style="font-size:12px;font-family:Verdana;">sc</span></sub></i><span style="font-size:12px;font-family:Verdana;">), fill factor (FF), open-circuit voltage (</span><i><span style="font-size:12px;font-family:Verdana;">V</span><sub><span style="font-size:12px;font-family:Verdana;">oc</span></sub></i><span style="font-size:12px;font-family:Verdana;">) and power conversion efficiencies (PCE) were improved. Especially, when the PCBM doping ratio in CH</span><sub><span style="font-size:12px;font-family:Verdana;">3</span></sub><span style="font-size:12px;font-family:Verdana;">NH</span><sub><span style="font-size:12px;font-family:Verdana;">3</span></sub><span style="font-size:12px;font-family:Verdana;">PbI</span><sub><span style="font-size:12px;font-family:Verdana;">3</span></sub><span style="font-size:12px;font-family:Verdana;"> (MAPbI</span><sub><span style="font-size:12px;font-family:Verdana;">3</span></sub><span style="font-size:12px;font-family:Verdana;">) precursor solution was 1</span><span><span><span style="font-family:;" "=""> </span></span></span><span><span><span style="font-family:;" "=""><span style="font-size:12px;font-family:Verdana;">wt%, the device obtained the smallest </span><i><span style="font-size:12px;font-family:Verdana;">V</span><sub><span style="font-size:12px;font-family:Verdana;">oc</span></sub></i><span style="font-size:12px;font-family:Verdana;"> decay (less than 1%) in the p-i-n type PSCs with poly</span></span></span></span><span><span><span style="font-family:;" "=""> </span></span></span><span><span><span style="font-family:;" "=""><span style="font-size:12px;font-family:Verdana;">(3,4-ethylenedioxythiophene):poly (styrene sulfonate) (PEDOT:PSS) as hole transport layer (HTL) and fullerene (C</span><sub><span style="font-size:12px;font-family:Verdana;">60</span></sub><span style="font-size:12px;font-family:Verdana;">) as electron transport layer (ETL). The PSCs </span><i><span style="font-size:12px;font-family:Verdana;">V</span><sub><span style="font-size:12px;font-family:Verdana;">oc</span></sub></i><span style="font-size:12px;font-family:Verdana;"> stability improvement is attri</span><span style="font-size:12px;font-family:Verdana;">buted to enhanced crystallinity of photoactive layer and decreased non-radiative </span><span style="font-size:12px;font-family:Verdana;">recombination by PCBM doping in the perovskites.</span></span></span></span>