The southern Laizhou Bay is mainly composed of silt-sandy coasts with diverse landforms, and its marine hydrodynamic environment is sensitive to human activities. Marine hydrodynamic and sedimentary environments of th...The southern Laizhou Bay is mainly composed of silt-sandy coasts with diverse landforms, and its marine hydrodynamic environment is sensitive to human activities. Marine hydrodynamic and sedimentary environments of the study area have changed under the influence of large-scale port projects in recent years. In this paper, the evolution of hydrodynamic environment, deposition rate, and geochemical characteristics were studied based on sediment grain size, element analysis and ^(210)Pb dating of two cores, in order to analyze the influence of Weifang Port on marine environmental evolution, and provide theoretical and practical basis for protecting marine environment in developing marine resources reasonably. Results showed that sediments of the two cores were relatively coarser and mainly composed of silty sand. Sediments above 230 cm in core WF1 and 218 cm in core WF2 were deposited since 1855 when the Yellow River appeared to deposit its sediments within the modern active delta, and the average deposition rate was between 0.3 and 0.5 cm a^(-1). Implement of Weifang Port projects in 1997 and 2007 created great influence on the sedimentary environment evolution in the surrounding waters, and the deposition rate was significantly increased. The average annual deposition rates were 5.1 cm and 3.5 cm in WF1 and WF2 respectively between 1997 and 2007. Content of heavy metals in sediments showed no obvious change in the vertical, indicating that the heavy metals were less affected by human activity and there was no significant accumulation of such metals in the study area.展开更多
The Hua’aobaote Pb-Zn-Ag Polymetallic orefield is situated in the southern section of the Great Xing’an Range(GXAR),which has experienced extensive magmatism.Since the Paleozoic,there are two stages of magmatism in ...The Hua’aobaote Pb-Zn-Ag Polymetallic orefield is situated in the southern section of the Great Xing’an Range(GXAR),which has experienced extensive magmatism.Since the Paleozoic,there are two stages of magmatism in Hua’aobaote orefield occurred in the Paleozoic and Mesozoic.The Mesozoic magmatism is of great significance for the PbZn-Ag Polymetallic mineralization in Hua’aobaote orefield.In this study,new geochemical data was obtained to discuss the timing and petrogenesis of the magmatic rocks and its geodynamic and metallogenic significance.Zircon U-Pb ages reveal that the felsic igneous rocks from the Hua’aobaote orefield were formed in the Early Permian(294.8±3.2 Ma)and Early Cretaceous(132.6±1.4 Ma).Geochemically,the Early Permian granodiorite porphyrite is characterized by high Sr/Y(42-63)ratios and Mg^(#)(62.24-70.74)values and low heavy rare earth element(HREE)(5.09-6.79 ppm)contents.The granodiorite porphyrite is also characterized by depleted Sr-Nd initial isotopic signatures[ε_(Nd)(t)=5.91-7.59,(^(87)Sr/^(86)Sr)i=0.7029-0.7030],exhibiting adakitic characteristics.The Early Cretaceous granite porphyry and rhyolite are A-type felsic igneous rocks,and demonstrate high SiO_(2),Na_(2)O+K_(2)O and rare earth element(REE)contents,low CaO and MgO contents,low(^(87)Sr/^(86)Sr)i ratios(0.7044-0.7058),and positive ε_(Nd)(t)values(2.57-4.65).Whole-rock Pb isotopic compositions in granodiorite porphyrite are:206Pb/204Pb=17.631-18.149,^(207)Pb/^(204)Pb=15.422-15.450,and ^(208)Pb/^(204)Pb=37.325-37.729.The granite porphyry and rhyolite have initial ^(206)Pb/^(204)Pb,^(207)Pb/^(204)Pb,and ^(208)Pb/^(204)Pb ratios of 18.106-19.309,15.489-15.539,and 37.821-38.05,respectively.Sr-Nd-Pb isotopic evidence suggests that the Early Permian granodiorite porphyrite is likely to derive from slab melts and modified by peridotitic mantle wedge in the subduction tectonic setting of the Paleo-Asian Ocean.The Early Cretaceous A-type felsic igneous rocks were derived from juvenile lower crust,accompanied by limited crustal contamination and various degree of fractional crystallisation during magma emplacement.The Early Cretaceous magmatism and related mineralization were formed in a post-orogenic tectonic setting that attributed to the closure of the Mongol-Okhotsk Ocean.Pb isotopic data for the various rock units in the study area indicate that the Mesozoic magma source contributed substantial Pb,Zn,and Ag to the Hua’aobaote deposit.展开更多
Rare metal ore reserves are an important strategic resource, and their metallogenic mechanism and mineralization studies have also been received widespread international attention.
The Southern Great Xing’an Range(SGXR) hosts a number of Early Cretaceous Sn and associated metal deposits, which can be divided into three principal types according to their geological characteristics: skarn type de...The Southern Great Xing’an Range(SGXR) hosts a number of Early Cretaceous Sn and associated metal deposits, which can be divided into three principal types according to their geological characteristics: skarn type deposits, porphyry type deposits and hydrothermal vein type deposits. Fluid inclusion assemblages of different types of deposits are quite different, which represent the complexities of metallogenic process and formation mechanism. CH4 and CO2 have been detected in fluid inclusions from some of deposits, indicating that the ore-forming fluids are affected by materials of Permian strata. Hydrogen and oxygen isotope data from ore minerals and associated gangue minerals indicate that the initial ore fluids were dominated by magmatic waters, some of which had clearly exchanged oxygen with wall rocks during their passage through the strata. The narrow range for the δ34S values presumably reflects the corresponding uniformity of the ore forming fluids, and these δ34S values have been interpreted to reflect magmatic sources for the sulfur. The comparation between lead isotope ratios of ore minerals and different geological units’ also reveals that deeply seated magma has been a significant source of lead in the ores.展开更多
The protection zones or capture zones of springs in desert environments can be hard to identify,but they are critical to spring protection.Most springs fed by regional aquifers are susceptible to contamination and gro...The protection zones or capture zones of springs in desert environments can be hard to identify,but they are critical to spring protection.Most springs fed by regional aquifers are susceptible to contamination and groundwater development.The U.S.Environmental Protection Agency has established hydrogeologic mapping methods to delineate protection zones for springs.However,it is often difficult to determine a regional aquifer system's flow pattern with this technique alone,and the use of these methods is not conducive to efficient groundwater management.Particle tracking analysis using a well-conceptualized and calibrated numerical model for the three-dimensional groundwater flow domain feeding a given group of springs can help facilitate the identification of spring capture zone boundaries.Building upon this basis,a multifaceted approach was developed to define clear boundaries of the capture zones for the springs in the Furnace Creek,Ash Meadows,and the Muddy River areas in the southern Great Basin,USA.Capture zones were first delineated from inverse particle tracking and Hydrologic Unit 12 watersheds.Afterwards,they were adjusted based on water budgets,geology,and hydrologically significant faults.Finally,a geochemical analysis of the groundwater chemistry and isotopic data was conducted to verify the extent of each spring capture zone.This multifaceted approach adds confidence to the new delineations.展开更多
The southern Great Xing'an Range is the most critical Sn-polymetallic metallogenic belt in northeast China.However,the tectonic setting of the Early Cretaceous magmatic-metallogenic”flare-up“event remains uncert...The southern Great Xing'an Range is the most critical Sn-polymetallic metallogenic belt in northeast China.However,the tectonic setting of the Early Cretaceous magmatic-metallogenic”flare-up“event remains uncertain.This paper presents an integrated study on the occurrence,petrology,zircon U-Pb ages,whole-rock geochemistry,and in situ zircon Hf isotopes for Wenduerchagan granites of Xi Ujimqin Banner,central-eastern Inner Mongolia.These granites consist primarily of granite porphyry(with ages of 137±1 Ma and 138±1 Ma)and(porphyritic)alkali feldspar granite(with an age of 141±2 Ma),corresponding to the early Early Cretaceous.They are A-type granites characterized by high silicon,alkali,and TFeO/MgO contents while being depleted of Ba,Nb,Ta,Sr,P,and Ti.They show right-dipping trend rare-earth element distribution characteristics with negative Eu anomalies(Eu/Eu^(*)=0.01-0.20)and weak heavy rare-earth element fractionation((Gd/Yb)_(N)=0.77-2.30).They demonstrate homogeneous zircon Hf isotopic compositions(positiveε_(Hf)(t)values from+5.3 to+7.1 and young two-stage Hf model ages of 851-742 Ma)and high zircon saturation temperatures(av.810℃).These geochemical characteristics indicate that Wenduerchagan granites originated from the partial melting of juvenile crust under high-temperature and low-pressure conditions.Wenduerchagan granites most likely formed in a post-collisional compression-extension transition regime caused by the closure of the Mongol-Okhotsk Ocean,when combined with regional geology.Such a transition regime can probably be attributed to the upwelling of the asthenospheric mantle caused by the break-off of a subducted Mongol-Okhotsk oceanic slab.Upwelling asthenospheric mantle provided sufficient energy and favorable tectonic conditions for magmatism and mineralization of the Early Cretaceous.展开更多
Voluminous Early Cretaceous granitoids and associated large-scale ore deposits are distributed within the southern Great Xing'an Range(SGXR),NE China.Based on previously published geochronology and zircon Hf-isoto...Voluminous Early Cretaceous granitoids and associated large-scale ore deposits are distributed within the southern Great Xing'an Range(SGXR),NE China.Based on previously published geochronology and zircon Hf-isotope data,Hf isotope mapping is undertaken to improve our understanding of crustal architecture and its controls on ore deposits.The ore-related Early Cretaceous granitoids were sourced predominantly from juvenile crust,with the involvement of variable proportions of ancient crustal materials.The crustal architecture,as inferred from Hf isotopic contour maps,indicates two distinct Hf isotopic domains in SGXR,including(1)a higher-ε_(Hf)(+7 to+11)juvenile crust containing minor ancient crustal material,and(2)a lower-ε_(Hf)(+2 to+6)juvenile crust containing a greater proportion of ancient crustal materials.The Hf isotopic maps identify links between crustal architecture and regional metallogeny.Copper deposits and other deposits with significant Cu production are restricted mainly to the higher-ε_(Hf)juvenile crustal regions in the northern and eastern SGXR.Deposits dominated by other metals(e.g.,Mo,Sn,W,Pb,Zn,and Ag)occur mainly in the lower-ε_(Hf)juvenile crustal regions in the southern and western SGXR.Interaction between juvenile crust-derived melts and ancient crustal components played an important role on the distribution of various ore metals.展开更多
基金financially supported by the Marine Commonweal Scientific Research Foundation (Grant No. 201005009)the Basic Scientific Fund for National Public Research Institutes of China (Grant No. 2015G08)
文摘The southern Laizhou Bay is mainly composed of silt-sandy coasts with diverse landforms, and its marine hydrodynamic environment is sensitive to human activities. Marine hydrodynamic and sedimentary environments of the study area have changed under the influence of large-scale port projects in recent years. In this paper, the evolution of hydrodynamic environment, deposition rate, and geochemical characteristics were studied based on sediment grain size, element analysis and ^(210)Pb dating of two cores, in order to analyze the influence of Weifang Port on marine environmental evolution, and provide theoretical and practical basis for protecting marine environment in developing marine resources reasonably. Results showed that sediments of the two cores were relatively coarser and mainly composed of silty sand. Sediments above 230 cm in core WF1 and 218 cm in core WF2 were deposited since 1855 when the Yellow River appeared to deposit its sediments within the modern active delta, and the average deposition rate was between 0.3 and 0.5 cm a^(-1). Implement of Weifang Port projects in 1997 and 2007 created great influence on the sedimentary environment evolution in the surrounding waters, and the deposition rate was significantly increased. The average annual deposition rates were 5.1 cm and 3.5 cm in WF1 and WF2 respectively between 1997 and 2007. Content of heavy metals in sediments showed no obvious change in the vertical, indicating that the heavy metals were less affected by human activity and there was no significant accumulation of such metals in the study area.
基金supported by the National Natural Science Foundation of China(Grant Nos.41972312,41672329)the National Key Research and Development Project of China(Grant No.2016YFC0600509)the Project of China Geological Survey(Grant No.1212011120341)。
文摘The Hua’aobaote Pb-Zn-Ag Polymetallic orefield is situated in the southern section of the Great Xing’an Range(GXAR),which has experienced extensive magmatism.Since the Paleozoic,there are two stages of magmatism in Hua’aobaote orefield occurred in the Paleozoic and Mesozoic.The Mesozoic magmatism is of great significance for the PbZn-Ag Polymetallic mineralization in Hua’aobaote orefield.In this study,new geochemical data was obtained to discuss the timing and petrogenesis of the magmatic rocks and its geodynamic and metallogenic significance.Zircon U-Pb ages reveal that the felsic igneous rocks from the Hua’aobaote orefield were formed in the Early Permian(294.8±3.2 Ma)and Early Cretaceous(132.6±1.4 Ma).Geochemically,the Early Permian granodiorite porphyrite is characterized by high Sr/Y(42-63)ratios and Mg^(#)(62.24-70.74)values and low heavy rare earth element(HREE)(5.09-6.79 ppm)contents.The granodiorite porphyrite is also characterized by depleted Sr-Nd initial isotopic signatures[ε_(Nd)(t)=5.91-7.59,(^(87)Sr/^(86)Sr)i=0.7029-0.7030],exhibiting adakitic characteristics.The Early Cretaceous granite porphyry and rhyolite are A-type felsic igneous rocks,and demonstrate high SiO_(2),Na_(2)O+K_(2)O and rare earth element(REE)contents,low CaO and MgO contents,low(^(87)Sr/^(86)Sr)i ratios(0.7044-0.7058),and positive ε_(Nd)(t)values(2.57-4.65).Whole-rock Pb isotopic compositions in granodiorite porphyrite are:206Pb/204Pb=17.631-18.149,^(207)Pb/^(204)Pb=15.422-15.450,and ^(208)Pb/^(204)Pb=37.325-37.729.The granite porphyry and rhyolite have initial ^(206)Pb/^(204)Pb,^(207)Pb/^(204)Pb,and ^(208)Pb/^(204)Pb ratios of 18.106-19.309,15.489-15.539,and 37.821-38.05,respectively.Sr-Nd-Pb isotopic evidence suggests that the Early Permian granodiorite porphyrite is likely to derive from slab melts and modified by peridotitic mantle wedge in the subduction tectonic setting of the Paleo-Asian Ocean.The Early Cretaceous A-type felsic igneous rocks were derived from juvenile lower crust,accompanied by limited crustal contamination and various degree of fractional crystallisation during magma emplacement.The Early Cretaceous magmatism and related mineralization were formed in a post-orogenic tectonic setting that attributed to the closure of the Mongol-Okhotsk Ocean.Pb isotopic data for the various rock units in the study area indicate that the Mesozoic magma source contributed substantial Pb,Zn,and Ag to the Hua’aobaote deposit.
基金financially supported by the National Natural Science Foundation of China(grant No.41302061)
文摘Rare metal ore reserves are an important strategic resource, and their metallogenic mechanism and mineralization studies have also been received widespread international attention.
基金supported by Key Discipline Construction Projects of Institute of Disaster Prevention (Quaternary Geology)Prospecting Projects of National Important Mineral Concentration Areas of Development Research Center of China Geological Survey (0747-1861SITCN149)
文摘The Southern Great Xing’an Range(SGXR) hosts a number of Early Cretaceous Sn and associated metal deposits, which can be divided into three principal types according to their geological characteristics: skarn type deposits, porphyry type deposits and hydrothermal vein type deposits. Fluid inclusion assemblages of different types of deposits are quite different, which represent the complexities of metallogenic process and formation mechanism. CH4 and CO2 have been detected in fluid inclusions from some of deposits, indicating that the ore-forming fluids are affected by materials of Permian strata. Hydrogen and oxygen isotope data from ore minerals and associated gangue minerals indicate that the initial ore fluids were dominated by magmatic waters, some of which had clearly exchanged oxygen with wall rocks during their passage through the strata. The narrow range for the δ34S values presumably reflects the corresponding uniformity of the ore forming fluids, and these δ34S values have been interpreted to reflect magmatic sources for the sulfur. The comparation between lead isotope ratios of ore minerals and different geological units’ also reveals that deeply seated magma has been a significant source of lead in the ores.
文摘The protection zones or capture zones of springs in desert environments can be hard to identify,but they are critical to spring protection.Most springs fed by regional aquifers are susceptible to contamination and groundwater development.The U.S.Environmental Protection Agency has established hydrogeologic mapping methods to delineate protection zones for springs.However,it is often difficult to determine a regional aquifer system's flow pattern with this technique alone,and the use of these methods is not conducive to efficient groundwater management.Particle tracking analysis using a well-conceptualized and calibrated numerical model for the three-dimensional groundwater flow domain feeding a given group of springs can help facilitate the identification of spring capture zone boundaries.Building upon this basis,a multifaceted approach was developed to define clear boundaries of the capture zones for the springs in the Furnace Creek,Ash Meadows,and the Muddy River areas in the southern Great Basin,USA.Capture zones were first delineated from inverse particle tracking and Hydrologic Unit 12 watersheds.Afterwards,they were adjusted based on water budgets,geology,and hydrologically significant faults.Finally,a geochemical analysis of the groundwater chemistry and isotopic data was conducted to verify the extent of each spring capture zone.This multifaceted approach adds confidence to the new delineations.
基金financial support from the National Natural Science Foundation of China(Grant Nos.41802222 and 42002102)the China Geological Survey Program(Grant Nos.1212011220453,DD20190570,DD20221692,DD20230053 and DD20230355)+1 种基金the Key R&D and Promotion Projects in Henan Province(Grant No.212102310030)the Open Fund of Hubei Key Laboratory of Resources and Eco-Environment Geology(Grant No.KJ2022-35)。
文摘The southern Great Xing'an Range is the most critical Sn-polymetallic metallogenic belt in northeast China.However,the tectonic setting of the Early Cretaceous magmatic-metallogenic”flare-up“event remains uncertain.This paper presents an integrated study on the occurrence,petrology,zircon U-Pb ages,whole-rock geochemistry,and in situ zircon Hf isotopes for Wenduerchagan granites of Xi Ujimqin Banner,central-eastern Inner Mongolia.These granites consist primarily of granite porphyry(with ages of 137±1 Ma and 138±1 Ma)and(porphyritic)alkali feldspar granite(with an age of 141±2 Ma),corresponding to the early Early Cretaceous.They are A-type granites characterized by high silicon,alkali,and TFeO/MgO contents while being depleted of Ba,Nb,Ta,Sr,P,and Ti.They show right-dipping trend rare-earth element distribution characteristics with negative Eu anomalies(Eu/Eu^(*)=0.01-0.20)and weak heavy rare-earth element fractionation((Gd/Yb)_(N)=0.77-2.30).They demonstrate homogeneous zircon Hf isotopic compositions(positiveε_(Hf)(t)values from+5.3 to+7.1 and young two-stage Hf model ages of 851-742 Ma)and high zircon saturation temperatures(av.810℃).These geochemical characteristics indicate that Wenduerchagan granites originated from the partial melting of juvenile crust under high-temperature and low-pressure conditions.Wenduerchagan granites most likely formed in a post-collisional compression-extension transition regime caused by the closure of the Mongol-Okhotsk Ocean,when combined with regional geology.Such a transition regime can probably be attributed to the upwelling of the asthenospheric mantle caused by the break-off of a subducted Mongol-Okhotsk oceanic slab.Upwelling asthenospheric mantle provided sufficient energy and favorable tectonic conditions for magmatism and mineralization of the Early Cretaceous.
基金funded by the National Natural Science Foundation of China(No.41903043)China Postdoctoral Science Foundation(No.2018M642948)Program of China Geological Survey Bureau:1:50000 Regional Geological Survey of Tubuqin,Bayar Tuhushuo,Hadayingzi,Alahada,and Yidanjialaga in Inner Mongolia(No.DD20160048-15)。
文摘Voluminous Early Cretaceous granitoids and associated large-scale ore deposits are distributed within the southern Great Xing'an Range(SGXR),NE China.Based on previously published geochronology and zircon Hf-isotope data,Hf isotope mapping is undertaken to improve our understanding of crustal architecture and its controls on ore deposits.The ore-related Early Cretaceous granitoids were sourced predominantly from juvenile crust,with the involvement of variable proportions of ancient crustal materials.The crustal architecture,as inferred from Hf isotopic contour maps,indicates two distinct Hf isotopic domains in SGXR,including(1)a higher-ε_(Hf)(+7 to+11)juvenile crust containing minor ancient crustal material,and(2)a lower-ε_(Hf)(+2 to+6)juvenile crust containing a greater proportion of ancient crustal materials.The Hf isotopic maps identify links between crustal architecture and regional metallogeny.Copper deposits and other deposits with significant Cu production are restricted mainly to the higher-ε_(Hf)juvenile crustal regions in the northern and eastern SGXR.Deposits dominated by other metals(e.g.,Mo,Sn,W,Pb,Zn,and Ag)occur mainly in the lower-ε_(Hf)juvenile crustal regions in the southern and western SGXR.Interaction between juvenile crust-derived melts and ancient crustal components played an important role on the distribution of various ore metals.