BACKGROUND Intrapancreatic fat deposition(IPFD)exerts a significant negative impact on patients with type 2 diabetes mellitus(T2DM),accelerates disease deterioration,and may lead to impairedβ-cell quality and functio...BACKGROUND Intrapancreatic fat deposition(IPFD)exerts a significant negative impact on patients with type 2 diabetes mellitus(T2DM),accelerates disease deterioration,and may lead to impairedβ-cell quality and function.AIM To investigate the correlation between T2DM remission and IPFD.METHODS We enrolled 80 abdominally obese patients with T2DM admitted to our institution from January 2019 to October 2023,including 40 patients with weight lossinduced T2DM remission(research group)and 40 patients with short-term intensive insulin therapy-induced T2DM remission(control group).We comparatively analyzed improvements in IPFD[differential computed tomography(CT)values of the spleen and pancreas and average CT value of the pancreas];levels of fasting blood glucose(FBG),2-h postprandial blood glucose(2hPBG),and insulin;and homeostasis model assessment of insulin resistance(HOMA-IR)scores.Correlation analysis was performed to explore the association between T2DM remission and IPFD.RESULTS After treatment,the differential CT values of the spleen and pancreas,FBG,2hPBG,and HOMA-IR in the research group were significantly lower than those before treatment and in the control group,and the average CT value of the pancreas and insulin levels were significantly higher.Correlation analysis revealed that the greater the T2DM remission,the lower the amount of IPFD.展开更多
Under deep and complex geological conditions,severe deformation occurs at intersection points of Y-type roadways with large cross sections during engineering projects in coal mines,especially at junction arches.Based ...Under deep and complex geological conditions,severe deformation occurs at intersection points of Y-type roadways with large cross sections during engineering projects in coal mines,especially at junction arches.Based on in-situ investigations and theoretical studies,we have summarized typical forms of destruction and identified high stress and unrestricted support at both sides of junction arch as its main causes.In this study,we also presented double-directional control bolt support technology for a large Y-type span intersection,applied to deep intersection engineering in the Jiahe Coal Mine,which has proved effective.展开更多
This paper deals with the metallogenic model of the sandstone type uranium deposit in the northeastern Ordos Basin from aspects of uranium source, migration and deposition. A superposition metallogenic model has been ...This paper deals with the metallogenic model of the sandstone type uranium deposit in the northeastern Ordos Basin from aspects of uranium source, migration and deposition. A superposition metallogenic model has been established due to complex uranium mineralization processes with superposition of oil-gas reduction and thermal reformation.展开更多
Red clay type gold deposits,located in the south of China,are situated not only in orogenic belts,but also in inner cratons,where climate is tropical-subtropical with clear arid and humid.The lateritic weathering crus...Red clay type gold deposits,located in the south of China,are situated not only in orogenic belts,but also in inner cratons,where climate is tropical-subtropical with clear arid and humid.The lateritic weathering crust often can be divided into five zones,including topsoil,siliceous duricrust zone,multi-color zone(or red clay zone in some deposits),pallid zone and saprolite zone from surface to the base rock,several of which are absent in some deposits.The base rocks are composed mainly of carbonate rocks with minor clastic rocks,intermediate-basic volcanic rocks and intermediate-acid and alkalic intrusions.The orebodies are mainly located in the multi-color zone with part of them in the pallid and saprolite zones.The ore sources include orebodies of Carlin-type gold deposits and porphyry gold deposits,as well as gold-rich base rocks.The red clay type gold deposits experienced early-stage endogenic gold mineralization and laterization during the Tertiary and Quaternary.The areas with endogenic gold deposits,especially Carlin-type gold deposits and porphyry gold deposits in karst depressions on the plateau,structual erosional platforms in the middle-lower mountains,and intermountain basins in southern China are well worth studying to trace red clay type gold deposits.展开更多
The Bulong gold deposit, located in the southwest Tianshan in China, occurs in the Upper Devonian finegrained clastic rocks. The gold orebodies are controlled by an gently inclined interlayer fractured zone. They are ...The Bulong gold deposit, located in the southwest Tianshan in China, occurs in the Upper Devonian finegrained clastic rocks. The gold orebodies are controlled by an gently inclined interlayer fractured zone. They are hosted only in quartz-barite veins though there are barite veins and quartz veins in the ore district. The δ34S values of pyrite in the ores range from 14.6‰ to 19.2‰ and those of barite from 35.0‰ to 39.6‰, indicating that the sulfur was derived from the strata. 3He/4He ratios of fluid inclusions in pyrite are 0.24-0.82 R/Ra, approximating to that of the crust. The 40Ar/39Ar ratios range from 338 to 471, slightly higher than that of the atmosphere. 40Ar /4He ratios of ore fluids range from 0.015 to 0.412 with a mean of 0.153. Helium and argon isotope compositions of fluid inclusions show that the ore fluids of the Bulong gold deposit were mainly derived from the crust.展开更多
Anatase and its allomorphic mineral rutile have the most prominent economic significance among titanium mineral resources and constitute one of the badly needed mineral resources currently in China. The Yantizishan-Mo...Anatase and its allomorphic mineral rutile have the most prominent economic significance among titanium mineral resources and constitute one of the badly needed mineral resources currently in China. The Yantizishan-Moshishan anatase deposit was formerly referred to as an iron deposit. Based on recent investigation and exploration the authors believe that it is actually a large metamorphosed sedimentary anatase-dominated deposit belonging to a new genetic type. Ore bodies occur in stratoid and lenticular forms in Mesoproterozoic (1751 Ma) schist, metasandstone (metasiltstone), and amphibolite. Rich ores have perthitic structure comprising chiefly interbedded quartz perthite (with disseminated anatase and rutile) and anatase perthite. Ore minerals are mainly anatase and subordinately rutile and ilmenite (±hematite), while nonmetallic minerals are chiefly quartz with a certain amount of anthophyllite and biotite (±garnet). The grain sizes of anatase, ruffle and ilmenite are 0.01-0.1 mm. Rich ores contain 3.14% to 15.46% TiO2. averaging 6.91%, while the low-grade ores have TiO2 content about 1.2%to 2.97%, averaging 1.76%. The ores have relatively high TFe and V contents. Trace elements in anatase and rutile such as Nb and Cr were analyzed by the electron microprobe. According to their relatively low Nb and Cr contents, source anatase and rutile must have come from meta-mafic rocks. Trace elements of the associated ilmenite show relatively high MnO and low MgO contents, just in contrast to those of ilmenite in V-Ti-magnetite ores of magmatic origin. The protoliths of amphibolite wall rocks should be basalt and picrite-basalt. Pertochemical data suggest that the tectonic setting of these rocks belongs to an island arc or a transitional belt between the island arc and oceanic ridge. Silicon isotope study shows that δ30Si values of different anatase ores, quartzite, and schist in this deposit are 0.1‰ to -0.9‰, similar to those of marine hydrothermal exhalative sedimentary deposits. All of these geological and geochemical characteristics of the ore deposit suggest that the anatase ores and amphibolite are products of submarine basic volcanism. The ores had chemical precipitation features, but were later subjected to regional intermediate (or somewhat lower) grade metamorphism (1158 Ma). Rutile was formed mainly in the process of this metamorphism. The ore belt locally underwent hydrothermal modification during the emplacement of Late Yanshanian granite (118 Ma).展开更多
The Tongling ore district is one of the most economically important ore areas in the Middle–Lower Yangtze River Metallogenic Belt, eastern China. It contains hundreds of polymetallic copper–gold deposits and occurre...The Tongling ore district is one of the most economically important ore areas in the Middle–Lower Yangtze River Metallogenic Belt, eastern China. It contains hundreds of polymetallic copper–gold deposits and occurrences. Those deposits are mainly clustered(from west to east) within the Tongguanshan, Shizishan, Xinqiao, Fenghuangshan, and Shatanjiao orefields. Until recently, the majority of these deposits were thought to be skarn-or porphyry–skarn-type deposits; however there have been recent discoveries of numerous vein-type Au, Ag, and Pb-Zn deposits that do not fall into either of these categories. This indicates that there is some uncertainty over this classification. Here, we present the results of several systematic geological studies of representative deposits in the Tongling ore district. From investigation of the ore-controlling structures, lithology of the host rock, mineral assemblages, and the characteristics of the mineralization and alteration within these deposits, three genetic types of deposits(skarn-, porphyry-, and vein-type deposits) have been identified. The spatial and temporal relationships between the orebodies and Yanshanian intrusions combined with the sources of the ore-forming fluids and metals, as well as the geodynamic setting of this ore district, indicate that all three deposit types are genetically related each other and constitute a magmatic–hydrothermal system. This study outlines a model that relates the polymetallic copper–gold porphyry-, skarn-, and vein-type deposits within the Tongling ore district. This model provides a theoretical basis to guide exploration for deep-seated and concealed porphyry-type Cu(–Mo, –Au) deposits as well as shallow vein-type Au, Ag, and Pb–Zn deposits in this area and elsewhere.展开更多
The Puziwan gold deposit is a special linear cryptoexplosive breccia type deposit found in northeastern Shanxi, China, in recent years. The deposit is located in a secondary metallogenic belt of the most famous Au-Ag ...The Puziwan gold deposit is a special linear cryptoexplosive breccia type deposit found in northeastern Shanxi, China, in recent years. The deposit is located in a secondary metallogenic belt of the most famous Au-Ag polymetallic metallogenic belt along the north margin of the North China platform. The secondary metallogenic belt is a synmagmatic tension-shear fault-fracture belt of ENE linear trend. The Indosinian cryptoexplosive breccia body, quartz monzonitic porphyry (beschtauite breccia), quartz monzonite (243.7 Ma, K-Ar), Yanshanian granite-porphyry (105±6 Ma, Rb-Sr) and orebodies mostly occur as dykes or veins and short lenses along the structural fracture belt. The orebodies are emplaced in the fractured cryptoexplosive breccia body in the tectonomagmatic belt and their attitude is consistent with that of the breccia body. The orebodies have two types: one is shallow-seated thick and big ones, which are short-lenticular in plan and wedge-shaped in cross section, shallow buried, large in size and high-grade; the other is lean orebodies, which occur as parallel veins at depths. The ores are mainly of Au-Ag polymetallic sulphide-rich breccia type. Pyrite (limonite) is the dominant metallic mineral, with subordinate chal-copyrite, galena, sphalerite, tenantite, native gold, electrum, native silver and argentite. The gangue minerals consist mainly of quartz and plagioclase, with subordinate carbonate minerals, alunite chalcedony and kaolin. Kaolinization is the characteristic alteration type. Sulphide minerals contain abundant trace minerals such as Cu, Pb, Ag, Sb and Hg, while in the ores Ag, Cu, Pb, Zn, As and Sb are the best indicator element assemblage of Au. The δ34S(%o) values of the ores rane from ?3.2%o to 5.3%o, with average ?0.102%o. The δO H2O(%o) and δ(%o) values are in the ranges from ?3.1%o to 7.73%o and from ?64%o to ?90%o respectively. The Pb isotopic compositions of the rocks and ores in this region indicate that Pb comes from three tectonic sources—upper mantle, lower crust and orogenic belt. The inclusion homogenization temperature are in the ranges of 110 to 220°C and 230 to 310°C, which suggests that the deposit formed under meso-epithermal conditions. The ore-forming pressures range from 6 to 32 MPa and the depths are 230 to 1200 m. In view of the above, the Puziwan gold deposit is genetically ascribed to a high-sulphur (alunite-kaolin) meso-epithermal gold deposit related to subvolcanic rocks. This gold deposit formed during the Indosinian stage (245.9±0.3 Ma) and then was influenced by a thermal event in the Yanshanian stage (142.9±0.5 Ma).展开更多
Objective A set of REE-rich clay rocks is formed at the top of the Emeishan basalt in the eastern Yunnan-Western Guizhou area,accompanied by Nb,Zr,Ga.It is a new type of REE deposit and has great resource potential.Th...Objective A set of REE-rich clay rocks is formed at the top of the Emeishan basalt in the eastern Yunnan-Western Guizhou area,accompanied by Nb,Zr,Ga.It is a new type of REE deposit and has great resource potential.This paper introduces its metallogenic conditions and element occurrence states,discusses the genetic mechanism.展开更多
Since 2011,certain advances have been made through the resource investigation,metallogenesis research,mining supervision and environmental protection of ion-adsorption type rare earth element (REE) deposit in South Ch...Since 2011,certain advances have been made through the resource investigation,metallogenesis research,mining supervision and environmental protection of ion-adsorption type rare earth element (REE) deposit in South China.Firstly,some progress has been made in REE prospecting in Jiangxi,Guangdong,Guangxi and Yunnan.REE deposits are not only found within the weathering crusts of granites and felsic volcanic rocks,but also within the weathering crusts of epimetamorphic rocks and basic magmatic rocks.Secondly,the methods of exploration,delineating ore bodies and calculation of reserves have been improved,which intuitively reflect the thickness,REE composition and value of weathering crust.Thirdly,the relationship between REEs and weathering degree and the rule of distribution,migration and enrichment of REEs in the weathering profile was summarized through the analysis of big data,which can predict the metallogenetic horizon of REEs.Fourthly,a method for quick,accurate and dynamic investigation of the REE deposit has been established by using high resolution remote sensing technology.Finally,the relation between the production status of REE mines and water pollution has been revealed based on long-term hydrochemical monitoring data of rivers and wells in mines and surrounding areas.展开更多
The central Zhuguang Mountains in Hunan Province is located at the junction of the three provinces,namely Hunan,Jiangxi,and Guangdong,where the famous Lujing uranium ore field lies.The uranium deposits occurring in th...The central Zhuguang Mountains in Hunan Province is located at the junction of the three provinces,namely Hunan,Jiangxi,and Guangdong,where the famous Lujing uranium ore field lies.The uranium deposits occurring in this area are all granite-related and they can be divided into three types,namely endogranitic ones,perigranitic ones,and contact zone types.The endogranitic uranium deposits are mainly controlled by the structural alteration zones developing within granites,with fragmentation,hematitization,and alkali metasomatism as their main mineralization characteristics.The perigranitic uranium deposits are mainly produced in the carbonaceous,siliceous,and argillaceous composite layers of epimetamorphic rocks and are controlled by fractured zones formed due to interlayer compression.The contact zone type uranium deposits mainly occur in the contact parts between the granites and favorable horizons.They have developed in favorable sections where multiple sets of structures are combined and intersected.The main metallogenic regularities of uranium in the central Zhuguang Mountains are as follows.The basic conditions for the uranium mineralization in this area include the framework consisting of regional deep large faults and their associated multi-set multi-direction favorable metallogenic structures,multi-cycle and multi-stage uranium-rich rock masses,and uranium-rich folded basement.Meanwhile,the uranium deposits in this area are closely related to granites in terms of genesis and space and they are formed in different structural parts subject to the same metallization.Furthermore,based on the summary of the characteristics and regularities of uranium mineralization in this area,the controlling factors of different types of uranium deposits in the area were explored and six metallogenic target areas were predicted.All these will provide references for the exploration of uranium deposits in this area.展开更多
1 Introduction Sareke glutenite-type copper deposit is located in the Sarekebayi basin,a sub-basin of southwest margin of the Tuoyun Mesozoic hinterland basin in the northwestern part of the Tarim Basin.The Tuoyun Mes...1 Introduction Sareke glutenite-type copper deposit is located in the Sarekebayi basin,a sub-basin of southwest margin of the Tuoyun Mesozoic hinterland basin in the northwestern part of the Tarim Basin.The Tuoyun Mesozoic hinterland展开更多
The carbonaceous-siliceous-argillitic rock type uranium deposit in the Zoige area is located in the northeastern margin of the Tibetan Plateau, and has gained much attention of many geologists and ore deposit experts ...The carbonaceous-siliceous-argillitic rock type uranium deposit in the Zoige area is located in the northeastern margin of the Tibetan Plateau, and has gained much attention of many geologists and ore deposit experts due to its scale, high grade and abundant associated ores. Because of the insufficient reliable dating of intrusive rocks, the relationship between mineralization and the magmatic activities is still unknown. In order to study this key scientific issue and the ore-forming processes of the Zoige uranium ore field, the LA-ICP-MS zircon U-Pb dating of magmatic rocks was obtained:64.08±0.59 Ma for the granite-prophyry and ~200 Ma for the dolerite. U-Pb dating results of uraninite from the Zoige uranium ore field are mainly concentrated on ~90 Ma and ~60 Ma. According to LA-ICP-MS U-Pb zircon dating, the ages for the dolerite, porphyry granite and granodiorite are 200 Ma, 64.08 Ma approximately and 226.5-200.88 Ma, respectively. This indicates that the mineralization has close relationship with activities of the intermediate-acidic magma. The ages of the granite porphyry are consistent with those uraninite U-Pb dating results achieved by previous studies, which reflects the magmatic and ore-forming event during the later Yanshanian. Based on the data from previous researches, the ore bodies in the Zoige uranium ore field can be divided into two categories:the single uranium type and the uranium with polymetal mineralization type. The former formed at late Cretaceous(about 90 Ma), while the latter, closely related to the granite porphyry, formed at early Paleogene(about 60 Ma). And apart from ore forming elemental uranium, the latter is often associated with polymetallic elements, such as molybdenum, nickel, zinc, etc.展开更多
Based upon a comprehensive study of 123 copper deposits in China. this paper reaches the following conclusions: 1. The crust in China was solidified pretty late; with the accretion of the plate, the copper mineralizat...Based upon a comprehensive study of 123 copper deposits in China. this paper reaches the following conclusions: 1. The crust in China was solidified pretty late; with the accretion of the plate, the copper mineralization moved towards its margin in space and became successively younger in age. 2. The major copper ore types ever found in the world have mostly been discovered in China, in which the porphyry type seems to be the most important and the massive sulfide type in the transitional bed between marine clastic and carbonate rocks is clearly defined. 3. Carbonate strata are widespread in China and their deposition lasted for a long geological period, so the proportion of copper deposits occurring in them is large as compared with other parts of the world. 4. Seven metallogenic epochs can be recognized, in which the Mesozoic one plays the leading role and the middle(late) Palaeozoic and Cenozoic ones are next in importance. Mineralization was comparatively simple in the early geological period. and became diversified later on. In the early epochs copper deposits related to basaltic magmatism and metamorphosed marine sediments predominated, whereas in the later epochs those related to granitic magmatism and continental sedimentation were dominant. 5. There exist in China thirteen metallogenic provinces, of which the Lower Yangtze downwarping belt, Sanjiang fold system, Jiangnan axis and Xikang-Yunnan axis are of greater significance. 6. The crustal mobility in China was rather pronounced, the polycyclic evolution of the crust has resulted in such obvious phenomena as the inheritance of mineralization, the coexistence of various types and the superposition of different genetic types.展开更多
The U-Th-REE-Nb(Ta)-polymetallic mineralization is generally related to either the silica-undersaturated syenites,the silica-oversaturated alkaline/peralkaline granites or igneous carbonatites.In this study,the author...The U-Th-REE-Nb(Ta)-polymetallic mineralization is generally related to either the silica-undersaturated syenites,the silica-oversaturated alkaline/peralkaline granites or igneous carbonatites.In this study,the authors report a new mineralization type,which is related to the magmatic-hydrothermal albitite(with mineral assemblage predominated by albite with volume content>90%),as exemplified by the Chachaxiangka deposit in Qinghai Province of China.The Chachaxiangka deposit is the first albititerelated U-Th-REE-Nb deposit recognized in China and the mineralization can be divided into 3 types:the vein-type,the disseminated veinlet type and breccia type,of which the former 2 are predominant.Three mineralization stages can be identified according to the detailed mineralogical analyses,including the magmatic stage,main hydrothermal mineralization stage and post-ore stage.By comprehensive analyses of the mineralogical,major and trace element compositions,the authors suggest that the albitite vein is magmatic-hydrothermal in origin and both the magmatic evolution and overprint of the hydrothermal fluids play important roles in the formation of the albitite and related polymetallic mineralization.Phase separation between the silicate melt and carbonate/phosphate melt might take place in the magmatic stage,yet the immiscibility between the silicate melt and chloride-dominated fluids is the most important mechanism for the REE mineralization and also causes the Nb-Th re-mobilization and enrichment.The red color of the albitite aplite vein is an eye-catching prospecting mark in the field and more mineralization can be expected at depth and in the surrounding areas.The discovery of the new albitite type U-Th-REENb mineralization give rise to new ideas during future U-Th-REE-Nb exploration,not only in the Qaidam-Altun belt,but also other areas across China.展开更多
Objective The Yubei area is located in the mid-east Maigaiti slope of southwestern Tarim Basin, China, with an exploration history of several years. Recent exploration has preliminarily indicated that the Ordovician ...Objective The Yubei area is located in the mid-east Maigaiti slope of southwestern Tarim Basin, China, with an exploration history of several years. Recent exploration has preliminarily indicated that the Ordovician carbonate formations in this area have some oil and gas potential. Carbonate microfacies provides material basis for reservoir development, seal formation and hydrocarbon generation. Therefore, this work utilized the standard microfacies (SMF) types to study the microfacies of the Ordovician formations in the Yubei area in order to provide theoretical basis for the next exploration.展开更多
Several Au deposits in Guizhou Province,southwest China,described as being similar to the highly productive Carlin-type gold deposits in northern Nevada.USA,were examined to identify similarities and differences betwe...Several Au deposits in Guizhou Province,southwest China,described as being similar to the highly productive Carlin-type gold deposits in northern Nevada.USA,were examined to identify similarities and differences between the two districts.Samples were collected along transects from lowto high-grade rock,where possible,and fram stockpiles at the Shuiyindong,Zimudang,Taipingdong,Yata and Jinfeng(formerly Lannigou)deposits.Methods used to examine ore and alteration minerals included hand-sample description:reflectance spectroscopy using an ASD Terraspec spectrometer;analyses of hand samples by carbonate staining with Alizaren red and potassium ferricyanide;transmitted and reflected light petrography;chemical analyses,mineral identification,and imaging using a JEOL.JSM-5610 scanning electron microscope:and quantitative chemical analyses using a JEOL JXA-8900 electron probe microanalyzer.Geochemical analyses of hand samples for 52 elements were done by ALS Chemex.Results indicate both similarities and differences between the two districts.Both districts have similar geologic histories.and deposits at both locations appear to have formed as a result of similar tectonic events.though the district in southwest China lacks evidence of eoeval felsic igneous activity;however,the ore-stage minerals and the fluids that produced the minerals and deposits have some significant differences.The Nevada deposits were dominated by fluid-rock reaction in which host rock Fe was sulfidized to form Au-bearing pyrite.Although ore fluids sulfidized host rock Fe in the Cuizhou deposits.the timing of Fe metasomatism is unknown,so whether the deposits formed in response to sulfidation or pyritization is unclear.Fluid-rock reaction between an acidic,aqueous fluid and highly reactive calcareous rocks in Nevada caused extensive decarbonatization of host rocks,jasperoid replacemerit of carbonate minerals,and alteration of silty rock components to illite and kaolinite.In Guizhou,CO2-bearing ore fluids with temperatures and pressures approaching 100℃ and 500 bars greater than temperatures and pressures detemained for ore fluids in the Nevada deposits,deposited Aubearing pyrite.In examined Guizhou deposits these fluids carbonatized host rocks and farmed both replacement and open-space-filling ore.The fluids,which may have been immiscible,were sufficiently overpressured to fracture wall rocks and to create significant open space filled by vein quartz.While deposit architecture,tectonic setting,and host rocks in Guizhou are quite similar to northern Nevada,ore and alteration minerals suggest that ore-forming processes in examined Guizhou deposits have important similarities to processes associated with formation of orogenic Au systems.The Guizhou deposits display characteristics of both Carlin-type and orogenic systems,perhaps indicating formation at conditions somewhat intermediate to conditions for Carlin-type deposits and orogenic systems.展开更多
The Shuiyindong gold deposit is one of the most famous and largest Carlin-type gold deposits in China and is located in southwest Guizhou, in the eastern part of the Huijiabao anticline. The Shuiyindong's gold min...The Shuiyindong gold deposit is one of the most famous and largest Carlin-type gold deposits in China and is located in southwest Guizhou, in the eastern part of the Huijiabao anticline. The Shuiyindong's gold mineralization occurred in bioclastic limestone of the Permian Longtan Formation. Sulfur, carbon, hydrogen, oxygen, and lead isotopic compositions are reported in this paper. The properties and sources of ore-forming fluid have been discussed and a metallogenic model for the Shuiyindong gold deposit has been proposed. The d34 S values of stibnite, realgar, orpiment, pyrite from orebodies, and pyrite from quartz veins are similar to or slightly higher than the d34 S values of mantle sulfur. It is suggested that the sulfur of hydrothermal sulfides was likely of magmatic origin with minor heavy sulfur contributed from the country rocks. The measured d D values and calculated d18OH2 O values of inclusion fluid in quartz plotted within or below a magmatic hydrothermal fluid field far from the meteoric water line. This indicates that the ore-forming fluid for the main-stage gold mineralization could have been derived mainly from a magmatic source and mixed with a small amount of meteoric water. The carbon and oxygen isotopic compositions of calcites in the d18 O vs. d13 C diagram suggest that the CO2 in ore-forming fluid was derived from dissolution of bioclastic limestone and oxidation of sedimentary organic carbon in limestone. However, the d13 C values of ore-related calcites, which contain intergrown realgar and/or orpiment, are similar to those of mantle carbon. Although no igneous intrusive rock has been observed in the vicinity of the gold deposits, the possibility of mantle fluid integrated into the ore-forming fluid cannot be eliminated based on the d13 C values of ore-related calcites. The lead isotopes of sulfides are distributed near the growth curves of upper crust and orogenic belt in the plumbotectonic diagram. Their calculated Dc and Db values plotted within the magmatism field of crust-mantle subduction zone in the Dc- Db diagram. This suggests that the lead of sulfides has an intimate connection with magmatism. Our S, H, O, C, and Pb isotopic studies for the Shuiyindong Carlin-type gold deposit in Guizhou manifest a concordant possibility that the ore-forming fluid was mainly derived from magmatic fluid with minor contribution from the surrounding strata. With the integration of comprehensive geology and isotopic geochemistry, we have proposed a magmatic hydrothermal model for the origin of the Shuiyindong gold deposit.展开更多
Geochemical studies of the Paiting and Miaolong Carlin-type gold deposits in the Sandu-Danzhai metal-logenic zone,Guizhou Province,have shown that the mineralized-altered rocks show LREE-enrichment patterns,generally ...Geochemical studies of the Paiting and Miaolong Carlin-type gold deposits in the Sandu-Danzhai metal-logenic zone,Guizhou Province,have shown that the mineralized-altered rocks show LREE-enrichment patterns,generally displaying negative Eu anomalies(δEu=0.51?0.97) and unobvious negative Ce anomalies(δCe=0.86?0.99).Calcite and fluorite in relation with metallogenesis show MREE-enrichment patterns,generally displaying rather weak negative Eu anomalies(δEu=0.74?0.93) and weak negative Ce(δCe=0.70?0.98) anomalies.The δ13CPDB values of carbon in calcite are-1.61‰?-5.82‰,the δ18OSMOW values of oxygen are 13.97‰?19.24‰,and the δ34SCDT values of sulfur in stibnite are 17.72‰?21.68‰.In regard to δD and δ18O,ore-forming fluids pos-sess the characteristics of metamorphic water.The process of metallogenesis of the Carlin-type gold deposits is con-trolled by the Yanshanian tectonic activities.The Yanshanian movement promoted the migration and mobilization of metamorphic fluids in the extensively developed medium-to high-grade metamorphic rocks in this region,carrying primarily enriched gold and associated elements such as Hg,As,and Sb in the Sinian metamorphosed black shales and Lower Cambrian black shales.The ore-forming fluids found their way into a suitable metallogenic environment along the fault zone,followed by gold precipitation to form gold deposits.展开更多
1 Introduction The Laurani porphyry deposit is located in the Altiplano,an extensive North-South trending structural basin that formed in Central-Andean metallogenic belt,Bolivia.The Altiplano poly-metallic province c...1 Introduction The Laurani porphyry deposit is located in the Altiplano,an extensive North-South trending structural basin that formed in Central-Andean metallogenic belt,Bolivia.The Altiplano poly-metallic province contains sub-volcanic ore展开更多
基金Kunming University of Science and Technology Joint School Medicine Project,No.KUST-WS2022002Zthe Ethic Committee of Wenshan Hospital,Kunming University of Science and Technology(Approval No.WYLS2022005).
文摘BACKGROUND Intrapancreatic fat deposition(IPFD)exerts a significant negative impact on patients with type 2 diabetes mellitus(T2DM),accelerates disease deterioration,and may lead to impairedβ-cell quality and function.AIM To investigate the correlation between T2DM remission and IPFD.METHODS We enrolled 80 abdominally obese patients with T2DM admitted to our institution from January 2019 to October 2023,including 40 patients with weight lossinduced T2DM remission(research group)and 40 patients with short-term intensive insulin therapy-induced T2DM remission(control group).We comparatively analyzed improvements in IPFD[differential computed tomography(CT)values of the spleen and pancreas and average CT value of the pancreas];levels of fasting blood glucose(FBG),2-h postprandial blood glucose(2hPBG),and insulin;and homeostasis model assessment of insulin resistance(HOMA-IR)scores.Correlation analysis was performed to explore the association between T2DM remission and IPFD.RESULTS After treatment,the differential CT values of the spleen and pancreas,FBG,2hPBG,and HOMA-IR in the research group were significantly lower than those before treatment and in the control group,and the average CT value of the pancreas and insulin levels were significantly higher.Correlation analysis revealed that the greater the T2DM remission,the lower the amount of IPFD.
基金supported by the National Basic Research Program of China (No.2006CB202200)the Major Program of the National Natural Science Foundation of China (No.50490270)the Innovative Team Development Project of the Ministry of Education of China (No.IRT0656)
文摘Under deep and complex geological conditions,severe deformation occurs at intersection points of Y-type roadways with large cross sections during engineering projects in coal mines,especially at junction arches.Based on in-situ investigations and theoretical studies,we have summarized typical forms of destruction and identified high stress and unrestricted support at both sides of junction arch as its main causes.In this study,we also presented double-directional control bolt support technology for a large Y-type span intersection,applied to deep intersection engineering in the Jiahe Coal Mine,which has proved effective.
文摘This paper deals with the metallogenic model of the sandstone type uranium deposit in the northeastern Ordos Basin from aspects of uranium source, migration and deposition. A superposition metallogenic model has been established due to complex uranium mineralization processes with superposition of oil-gas reduction and thermal reformation.
基金supported by the National Basic Research Program of China(973 Program)(No. 2009CB421008)111 Project(No.B07011)Program for Changjiang Scholars and Innovative Research Team in University(PCSIRT)
文摘Red clay type gold deposits,located in the south of China,are situated not only in orogenic belts,but also in inner cratons,where climate is tropical-subtropical with clear arid and humid.The lateritic weathering crust often can be divided into five zones,including topsoil,siliceous duricrust zone,multi-color zone(or red clay zone in some deposits),pallid zone and saprolite zone from surface to the base rock,several of which are absent in some deposits.The base rocks are composed mainly of carbonate rocks with minor clastic rocks,intermediate-basic volcanic rocks and intermediate-acid and alkalic intrusions.The orebodies are mainly located in the multi-color zone with part of them in the pallid and saprolite zones.The ore sources include orebodies of Carlin-type gold deposits and porphyry gold deposits,as well as gold-rich base rocks.The red clay type gold deposits experienced early-stage endogenic gold mineralization and laterization during the Tertiary and Quaternary.The areas with endogenic gold deposits,especially Carlin-type gold deposits and porphyry gold deposits in karst depressions on the plateau,structual erosional platforms in the middle-lower mountains,and intermountain basins in southern China are well worth studying to trace red clay type gold deposits.
基金the Ministry of Science and Technology of China(grants G 2001CB 409807,G 1999043216).
文摘The Bulong gold deposit, located in the southwest Tianshan in China, occurs in the Upper Devonian finegrained clastic rocks. The gold orebodies are controlled by an gently inclined interlayer fractured zone. They are hosted only in quartz-barite veins though there are barite veins and quartz veins in the ore district. The δ34S values of pyrite in the ores range from 14.6‰ to 19.2‰ and those of barite from 35.0‰ to 39.6‰, indicating that the sulfur was derived from the strata. 3He/4He ratios of fluid inclusions in pyrite are 0.24-0.82 R/Ra, approximating to that of the crust. The 40Ar/39Ar ratios range from 338 to 471, slightly higher than that of the atmosphere. 40Ar /4He ratios of ore fluids range from 0.015 to 0.412 with a mean of 0.153. Helium and argon isotope compositions of fluid inclusions show that the ore fluids of the Bulong gold deposit were mainly derived from the crust.
基金the National Natural Science Foundation of China(Grant 40773038)Geological Exploration Project Office of Inner Mongolia (05-1-TK01)the Institute of Mineral Resources, Chinese Academy of Geological Sciences(K0714)
文摘Anatase and its allomorphic mineral rutile have the most prominent economic significance among titanium mineral resources and constitute one of the badly needed mineral resources currently in China. The Yantizishan-Moshishan anatase deposit was formerly referred to as an iron deposit. Based on recent investigation and exploration the authors believe that it is actually a large metamorphosed sedimentary anatase-dominated deposit belonging to a new genetic type. Ore bodies occur in stratoid and lenticular forms in Mesoproterozoic (1751 Ma) schist, metasandstone (metasiltstone), and amphibolite. Rich ores have perthitic structure comprising chiefly interbedded quartz perthite (with disseminated anatase and rutile) and anatase perthite. Ore minerals are mainly anatase and subordinately rutile and ilmenite (±hematite), while nonmetallic minerals are chiefly quartz with a certain amount of anthophyllite and biotite (±garnet). The grain sizes of anatase, ruffle and ilmenite are 0.01-0.1 mm. Rich ores contain 3.14% to 15.46% TiO2. averaging 6.91%, while the low-grade ores have TiO2 content about 1.2%to 2.97%, averaging 1.76%. The ores have relatively high TFe and V contents. Trace elements in anatase and rutile such as Nb and Cr were analyzed by the electron microprobe. According to their relatively low Nb and Cr contents, source anatase and rutile must have come from meta-mafic rocks. Trace elements of the associated ilmenite show relatively high MnO and low MgO contents, just in contrast to those of ilmenite in V-Ti-magnetite ores of magmatic origin. The protoliths of amphibolite wall rocks should be basalt and picrite-basalt. Pertochemical data suggest that the tectonic setting of these rocks belongs to an island arc or a transitional belt between the island arc and oceanic ridge. Silicon isotope study shows that δ30Si values of different anatase ores, quartzite, and schist in this deposit are 0.1‰ to -0.9‰, similar to those of marine hydrothermal exhalative sedimentary deposits. All of these geological and geochemical characteristics of the ore deposit suggest that the anatase ores and amphibolite are products of submarine basic volcanism. The ores had chemical precipitation features, but were later subjected to regional intermediate (or somewhat lower) grade metamorphism (1158 Ma). Rutile was formed mainly in the process of this metamorphism. The ore belt locally underwent hydrothermal modification during the emplacement of Late Yanshanian granite (118 Ma).
基金funded by the National Natural Science Foundation of China(NSFC)(grant numbers 41472066,40972063 and 41672038)the Program of the Deep Exploration in China(SinoProb-03-05)+1 种基金the National KeyR&S Program of China(2016 YFC0600209)the Land and Resources Science and Techonolgy Foundation of Anhui Province(2016-K-03 and No.2014-K-03)
文摘The Tongling ore district is one of the most economically important ore areas in the Middle–Lower Yangtze River Metallogenic Belt, eastern China. It contains hundreds of polymetallic copper–gold deposits and occurrences. Those deposits are mainly clustered(from west to east) within the Tongguanshan, Shizishan, Xinqiao, Fenghuangshan, and Shatanjiao orefields. Until recently, the majority of these deposits were thought to be skarn-or porphyry–skarn-type deposits; however there have been recent discoveries of numerous vein-type Au, Ag, and Pb-Zn deposits that do not fall into either of these categories. This indicates that there is some uncertainty over this classification. Here, we present the results of several systematic geological studies of representative deposits in the Tongling ore district. From investigation of the ore-controlling structures, lithology of the host rock, mineral assemblages, and the characteristics of the mineralization and alteration within these deposits, three genetic types of deposits(skarn-, porphyry-, and vein-type deposits) have been identified. The spatial and temporal relationships between the orebodies and Yanshanian intrusions combined with the sources of the ore-forming fluids and metals, as well as the geodynamic setting of this ore district, indicate that all three deposit types are genetically related each other and constitute a magmatic–hydrothermal system. This study outlines a model that relates the polymetallic copper–gold porphyry-, skarn-, and vein-type deposits within the Tongling ore district. This model provides a theoretical basis to guide exploration for deep-seated and concealed porphyry-type Cu(–Mo, –Au) deposits as well as shallow vein-type Au, Ag, and Pb–Zn deposits in this area and elsewhere.
文摘The Puziwan gold deposit is a special linear cryptoexplosive breccia type deposit found in northeastern Shanxi, China, in recent years. The deposit is located in a secondary metallogenic belt of the most famous Au-Ag polymetallic metallogenic belt along the north margin of the North China platform. The secondary metallogenic belt is a synmagmatic tension-shear fault-fracture belt of ENE linear trend. The Indosinian cryptoexplosive breccia body, quartz monzonitic porphyry (beschtauite breccia), quartz monzonite (243.7 Ma, K-Ar), Yanshanian granite-porphyry (105±6 Ma, Rb-Sr) and orebodies mostly occur as dykes or veins and short lenses along the structural fracture belt. The orebodies are emplaced in the fractured cryptoexplosive breccia body in the tectonomagmatic belt and their attitude is consistent with that of the breccia body. The orebodies have two types: one is shallow-seated thick and big ones, which are short-lenticular in plan and wedge-shaped in cross section, shallow buried, large in size and high-grade; the other is lean orebodies, which occur as parallel veins at depths. The ores are mainly of Au-Ag polymetallic sulphide-rich breccia type. Pyrite (limonite) is the dominant metallic mineral, with subordinate chal-copyrite, galena, sphalerite, tenantite, native gold, electrum, native silver and argentite. The gangue minerals consist mainly of quartz and plagioclase, with subordinate carbonate minerals, alunite chalcedony and kaolin. Kaolinization is the characteristic alteration type. Sulphide minerals contain abundant trace minerals such as Cu, Pb, Ag, Sb and Hg, while in the ores Ag, Cu, Pb, Zn, As and Sb are the best indicator element assemblage of Au. The δ34S(%o) values of the ores rane from ?3.2%o to 5.3%o, with average ?0.102%o. The δO H2O(%o) and δ(%o) values are in the ranges from ?3.1%o to 7.73%o and from ?64%o to ?90%o respectively. The Pb isotopic compositions of the rocks and ores in this region indicate that Pb comes from three tectonic sources—upper mantle, lower crust and orogenic belt. The inclusion homogenization temperature are in the ranges of 110 to 220°C and 230 to 310°C, which suggests that the deposit formed under meso-epithermal conditions. The ore-forming pressures range from 6 to 32 MPa and the depths are 230 to 1200 m. In view of the above, the Puziwan gold deposit is genetically ascribed to a high-sulphur (alunite-kaolin) meso-epithermal gold deposit related to subvolcanic rocks. This gold deposit formed during the Indosinian stage (245.9±0.3 Ma) and then was influenced by a thermal event in the Yanshanian stage (142.9±0.5 Ma).
基金supported by the National Natural Science Foundation of China(grant No.41602120)CGS Geological survey project(grant No.DD20189507).
文摘Objective A set of REE-rich clay rocks is formed at the top of the Emeishan basalt in the eastern Yunnan-Western Guizhou area,accompanied by Nb,Zr,Ga.It is a new type of REE deposit and has great resource potential.This paper introduces its metallogenic conditions and element occurrence states,discusses the genetic mechanism.
文摘Since 2011,certain advances have been made through the resource investigation,metallogenesis research,mining supervision and environmental protection of ion-adsorption type rare earth element (REE) deposit in South China.Firstly,some progress has been made in REE prospecting in Jiangxi,Guangdong,Guangxi and Yunnan.REE deposits are not only found within the weathering crusts of granites and felsic volcanic rocks,but also within the weathering crusts of epimetamorphic rocks and basic magmatic rocks.Secondly,the methods of exploration,delineating ore bodies and calculation of reserves have been improved,which intuitively reflect the thickness,REE composition and value of weathering crust.Thirdly,the relationship between REEs and weathering degree and the rule of distribution,migration and enrichment of REEs in the weathering profile was summarized through the analysis of big data,which can predict the metallogenetic horizon of REEs.Fourthly,a method for quick,accurate and dynamic investigation of the REE deposit has been established by using high resolution remote sensing technology.Finally,the relation between the production status of REE mines and water pollution has been revealed based on long-term hydrochemical monitoring data of rivers and wells in mines and surrounding areas.
基金funded by the project titled Prospect Survey and Exploration Demonstration of Hardrock Mineral Resources such as Uranium and Thorium(12120115014101)initiated by the Tianjin Center of China Geological Survey.The data and achievements cited in this paper are mainly from relevant scientific research,geological survey,and mineral exploration projects undertaken by the No.302 Brigade of Hunan Nuclear Industry Geology Bureau in recent years.
文摘The central Zhuguang Mountains in Hunan Province is located at the junction of the three provinces,namely Hunan,Jiangxi,and Guangdong,where the famous Lujing uranium ore field lies.The uranium deposits occurring in this area are all granite-related and they can be divided into three types,namely endogranitic ones,perigranitic ones,and contact zone types.The endogranitic uranium deposits are mainly controlled by the structural alteration zones developing within granites,with fragmentation,hematitization,and alkali metasomatism as their main mineralization characteristics.The perigranitic uranium deposits are mainly produced in the carbonaceous,siliceous,and argillaceous composite layers of epimetamorphic rocks and are controlled by fractured zones formed due to interlayer compression.The contact zone type uranium deposits mainly occur in the contact parts between the granites and favorable horizons.They have developed in favorable sections where multiple sets of structures are combined and intersected.The main metallogenic regularities of uranium in the central Zhuguang Mountains are as follows.The basic conditions for the uranium mineralization in this area include the framework consisting of regional deep large faults and their associated multi-set multi-direction favorable metallogenic structures,multi-cycle and multi-stage uranium-rich rock masses,and uranium-rich folded basement.Meanwhile,the uranium deposits in this area are closely related to granites in terms of genesis and space and they are formed in different structural parts subject to the same metallization.Furthermore,based on the summary of the characteristics and regularities of uranium mineralization in this area,the controlling factors of different types of uranium deposits in the area were explored and six metallogenic target areas were predicted.All these will provide references for the exploration of uranium deposits in this area.
基金financial support by The Ministry of Land and Resources Public Welfare Industry Scientific Research Special Project (201511016-1)China Geological Survey Geological Survey Project (12120114081501)
文摘1 Introduction Sareke glutenite-type copper deposit is located in the Sarekebayi basin,a sub-basin of southwest margin of the Tuoyun Mesozoic hinterland basin in the northwestern part of the Tarim Basin.The Tuoyun Mesozoic hinterland
基金supported financially by the National Natural Scientific Foundation of China (Grants No. 40872069 and 41173059)the National Basic Research Program of China (973 Program) (Grants No. 2015CB453000)+1 种基金China Geological Survey (Grants No. 12120113095500)the Foundation of China Nuclear Geology (Grants No. 201148)
文摘The carbonaceous-siliceous-argillitic rock type uranium deposit in the Zoige area is located in the northeastern margin of the Tibetan Plateau, and has gained much attention of many geologists and ore deposit experts due to its scale, high grade and abundant associated ores. Because of the insufficient reliable dating of intrusive rocks, the relationship between mineralization and the magmatic activities is still unknown. In order to study this key scientific issue and the ore-forming processes of the Zoige uranium ore field, the LA-ICP-MS zircon U-Pb dating of magmatic rocks was obtained:64.08±0.59 Ma for the granite-prophyry and ~200 Ma for the dolerite. U-Pb dating results of uraninite from the Zoige uranium ore field are mainly concentrated on ~90 Ma and ~60 Ma. According to LA-ICP-MS U-Pb zircon dating, the ages for the dolerite, porphyry granite and granodiorite are 200 Ma, 64.08 Ma approximately and 226.5-200.88 Ma, respectively. This indicates that the mineralization has close relationship with activities of the intermediate-acidic magma. The ages of the granite porphyry are consistent with those uraninite U-Pb dating results achieved by previous studies, which reflects the magmatic and ore-forming event during the later Yanshanian. Based on the data from previous researches, the ore bodies in the Zoige uranium ore field can be divided into two categories:the single uranium type and the uranium with polymetal mineralization type. The former formed at late Cretaceous(about 90 Ma), while the latter, closely related to the granite porphyry, formed at early Paleogene(about 60 Ma). And apart from ore forming elemental uranium, the latter is often associated with polymetallic elements, such as molybdenum, nickel, zinc, etc.
文摘Based upon a comprehensive study of 123 copper deposits in China. this paper reaches the following conclusions: 1. The crust in China was solidified pretty late; with the accretion of the plate, the copper mineralization moved towards its margin in space and became successively younger in age. 2. The major copper ore types ever found in the world have mostly been discovered in China, in which the porphyry type seems to be the most important and the massive sulfide type in the transitional bed between marine clastic and carbonate rocks is clearly defined. 3. Carbonate strata are widespread in China and their deposition lasted for a long geological period, so the proportion of copper deposits occurring in them is large as compared with other parts of the world. 4. Seven metallogenic epochs can be recognized, in which the Mesozoic one plays the leading role and the middle(late) Palaeozoic and Cenozoic ones are next in importance. Mineralization was comparatively simple in the early geological period. and became diversified later on. In the early epochs copper deposits related to basaltic magmatism and metamorphosed marine sediments predominated, whereas in the later epochs those related to granitic magmatism and continental sedimentation were dominant. 5. There exist in China thirteen metallogenic provinces, of which the Lower Yangtze downwarping belt, Sanjiang fold system, Jiangnan axis and Xikang-Yunnan axis are of greater significance. 6. The crustal mobility in China was rather pronounced, the polycyclic evolution of the crust has resulted in such obvious phenomena as the inheritance of mineralization, the coexistence of various types and the superposition of different genetic types.
基金This study was financially supported by the National Key R&D Program of China(2016YFE0206300)Natural Science Foundation of China(41772082)+1 种基金China Geological Survey(DD2016013601)China Nuclear Geological Bureau(201654).Colleagues from No.203 Research Institute of Nuclear Industry are greatly appreciated for their field support.
文摘The U-Th-REE-Nb(Ta)-polymetallic mineralization is generally related to either the silica-undersaturated syenites,the silica-oversaturated alkaline/peralkaline granites or igneous carbonatites.In this study,the authors report a new mineralization type,which is related to the magmatic-hydrothermal albitite(with mineral assemblage predominated by albite with volume content>90%),as exemplified by the Chachaxiangka deposit in Qinghai Province of China.The Chachaxiangka deposit is the first albititerelated U-Th-REE-Nb deposit recognized in China and the mineralization can be divided into 3 types:the vein-type,the disseminated veinlet type and breccia type,of which the former 2 are predominant.Three mineralization stages can be identified according to the detailed mineralogical analyses,including the magmatic stage,main hydrothermal mineralization stage and post-ore stage.By comprehensive analyses of the mineralogical,major and trace element compositions,the authors suggest that the albitite vein is magmatic-hydrothermal in origin and both the magmatic evolution and overprint of the hydrothermal fluids play important roles in the formation of the albitite and related polymetallic mineralization.Phase separation between the silicate melt and carbonate/phosphate melt might take place in the magmatic stage,yet the immiscibility between the silicate melt and chloride-dominated fluids is the most important mechanism for the REE mineralization and also causes the Nb-Th re-mobilization and enrichment.The red color of the albitite aplite vein is an eye-catching prospecting mark in the field and more mineralization can be expected at depth and in the surrounding areas.The discovery of the new albitite type U-Th-REENb mineralization give rise to new ideas during future U-Th-REE-Nb exploration,not only in the Qaidam-Altun belt,but also other areas across China.
基金funded by the National Natural Science Foundation of China(grant No.41572117)Technological&Developmental Department of China Petroleum&Chemical Corporation(grants No.P13040 and P14128)China Geological Survey(grant No.DD20160175-1-1)
文摘Objective The Yubei area is located in the mid-east Maigaiti slope of southwestern Tarim Basin, China, with an exploration history of several years. Recent exploration has preliminarily indicated that the Ordovician carbonate formations in this area have some oil and gas potential. Carbonate microfacies provides material basis for reservoir development, seal formation and hydrocarbon generation. Therefore, this work utilized the standard microfacies (SMF) types to study the microfacies of the Ordovician formations in the Yubei area in order to provide theoretical basis for the next exploration.
基金We would also like to acknowledge financial support from Key Project 40930423 from the National Natural Science Foun dation of China.
文摘Several Au deposits in Guizhou Province,southwest China,described as being similar to the highly productive Carlin-type gold deposits in northern Nevada.USA,were examined to identify similarities and differences between the two districts.Samples were collected along transects from lowto high-grade rock,where possible,and fram stockpiles at the Shuiyindong,Zimudang,Taipingdong,Yata and Jinfeng(formerly Lannigou)deposits.Methods used to examine ore and alteration minerals included hand-sample description:reflectance spectroscopy using an ASD Terraspec spectrometer;analyses of hand samples by carbonate staining with Alizaren red and potassium ferricyanide;transmitted and reflected light petrography;chemical analyses,mineral identification,and imaging using a JEOL.JSM-5610 scanning electron microscope:and quantitative chemical analyses using a JEOL JXA-8900 electron probe microanalyzer.Geochemical analyses of hand samples for 52 elements were done by ALS Chemex.Results indicate both similarities and differences between the two districts.Both districts have similar geologic histories.and deposits at both locations appear to have formed as a result of similar tectonic events.though the district in southwest China lacks evidence of eoeval felsic igneous activity;however,the ore-stage minerals and the fluids that produced the minerals and deposits have some significant differences.The Nevada deposits were dominated by fluid-rock reaction in which host rock Fe was sulfidized to form Au-bearing pyrite.Although ore fluids sulfidized host rock Fe in the Cuizhou deposits.the timing of Fe metasomatism is unknown,so whether the deposits formed in response to sulfidation or pyritization is unclear.Fluid-rock reaction between an acidic,aqueous fluid and highly reactive calcareous rocks in Nevada caused extensive decarbonatization of host rocks,jasperoid replacemerit of carbonate minerals,and alteration of silty rock components to illite and kaolinite.In Guizhou,CO2-bearing ore fluids with temperatures and pressures approaching 100℃ and 500 bars greater than temperatures and pressures detemained for ore fluids in the Nevada deposits,deposited Aubearing pyrite.In examined Guizhou deposits these fluids carbonatized host rocks and farmed both replacement and open-space-filling ore.The fluids,which may have been immiscible,were sufficiently overpressured to fracture wall rocks and to create significant open space filled by vein quartz.While deposit architecture,tectonic setting,and host rocks in Guizhou are quite similar to northern Nevada,ore and alteration minerals suggest that ore-forming processes in examined Guizhou deposits have important similarities to processes associated with formation of orogenic Au systems.The Guizhou deposits display characteristics of both Carlin-type and orogenic systems,perhaps indicating formation at conditions somewhat intermediate to conditions for Carlin-type deposits and orogenic systems.
基金supported financially by project 2014CB440905 under the Major State Basic Research Development Program of China (973 Program)the 12th Five-Year Plan Project of State Key Laboratory of Ore-deposit Geochemistry, Chinese Academy of Sciences (SKLODG-ZY125-01)
文摘The Shuiyindong gold deposit is one of the most famous and largest Carlin-type gold deposits in China and is located in southwest Guizhou, in the eastern part of the Huijiabao anticline. The Shuiyindong's gold mineralization occurred in bioclastic limestone of the Permian Longtan Formation. Sulfur, carbon, hydrogen, oxygen, and lead isotopic compositions are reported in this paper. The properties and sources of ore-forming fluid have been discussed and a metallogenic model for the Shuiyindong gold deposit has been proposed. The d34 S values of stibnite, realgar, orpiment, pyrite from orebodies, and pyrite from quartz veins are similar to or slightly higher than the d34 S values of mantle sulfur. It is suggested that the sulfur of hydrothermal sulfides was likely of magmatic origin with minor heavy sulfur contributed from the country rocks. The measured d D values and calculated d18OH2 O values of inclusion fluid in quartz plotted within or below a magmatic hydrothermal fluid field far from the meteoric water line. This indicates that the ore-forming fluid for the main-stage gold mineralization could have been derived mainly from a magmatic source and mixed with a small amount of meteoric water. The carbon and oxygen isotopic compositions of calcites in the d18 O vs. d13 C diagram suggest that the CO2 in ore-forming fluid was derived from dissolution of bioclastic limestone and oxidation of sedimentary organic carbon in limestone. However, the d13 C values of ore-related calcites, which contain intergrown realgar and/or orpiment, are similar to those of mantle carbon. Although no igneous intrusive rock has been observed in the vicinity of the gold deposits, the possibility of mantle fluid integrated into the ore-forming fluid cannot be eliminated based on the d13 C values of ore-related calcites. The lead isotopes of sulfides are distributed near the growth curves of upper crust and orogenic belt in the plumbotectonic diagram. Their calculated Dc and Db values plotted within the magmatism field of crust-mantle subduction zone in the Dc- Db diagram. This suggests that the lead of sulfides has an intimate connection with magmatism. Our S, H, O, C, and Pb isotopic studies for the Shuiyindong Carlin-type gold deposit in Guizhou manifest a concordant possibility that the ore-forming fluid was mainly derived from magmatic fluid with minor contribution from the surrounding strata. With the integration of comprehensive geology and isotopic geochemistry, we have proposed a magmatic hydrothermal model for the origin of the Shuiyindong gold deposit.
基金supported jointly by the National Science and Technology Supporting Program(2006BAB01A13)the Supporting-Guizhou Engineering Projectthe Autonomous Research Project of the State Key Lab. of Ore Deposit Geochemistry,CAS
文摘Geochemical studies of the Paiting and Miaolong Carlin-type gold deposits in the Sandu-Danzhai metal-logenic zone,Guizhou Province,have shown that the mineralized-altered rocks show LREE-enrichment patterns,generally displaying negative Eu anomalies(δEu=0.51?0.97) and unobvious negative Ce anomalies(δCe=0.86?0.99).Calcite and fluorite in relation with metallogenesis show MREE-enrichment patterns,generally displaying rather weak negative Eu anomalies(δEu=0.74?0.93) and weak negative Ce(δCe=0.70?0.98) anomalies.The δ13CPDB values of carbon in calcite are-1.61‰?-5.82‰,the δ18OSMOW values of oxygen are 13.97‰?19.24‰,and the δ34SCDT values of sulfur in stibnite are 17.72‰?21.68‰.In regard to δD and δ18O,ore-forming fluids pos-sess the characteristics of metamorphic water.The process of metallogenesis of the Carlin-type gold deposits is con-trolled by the Yanshanian tectonic activities.The Yanshanian movement promoted the migration and mobilization of metamorphic fluids in the extensively developed medium-to high-grade metamorphic rocks in this region,carrying primarily enriched gold and associated elements such as Hg,As,and Sb in the Sinian metamorphosed black shales and Lower Cambrian black shales.The ore-forming fluids found their way into a suitable metallogenic environment along the fault zone,followed by gold precipitation to form gold deposits.
基金supported by NNSF (No.41572060)projects of CGS (NO.12120113095900)+2 种基金university and company cooperation (2012-01)YM Lab(2011)Innovation Team of Yunnan province and KMUST (2008,2012)
文摘1 Introduction The Laurani porphyry deposit is located in the Altiplano,an extensive North-South trending structural basin that formed in Central-Andean metallogenic belt,Bolivia.The Altiplano poly-metallic province contains sub-volcanic ore