Anti-plane punch-through shear test and anti-planefour-point bending test are used to study the crack initiation and propagation under anti-plane shear (Mode Ⅲ) loading. The tensile and shear stresses at the crack ti...Anti-plane punch-through shear test and anti-planefour-point bending test are used to study the crack initiation and propagation under anti-plane shear (Mode Ⅲ) loading. The tensile and shear stresses at the crack tip are calculated by finite element method. The results show that under Mode Ⅲ loading the maximum principal stress σ1 at crack tip is smaller or a little larger than the maximum shear stress τmax. Since the tensile strength of brittle rock is much lower than its shear strength, σ1 is easy to reach its critical value before τmax reaches its critical value and thus results in Mode I fracture. The fracture trajectory is helicoid and the normal direction of tangential plane with the fractured helicoid is along the predicted direction of the maximum principal stress at the notch tip. It is further proved that Mode Ⅰ instead of Mode Ⅲ fracture occurs in brittle rock under Mode Ⅲ loading. The fracture mode depending on the fracture mechanism must be distinguished from the loading form.展开更多
Iron(Ⅲ) loaded novolac-based network adsorbents 1 and 2 were studied for efficient removal of azo-dye pollutants from aqueous solutions. The adsorption behavior was evaluated by using methyl orange and orange-G as mo...Iron(Ⅲ) loaded novolac-based network adsorbents 1 and 2 were studied for efficient removal of azo-dye pollutants from aqueous solutions. The adsorption behavior was evaluated by using methyl orange and orange-G as model azo dyes. The effect of parameters such as contact time and initial dye concentration on the adsorption of azo dyes was studied. The results showed that loading of Fe(Ⅲ) onto the sorbent networks has noticeable effect on azo-dye sorption capacity. The adsorption equilibrium data were fitted to Freundlich isotherm model. Besides, the reusability of the dye loaded sorbents was investigated on adjusting pH of solutions.展开更多
基金Project (50374073)supported by the National Natural Science Foundation of China project (2002032256)supported bythe Postdoctor Science Foundation of China
文摘Anti-plane punch-through shear test and anti-planefour-point bending test are used to study the crack initiation and propagation under anti-plane shear (Mode Ⅲ) loading. The tensile and shear stresses at the crack tip are calculated by finite element method. The results show that under Mode Ⅲ loading the maximum principal stress σ1 at crack tip is smaller or a little larger than the maximum shear stress τmax. Since the tensile strength of brittle rock is much lower than its shear strength, σ1 is easy to reach its critical value before τmax reaches its critical value and thus results in Mode I fracture. The fracture trajectory is helicoid and the normal direction of tangential plane with the fractured helicoid is along the predicted direction of the maximum principal stress at the notch tip. It is further proved that Mode Ⅰ instead of Mode Ⅲ fracture occurs in brittle rock under Mode Ⅲ loading. The fracture mode depending on the fracture mechanism must be distinguished from the loading form.
文摘Iron(Ⅲ) loaded novolac-based network adsorbents 1 and 2 were studied for efficient removal of azo-dye pollutants from aqueous solutions. The adsorption behavior was evaluated by using methyl orange and orange-G as model azo dyes. The effect of parameters such as contact time and initial dye concentration on the adsorption of azo dyes was studied. The results showed that loading of Fe(Ⅲ) onto the sorbent networks has noticeable effect on azo-dye sorption capacity. The adsorption equilibrium data were fitted to Freundlich isotherm model. Besides, the reusability of the dye loaded sorbents was investigated on adjusting pH of solutions.
