Comparative review of corrosion-resistant coatings on metal bipolar plates of proton exchange membrane fuel cells

In the realm of proton exchange membrane fuel cells(PEMFCs),the bipolar plates(BPs)are indispensable and serve pivotal roles in distributing reactant gases,collecting current,facilitating product water removal,and cooling the stack.Metal BPs,characterized by outstanding manufacturability,cost-effectiveness,higher power density,and mechanical strength,are emerging as viable alternatives to traditional graphite BPs.The foremost challenge for metal BPs lies in enhancing their corrosion resistance and conductivity under acidic conditions,necessitating the application of various coatings on their surfaces to ensure superior performance.This review summarizes and compares recent advancements in the research of eight distinct types of coatings for BPs in PEMFCs,including noble metal,carbide,ni-tride,and amorphous carbon(a-C)/metal compound composite coatings.The various challenges encountered in the manufacturing and fu-ture application of these coatings are also delineated.

Residual Stresses and Forming Quality of Metal Bipolar Plates for PEMFC During the Stamping Process

Stamping is a critical step in the manufacture of metallic bipolar plates.Typically,residual stress and a spring back effect appear on the bipolar plate after the stamping process,which impacts on the performance and lifetime of the proton exchange membrane fuel cell(PEMFC).The residual stress and spring back behavior which occur as a result of stamping a bipolar plate are investigated in this study.The effects of the punch radius,the die radius,the channel depth,and the clearance between the punch and the die on the residual stress and forming quality of the bipolar plate are examined.The stamping process can be divided into three stages.The high stress area and the middle section residual stress area were selected to study the formation process and to obtain the composition of the residual stress regions.Spring back was mainly related to the position of the fixed end of the sheet and the degree of plastic deformation,and the sheet thickness have increased by 2μm after spring back.Based on the results of finite element analysis,as described by the distribution of residual stress,the formation,the thickness of the middle cross section and the equivalent plastic strain,it was found that all the tool parameters affected the distribution of the residual stress.This research can provide a design reference for the manufacture of metallic bipolar plates based on the stamping process.

Vibration of a Two-Layer“Metal+PZT”Plate Contacting with Viscous Fluid

The present work investigates the mechanically forced vibration of the hydro-elasto-piezoelectric system consisting of a two-layer plate“elastic+PZT”,a compressible viscous fluid,and a rigid wall.It is assumed that the PZT(piezoelectric)layer of the plate is in contact with the fluid and time-harmonic linear forces act on the free surface of the elastic-metallic layer.This study is valuable because it considers for the first time the mechanical vibration of the metal+piezoelectric bilayer plate in contact with a fluid.It is also the first time that the influence of the volumetric concentration of the constituents on the vibration of the hydro-elasto-piezoelectric system is studied.Another value of the present work is the use of the exact equations and relations of elasto-electrodynamics for elastic and piezoelectric materials to describe the motion of the plate layers within the framework of the piecewise homogeneous body model and the use of the linearized Navier-Stokes equations to describe the flow of the compressible viscous fluid.The plane-strain state in the plate and the plane flow in the fluid take place.For the solution of the corresponding boundary-value problem,the Fourier transform is used with respect to the spatial coordinate on the axis along the laying direction of the plate.The analytical expressions of the Fourier transform of all the sought values of each component of the system are determined.The origins of the searched values are determined numerically,after which numerical results on the stress on the fluid and plate interface planes are presented and discussed.These results are obtained for the case where PZT-2 is chosen as the piezoelectric material,steel and aluminum as the elastic metal materials,and Glycerin as the fluid.Analysis of these results allows conclusions to be drawn about the character of the problem parameters on the frequency response of the interfacial stress.In particular,it was found that after a certain value of the vibration frequency,the presence of the metal layer in the two-layer plate led to an increase in the absolute values of the above interfacial stress.

Driving inward growth of lithium metal in hollow microcapsule hosts by heteroatom‐controlled nucleation

The application of Li metal anodes in rechargeable batteries is impeded by safety issues arising from the severe volume changes and formation of dendritic Li deposits.Three‐dimensional hollow carbon is receiving increasing attention as a host material capable of accommodating Li metal inside its cavity;however,uncontrollable and nonuniform deposition of Li remains a challenge.In this study,we synthesize metal–organic framework‐derived carbon microcapsules with heteroatom clusters(Zn and Ag)on the capsule walls and it is demonstrated that Ag‐assisted nucleation of Li metal alters the outward‐to‐inward growth in the microcapsule host.Zn‐incorporated microcapsules are prepared via chemical etching of zeolitic imidazole framework‐8 polyhedra and are subsequently decorated with Ag by a galvanic displacement reaction between Ag^(+) and metallic Zn.Galvanically introduced Ag significantly reduces the energy barrier and increases the reaction rate for Li nucleation in the microcapsule host upon Li plating.Through combined electrochemical,microstructural,and computational studies,we verify the beneficial role of Ag‐assisted Li nucleation in facilitating inward growth inside the cavity of the microcapsule host and,in turn,enhancing electrochemical performance.This study provides new insights into the design of reversible host materials for practical Li metal batteries.

Self-Adaptive and Electric Field-Driven Protective Layer with Anchored Lithium Deposition Enable Stable Lithium Metal Anode

Lithium metal battery has great development potential because of its lowest electrochemical potential and highest theoretical capacity.However,the uneven deposition of Li^(+)flux in the process of deposition and stripping induces the vigorous growth of lithium dendrites,which results in severely battery performance degradation and serious safety hazards.Here,the tetragonal BaTiO3 polarized by high voltage corona was used to build an artificial protective layer with uniform positive polarization direction,which enables uniform Li^(+)flux.In contrast to traditional strategies of using protective layer,which can guide the uniform deposition of lithium metal.The ferroelectric protective layer can accurately anchor the Li^(+)and achieve bottom deposition of lithium due to the automatic adjustment of the electric field.Simultaneously,the huge volume changes caused by Li^(+)migration change of the lithium metal anode during charging and discharging is functioned to excite the piezoelectric effect of the protective layer,and achieve seamless dynamic tuning of lithium deposition/stripping.This dynamic effect can accurately anchor and capture Li^(+).Finally,the layer-modified Li anode enables reversible Li plating/stripping over 1500 h at 1 mA cm^(-2)and 50℃in symmetric cells.In addition,the assembled Li-S full cell exhibits over 300 cycles with N/P≈1.35.This work provides a new perspective on the uniform Li^(+)flux at the Li-anode interface of the artificial protective layer.

Oblique perforation of thick metallic plates by rigid projectiles

Oblique perforation of thick metallic plates by rigid projectiles with various nose shapes is studied in this paper. Two perforation mechanisms, i.e., the hole enlargement for a sharp projectile nose and the plugging formation for a blunt projectile nose, are considered in the proposed analytical model. It is shown that the perforation of a thick plate is dominated by several non-dimensional numbers, i.e., the impact function, the geometry function of projectile, the non-dimensional thickness of target and the impact obliquity. Explicit formulae are obtained to predict the ballistic limit, residual velocity and directional change for the oblique perforation of thick metallic plates. The proposed model is able to predict the critical condition for the occurrence of ricochet. The proposed model is validated by comparing the predictions with other existing models and independent experimental data.

Characteristics of Eddy Current Attenuation and Thickness Measurement of Metallic Plate

In eddy current testing, the law of attenuation of eddy current(EC) is of great concern. In conductive half space under the excitation of uniform magnetic field, the EC density decreases exponentially in the depth direction. However, in conductor with finite thickness tested by coil, the distribution of EC in the depth direction is more complicated. This paper studies the characteristics of EC attenuation in metallic plate of finite thickness. Simulation results show that there is an EC reflection at the bottom of plate, which changes the law of EC attenuation. A new concept, namely the equivalent attenuation coefficient, is proposed to quantify the speed of EC attenuation. The characteristics of EC attenuation are utilized to explain the nonmonotonic relation between coil voltage and plate thickness. Procedure of selecting frequency is discussed. Thereafter, measurement of plate thickness is carried out and accurate result is obtained.

Damage of multi-layer spaced metallic target plates impacted by radial layered PELE

Three different kinds of PELE(the penetrator with lateral efficiency) were launched by ballistic artillery to impact the multi-layer spaced metal target plates.The lmpact velocities of the projectiles were measured by the velocity measuring system.The damage degree and process of each laye r of target plate impacted by the three kinds of projectiles were analyzed.The experimental results show that all the three kinds of projectiles have the effect of expanding holes on the multi-layer spaced metal target plates.For the normal structure PELE(without layered) with tungsten alloy jacket and the radial layered PELE with tungsten alloy jacket,the diameters of holes on the seco nd layer of plates are 3.36 times and 3.76 times of the diameter of the projectile,re spectively.For radial layered PELE with W/Zr-based amorphous composite jacket,due to the large number of tungsten wires dispersed after the impact,the diameter of the holes on the four-layer spaced plates can reach 2.4 times,3.04 times,5.36 times and 2.68 times of the diameter of the projectile.Besides,the normal structure PELE with tungsten alloy jacket and the radial layered PELE whit tungsten alloy jacket formed a large number of fragments impact marks on the third target plate.Although the number of fragments penetrating the third target plate is not as large as that of the normal structure PELE,the area of dispersion of fragments impact craters on the third target plate is larger by the radial layered PELE.The radial layered PELE with W/Zr-based amorphous composite jacket released a lot of heat energy due to the impact of the matrix material,and formed a large area of ablation marks on the last three target plates.

Edge effects of metal plate in laser forming

To search for the new scanning plan that can reduce the bending angle variation and the bending curvatures of the bending edge, an explanation for the causes of the edge effects was given. Six new scanning strategies were proposed through the change of the scanning length of middle and two ends based on the above analyses. Numerical simulations were carried out to study the edge effects using the six new scanning strategies. The simulation results show that the new scanning strategies can improve effectively the quality of the forming parts.

A three-stage model for the perforation of finite metallic plates by long rods at high velocities

A three-stage theoretical model is presented herein to predict the perforation of a thick metallic plate struck normally by a long rod at high velocities. The model is suggested on the basis of the assumption that the perforation of a thick metallic plate by a long rod can be divided into three stages:(1) initial penetration;(2) plug formation and (3) plug slipping and separation. Various analytical equations are derived which can be employed to predict the ballistic limit, residual velocity and residual length of the long rod. It is demonstrated that the present model predictions are in good agreement with available experimental results for the perforation of finite steel targets struck normally by steel as well as tungsten alloy long rods at high velocities. It is also demonstrated that the dynamic maximum shear stress of a plate material has strong effect on plug formation and plug thickness which, in turn, exerts considerable influence on the residual velocities and lengths of a long rod at impact velocities just above the ballistic limit.

Thermal modeling and the optimized design of metal plate cooling systems for single concentrator solar cells

A metal plate cooling model for 400~ single concentrator solar cells was established. The effects of the thickness and the radius of the metal plate, and the air environment on the temperature of the solar cells were analyzed in detail. It is shown that the temperature of the solar cells decreased sharply at the beginning, with the increase in the thickness of the metal plate, and then changed more smoothly. When the radius of the metal plate was 4 cm and the thickness increased to 2 mm or thicker, the temperature of the solar cell basically stabilized at about 53℃. Increasing the radius of the metal plate and the convective transfer coefficient made the temperature of the solar cell decrease remarkably. The effects of A1 and Cu as the metal plate material on cooling were analyzed contrastively, and demonstrated the superiority of A1 material for the cooling system. Furthermore, considering cost reduction, space holding and the stress of the system, we optimized the structural design of the metal plate. The simulated results can be referred to the design of the structure for the metal plate. Finally, a method to devise the structure of the metal plate for single concentrator solar cells was given.

Numerical Controlled Rolling Process of Thick Metal Plate

Thick metal plate rolling process has become more and more important in building a flat roof of drilling on the bottom at sea. This is because not only the product quality requirement higher and higher but also the marketing competition. To improve the process of thick metal plate rolling and to increase productivity a numerical controlled rolling process is developed, which include the process planning, the mathematical model establishment and the numerical control system development. The process is for the 17 000 kN×3 000 mm movable up roller bending machine. According to the machine configuration non-symmetry rolling process is planed. This makes it possible to integrate all the steps of plate shaping up such as end side bending, several times of semi-shape bending and the last shape finishing. Since the process will perform under the numerical controlled condition whole steps of the process are considered can be worked in the automatic cycle. The mathematic model consists of two sections, the theory model and the experience parameters model. Which takes the original plate parameters such as geometry and mechanics, characters of the machine such as the movement limits, tonnage and so on as input and calculates all the parameters needed in process performing. Meanwhile, the mathematic Model is totally adapted to the control system. The numerical control system development scheme is based on all the works above. Here, a system plan is provided. The functional modules and hardware selection, in detail, are introduced. The system software on top level and the controlling software for controller are developed. And some unit techniques in the system such as timer setting, communication between system and controller, video integration, and the ability of resisting impact force are introduced. The process has been used successfully in production for more than two years. Practice approves that the process is robust.

THz time domain monostatic radar cross section measurement of metallic plates and dihedrons

THz Radar Cross Section(RCS)measurement setup based on THz Time Domain Spectroscopy(TDS)is built to provide large scaled targets test ability in recent years.As calibrations,the metal plates and dihedrons are used in our experiments.The measurements are performed in a monostatic terahertz time-domain setup.The author proposed time domain and frequency domain calibration methods for angular RCS of calibrations,comparing the measurements with the theory to verify the ability of the time domain measurement setup.

Electromagnetic Modeling of Metallic Elliptical Plates

This paper presents the evaluation of the capacitance of an isolated elliptical plate and two parallel elliptical plates. Integral equations are formed by relating the previously unknown charges on the elliptical plates and the potential on the metallic plates. The integral equations are solved by applying the method of moments based on the pulse function and point matching. The elements of the matrix in the method of moments are found by dividing the structure into triangular subsections. The matrix equation is solved in order to compute the unknown charges on each subsection. Numerical results on the capacitance as a function of the geometrical parameters of the ellipse are presented.

Gas metal arc welding of duplex stainless clad steel plates

The 2205 duplex stainless ＋ DH36 clad steel plate was welded by gas metal arc welding（GMAW）, and the welding performance of the clad steel plate was investigated. The results show that the adaptability of the welding procedure for the base metal of carbon steel, the transition layer, and the cladding material is excellent. The test results indicate that the phase proportion and component dilution of the GMAW-welded joints of clad steel plate can be effectively controlled to yield joints with good mechanical properties and corrosion resistance.

Mandibular Sequela Noma: Metal Plate Repair Associated with a Submental Flap, about One Case

Introduction: Noma is a severe and mutilating gangrenous stomatitis of the orofacial sphere, starting on periodontal side. It is rare and occurs mainly in children that land is weakened by malnutrition. We report a case of mandibular sequela noma requiring plastic surgery. Clinical case: This was a 7-year-old patient with moderate acute malnutrition. She was referred from a peripheral care facility for gangrene of the left cheek, communicating the oral cavity with the outside, through an orostoma. This lesion had been evolving for two months, with a tendency towards progressive destruction of the soft tissues of the cheek and the mandibular bone. The neck and facial CT-Scan demonstrated destruction of the mandibular bone exposed on the left side, without signs of tumor invasion. After correction of nutritional status and local infection, the patient was treated with a metal plate recovered by sub-mental flap. Conclusion: Noma is a severe gangrenous stomatitis that transforms patients’ faces into ghosts by destroying soft tissues and underlying bone planes. The management of his sequelae is surgical, sometimes using complex techniques of plastic surgery.

Scattering Characteristics of Metallic Plates in Radial Waveguide

Mode matching is a useful method to analyze the mode characteristics during the section change of a waveguide. By applying this method to the radial waveguide, and solving specific problems due to the radial transmission of electromagnetic wave, this presents a calculating method in radial waveguide based on mode matching. The scattering characteristics of metallic plates in the radial waveguide are calculated, and verified qualitatively using an electromagnetic simulator, which confirmed the validity of this method.

Melting and Solidification Heat Transfer Characteristics of a Phase-Change Material in a Latent Heat Storage Vessel: Effects of a Perforated Partition Plate and Metal Fiber

Today, latent heat storage technology has advanced to allow reuse of waste heat in the middle-temperature range. This paper describes an approach to develop a latent heat storage system using middle-temperature waste heat (~100oC - 200oC) from factories. Direct contact melting and solidification behavior between a heat-transfer fluid (oil) and a latent heat storage material mixture were observed. The mixture consisted of mannitol and erythritol (Cm = 70 mass %, Ce = 30 mass %) as a phase-change material (PCM). The weight of the PCM was 3.0 kg and the flow rate of the oil, foil, was 1.0, 1.5, or 2.0 kg/min. To decrease the solidified height of the PCM mixture during the solidification process, a perforated partition plate was installed in the PCM region in the heat storage vessel. PCM coated oil droplets were broken by the perforated partition plate, preventing the solidified height of the PCM from increasing. The solidification and melting processes were repeated using metal fiber. It was found that installing the metal fiber was more effective than installing the perforated partition plate to prevent the flow out problem of the PCM.

RESEARCH ON DYNAMIC BEHAVIOUR AND NOISE REDUCTION OF METAL CUTTING SAW PLATES

Based upon theoretical and experimental methods of acoustics and vibration, the dynamic characteristics of cutting processes have been researched systematically, and a simplified method of quickly estimating the modal parameters of elastic circular plate structures under clamping has also been advanced. Furthermore, we try the best to explore effectively the noise-reducing ways in the sawing process. In fact, satisfactory results have been achieved in practice.

Multichip on Aluminum Metal Plate Technology for High Power LED Packaging

Multichip on Ahnnintnn Metal Plate（MOAMP） technology with simple structure and low thermal resistance is developed for effective heat reratrval of Light Emitting Diode（LED） p-n junction and LED lighting module to have high reliability. The thermal resistance of LED modules was numerical and experimental. Thermal resistance from the jtnction to aluminten metal plate, considering input power of IFD module using MOAMP technology, is 3.02 K/W, 3.23 K/W for the measured and calculated, respectively. We expect that the reported MOAMP technology with low thermal resistance will be a promising solution for high power LED fighting modules.