常减压装置低温余热回收利用项目节能效果显著

常减压装置各侧线油品换热后还有部分低温余热,需要经过循环水冷却降温后送入罐区,同时除盐水装置冬季原水需要使用大量蒸气加温至25℃左右,为了实现能源合理利用,根据低温余热回收利用策略,提出将除盐水用原水引入常减压装置油品水冷器,升温后返回除盐水原水箱前,经过实施技术改造,年可节约蒸气1.30万t,同时减少冷却用循环水127.87万t,合计年可节约成本336万元,节能效果及经济效益显著。

塑料包装废弃物的回收处理与再利用技术

随着经济的发展和包装工业的迅速崛起,包装废弃物也同时大量增加,若不及时加以处理,将会严重地污染环境,久而久之形成一种恶性的不可治理的趋势.目前包装废弃物的回收处理与再利用已成为各国环境保护的当务之急,也是治理全球性环境污染的首要措施.本文拟对塑料包装废弃物的回收处理及再利用技术作一些阐述.

Recycling of automotive aluminum

With the global warming of concern,the secondary aluminum stream is becoming an even more important component of aluminum production and is attractive because of its economic and environmental benefits.In this work,recycling of automotive aluminum is reviewed to highlight environmental benefits of aluminum recycling,use of aluminum alloys in automotive applications,automotive recycling process,and new technologies in aluminum scrap process.Literature survey shows that newly developed techniques such as laser induced breakdown spectroscopy(LIBS) and solid state recycling provide promising alternatives in aluminum scrap process.Compared with conventional remelting and subsequent refinement,solid state recycling utilizing compression and extrusion at room or moderate temperature can result in significant energy savings and higher metal yield.

Pervaporation Separation of Butanol-Water Mixtures Using Polydimethylsiloxane/Ceramic Composite Membrane

Pervaporation has attracted considerable interest owing to its potential application in recovering biobutanol from biomass acetone-butanol-ethanol (ABE) fermentation broth. In this study, butanol was recovered from its aqueous solution using a polydimethylsiloxane (PDMS)/ceramic composite pervaporation membrane. The effects of operating temperature, feed concentration, feed flow rate and operating time on the membrane pervaporation performance were investigated. It was found that with the increase of temperature or butanol concentration in the feed, the total flux through the membrane increased while the separation factor decreased slightly. As the feed flow rate increased, the total flux increased gradually while the separation factor changed little. At 40°C and 1% (by mass) butanol in the feed, the total flux and separation factor of the membrane reached 457.4 g·m?2·h?1 and 26.1, respectively. The membrane with high flux is suitable for recovering butanol from ABE fermentation broth.

Energy and Water Optimization in Biofuel Plants

In this paper we address the topic of energy and water optimization in the production of bioethanol from corn and switchgrass. We show that in order for these manufacturing processes to be attractive,there is a need to go beyond traditional heat integration and water recycling techniques. Thus,we propose a strategy based on mathe-matical programming techniques to model and optimize the structure of the processes,and perform heat integration including the use of multi-effect distillation columns and integrated water networks to show that the energy effi-ciency and water consumption in bioethanol plants can be significantly improved. Specifically,under some circum-stances energy can even be produced and the water consumption can be reduced below the values required for the production of gasoline.

Hydrometallurgical recovery of zinc from industrial hot dipping top ash

Top ash from hot-dip galvanizing plant was investigated as a source of secondary zinc to be returned to galvanizing bath.The waste material contained 63%Zn as metallic,oxide and hydroxychloride phases.It was leached in H2SO4 solutions(20%and 25%)at various bath loadings(100-300 g/L).Leaching behaviors of zinc,manganese,iron and chloride ions were investigated.A few strategies of iron elimination from leaching liquors were examined.Flocculant addition was harmful for subsequent filtration of iron precipitates due to increased viscosity of solution,while a combination of zinc oxide and calcium carbonate for rising pH resulted in the formation of dense suspension unenforceable to separate from zinc sulphate solution.Zinc electrowinning was carried out at different pH(from-0.5 to 2.8)using a range of current densities(3-10 A/dm^2).Optimal conditions for pure metal recovery were:leaching in 20%H2SO4 solution at zinc ash content 100-150 g/L,Fe2O3·xH2O precipitation using H2O2 and CaCO3,zinc electrowinning at pH of 0.1-1.0 at 3-6 A/dm2.Correlations between pH and free H2SO4 concentration in electrolyte solutions were also discussed.pH-acid concentration dependence for zinc electrolyte was between experimental and calculated curves for pure H2SO4 solutions,while the curve was shifted towards lower pH if ferric ions were in the solution.

Roadway layout for recycling residual coal pillar in room-and-pillar mining of thick coal seam

In the context of a room-and-pillar mining gob in Shanxi province in China,this paper numerically investigates the stress distribution and deformation rules of roadway surrounding rocks at various locations of residual coal pillars in room-and-pillar mining gobs using software FLAC3 D.It is found that the concentrated stress beneath coal pillars distributes in a shape of ellipse.A reasonable roadway layout is then proposed.In this design,it is indicated that roadways should be designed to avoid the supporting zones of pillars with increasing compression and take into account the roof falling and crushing in the upper gob.According to the surrounding rock deformation characteristics and mining roadway locations as well as the supporting principles of timely support,rock reinforcing,piecewise management and suiting local conditions,a new asymmetric shield supporting plan is proposed.The field surveying results show that this supporting plan can effectively control the roadway rock deformation,thus guarantee the safe and smooth construction of roadways.

Selective removal technology using chemical etching and excimer assistance in precision recycle of color filter

Color filters are produced using semiconductor production techniques although problems with low yield remain to be addressed. This study presents a new means of selective removal using excimer irradiation, chemical etching, or electrochemical machining on the fifth generation TFT LCDs. The selective removal of microstructure layers from the color filter surface of an optoelectronic flat panel display, as well as complete removal of the ITO thin-films, RGB layer, or resin black matrix (BM) layer from the substrate is possible. Individual defective film layers can be removed, or all films down to the Cr layer or bare glass can be completely eliminated. Experimental results demonstrate that defective ITO thin-films, RGB layers, or the resin BM layer can now be recycled with a great precision. When the ITO or RGB layer proves difficult to remove, excimer light can be used to help with removal. During this recycling process, the use of 225 nm excimer irradiation before chemical etching, or electrochemical machining, makes removal of stubborn film residues easy, effectively improving the quality of recycled color filters and reducing fabrication cost.

Evaluating the treatment of E-waste──a case study of discarded refrigerators

Disassembly and recycling of E-waste creates a series of environmental problems. The selection of a technologically reliable, environmentally friendly, economically affordable and socially acceptable recycling technology for E-waste is a significant question. This study establishes a Monte-Carlo mathematical model of cost minimization, given the constraints of environmentally sound handling of the e-waste, in the context of Crystal Ball risk assessment and evaluation software. By following the streams of the different treatment processes, which consist of various technologies including disassembly, recycling and disposal, the econom-ics of various possibilities were identified and the optimal recycling technology proposed. The key factors of the proposed scenarios were determined by using sensitivity analysis. The results of this study show that, for discarded refrigerators, the operating life span plays the key role. The model supports maintenance and resale of the short lived refrigerators. For the longer lived refrigerators material recycling is recommended by the model. Sensitivity analysis shows that purchase cost, plastic sale price, condenser sale price and disassembly costs are the main effects. This study provides a significant technical support for policy making in E-waste management.

CH4 emission and recovery from Municipal Solid Waste in China

Methane (CH 4) is an important greenhouse gas and a major environmental pollutant, second only to carbon dioxide (CO 2) in its contribution to potential global warming. In many cases, methane emission from landfills otherwise emitted to the atmosphere can be removed and utilized, or significantly reduced in quantity by using cost effective management methods. The gas can also be used as a residential, commercial, or industrial fuel. Therefore, emission reduction strategies have the potential to become low cost, or even profitable. The annual growth rate of Municipal Solid Waste (MSW) output in China is 6.24%, with the highest levels found in South China, Southwest China and East China. Cities and towns are developing quickly in these regions. MSW output was only 76.36 Mt in 1991 and increased to 109.82 Mt in 1997, registering an average increase of 43.8%. In China, methane emission from landfills also increased from 5.88 Mt in 1991 to 8.46 Mt in 1997; so the recovery of methane from landfills is a profitable project.

Integration of Low-level Waste Heat Recovery and Liquefied Nature Gas Cold Energy Utilization

Two novel thermal cycles based on Brayton cycle and Rankine cycle are proposed, respectively, which integrate the recovery of low-level waste heat and Liquefied Nature Gas （LNG） cold energy utilization for power generation. Cascade utilization of energy is realized in the two thermal cycles, where low-level waste heat,low-temperature exergy and pressure exergy of LNG are utilized efficiently through the system synthesis. The simulations are carried out using the commercial Aspen Plus 10.2, and the results are analyzed. Compared with the conventional Brayton cycle and Rankine cycle, the two novel cycles bring 60.94% and 60% in exergy efficiency, respectively and 53.08% and 52.31% in thermal efficiency, respectively.

A unified graphical method for integration of hydrogen networks with purification reuse

Introducing purifiers into hydrogen network can enhance the recovery and reuse of hydrogen in refineries, further reducing the consumption of fresh hydrogen. Based on previous graphical methods, this work proposes a simple and unified graphical method for integration of hydrogen networks with purification processes. Scenarios with different hydrogen concentrations of purified product can be analyzed by the unified procedure. As a result, the maximum hydrogen saved by purification reuse can he identified and the corresponding purification process can be optimized, The proposed method is easy and non-iterative, and it is valid to purification processes with any feed concentration. A conventional hydrogen network is analyzed to test the effectiveness of the proposed method.

A Novel Process for Natural Gas Liquids Recovery from Oil Field Associated Gas with Liquefied Natural Gas Cryogenic Energy Utilization

A novel process to recovery natural gas liquids from oil field associated gas with liquefied natural gas (LNG)cryogenic energy utilization is proposed.Compared to the current electric refrigeration process,the proposed process uses the cryogenic energy of LNG and saves 62.6%of electricity.The proposed process recovers ethane, liquid petroleum gas(propane and butane)and heavier hydrocarbons,with total recovery rate of natural gas liquids up to 96.8%.In this paper,exergy analysis and the energy utilization diagram method(EUD)are used to assess the new process and identify the key operation units with large exergy loss.The results show that exergy efficiency of the new process is 44.3%.Compared to the electric refrigeration process,exergy efficiency of the new process is improved by 16%.The proposed process has been applied and implemented in a conceptual design scheme of the cryogenic energy utilization for a 300 million tons/yr LNG receiving terminal in a northern Chinese harbor.

Recovery of antimony from antimony-bearing dusts through reduction roasting process under CO–CO_2 mixture gas atmosphere after firstly oxidation roasted

This paper mainly investigated the antimony recovery from antimony-bearing dusts through reduction roasting process after the dust firstly oxidation roasted.CO–CO2 mixture gas was used as reducing agent,and the antimony-containing phase was reduced into Sb4O6,volatilized into smoke,and finally recovered through the cooling cylinder.The antimony recovery rate increased from 66.00 wt%to 73.81 wt%in temperature range of 650 to 800°C,and decreased with temperature increased further to 900°C due to the reduction of Sb4O6 to the nonvolatile Sb.Similarly,the CO partial pressure also played a double role in this test.Under optimized conditions of roasting temperature of 800°C,CO partial pressure of 7.5 vol%and roasting time of 120 min,98.40 wt%of arsenic removal rate and 80.40 wt%antimony recovery rate could be obtained.In addition,the“As2O3”product could be used for preparing ferric arsenate which realized the harmless treatment of it.

Turning Industrial Residues into Resources： An Environmental Impact Assessment of Goethite Valorization

Goethite is a metals-rich residue that occurs during zinc production. The feasibility of metal recovery from goethite has been demonstrated, but is not economically viable on an industrial scale. Therefore, goethite is landfilled with considerable economic costs and environmental risks. The goal of this study is to evaluate the environmental performance of a new valorization strategy for goethite residues from zinc production, with the aims of： ① recovering the valuable zinc contained in the goethite and ② avoiding the landfilling of goethite by producing a clean byproduct. The presented goethite valoriza- tion strategy consists of a sequence of two processes： ① plasma fuming and ② inorganic polymerization of the fumed slag. Plasma fuming recovers the valuable metals by fuming the goethite. The metals-flee fumed slag undergoes a process of inorganic polymerization to form inorganic polymers, that can be used as a novel building material, as an alternative to ordinary Portland cement （OPC）-based concrete. Life- cycle assessment （LCA） is used to compare the environmental performance of the inorganic polymer with the environmental performances of equivalent OPC-based concrete. The LCA results show the tradeoff between the environmental burdens of the fuming process and inorganic polymerization versus the environmental benefits of metal recovery, OPC concrete substitution, and the avoidance of goethite land- filling. The goethite-based inorganic polymers production shows better performances in several environ- mental impact categories, thanks to the avoided landfilling of goethite. However, in other environmental impact categories, such as global warming, the goethite valorization is strongly affected by the high-energy requirements of the plasma-fuming process, which represent the environmental hotspots of the proposed goethite recycling scheme. The key elements toward the sustainability of goethite valorization have been identified, and include the use of a clean electric mix, more effective control of the fumed gas emissions, and a reduced use of fumed slag through increased efficiency of the inorganic polymerization process.

Direct oxygen removal from titanium aluminide scraps by yttrium reduction

Titanium aluminum(TiAl)scraps with a high oxygen content were treated with yttrium(Y)in a liquid chemical deoxidization process for recycling.The Gibbs free energy and the equilibrium constant of the deoxidization reaction were calculated,and the effects of the yttrium content and the system pressure on the oxygen content in the product were determined.The results showed that the oxygen in TiAl scraps could be removed by yttrium,and the oxygen content of the deoxidized TiAl scraps had only 10%of the original content after deoxidization.Furthermore,the oxygen content of the deoxidized TiAl scraps was decreased with the increase of yttrium addition.The higher the chamber pressure,the greater the oxygen content in the final TiAl alloys.These results were consistent with calculated values.The microstructure of the deoxidized alloys was akin to that of the original material;however,Y_(2)O_(3) particles were observed in the deoxidized alloys.

Efficiency analysis of trilateral-cycle power systems for waste heat recovery-to-power generation

Numerous innovative heat recovery-to-power technologies have been resourcefully and technologically exploited to bridge the growing gap between energy needs and its sustainable and affordable supply.Among them,the proposed trilateral-cycle(TLC) power system exhibits high thermodynamic efficiency during heat recovery-to-power from low-to-medium temperature heat sources.The TLCs are proposed and analysed using n-pentane as working fluid for waste heat recovery-to-power generation from low-grade heat source to evaluate the thermodynamic efficiency of the cycles.Four different single stage TLC configurations with distinct working principles are modelled thermodynamically using engineering equation solver.Based on the thermodynamic framework,thermodynamic performance simulation and efficiency analysis of the cycles as well as the exergy efficiencies of the heating and condensing processes are carried out and compared in their efficiency.The results show that the simple TLC,recuperated TLC,reheat TLC and regenerative TLC operating at subcritical conditions with cycle high temperature of 473 K can attain thermal efficiencies of 21.97%,23.91%,22.07% and 22.9%,respectively.The recuperated TLC attains the highest thermodynamic efficiency at the cycle high temperature because of its lowest exergy destruction rates in the heat exchanger and condenser.The efficiency analysis carried out would assist in guiding thermodynamic process development and thermal integration of the proposed cycles.

Study on Immobilized Algal Cells for Treatment and Recycle of Refinery Wastewater

Compared to the algal oxidation pond, treatment of wastewater using the immobilized algal cell technology has excellent effect, which not only can effectively avoid the disadvantage of oxidation pond, but can also remarkably improve the efficiency of treating system and the effluent quality. When the treating system operates umder an optimal control conditions, such as a 55% loading rate, an illumination intensity of 2500-3500 lux and a hydraulic residence time of 4 hours, the COD and ammonia nitrogen removal can reach 90%. Water after deep treatment can comply with the requirement of the refinery for the quality of recycled water.

Emergy analysis of ecosystem at reclamation area

The emergy theory was used to analyze the emergy structure of the ecosystem at reclamation area in order to find the problem existed in the reclamation ecosystem through compared with the modern agriculture.The research results show that the propor- tion of assistant emergy input into the system is higher which indicate that the productivity of reclamation land has not resumed and a lot of assistant emergy needed to improve the productivity.The ecosystem overly depend on chemical fertilizer,which is bad to agricul- tural ecosystem;the agricultural ecosystem in reclamation area belongs to traditional agriculture because the main power come from manpower and the usage of organic ferti- lizer is little,through compare the index of emergy with modern agriculture,the value of EyR and ED in reclamation area is less than the modern agriculture.

Informal Sector Solid Waste Collection and Recycling in Zaria, Nigeria

Management of solid wastes has become a critical issue for almost all the major cities in Nigeria. Although the responsibility for solid waste management remains primarily with the local government councils, several other stakeholders are playing significant roles in the system. In Zaria, the scavengers, waste pickers and collectors eke out a living by collecting waste and selling recyclable materials out of the urban solid wastes. The paper utilized data collected using questionnaire survey, in-depth discussion guides and open-ended interviews to examine the socio-economic characteristics, the functions, aspects of involvement of children, the working conditions and problems of waste collectors and pickers in Zaria. The paper found that the sector is the only means of solid waste collection in several sections of the town and is a source of livelihood for the poor. The activities help in realizing the aim of modern waste management, that is to move up the solid waste management hierarchy by reducing reliance on disposal and increasing recycling. In spite of these important functions, informal waste collection and recycling are associated with problems of unsanitary conditions and health risks to the communities and the waste collectors. Recommendations have been made to integrate the informal sector into the formal waste management by incorporating the employment needs of the urban poor and enhancing the efficiency of government in addressing the main problems.