便携式分析仪器在环境空气、水质监测中的应用进展

当前环境问题和环境质量受到广泛关注,在环境质量监测工作中,便携式分析仪器因其操作简便快速、可移动、准确度高和精密度好等优点,已得到广泛应用。本文综述了便携式分析仪器在环境空气、水质监测中的应用进展,并对今后的发展进行了展望。

地表水水质监测的现状及对策分析

我国是水资源大国,拥有28124亿m^(3)的水资源,这些水资源中96%为地表水。但是,从现阶段的实际情况看,城市化进程不断推进,工业和农业快速发展,这些都大幅提高了废水的排放量,造成地表水的严重污染,使部分河流始终处于不同程度的污染状态。在这种情况下,需要进行水质监测,便于掌握地表水环境质量状况和变化趋势。所以,相关部门及人员必须认识到地表水水质监测的重要性,及时对水质监测现状进行分析,对其中存在的问题进行总结,优化水质监测方案,为地表水水质监测质量的提高创造有利条件。本文将围绕地表水水质监测现状及对策进行详细分析。

Electrolyte engineering for optimizing anode/electrolyte interface towards superior aqueous zinc-ion batteries:A review

Aqueous zinc-ion batteries(AZIBs) are promising candidates for the large-scale energy storage systems due to their high intrinsic safety,cost-effectiveness and environmental friendliness.However,issues such as dendrite growth,hydrogen evolution reaction,and interfacial passivation occurring at the anode/electrolyte interface(AEI) have hindered their practical application.Constructing a stable AEI plays a key role in regulating zinc deposition and improving the cycle life of AZIBs.The fundamentals of AEI and the challenges faced by the Zn anode due to unstable interfaces are discussed.A comprehensive summary of electrolyte regulation strategies by electrolyte engineering to achieve a stable Zn anode is provided.The effectiveness evaluation techniques for stable AEI are also analyzed,including the interfacial chemistry and surface morphology evolution of the Zn anode.Finally,suggestions and perspectives for future research are offered about enabling a durable and stable AEI via electrolyte engineering,which may pave the way for developing high-performance AZIBs.

Effect of inorganic salt impurities on seeded precipitation of silica hydrate from sodium silicate solution

To clarify the precipitation of silica hydrate from the real desilication solutions of aluminosilicate solid wastes by adding seeds and improve integrated waste utilization,the seeded precipitation was studied using synthesized sodium silicate solution containing different inorganic salt impurities.The results show that sodium chloride,sodium sulfate,sodium carbonate,or calcium chloride can change the siloxy group structure.The number of high-polymeric siloxy groups decreases with increasing sodium chloride or sodium sulfate concentration,which is detrimental to seeded precipitation.Calcium chloride favors the polymerization of silicate ions,and even the chain groups precipitate with the precipitation of high-polymeric sheet and cage-like siloxy groups.The introduced sodium cations in sodium carbonate render a more open network structure of high-polymeric siloxy groups,although the carbonate ions favor the polymerization of siloxy groups.No matter how the four impurities affect the siloxy group structure,the precipitates are always amorphous opal-A silica hydrate.

Dynamic response characteristics of muddy sandstone in pumped storage mine under action of high-stress dynamic disturbance

During the construction and operation of the abandoned mine pumped storage power station,the underground space surrounding rock body faces the complex stress environment under the action of mining disturbance,frequent pumping,water storage and other dynamic disturbances.The stability of the abandoned mine surrounding rock body is the basis for guaranteeing the safety and effectiveness of water storage in the underground space of the abandoned mine.By considering the two main factors of different stress levels and disturbance amplitudes,the mechanical properties,damage characteristics and acoustic emission characteristics of the abandoned mine perimeter rock body under dynamic disturbance were investigated using a creep-disturbed dynamic impact loading system.The experimental results show that:1)The stress level is considered to be the major contributing factor of the failure of muddy sandstone,followed by the amplitude of the disturbances;2)The time required for the destruction of muddy sandstone decreases with the increase of amplitude.When the stress level is 80%,the sandstone specimens have a decreasing number of cycles as the disturbance amplitude increases.The disturbance amplitude is sequentially increased from 4 MPa to 5,6,7,and 8 MPa,the number of cycles required for specimen destruction decreases significantly by 96.71%,99.13%,99.60%,and 99.93%,respectively;3)Disturbance amplitude and stress level have a significant effect on muddy sandstone damage and damage occurs only after a certain threshold is reached.With the increase of stress level and disturbance amplitude,the macroscopic damage of muddy sandstone is mainly conical,with obvious flake spalling and poor damage integrity;4)According to the time-dependent changes in AE energy and ringing counts,the acoustic emission activity during the failure process could be divided into three phases,namely,weakening period,smooth period,and surge period,corresponding to the compaction phase,elastic rise phase and post-peak damage phase.The research results are of reference significance for the damage evolution analysis of muddy sandstone under dynamic disturbance and the safety and stability of abandoned mine perimeter rock body.

水利工程设计中数字化技术与智能监测系统的应用

本研究探讨了数字化技术和智能监测系统在水利工程设计中的应用。研究的主论点集中在利用无人机(UAV)和物联网(IoT)技术进行实时水质与水位监测。实验中,我们使用了配备了多重传感器的UAV,与基于LoRaWAN网络的物联网设备联合工作。数据显示,在这一技术的应用下,水位监测的准确率达到了98.7%,而水质检测的准确性也提升到了95.4%。该系统不仅提高了数据准确性,而且降低了人力和物力消耗。通过机器学习算法,这些数据还能用于预测潜在的水资源问题,从而更高效地进行水利工程的规划和治理。

Water quality changing trends of the Miyun Reservoir

In order to simulate changes in the water quality of the Miyun Reservoir dueto continuous descent of surface water level, a 3-D ecological hydrodynamic model was developedthrough coupling the water quality analysis simulation program (WASP) with the environmental fluiddynamics code (EFDC). The model was then calibrated and verified. Four scenarios (S1, S21, S22 andS23) were simulated using the model. Results show that the water quality of the Miyun Reservoirunder conditions of low surface water level is apparently affected by different amounts of inflowand different total phosphorus (TP) loadings. The chlorophyll-a concentration might exceed 10 μg/Lin many areas of the Miyun Reservoir (This limitative value is seen as a critical value ofeutrophication) when large loadings of TP enter due to the amount of inflow increasing. Results ofscenario S23 indicate that control of TP loadings can decrease chlorophyll-a concentrationeffectively, and the water quality of the Miyun Reservoir will improve or retain its status quo.

Water Quality Evaluation Index System for Freshwater Aquaculture Pond

[Objective] The aim was to establish the water quality evaluation index system for freshwater aquaculture pond.[Method] The expert survey,DELPHI,field research and other methods were used.Based on the analysis of factors influencing water quality of freshwater aquaculture pond,and the importance degree of 14 factors influencing water quality of freshwater aquaculture pond was ordered.Then,five factors were selected as index to establish the water quality evaluation index system of freshwater aquaculture with the determination for thresholds of these factors.[Result] The importance degree of water quality of freshwater aquaculture pond showed an order of Dissolved oxygenpHPhytoplankton biomassSecchi depthTotal NitrogenZooplankton biomassWater temperatureBiochemical Oxygen DemandWater colorSalinityTotal hardness;according to the value of importance degree,the dissolved oxygen,pH,secchi depth,phytoplankton biomass and total nitrogen these five factors were selected as the index system of water quality evaluation of pond.The level of water quality of freshwater aquaculture pond was divided into five,and the tolerance range of fish to each index was obtained by expert observation.[Conclusion] This study had provided a scientific basis for water quality evaluation system of freshwater aquaculture pond.

Integrated assessment of sea water quality based on BP artificial neural network

In order to carry out an integrated assessment of sea water quality objectively, this paper based on the concept and principle of artificial neural network, generated appropriate training samples for BP artificial neural network model through the method of producing samples to the concentration of various pollution index of sea water quality from the viewpoint of threshold, established the BP artificial neural network model of sea water quality assessment using multi-layer neural network with error back-propagation algorithm. This model was used to assess water environment and obtain sea water quality categories of offshore area in Bohai Bay through calculating. The calculations shown that pollution index in river＇s wet season was higher than that in dry season from 2004 to 2007, and the pollution was particularly serious in 2005 and 2006, but a little better in 2007. The assessed results of cases shown that the model was reasonable in design and higher in generalization, meanwhile, it was common, objective and practical to sea water quality assessment.

Design and Implementation of Aquaculture Pond Water Quality Assessment System Based on Fuzzy Mathematics

The aquaculture pond water quality was taken as research objects,based on the general analysis of factors influencing the pond water quality,the system of index estimation and assessment standard were established after sorting by importance of the factors by means of Delphi and expert investigation.In this study,index weight was confirmed according to the importance of the factors and relative membership grade of the measured values,thus and the fuzzy comprehensive evaluation model of aquaculture pond water quality was constructed,and the fuzzy comprehensive evaluation system of freshwater aquaculture pond water quality was designed and implemented.The application of this system in the assessment of aquaculture pond water quality by a company had achieved better result.

Application of Fuzzy Comprehensive Evaluation Method Based on Entropy Weight to Evaluate Pond Water Quality

[Objective] This study was to provide references for the evaluation of water quality in aquaculture ponds by evaluating the pond water quality using fuzzy comprehensive evaluation method based on entropy weight. [Method] The fuzzy compre- hensive evaluation method based on entropy weight was used to evaluate the water quality in the ponds with Ukraine scale carp （Cyprinus carpio） as the main cultivated fish. The average size of the fish was 71.4 g/ind, and totally three groups of pond were set with the population density of 6 000, 9 000, 12 000 ind/hm2. [Result] According to the GB3838-2002 Environmental Quality Standards for Surface Water of China, the water quality of 6 000 ind/hm2 group was Grade I, and the water quality of 9 000 and 12 000 ind/hm2 were Grade V. [Conclusion] With the increasing of feeding density, the pond water quality would worsen, however, there is no difference on water quality between 9 000 and 12 000 ind/hm2 groups.

Early-warning of Mud Expansion in Sewage Treatment Plants by A/O Technology

Early-warning is an effective way to control mud expansion in sewage treatment plants with A/O technology. In the research, warning indices and technology of active mud were explored and it is concluded that bacteria growth in mud can be obtained by observation of mud appearance and microorganism variety, and measurement of the number of filamentous bacteria, water quality, mud load and age, dissolved oxygen, temperature and pH. Furthermore, filamentous bacteria in mud can be researched through fluorescence in situ hybridization, PCR-temperature denaturing gradient gel electrophoresis and PCR-single-stranded conformation polymorphism in order to determine the characters and states of active mud to achieve early warning of mud expansion.

Testing and analysis of rainwater quality in Shenyang

To explore the influence of rainwater quality on rain utilization projects the rainwater of building roofs community runoff and municipal outlets which were taken from Hunnan New District of Shenyang was detected and analyzed for one year. The results show that the main pollutants affecting the quality of the rainwater are chemical oxygen demand COD and suspended solids SS which is especially obvious at the beginning of rainfall. With the duration of the rainfall water quality improves.The contents of COD and SS in municipal outlets are the highest which are 167 to 249 mg/L and 119 to 332 mg/L respectively. The contents of COD and SS are 27 to 85 and 106 to 269 mg/L in community runoff 15 to 80 and 50 to 153 mg/L in the rainwater of building roofs.NH4＋-N concentrations of the three sampling sites are 1.7 to 5.2 3.7 to 18.2 and 5.2 to 25.6 mg/L.

Macrobenthos Community Structure and Its Relations With Environmental Factors in Three Reservoirs in Tianjin

[Objective] The aim was to research macrobenthos community structure and its relations with environmental factors in three reservoirs. [Method] Benthic diversity and water quality of Yuqiao Reservoir, Beidagang Reservoir and Er- wangzhuang Reservoir were investigated in May, July and September 2011, respec- tively. []Result] Of all the 14 sampling sites, 22 species of macroinvertebrates were collected, totally, which included 6 species of aquatic insects, 7 species of Mollusca, 2 species of Crustacean, 7 species of Oligochaeta. The species of macroinverte- brates during May, July and September in Yuqiao reservoir were 11, 8 and 10, respectively. The dominant species were Chironomus sinicus, and Monopylephorus limosus. The average density and biomass of the macrobenthos were 132.43 ind./m2 and 50.09 g/m2. Yuqiao reservoir was mostly at status of premediate polluted, according to the Margalef index, Shannon index and Pielou index. The species of during May, July and September in Beidagang reservoir were 5 5 and 5, respectively. The dominant species were Chironomus sinicus, Penaeus vannamei. The average density and biomass of the macrobenthos were 218 ind./m2 and 2.70 g/m2. Beidagang reservoir was mostly at status of heavy polluted, accord- ing to the Margalef index, Shannon-wiener index, Pielou index. The species of during May, July and September in Erwangzhuang reservoir were 3, 5 and 5, respectively. The dominant species were Monopylephorus limosus, Chi- ronomus sinicus. The average density and biomass of the macrobenthos were 104 ind/m2 and 0.20 g/m2. Erwangzhuang reservoir was mostly at status of intermediate polluted, according to the Margalef index, Shannon index, Pielou index. The density of zoobenthos in Yuqiao Reservoir was positively significantly correlated with TP （P〉 0.05）, negatively correlated with NH4＋-N （P〉0.05）, positively correlated with COD （P〈 0.01）, not significantly correlated with other environment factors （P〉0.05）. There was no significant correlation between biomass of zoobenthos and environment factors. The density of zoobenthos in Beidagang Reservoir with NH4＋-N was positively signif- icantly correlated （P〈0.05）, not significantly correlated with other aquatic environment factors （P〉0.05）. There was no significant correlation between biomass of zoobenthos and environment factors. The density of zoobenthos in Erwangzhuang Reser- voir with NO3-N was positively significantly correlated （P〈0.05）, not significant cor- related with other aquatic environment factors （F〉0.05）. The biomass of zoobenthos in Erwangzhuang Reservoir with NH4＋-N was positively significantly correlated （P〈 0.05）, not significant correlated with other aquatic environment factors （P〉0.05）. [Conclusion] It is indicated that this three reservoirs were all eutrophied and polluted, and the eurephication extent change of water in three reservoirs is as follows： Beidagang reservoir〉Erwangzhuang reservoir〉Yuqiao reservoir.

Comprehensive evaluation of water quality parameters in Tianjin Dagu Dainage Canal

In this paper, some indices of sulfide, organic carbon, oil and heavy metals （copper, lead, zinc, cadmium, mercury, arsenic and chromium） in the sediments from Dagu Dainage Canal at the Bohai Bay during four seasons in 2012 - 2013 are selected, and Water Quality Pollution Index （API） is applied to evaluate water quality indices, aiming for the systematic evaluation of the water quality of Dagu Dainage Canal. The results showed that four stations of D3, D6, D7and D9 for S2 had the type Ⅱand Ⅲ of water; others had the type Ⅰ ; the total level of TOC, TPH, Cu, Pb, Zn, Cd, Hg, As and Cr were type Ⅰ, Ⅳ, Ⅱ, Ⅴ, Ⅱ, Ⅴ, Ⅲ, Vand Ⅴ. Water Quality Pollution Index （API） was 3.28, which illustrated Dagu Dainage Canal was in the state of contamination and the degree of pollution exceeded the standard functional areas.

Environment Quality Assessment of Marine Fishery in Zhujiajian Sea Area in Zhoushan

Based on the monitoring data on Zhujiajian sea area in Zhoushan in De- cember 2015, the assessment and analysis of seawater quality of this sea area were carried out according to relevant environmental quality standards. The contents of heavy metals and inorganic nitrogen were lower than the water quality standards, and the main pollutant was phosphate （PO4-P）.

Importance of Proficiency Testing in Water Quality Monitoring

The monitoring data is undoubtedly important to the water quality monitor- ing department. The proficiency testing is an important way to improve the monitor- ing capacity and enhance the quality management of laboratories. It plays an impor- tant role in ensuring the accuracy, integrity and comparability of monitoring data. In this paper, the positive role of proficiency testing in the water quality monitoring was analyzed. In addition, how to improve the water quality monitoring capacity and the quality management level of laboratories through the proficiency testing was also discussed.

Effects of Social and Economic Development of Regions Surrounding Chao Lake on Water Quality Change of Chao Lake

The research analyzed social and economic development around Chao Lake as well as changes of water quality in Chao Lake and explored the relation- ships of local population and GDP with water chemical oxygen demand （COD）, total phosphorus （TP）, total nitrogen （TN）, chlorophyll and eutrophication index. The re- sults showed that population around Chao Lake and GDP kept growing from 2001 to 2013, and water quality was improving. In addition, correlation analysis indicated that except of water eutrophication, GDP and population showed inverse correlation with other indices, demonstrating that water quality has been effectively controlled in Chao Lake recently.

Controlling effects of forest belts on non-point source pollution of agricultural lands in Taihu Lake area, China

Taihu Lake area is one of the most developed areas in agricultural production. Application of fertilizers and pesticides in large quantities greatly aggravate environmental pollution of this area, and water pollution has worsened to an unbearable condition. Two sampling farms (respectively 1 hm2) under rape-rice rotation and wheat-rice rotation were selected as studied ecosystem and a 5-yr-old Poplar forest and 8-yr-old Metasequoia forest were chosen in the selected areas. By collecting samples of Nitrogen, Phosphorus in water, crops and underground of forest, the transfer and loss of N and P (main water pollutants) in faming ecosystem were studied, and the effects of forest belts on non-point source pollution of agricultural lands was analyzed. The results indicated that the transfer and loss of N and P vary with means of rotation, types of crops and the amount of fertilizer application. Buffering forest belts betweens farmlands and ditches can effectively stop and purify such elements as N and P in soil runoffs, thus controlling non-point source pollution of agricultural lands. When the width ratio of farmland to forest belt is 100 to 40, 50.05% losing N, 29.37% losing P can be absorbed by forest under rape-rice rotation and 30.98% N, 86.73% P can be absorbed by forest under wheat-rice rotation. When the width ratio of farmland to forest belt is 150 to 40, 33.37% losing N, 19.58% losing P can be absorbed by the forest under rape-rice rotation, and under wheat-rice rotation 20.65% lost N and 57.82% lost P can be absorbed. There is only some purification effect when the width ration of farmland to forest belt is 200 to 40. Based on model of buffering forest belts, the width ratio of farmland to forest is determined between 100 to 40 and 150 to 40, because it not only can purify water, but also occupy less farmland. It is suggested that Poplars, with the characteristics of fast-growing and high value, are suitable to be planted as shelter-forest in Taihu Lake Watershed.

Study of the water quality in Liaohe Park based on the model of GAM

This paper assesses the quality of Daliao river through Liaohe Park based on the model of GAM for water quality analysis and the monitoring data from 2006 to 2011.The results showed that the value of pH per year tended to the average; the DO in 2011 was much higher than that in other years, and the DO in 2006 .was lower than the standard value; the quality risk in six sections was still higher than the standard value in 2007, which was caused by the high concentrations of COD. However, the value of ammonia nitrogen changes was only 40% related to DO and COD.