The application of computer in the quantitative analysis chemistry experiment is a chemistry experiment teaching applications software, developed by Visual Basic （6.0）, based on the content of quantitative analysis ...The application of computer in the quantitative analysis chemistry experiment is a chemistry experiment teaching applications software, developed by Visual Basic （6.0）, based on the content of quantitative analysis chemistry experiment of chemistry major in higher institute. This software has the function of the automatic processing the experimental data, the automatic generation of test report copies, and the automatic evaluation of students＇ experimental results, which solve the reliability, objectivity and accuracy problems of the students＇ experiment data processing and evaluation, and avoid interference with human factors. The software has the characteristic of the easy installation, the easy operation, the strong practicability, pertinence, the systematicness and the running stability, so it provides a platform in the quantitative analysis chemistry experiment for the students＇ assessment system of automatic processing, and it has a high popularization value. The project＇s technical route design is reasonable, the research method is correct, and the experimental data processing results are reliable, which has reached the leading domestic level in the quantitative analysis chemistry experiment teaching field of computer data processing. And this project has been through the achievements appraisal of Gansu Provincial Sci. ＆ Tech. Department.展开更多
A novel thermal-assisted ultra-violet(UV) photocatalysis digestion method for the determination of total phosphorus(TP) in water samples was introduced in this work. The photocatalytic experiments for TP digestion wer...A novel thermal-assisted ultra-violet(UV) photocatalysis digestion method for the determination of total phosphorus(TP) in water samples was introduced in this work. The photocatalytic experiments for TP digestion were conducted using a 365 nm wavelength UV light and Ti O2 particles as the photocatalyst. Sodium tripolyphosphate and sodium glycerophosphate were used as the typical components of TP and the digested samples were then determined by spectrophotometry after phosphomolybdenum blue reaction. The effects of operational parameters such as reaction time and temperature were studied for the digestion of TP and the kinetic analysis of two typical components was performed in this paper. The pseudo-first-order rate constants k of two phosphorus compounds at different temperatures were obtained and the Arrhenius equation was employed to explain the effect of temperature on rate constant k. Compared with the conventional thermal digestion method for TP detection, it was found that the temperature was decreased from 120 °C to 60 °C with same conversion rate and time in this thermal-assisted UV digestion method, which enabled the digestion process work at normal pressure. Compared with the individual ultra-violet(UV) photocatalysis process, the digestion time was also decreased from several hours to half an hour using the thermal-assisted UV digestion method. This method will not lead to secondary pollution since no oxidant was needed in the thermal-assisted UV photocatalysis digestion process, which made it more compatible with electrochemical detection of TP.展开更多
This study aims the physico-chemical characterization of surface water of the Bir M＇Cherga reservoir and its effluents which are located in Zaghouan governorate of Tunisia. It required measures in situ of physicochem...This study aims the physico-chemical characterization of surface water of the Bir M＇Cherga reservoir and its effluents which are located in Zaghouan governorate of Tunisia. It required measures in situ of physicochemical parameters and chemical analysis at laboratory of major element and nutritive salts. The results of this study revealed the presence of pollutants in the Miliane river at El Fahs area and the eutrophication of water in the Bit M＇Cherga reservoir. According to the classification of Stuyfzand and Piper, water in the wadis of Melah, Hdada, Miliane and Boudebbane respectively is brackish, salty, extremely hard, chlorinated, sulphated, calcic, and magnesic. Water in the Bir M＇Cherga reservoir is characterized by calcic facies chlorinated sulphated and sodic. Thus, the Bir M＇Cherga reservoir presents a worrying situation and a risk of qualitative degradation of its water.展开更多
In this study, groundwater quality and water features of Diyarbakir urban basalt aquifer which contains Baglar, Kayapmar, Sur and Yenisehir residential areas aimed to be determined. At this location, water wells opene...In this study, groundwater quality and water features of Diyarbakir urban basalt aquifer which contains Baglar, Kayapmar, Sur and Yenisehir residential areas aimed to be determined. At this location, water wells opened for drinking water and irrigation water are used in the agricultural field. Therefore, in the study area, which opened in water samples taken from water wells were examined. It was reformed in the field, water samples were taken from the predrilled water wells. Water wells in the same coordinates are determined by Garmin etrex 30 handheld GPS system. Chemical analysis of water samples taken in the laboratory was made. The wells water＇s pH, Electrical Conductivity （EC） and Dissolved Solids （TDS） features were acquired by Portable Hanna HI 98125 pH/EC/TDS/℃ meter device at the field. At this study, basalt aquifer features are considered, and water quality and water chemical properties were determined in Diyarbakir city centre, pH, EC and TDS values of the water samples taken on site and those water chemical analyses were measured in the laboratory. Then, they were modelled by using ARC INFO 10.2.1 GIS programme and geostatistical analyst extension tool. At the end of this process, thematic map of Diyarbakir＇s basalt aquifer pH, EC and TDS were produced.展开更多
文摘The application of computer in the quantitative analysis chemistry experiment is a chemistry experiment teaching applications software, developed by Visual Basic （6.0）, based on the content of quantitative analysis chemistry experiment of chemistry major in higher institute. This software has the function of the automatic processing the experimental data, the automatic generation of test report copies, and the automatic evaluation of students＇ experimental results, which solve the reliability, objectivity and accuracy problems of the students＇ experiment data processing and evaluation, and avoid interference with human factors. The software has the characteristic of the easy installation, the easy operation, the strong practicability, pertinence, the systematicness and the running stability, so it provides a platform in the quantitative analysis chemistry experiment for the students＇ assessment system of automatic processing, and it has a high popularization value. The project＇s technical route design is reasonable, the research method is correct, and the experimental data processing results are reliable, which has reached the leading domestic level in the quantitative analysis chemistry experiment teaching field of computer data processing. And this project has been through the achievements appraisal of Gansu Provincial Sci. ＆ Tech. Department.
基金Supported by the National Natural Science Foundation(61372053)the National High Technology Research and Development Program(2012AA040506)
文摘A novel thermal-assisted ultra-violet(UV) photocatalysis digestion method for the determination of total phosphorus(TP) in water samples was introduced in this work. The photocatalytic experiments for TP digestion were conducted using a 365 nm wavelength UV light and Ti O2 particles as the photocatalyst. Sodium tripolyphosphate and sodium glycerophosphate were used as the typical components of TP and the digested samples were then determined by spectrophotometry after phosphomolybdenum blue reaction. The effects of operational parameters such as reaction time and temperature were studied for the digestion of TP and the kinetic analysis of two typical components was performed in this paper. The pseudo-first-order rate constants k of two phosphorus compounds at different temperatures were obtained and the Arrhenius equation was employed to explain the effect of temperature on rate constant k. Compared with the conventional thermal digestion method for TP detection, it was found that the temperature was decreased from 120 °C to 60 °C with same conversion rate and time in this thermal-assisted UV digestion method, which enabled the digestion process work at normal pressure. Compared with the individual ultra-violet(UV) photocatalysis process, the digestion time was also decreased from several hours to half an hour using the thermal-assisted UV digestion method. This method will not lead to secondary pollution since no oxidant was needed in the thermal-assisted UV photocatalysis digestion process, which made it more compatible with electrochemical detection of TP.
文摘This study aims the physico-chemical characterization of surface water of the Bir M＇Cherga reservoir and its effluents which are located in Zaghouan governorate of Tunisia. It required measures in situ of physicochemical parameters and chemical analysis at laboratory of major element and nutritive salts. The results of this study revealed the presence of pollutants in the Miliane river at El Fahs area and the eutrophication of water in the Bit M＇Cherga reservoir. According to the classification of Stuyfzand and Piper, water in the wadis of Melah, Hdada, Miliane and Boudebbane respectively is brackish, salty, extremely hard, chlorinated, sulphated, calcic, and magnesic. Water in the Bir M＇Cherga reservoir is characterized by calcic facies chlorinated sulphated and sodic. Thus, the Bir M＇Cherga reservoir presents a worrying situation and a risk of qualitative degradation of its water.
文摘In this study, groundwater quality and water features of Diyarbakir urban basalt aquifer which contains Baglar, Kayapmar, Sur and Yenisehir residential areas aimed to be determined. At this location, water wells opened for drinking water and irrigation water are used in the agricultural field. Therefore, in the study area, which opened in water samples taken from water wells were examined. It was reformed in the field, water samples were taken from the predrilled water wells. Water wells in the same coordinates are determined by Garmin etrex 30 handheld GPS system. Chemical analysis of water samples taken in the laboratory was made. The wells water＇s pH, Electrical Conductivity （EC） and Dissolved Solids （TDS） features were acquired by Portable Hanna HI 98125 pH/EC/TDS/℃ meter device at the field. At this study, basalt aquifer features are considered, and water quality and water chemical properties were determined in Diyarbakir city centre, pH, EC and TDS values of the water samples taken on site and those water chemical analyses were measured in the laboratory. Then, they were modelled by using ARC INFO 10.2.1 GIS programme and geostatistical analyst extension tool. At the end of this process, thematic map of Diyarbakir＇s basalt aquifer pH, EC and TDS were produced.
