Smart material and structure (SMS) is a challenging novel technique for the 21 century especially in fields of aviation and aerospace. Vibration and noise suppression smart structure is an important branch of SMS. T...Smart material and structure (SMS) is a challenging novel technique for the 21 century especially in fields of aviation and aerospace. Vibration and noise suppression smart structure is an important branch of SMS. There are several typical structures such as the cabin of an airplane, space station, the solar board of satellite and the rotor blade of a helicopter, of which the vibrations and radiation noises have bad influences on precise equipments and aiming systems. In order to suppress vibrations and noises of these structures, several algorithms are applied to the models which simulate the structures. Experiments are performed to suppress vibrations and noises by bonding sensors and actuators to the structures at the optimized locations and using computer based measurement and control systems. For the blade vibration control of a helicopter, a non contact method of signal transmission by magneto electric coupling is discussed. The experimental results demonstrate that the methods used for active control are effective.展开更多
This paper addresses the need for systematic evaluation of the station keeping systems of deepwater drilling semi-submersibles.Based on the selected drilling semi-submersible configuration, the mooring systems were an...This paper addresses the need for systematic evaluation of the station keeping systems of deepwater drilling semi-submersibles.Based on the selected drilling semi-submersible configuration, the mooring systems were analyzed and designed for a range of water depths using different mooring line materials.These were steel wire rope, polyester rope and HMPE (high modulus poly ethylene).The mooring analysis was carried out using the advanced fully coupled time domain analysis method in the computer software package HARP.Diffraction analysis was first applied to solve the hydrodynamic properties of the vessel and then the motion equations of the complete dynamic system including the drilling rig, the mooring lines and risers were developed and solved in the time domain.Applying the advanced analysis method, a matrix of mooring systems was developed for operating in water depths of 1000 m, 1500 m, and 2 000 m using various mooring materials.The development of mooring systems was conducted in accordance with the commonly adopted mooring design code, API RP 2SK and API RP 2SM.Fresh attempts were then made to comparatively evaluate the mooring system's characteristics and global performance.Useful results have been obtained in terms of mooring materials, water depths, and key parameters of mooring configurations.The results provide in-depth insight for the design and operation of deepwater mooring systems in the South China Sea environment.展开更多
Micro-scale functionally graded material(FGM)pipes conveying fluid have many significant applications in engineering fields.In this work,the thermoelastic vibration of FGM fluid-conveying tubes in elastic medium is st...Micro-scale functionally graded material(FGM)pipes conveying fluid have many significant applications in engineering fields.In this work,the thermoelastic vibration of FGM fluid-conveying tubes in elastic medium is studied.Based on modified couple stress theory and Hamilton’s principle,the governing equation and boundary conditions are obtained.The differential quadrature method(DQM)is applied to investigating the thermoelastic vibration of the FGM pipes.The effect of temperature variation,scale effect of the microtubule,micro-fluid effect,material properties,elastic coefficient of elastic medium and outer radius on thermoelastic vibration of the FGM pipes conveying fluid are studied.The results show that in the condition of considering the scale effect and micro-fluid of the microtubule,the critical dimensionless velocity of the system is higher than that of the system which calculated using classical macroscopic model.The results also show that the variations of temperature,material properties,elastic coefficient and outer radius have significant influences on the first-order dimensionless natural frequency.展开更多
In order to further improve the driving performance of ionic polymer metal composites(IPMCs),Nafion/graphene quantum dots(GQDs)hybrid membranes incorporating GQDs with various contents of 0,0.1 wt.%,0.5 wt.%,1.0 wt.%,...In order to further improve the driving performance of ionic polymer metal composites(IPMCs),Nafion/graphene quantum dots(GQDs)hybrid membranes incorporating GQDs with various contents of 0,0.1 wt.%,0.5 wt.%,1.0 wt.%,2.0 wt.%and 4.0 wt.%were fabricated by solution casting,and then IPMCs were manufactured by electroless plating.The water contents and elastic moduli of the hybrid membranes were tested.The morphology characteristics of the hybrid membranes and the IPMCs were observed,and the current,AC impedance,blocking force and displacement of the IPMCs were measured.The results show that the elastic modulus of the hybrid membranes decreases,the water content increases,and the actuation performance of the IPMCs improves significantly after the addition of GQDs.IPMC with 1.0 wt.%GQDs exhibits the best driving property.Compared with the IPMC without GQDs,the working current,ion conductivity,blocking force,and tip displacement increase by 94.67%,311.11%,53.66%,and 66.07%,respectively.These results lay a solid foundation for the preparation of IPMCs with high performance,and further broaden their applications in biomedical devices and bionic robots.展开更多
Functionalized graphene nano-sheets(FGN) of 0.01%-0.05%(mass fraction) were added to produce FGN-cement composites in the form of mortars. Flow properties, mechanical properties and microstructure of the cementitious ...Functionalized graphene nano-sheets(FGN) of 0.01%-0.05%(mass fraction) were added to produce FGN-cement composites in the form of mortars. Flow properties, mechanical properties and microstructure of the cementitious material were then investigated. The results indicate that the addition of FGN decreases the fluidity slightly and improves mechanical properties of cement-based composites significantly. The highest strength is obtained with FGN content of 0.02% where the flexural strength and compressive strength at 28 days are 12.917 MPa and 52.42 MPa, respectively. Besides, scanning electron micrographs show that FGN can regulate formation of massive compact cross-linking structures and thermo gravimetric analysis indicates that FGN can accelerate the hydration reaction to increase the function of the composite effectively.展开更多
This paper briefly introduces the application of new materials in sports and effect on sports performance, points out that development of competitive sports in the process, must pay attention to the development and ut...This paper briefly introduces the application of new materials in sports and effect on sports performance, points out that development of competitive sports in the process, must pay attention to the development and utilization of new materials, development.展开更多
Borohydrides have been recently hightlighted as prospective new materials due to their high gravimetric capacities for hydrogen storage. It is, therefore, important to under- stand the underlying dehydrogenation mecha...Borohydrides have been recently hightlighted as prospective new materials due to their high gravimetric capacities for hydrogen storage. It is, therefore, important to under- stand the underlying dehydrogenation mechanisms for further development of these ma- terials. We present a systematic theoretical investigation on the dehydrogenation mecha- nisms of the Mg2(BH4)2(NH2)2 compounds. We found that dehydrogenation takes place most likely via the intermolecular process, which is favorable both kinetically and thermo- dynamically in comparison with that of the intramolecular process. The dehydrogenation of Mg2(BH4)2(NH2)2 initially takes place via the direct combination of the hydridie H in BH4 and the protie H in NH2-, followed by the formation of Mg-H and subsequent ionic recombination of Mg-Hδ-…Hδ+-N.展开更多
Our civilization is facing an urgent need to include innovative, large-scale sources of energy and raw materials into its technological cycles. One potential source is magma, which now still inspires awe with its unpr...Our civilization is facing an urgent need to include innovative, large-scale sources of energy and raw materials into its technological cycles. One potential source is magma, which now still inspires awe with its unpredictable power of volcanic eruptions. We propose a method of remote control of lava flow which is based on a special design of a pipe which is lowered into the crater of a volcano. The magma is raised with the help of a well-known method for raising liquids, the airlift. This article includes a detailed description of the structure of the disperser that we shall use to introduce gas into the magma, explains the possible ways to manage the flow of magma, and describes the results that can be achieved. There is potential for the establishment of a whole new industry that will produce cheap electricity, hydrogen, rare metals, fertilizers and innovative construction materials.展开更多
Nanoparticles are increasingly being used to improve the friction and wear performance of polymers. In this study, we investigated the tribological behavior and energy dissipation characteristics of nano-Al_2O_3-reinf...Nanoparticles are increasingly being used to improve the friction and wear performance of polymers. In this study, we investigated the tribological behavior and energy dissipation characteristics of nano-Al_2O_3-reinforced polytetrafluoroethylenepolyphenylene sulfide(PTFE-PPS) composites in a sliding system. The tribological behaviors of the composites were evaluated under different normal loads(100–300 N) at a high linear velocity(2 m/s) using a block-on-ring tester. Addition of the nano-Al_2O_3 filler improved the antiwear performance of the PTFE-PPS composites, and the friction coefficient increased slightly. The lowest wear rate was obtained when the nano-Al_2O_3 content was 3%(volume fraction). Further, the results indicated a linear correlation between wear and the amount of energy dissipated, even though the wear mechanism changed with the nano-Al_2O_3 content, independent of the normal load applied.展开更多
Mg-x(Ti0.9 Zr0.2 Mn1.5 Cr0.3)(x=20%,30%,40%) (mass fraction) composite powders were prepared by reactive ball milling with hydrogen and their hydrogen storage properties and microstructure were investigated by XRD,SEM...Mg-x(Ti0.9 Zr0.2 Mn1.5 Cr0.3)(x=20%,30%,40%) (mass fraction) composite powders were prepared by reactive ball milling with hydrogen and their hydrogen storage properties and microstructure were investigated by XRD,SEM and pressure-composition-temperature measurement.The results show that the composites have 3.83%-5.07%hydrogen capacity at 553 K and good hydrogenation kinetics,even at room temperature.Among them,the milled Mg-30%(Ti0.9Zr0.2Mn1.5Cr0.3)composite has the highest hydrogenation kinetics as it can quickly absorb 2.1%hydrogen at 373 K,3.5%in 2 000 s at 473 K,even 3.26%in 60 s at 553 K under 3 MPa hydrogen pressure.The improved hydrogenation properties come from the catalytic effect of Ti0.9 Zr0.2 Mn1.5 Cr0.3 particles dispersed uniformly on the surface of Mg particles.展开更多
Energy harvesting is an appealing technology that makes use of the ambient energy which is otherwise wasted. Piezoelectric materials directly convert the elastic energy to the electric energy, and thus have a great ad...Energy harvesting is an appealing technology that makes use of the ambient energy which is otherwise wasted. Piezoelectric materials directly convert the elastic energy to the electric energy, and thus have a great advantage in scavenging vibrational energy for simplicity in device structure with relatively high power density. This paper provides an overview on the research of piezoelectric materials in energy harvesting in recent decades, from basics of piezoelectricity and working principle of energy harvesting with piezoelectric materials, to the progress of development of high-performance piezoelectrics including ceramics, single crystals and polymers, then to experimental attempts on the device fabrication and optimization, finally to perspective applications of piezoelectric energy harvesting(PEH). The criteria for selection of materials for PEH applications are introduced. Not only the figure of merit but also maximum allowable stress of materials are taken into account in the evaluation of their potential in achieving high energy density and output power density. The influence of the device configuration on the performance is also acknowledged and discussed. The magnitude and distribution of induced stress in the piezoelectric unit upon excitation by the vibration source play an important role in determining the output power density and can be tuned via proper design of device configuration without changing its resonant frequency. Approaches to address the issue of frequency match accompanying with the resonant mode are illustrated with literature examples. Usage of PEH devices can be extended to a variety of vibration sources in everyday life as well as in nature. Some appealing applications of PEH, such as in implantable and wearable devices, are reviewed.展开更多
A recently emerging family of smart materials,photostrictive materials,exhibit large photostriction under uniform illumination of high-energy light.This photostriction mechanism arises from a superposition phenomenon ...A recently emerging family of smart materials,photostrictive materials,exhibit large photostriction under uniform illumination of high-energy light.This photostriction mechanism arises from a superposition phenomenon of photovoltaic and converse piezoelectric effects.A photostrictive type of opto-electromechanical actuator activated by high-energy lights can introduce actuation and control effects without hard-wired connections.The control light intensity applied to the actuator is proportional to the transverse velocity at a positioned point,which is measured by a laser vibrometer.In this paper,photostrictive films are numerically analyzed to evaluate their use as wireless actuators for future remote vibration control of flexible structures.A novel opto-electromechanical solid shell finite element formulation is developed for accurate analysis of the multiple physics effects of photovoltaic,pyroelectric and thermal expansion of photostrictive materials.Available experimental data and analytical solutions have been used to verify the present finite element results.The simulation in this study demonstrates that the present formulation is very reliable,accurate and also computationally efficient and that the use of photostrictive actuators can provide good controllability of structural vibration.展开更多
Small Ag clusters confined in the channels of ordered mesoporous anatase TiO2 have been fabricated via a vacuum-assisted wet-impregnation method, utilizing well-ordered mesoporous anatase TiO2 with high thermal stabil...Small Ag clusters confined in the channels of ordered mesoporous anatase TiO2 have been fabricated via a vacuum-assisted wet-impregnation method, utilizing well-ordered mesoporous anatase TiO2 with high thermal stability as the host. The composites have been characterized in detail by X-ray diffraction, X-ray photoelectron spectroscopy X-ray absorption fine structure (XAFS) spectroscopy, N2 adsorption, UV-visible diffuse reflectance spectroscopy and transmission electron microscopy. The results indicate that small Ag clusters are formed and uniformly confined in the channels of mesoporous TiO2 with an obvious confinement effect. The presence of strong AgO interactions involving the Ag clusters in intimate contact with the pore walls of mesoporous TiO2 is confirmed by XAFS analysis, and favors the separation of photogenerated electron-hole pairs, as shown by steady-state surface photovoltage spectroscopy and transient-state surface photovoltage measurements. The ordered mesoporous Ag/TiO2 composites exhibit excellent solar-light-driven photocatalytic performance for the degradation of phenol. This is attributed to the synergistic effects between the small Ag clusters acting as traps to effectively capture the photogenerated electrons, and the surface plasmon resonance of the Ag clusters promoting the absorption of visible light. This study clearly demonstrates the high-efficiency utilization of noble metals in the fabrication of high-performance solar-light-driven photocatalysts.展开更多
Regulating metal surfaces with micro-/nanoscale structures is of great significance for both material science and potential applications.However,the intrinsic properties of metals,such as fixed isotropic moduli and in...Regulating metal surfaces with micro-/nanoscale structures is of great significance for both material science and potential applications.However,the intrinsic properties of metals,such as fixed isotropic moduli and inflexible structures,in a sense present major limitations in developing next-generation smart patterned surfaces.In this work,a facile and general patterning strategy is proposed to endow insensitive metal surfaces with controllable spontaneous topologies and dynamic performance by exquisitely introducing an essential photosensitive interlayer.The arresting anthracene-containing photocrosslinking interlayer can selectively predetermine the anisotropic property of compliant bilayers without damaging metals’homogeneous properties,and realize a changeable stiff/soft layer.Furthermore,the mechanical transition mechanism of the self-adaptive wrinkling modes in metalbased trilayer systems is revealed to pave the pathway for regulating functional wrinkled metal surfaces.This photodriven metal patterning strategy can promote the development of brand-new methods for tuning the instability of multilayered materials,and be potentially applied in smart optical devices with dynamic reflectance,including light gratings and"magic"mirrors.展开更多
Lithium ion batteries (LIBs) represent one of the most promising solutions for environmentally friendly transportation such as electric vehicles. The demand for high energy density, low cost and environmentally frie...Lithium ion batteries (LIBs) represent one of the most promising solutions for environmentally friendly transportation such as electric vehicles. The demand for high energy density, low cost and environmentally friendly batteries makes high-capacity cathode materials very attractive for future LIBs. Layered LiNixCoyMn2O2 (x+y+z=1), Li-rich oxides and Li-V-O compounds have attracted much attention due to their high capacities in recent years. In this review, we focus on the state-of-the-art research activities related to LiNixCoyMn2O2, Li-rich oxides and Li-V-O compounds, including their structures, reaction mechanisms during cycling, challenges and strategies that have been studied to improve their electrochemical performances.展开更多
As the size of the electronic system continuously reduces, characteristics of small volume, light weight, high energy it is very important to develop micro power generator, which has density and continuous energy supp...As the size of the electronic system continuously reduces, characteristics of small volume, light weight, high energy it is very important to develop micro power generator, which has density and continuous energy supplying. Vibration energy exists widely in daily environment. Micro vibration power generator can harvest and exchange the vibration energy to the electrical energy. Micro electret power generator is one kind of the power generators for harvesting vibration energy and has been paid much attention by researchers. This paper describes the development and status of micro electret power generators, including electret materials and charging methods, vibration energy harvesting structures and conversion efficiency improvement.展开更多
文摘Smart material and structure (SMS) is a challenging novel technique for the 21 century especially in fields of aviation and aerospace. Vibration and noise suppression smart structure is an important branch of SMS. There are several typical structures such as the cabin of an airplane, space station, the solar board of satellite and the rotor blade of a helicopter, of which the vibrations and radiation noises have bad influences on precise equipments and aiming systems. In order to suppress vibrations and noises of these structures, several algorithms are applied to the models which simulate the structures. Experiments are performed to suppress vibrations and noises by bonding sensors and actuators to the structures at the optimized locations and using computer based measurement and control systems. For the blade vibration control of a helicopter, a non contact method of signal transmission by magneto electric coupling is discussed. The experimental results demonstrate that the methods used for active control are effective.
基金Supported by China National 111 Project under Grant No.B07019
文摘This paper addresses the need for systematic evaluation of the station keeping systems of deepwater drilling semi-submersibles.Based on the selected drilling semi-submersible configuration, the mooring systems were analyzed and designed for a range of water depths using different mooring line materials.These were steel wire rope, polyester rope and HMPE (high modulus poly ethylene).The mooring analysis was carried out using the advanced fully coupled time domain analysis method in the computer software package HARP.Diffraction analysis was first applied to solve the hydrodynamic properties of the vessel and then the motion equations of the complete dynamic system including the drilling rig, the mooring lines and risers were developed and solved in the time domain.Applying the advanced analysis method, a matrix of mooring systems was developed for operating in water depths of 1000 m, 1500 m, and 2 000 m using various mooring materials.The development of mooring systems was conducted in accordance with the commonly adopted mooring design code, API RP 2SK and API RP 2SM.Fresh attempts were then made to comparatively evaluate the mooring system's characteristics and global performance.Useful results have been obtained in terms of mooring materials, water depths, and key parameters of mooring configurations.The results provide in-depth insight for the design and operation of deepwater mooring systems in the South China Sea environment.
文摘Micro-scale functionally graded material(FGM)pipes conveying fluid have many significant applications in engineering fields.In this work,the thermoelastic vibration of FGM fluid-conveying tubes in elastic medium is studied.Based on modified couple stress theory and Hamilton’s principle,the governing equation and boundary conditions are obtained.The differential quadrature method(DQM)is applied to investigating the thermoelastic vibration of the FGM pipes.The effect of temperature variation,scale effect of the microtubule,micro-fluid effect,material properties,elastic coefficient of elastic medium and outer radius on thermoelastic vibration of the FGM pipes conveying fluid are studied.The results show that in the condition of considering the scale effect and micro-fluid of the microtubule,the critical dimensionless velocity of the system is higher than that of the system which calculated using classical macroscopic model.The results also show that the variations of temperature,material properties,elastic coefficient and outer radius have significant influences on the first-order dimensionless natural frequency.
基金Projects(51605220,U1637101)supported by the National Natural Science Foundation of ChinaProject(BK20160793)supported by the Jiangsu Provincial Natural Science Foundation,ChinaProject(NS2020029)supported by the Fundamental Research Funds for the Central Universities,China。
文摘In order to further improve the driving performance of ionic polymer metal composites(IPMCs),Nafion/graphene quantum dots(GQDs)hybrid membranes incorporating GQDs with various contents of 0,0.1 wt.%,0.5 wt.%,1.0 wt.%,2.0 wt.%and 4.0 wt.%were fabricated by solution casting,and then IPMCs were manufactured by electroless plating.The water contents and elastic moduli of the hybrid membranes were tested.The morphology characteristics of the hybrid membranes and the IPMCs were observed,and the current,AC impedance,blocking force and displacement of the IPMCs were measured.The results show that the elastic modulus of the hybrid membranes decreases,the water content increases,and the actuation performance of the IPMCs improves significantly after the addition of GQDs.IPMC with 1.0 wt.%GQDs exhibits the best driving property.Compared with the IPMC without GQDs,the working current,ion conductivity,blocking force,and tip displacement increase by 94.67%,311.11%,53.66%,and 66.07%,respectively.These results lay a solid foundation for the preparation of IPMCs with high performance,and further broaden their applications in biomedical devices and bionic robots.
基金Project(51102035)supported by the National Natural Science Foundation of China
文摘Functionalized graphene nano-sheets(FGN) of 0.01%-0.05%(mass fraction) were added to produce FGN-cement composites in the form of mortars. Flow properties, mechanical properties and microstructure of the cementitious material were then investigated. The results indicate that the addition of FGN decreases the fluidity slightly and improves mechanical properties of cement-based composites significantly. The highest strength is obtained with FGN content of 0.02% where the flexural strength and compressive strength at 28 days are 12.917 MPa and 52.42 MPa, respectively. Besides, scanning electron micrographs show that FGN can regulate formation of massive compact cross-linking structures and thermo gravimetric analysis indicates that FGN can accelerate the hydration reaction to increase the function of the composite effectively.
文摘This paper briefly introduces the application of new materials in sports and effect on sports performance, points out that development of competitive sports in the process, must pay attention to the development and utilization of new materials, development.
文摘Borohydrides have been recently hightlighted as prospective new materials due to their high gravimetric capacities for hydrogen storage. It is, therefore, important to under- stand the underlying dehydrogenation mechanisms for further development of these ma- terials. We present a systematic theoretical investigation on the dehydrogenation mecha- nisms of the Mg2(BH4)2(NH2)2 compounds. We found that dehydrogenation takes place most likely via the intermolecular process, which is favorable both kinetically and thermo- dynamically in comparison with that of the intramolecular process. The dehydrogenation of Mg2(BH4)2(NH2)2 initially takes place via the direct combination of the hydridie H in BH4 and the protie H in NH2-, followed by the formation of Mg-H and subsequent ionic recombination of Mg-Hδ-…Hδ+-N.
文摘Our civilization is facing an urgent need to include innovative, large-scale sources of energy and raw materials into its technological cycles. One potential source is magma, which now still inspires awe with its unpredictable power of volcanic eruptions. We propose a method of remote control of lava flow which is based on a special design of a pipe which is lowered into the crater of a volcano. The magma is raised with the help of a well-known method for raising liquids, the airlift. This article includes a detailed description of the structure of the disperser that we shall use to introduce gas into the magma, explains the possible ways to manage the flow of magma, and describes the results that can be achieved. There is potential for the establishment of a whole new industry that will produce cheap electricity, hydrogen, rare metals, fertilizers and innovative construction materials.
基金Project(51165022)supported by the National Natural Science Foundation of ChinaProject(20122117)supported by the Lanzhou Science and Technology Bureau Foundation,ChinaProject(1310RJZA036)supported by the Natural Science Foundation of Gansu Province,China
文摘Nanoparticles are increasingly being used to improve the friction and wear performance of polymers. In this study, we investigated the tribological behavior and energy dissipation characteristics of nano-Al_2O_3-reinforced polytetrafluoroethylenepolyphenylene sulfide(PTFE-PPS) composites in a sliding system. The tribological behaviors of the composites were evaluated under different normal loads(100–300 N) at a high linear velocity(2 m/s) using a block-on-ring tester. Addition of the nano-Al_2O_3 filler improved the antiwear performance of the PTFE-PPS composites, and the friction coefficient increased slightly. The lowest wear rate was obtained when the nano-Al_2O_3 content was 3%(volume fraction). Further, the results indicated a linear correlation between wear and the amount of energy dissipated, even though the wear mechanism changed with the nano-Al_2O_3 content, independent of the normal load applied.
基金Projects(20833009,20873148,U0734005) supported by the National Natural Science Foundation of ChinaProject(2010CB631303) supported by the National Basic Research Program of China+2 种基金Project(2009A11GX052) supported by Dalian Science and Technology Foundation,ChinaProject(KFJJ10-1Z) supported by the State Key Laboratory of Explosion Science and Technology,Beijing Institute of Technology,ChinaProject(Y4090507) supported by the Zhejiang Basic Research Program of China
文摘Mg-x(Ti0.9 Zr0.2 Mn1.5 Cr0.3)(x=20%,30%,40%) (mass fraction) composite powders were prepared by reactive ball milling with hydrogen and their hydrogen storage properties and microstructure were investigated by XRD,SEM and pressure-composition-temperature measurement.The results show that the composites have 3.83%-5.07%hydrogen capacity at 553 K and good hydrogenation kinetics,even at room temperature.Among them,the milled Mg-30%(Ti0.9Zr0.2Mn1.5Cr0.3)composite has the highest hydrogenation kinetics as it can quickly absorb 2.1%hydrogen at 373 K,3.5%in 2 000 s at 473 K,even 3.26%in 60 s at 553 K under 3 MPa hydrogen pressure.The improved hydrogenation properties come from the catalytic effect of Ti0.9 Zr0.2 Mn1.5 Cr0.3 particles dispersed uniformly on the surface of Mg particles.
基金supported by the National Natural Science Foundation of China(Grant No.51302143)Shenzhen Special Fund for the Development of Emerging Industries(Grant No.JCYJ20140417115840233)Shenzhen Peacock Plan(Grant No.KQCX20140521161756228)
文摘Energy harvesting is an appealing technology that makes use of the ambient energy which is otherwise wasted. Piezoelectric materials directly convert the elastic energy to the electric energy, and thus have a great advantage in scavenging vibrational energy for simplicity in device structure with relatively high power density. This paper provides an overview on the research of piezoelectric materials in energy harvesting in recent decades, from basics of piezoelectricity and working principle of energy harvesting with piezoelectric materials, to the progress of development of high-performance piezoelectrics including ceramics, single crystals and polymers, then to experimental attempts on the device fabrication and optimization, finally to perspective applications of piezoelectric energy harvesting(PEH). The criteria for selection of materials for PEH applications are introduced. Not only the figure of merit but also maximum allowable stress of materials are taken into account in the evaluation of their potential in achieving high energy density and output power density. The influence of the device configuration on the performance is also acknowledged and discussed. The magnitude and distribution of induced stress in the piezoelectric unit upon excitation by the vibration source play an important role in determining the output power density and can be tuned via proper design of device configuration without changing its resonant frequency. Approaches to address the issue of frequency match accompanying with the resonant mode are illustrated with literature examples. Usage of PEH devices can be extended to a variety of vibration sources in everyday life as well as in nature. Some appealing applications of PEH, such as in implantable and wearable devices, are reviewed.
基金supported by the National Natural Science Foundation of China (Grant Nos. 10872090, 50830201)NUAA Research Funding (Grant No. NJ2010011)
文摘A recently emerging family of smart materials,photostrictive materials,exhibit large photostriction under uniform illumination of high-energy light.This photostriction mechanism arises from a superposition phenomenon of photovoltaic and converse piezoelectric effects.A photostrictive type of opto-electromechanical actuator activated by high-energy lights can introduce actuation and control effects without hard-wired connections.The control light intensity applied to the actuator is proportional to the transverse velocity at a positioned point,which is measured by a laser vibrometer.In this paper,photostrictive films are numerically analyzed to evaluate their use as wireless actuators for future remote vibration control of flexible structures.A novel opto-electromechanical solid shell finite element formulation is developed for accurate analysis of the multiple physics effects of photovoltaic,pyroelectric and thermal expansion of photostrictive materials.Available experimental data and analytical solutions have been used to verify the present finite element results.The simulation in this study demonstrates that the present formulation is very reliable,accurate and also computationally efficient and that the use of photostrictive actuators can provide good controllability of structural vibration.
文摘Small Ag clusters confined in the channels of ordered mesoporous anatase TiO2 have been fabricated via a vacuum-assisted wet-impregnation method, utilizing well-ordered mesoporous anatase TiO2 with high thermal stability as the host. The composites have been characterized in detail by X-ray diffraction, X-ray photoelectron spectroscopy X-ray absorption fine structure (XAFS) spectroscopy, N2 adsorption, UV-visible diffuse reflectance spectroscopy and transmission electron microscopy. The results indicate that small Ag clusters are formed and uniformly confined in the channels of mesoporous TiO2 with an obvious confinement effect. The presence of strong AgO interactions involving the Ag clusters in intimate contact with the pore walls of mesoporous TiO2 is confirmed by XAFS analysis, and favors the separation of photogenerated electron-hole pairs, as shown by steady-state surface photovoltage spectroscopy and transient-state surface photovoltage measurements. The ordered mesoporous Ag/TiO2 composites exhibit excellent solar-light-driven photocatalytic performance for the degradation of phenol. This is attributed to the synergistic effects between the small Ag clusters acting as traps to effectively capture the photogenerated electrons, and the surface plasmon resonance of the Ag clusters promoting the absorption of visible light. This study clearly demonstrates the high-efficiency utilization of noble metals in the fabrication of high-performance solar-light-driven photocatalysts.
基金supported by the National Key R&D Program of China(2021YFB4001100)the National Natural Science Foundation of China(52025032,52103144,12032015,12121002,and 12172216)Science and Technology Innovation Action Plan of Shanghai(21190760100)。
文摘Regulating metal surfaces with micro-/nanoscale structures is of great significance for both material science and potential applications.However,the intrinsic properties of metals,such as fixed isotropic moduli and inflexible structures,in a sense present major limitations in developing next-generation smart patterned surfaces.In this work,a facile and general patterning strategy is proposed to endow insensitive metal surfaces with controllable spontaneous topologies and dynamic performance by exquisitely introducing an essential photosensitive interlayer.The arresting anthracene-containing photocrosslinking interlayer can selectively predetermine the anisotropic property of compliant bilayers without damaging metals’homogeneous properties,and realize a changeable stiff/soft layer.Furthermore,the mechanical transition mechanism of the self-adaptive wrinkling modes in metalbased trilayer systems is revealed to pave the pathway for regulating functional wrinkled metal surfaces.This photodriven metal patterning strategy can promote the development of brand-new methods for tuning the instability of multilayered materials,and be potentially applied in smart optical devices with dynamic reflectance,including light gratings and"magic"mirrors.
文摘Lithium ion batteries (LIBs) represent one of the most promising solutions for environmentally friendly transportation such as electric vehicles. The demand for high energy density, low cost and environmentally friendly batteries makes high-capacity cathode materials very attractive for future LIBs. Layered LiNixCoyMn2O2 (x+y+z=1), Li-rich oxides and Li-V-O compounds have attracted much attention due to their high capacities in recent years. In this review, we focus on the state-of-the-art research activities related to LiNixCoyMn2O2, Li-rich oxides and Li-V-O compounds, including their structures, reaction mechanisms during cycling, challenges and strategies that have been studied to improve their electrochemical performances.
基金supported by the National Basic Research Program of China ("973" Program) (Grant No. 2009CB320300)
文摘As the size of the electronic system continuously reduces, characteristics of small volume, light weight, high energy it is very important to develop micro power generator, which has density and continuous energy supplying. Vibration energy exists widely in daily environment. Micro vibration power generator can harvest and exchange the vibration energy to the electrical energy. Micro electret power generator is one kind of the power generators for harvesting vibration energy and has been paid much attention by researchers. This paper describes the development and status of micro electret power generators, including electret materials and charging methods, vibration energy harvesting structures and conversion efficiency improvement.