The non-random two liquids （NRTL） equation together with the Pitzer/Curl Virial equation of state are used to investigate the simultaneous representation of excess enthalpies （h^E） and vapour-liquid equilibria （...The non-random two liquids （NRTL） equation together with the Pitzer/Curl Virial equation of state are used to investigate the simultaneous representation of excess enthalpies （h^E） and vapour-liquid equilibria （VLE） and the VLE prediction from h^E data. The calculation strategy for properly determining NRTL parameters and the effect of their temperature dependence on the simultaneous correlation of h^E and VLE data and the VLE extrapolation are analysed in detail.展开更多
An equation of state （EOS） for high-pressure liquids, i.e., Tait EOS, is deduced according to isothermal 1 3V compressibility KT= -1/V· （2V/2p）T·.Based on the equation, a generalized EOS for high pressu...An equation of state （EOS） for high-pressure liquids, i.e., Tait EOS, is deduced according to isothermal 1 3V compressibility KT= -1/V· （2V/2p）T·.Based on the equation, a generalized EOS for high pressure-liquids is established by using the reduced state principle and introducing a characteristic parameter-configuration factor ξ. Reasonably satisfactory P-V-T data for many organic compounds, including some polar components, were calculated by using the equation.展开更多
The interfacial evaporative heat transfer was included in the semi-empirical study of the heat transfer for the falling liquid film flow. The investigations showed that, the inclusion of the interfacial eveiporative h...The interfacial evaporative heat transfer was included in the semi-empirical study of the heat transfer for the falling liquid film flow. The investigations showed that, the inclusion of the interfacial eveiporative heat transfer in the turbulent model would lower the predicted convective heat transfer coefficient. Predictions of the new model resulted in a prominent deviation from that predictions of the normal model in the case of large mass flow rate and low wall heat flux. This deviation will be decreased with increasing wall heat flux, such that it will be asymptotic zero at very high wall heat flux. Predictions of the new model agreed well with the current experimental measurements. This study has verified that the Reynolds number is not the sole crucial parameter for heat transfer of falling liquid film flow, and wall heat flux will be another important independent parameter. This result is consistent with our previous studies.展开更多
A new general equation of state is presented, which can be used to express not only common cubic equations of state, but also quartic equations of state and so on. Main advantage of the new equation over the previous ...A new general equation of state is presented, which can be used to express not only common cubic equations of state, but also quartic equations of state and so on. Main advantage of the new equation over the previous general equations is that it is in simple form, and is easy to manipulate mathematically.展开更多
A new numerical algorithm is presented to simulate the explosion reaction process of mine explosives based on the equation of state, the equation of mass conservation and thermodynamics balance equation of explosion p...A new numerical algorithm is presented to simulate the explosion reaction process of mine explosives based on the equation of state, the equation of mass conservation and thermodynamics balance equation of explosion products. With the affection of reversible reaction of explosion products to explosion reaction equations and thermodynamics parameters considered, the computer program has been developed. The computation values show that computer simulation results are identical with the testing ones.展开更多
According to the construction characteristic of RCC dam cast by layers, three-dimensional finite element relocating mesh method is developed to simulate construction process and compute temperature field. The computat...According to the construction characteristic of RCC dam cast by layers, three-dimensional finite element relocating mesh method is developed to simulate construction process and compute temperature field. The computation model of relocating mesh method is expatiated in detail; based on the thermodynamic properties of RCC materials, the feasibility and error of relocating mesh method are analyzed and demonstrated; The computation results in this article are verified by means of the temperature observation data of certain RCC gravity dam. The results show that the temperature field computed by three-dimensional finite element relocating mesh method can not only ensure the computation precision, but also improve the calculation efficiency greatly. This provides an effective method for simulating construction process and computing temperature field of RCC dam.展开更多
基金Supported by Deutsche Forschungsgemeinschaft(DFG) (LE 886/4-1)
文摘The non-random two liquids （NRTL） equation together with the Pitzer/Curl Virial equation of state are used to investigate the simultaneous representation of excess enthalpies （h^E） and vapour-liquid equilibria （VLE） and the VLE prediction from h^E data. The calculation strategy for properly determining NRTL parameters and the effect of their temperature dependence on the simultaneous correlation of h^E and VLE data and the VLE extrapolation are analysed in detail.
文摘An equation of state （EOS） for high-pressure liquids, i.e., Tait EOS, is deduced according to isothermal 1 3V compressibility KT= -1/V· （2V/2p）T·.Based on the equation, a generalized EOS for high pressure-liquids is established by using the reduced state principle and introducing a characteristic parameter-configuration factor ξ. Reasonably satisfactory P-V-T data for many organic compounds, including some polar components, were calculated by using the equation.
基金Supported by the National Natural Science Foundation of China (No. 59995550-3) and Science Funds from the Ministry of Education (No. 97000357).
文摘The interfacial evaporative heat transfer was included in the semi-empirical study of the heat transfer for the falling liquid film flow. The investigations showed that, the inclusion of the interfacial eveiporative heat transfer in the turbulent model would lower the predicted convective heat transfer coefficient. Predictions of the new model resulted in a prominent deviation from that predictions of the normal model in the case of large mass flow rate and low wall heat flux. This deviation will be decreased with increasing wall heat flux, such that it will be asymptotic zero at very high wall heat flux. Predictions of the new model agreed well with the current experimental measurements. This study has verified that the Reynolds number is not the sole crucial parameter for heat transfer of falling liquid film flow, and wall heat flux will be another important independent parameter. This result is consistent with our previous studies.
文摘A new general equation of state is presented, which can be used to express not only common cubic equations of state, but also quartic equations of state and so on. Main advantage of the new equation over the previous general equations is that it is in simple form, and is easy to manipulate mathematically.
文摘A new numerical algorithm is presented to simulate the explosion reaction process of mine explosives based on the equation of state, the equation of mass conservation and thermodynamics balance equation of explosion products. With the affection of reversible reaction of explosion products to explosion reaction equations and thermodynamics parameters considered, the computer program has been developed. The computation values show that computer simulation results are identical with the testing ones.
文摘According to the construction characteristic of RCC dam cast by layers, three-dimensional finite element relocating mesh method is developed to simulate construction process and compute temperature field. The computation model of relocating mesh method is expatiated in detail; based on the thermodynamic properties of RCC materials, the feasibility and error of relocating mesh method are analyzed and demonstrated; The computation results in this article are verified by means of the temperature observation data of certain RCC gravity dam. The results show that the temperature field computed by three-dimensional finite element relocating mesh method can not only ensure the computation precision, but also improve the calculation efficiency greatly. This provides an effective method for simulating construction process and computing temperature field of RCC dam.
