底气

“春兰，来领你的500元助学金。”听着老师沉闷的语气，望着他严肃的面庞，我低着头一声不吭地走上讲台领走贫困助学金。老师从没对我笑过，他时常对班长绽放出的阳光般的笑容从未洒落到我身上过。

Enhancement of nucleation of diamond films deposited on copper substrate by nickel modification layer

A Ni layer with a thickness of about 100 nm was sputtered on Cu substrates,followed by an ultrasonic seeding with nanodiamond suspension.High-quality diamond film with its crystalline grains close to thermal equilibrium shape was deposited on Cu substrates by hot-filament chemical vapor deposition（HF-CVD）,and the sp2 carbon content was less than 5.56%.The nucleation and growth of diamond film were investigated by micro-Raman spectroscopy,scanning electron microscopy,and X-ray diffraction.The results show that the nucleation density of diamond on the Ni-modified Cu substrates is 10 times higher than that on blank Cu substrates.The enhancement mechanism of the nucleation kinetics by Ni modification layer results from two effects：namely,the nanometer rough Ni-modified surface shows an improved absorption of nanodiamond particles that act as starting points for the diamond nucleation during HF-CVD process;the strong catalytic effect of the Ni-modified surface causes the formation of graphite layer that acts as an intermediate to facilitate diamond nucleation quickly.

Using 4C OBS to reveal the distribution and velocity attributes of gas hydrates at the northern continental slope of South China Sea

To investigate the distribution and velocity attributes of gas hydrates in the northern continental slope of South China Sea, Guangzhou Marine Geological Survey conducted four-component （4C） ocean-bottom seismometer （OBS） surveys. A case study is presented to show the results of acquiring and processing OBS data for detecting gas hydrates. Key processing steps such as repositioning, reorientation, PZ summation, and mirror imaging are discussed. Repositioning and reorientation find the correct location and direction of nodes. PZ summation matches P- and Z-components and sums them to separate upgoing and downgoing waves. Upgoing waves are used in conventional imaging, whereas downgoing waves are used in mirror imaging. Mirror imaging uses the energy of the receiver ghost reflection to improve the illumination of shallow structures, where gas hydrates and the associated bottom-simulating reflections （BSRs） are located. We developed a new method of velocity analysis using mirror imaging. The proposed method is based on velocity scanning and iterative prestack time migration. The final imaging results are promising. When combined with the derived velocity field, we can characterize the BSR and shallow structures; hence, we conclude that using 4C OBS can reveal the distribution and velocity attributes of gas hydrates.

Detection of gas hydrate sediments using prestack seismic AVA inversion

Bottom-simulating reflectors (BSRs) in seismic profile always indicate the bottom of gas hydrate stability zone, but is difficult to determine the distribution and features of gas hydrate sediments (GHS). In this study, based on AVA forward modeling and angle-domain common-image gathers we use prestack AVA parameters consistency inversion in predicting gas hydrate sediments in the Shenhu area at northern slope of South China Sea, and obtain the vertical and lateral features and saturation of GHS.

Nitrogen Release Kinetics and Nitrification-Denitrification on Surface Sediments under Aerating Disturbance Condition

[Objective] This study aimed to investigate the nitrogen release kinetics and nitrification-denitrification on surface sediments under aerating disturbance condition, with the purpose to solve the sediment nitrogen release and secondary pollution problems. [Method] The effect of in situ sediments aeration on the release of nitrogen pollutants was investigated, and the nitrogen release kinetics parameters were analyzed. The process of nitrification and denitrification under sediments aeration condition was investigated in laboratory. [Result] The nitrogen released from sediments was enhanced by aeration disturbance. The concentration of NH4＋-N and TN reached the maximum value in 30 min, and release rates were proportional to the disturbance strength. In this study, with the distance of aerator to the sediments surface of 0, 1, 2 and 3 cm, the suspended sediments concentrations were 3.52, 3.41, 3.26 and 3.01 g/L, respectively. Maximum release concentration of NH4＋-N and TN were 14.3, 13.8, 13.2, 12.2 mg/L and 33.21, 30.98, 29.83, 27.30 mg/L, respec- tively. In addition, both NH4＋-N and TN release kinetics could be described by Double Constant Equation as InC=A＋Blnt. Nitrification reaction occurred and was promoted by continued aerating to sediments.The concentration of NH4＋-N dropped down from 12.4 mg/L to 0.2 mg/L in 8 d, with the concentration of NO3--N increased to the maximum value of 10.8 mg/L. In addition, concentration of NO3--N and TN decreased from 10.8 mg/L and 37.4 mg/L to 0.36 mg/L and 23.2 mg/L after the stop of aeration for 12 d, indicating the occurrence of denitdfication reaction. Therefore, sediment aeration could accelerate nitrogen release and nitrification reaction, and with intermittent aeration, nitrogen could be removed from sediments in-situ by nitrification and denitrification. [Conclusion] The results provided technical reference for the in situ sediment remediation for the black-odor rivers in cities.

Contrast of Seismic Reflection Characteristics of Gas Hydrate Distribution between Northeast SCS Slope and Hengchun Ridge

By analyzing and interpreting the newly acquired seismic profile supported by the national 973 Program and synthesizing the data with other geologic ＆ geographic information, we draw conclusions as follows, a） Two seismic reflections located at the northeast South China Sea （SCS） slope and the Hengchun ridge are the Bottom Simulated Reflections （BSRs）. Yet, the genesis and process of the gas hydrate in these two areas are different because of different regional tectonics and geological environments; b） The genesis of gas hydrate located at the northeast SCS slope area is related to the broadly existing fracture zones, slumping tectosomes, and the distinctive shielding environment of pressure masking field formed by them. But the genesis of the gas hydrate at the Hengchun ridge is associated with the thrust nappe structures and accretionary wedges formed along the Manila subduction zone and the related sub-floor fluid channel system built by them; c） Since the analogous geologic bodies are broadly distributed at slope areas around SCS and the temperature-press environment is very suitable to the formation and conservation of the gas hydrate, we suggest that much more of this resource should be stored in these areas.

EFFECT OF GRID BIAS ON DEPOSITION OF NANOCRYSTALLINE DIAMOND FILMS

A positive grid bias and a negative substrate bias voltages are applied to the self-made hot filament chemical vapor deposited （HFCVD） system. The high quality nanocrystalline diamond （NCD） film is successfully deposited by double bias voltage nucleation and grid bias voltage growth. The Micro-Raman XRD SEM and AFM are used to investigate the diamond grain size, microstructure, surface morphology, and nucleation density. Results show that the obtained NCD has grain size of about 20 nm. The effect of grid bias voltage on the nucleation and the diamond growth is studied. Experimental results and theoretical analysis show that the positive grid bias increases the plasma density near the hot filaments, enhances the diamond nucleation, keeps the nanometer size of the diamond grains, and improves the quality of diamond film.

"Environmental phosphorylation"boosting photocatalytic CO_(2)reduction over polymeric carbon nitride grown on carbon paper at air-liquid-solid joint interfaces

The limited CO_(2)content in aqueous solution and low adsorption amount of CO_(2)on catalyst surface lead to poor photocatalytic CO_(2)reduction activity and selectivity.Herein,the design and fabrication of a novel photocatalytic architecture is reported,accomplished via chemical vapor deposition of polymeric carbon nitride on carbon paper.The as-obtained samples with a hydrophobic surface exhibit excellent CO_(2)transport and adsorption ability,as well as the building of triphase air-liquid-solid(CO_(2)-H_(2)O-catalyst)joint interfaces,eventually resulting in the inhibition of H2 evolution and great promotion of CO_(2)reduction with a selectivity of 78.6%.The addition of phosphate to reaction environment makes further improvement of CO_(2)photoreduction into carbon fuels with a selectivity of 93.8%and an apparent quantum yield of 0.4%.This work provides new insight for constructing efficient photocatalytic architecture of CO_(2)photoreduction in aqueous solution and demonstrates that phosphate could play a key role in this process.

Cold model on bubble growth and detachment in bottom blowing process

The bubble growth and detachment behavior in the bottom blowing process were investigated. Four multi-hole nozzle configurations with different opening ratios were assessed experimentally using high-speed photography and digital image processing. For these configurations, the experiments reveal that the bubble growth consists of a petal-like stage, an expansion stage and a detachment stage. The petal-like shape is qualitatively described through the captured images, while the non-spherical bubbles are analyzed by the aspect ratio. The bubble size at the detachment is quantified by the maximum caliper distance and the bubble equivalent diameter. Considering the dependence on the opening ratio, different prediction models for the ratio of maximum caliper distance to hydraulic diameter of the nozzle outlet and the dimensionless bubble diameter are established. The comparative analysis results show that the proposed prediction model can accurately predict the bubble detachment size under the condition of multi-hole nozzles.

Copper smelting mechanism in oxygen bottom-blown furnace

The SKS furnace is a horizontal cylindrical reactor similar to a Noranda furnace,however,the oxygen enriched air isblown into the furnace from the bottom.Mechanism model of the SKS process was developed by analyzing the smeltingcharacteristics deeply.In our model,the furnace section from top to bottom is divided into seven functional layers,i.e.,gas layer,mineral decomposition transitioning layer,slag layer,slag formation transitioning layer,matte formation transitioning layer,weakoxidizing layer and strong oxidizing layer.The furnace along the length direction is divided into three functional regions,that is,reaction region,separation transitioning region and liquid phase separation and settling region.These layers or regions play differentroles in the model in describing the mechanism of the smelting process.The SKS smelting is at a multiphase non-steady equilibriumstate,and the oxygen and sulfur potentials change gradually in the length and cross directions.The smelting capacity of the SKSprocess could be raised through reasonably controlling the potential values in different layers and regions.

Multiphase equilibrium modeling of oxygen bottom-blown copper smelting process

A computational thermodynamics model for the oxygen bottom-blown copper smelting process(Shuikoushan,SKS process)was established,based on the SKS smelting characteristics and theory of Gibbs free energy minimization.The calculated results of the model show that,under the given stable production condition,the contents of Cu,Fe and S in matte are71.08%,7.15%and17.51%,and the contents of Fe,SiO2and Cu in slag are42.17%,25.05%and3.16%.The calculated fractional distributions of minor elements among gas,slag and matte phases are As82.69%,11.22%,6.09%,Sb16.57%,70.63%,12.80%,Bi68.93%,11.30%,19.77%,Pb19.70%,24.75%,55.55%and Zn17.94%,64.28%,17.79%,respectively.The calculated results of the multiphase equilibrium model agree well with the actual industrial production data,indicating that the credibility of the model is validated.Therefore,the model could be used to monitor and optimize the industrial operations of SKS process.

Analysis of influencing factors on suction capacity in seabed natural gas hydrate by cutter-suction exploitation

The mathematical and simulation models of working head in the deep-sea working environment were built to analyze the effects of cutter-suction flow,cutter-head rotating speed,cutting depth and suction port position on the cutter-suction capacity.The efficiency of the cutter-suction is analyzed based on the analysis of the variation law of the solid-phase volume fraction of the flow field,the variation law of the velocity distribution in the flow field and the distribution law of the solid-phase concentration.The results show that the increase of cutter-suction flow can significantly improve the cutter-suction efficiency when it is less than1000m3/h.However,when it is more than1000m3/h,it is helpless.When the cutter-head rotate speed is within the range of10–25r/min,the cutter-suction efficiency stabilizes at about95%.While the speed is greater than25r/min,the cutter-suction efficiency decreases sharply with the increase of cutter-head rotate speed.With the increase of cutting depth,the cutter-suction efficiency first increases and then remains stable and finally decreases.The cutter-suction efficiency remains at about94%when the suction port position deviation ranges from0°to30°,but it has a sharply reduction when the deviation angle is more than30°.

GENETIC OPTIMIZATION OF HOT FILAMENT PARAMETERS IN HFCVD SYSTEM

In HFCVD system the substrate temperature is a key factor which deeply affects the quality of diamond films. Th e magnitude and the variation of the substrate temperature must be limited in a suitable range to deposit diamond films of uniform thickness over large areas. In this paper, the hot filament parameters are investigated on the basi s of GAs to realize a good substrate temperature profile. Computer simulations d emonstrate that on parameters optimized by GAs a uniform substrate temperatur e field can be formed over a relatively large circle area with R s=10 cm.

Three-phase flow of submarine gas hydrate pipe transport

In the hydraulic transporting process of cutter-suction mining natural gas hydrate, when the temperature-pressure equilibrium of gas hydrate is broken, gas hydrates dissociate into gas. As a result, solid-liquid two-phase flow(hydrate and water) transforms into gas-solid-liquid three-phase flow(methane, hydrate and water) inside the pipeline. The Euler model and CFD-PBM model were used to simulate gas-solid-liquid three-phase flow. Numerical simulation results show that the gas and solid phase gradually accumulate to the center of the pipe. Flow velocity decreases from center to boundary of the pipe along the radial direction. Comparison of numerical simulation results of two models reveals that the flow state simulated by CFD-PBM model is more uniform than that simulated by Euler model, and the main behavior of the bubble is small bubbles coalescence to large one. Comparison of numerical simulation and experimental investigation shows that the values of flow velocity and gas fraction in CFD-PBM model agree with experimental data better than those in Euler model. The proposed PBM model provides a more accurate and effective way to estimate three-phase flow state of transporting gas hydrate within the submarine pipeline.

Behaviour of Ti Based on Si(111) Substrate at High Temperature in Oxygen

The behavior of Ti based on Si（lll） in oxygen under high temperatures（700 ℃, 800 ℃ , 900 ℃ , I 000 ℃ and 1 100℃） is reported. X-ray diffraction（XRD） and Fourier transform infrared spectroscopy （FTIR） are used to analyze the structure and composition of the samples annealing at different temperatures in oxygen ambience. It is found that raising temperature is helpful to the formation of both TiSi2 and TiO2 and helpful to the diffusion of Ti to Si substrate.

Base Stress of the Opened Bottom Cylinder Structures

The base stress of the opened bottom cylinder structure differs greatly from that of the structure with a closed bottom. By investigating the inner soil pressure on the cylinder wall and the base stress of the cylinder base, which were obtained from the model experiments, the interactions among the filler inside the cylinder, subsoil and cylinder are analyzed. The adjusting mechanism of frictional resistance between the inner filler and the wall of the cylinder during the overturning of the cylinder is discussed. Based on the experimental study, a method for calculating the base stress of the opened bottom cylinder structure is proposed. Meanwhile, the formulas for calculating the effective anti-overturning ratio of the opened bottom cylinder are derived.

Release of Mercury from Intertidal Sediment to Atmosphere in Summer and Winter

The release of mercury from intertidal sediment to atmosphere was studied based on the simulated experiment. The experiment samples were collected from the Haibo Estuary (S1) and the Licun Estuary (S2) of the Jiaozhou Bay in China,which are seriously polluted with mercury. The results show that the mercury in sediment releases rapidly to atmosphere under solar radiation. After 8 hours of solar radiation,mercury concentrations decrease from 5.62 μg/g and 2.92 μg/g to 2.34 μg/g and 1.39 μg/g in S1 and S2 sediments respectively in summer,and decrease from 5.62 μg/g and 2.92 μg/g to 4.58 μg/g and 2.13 μg/g respectively in winter. The mercury species in the sediment change markedly under solar radiation. The concentrations of mercury bound to organic matter decrease significantly from 2.73 μg/g to 0.31 μg/g in S1 and from 2.07 μg/g to 0.31 μg/g in S2,and the released mercury mainly comes from mercury bound to organic matter. Mercury flux shows distinguishing characteristic of diurnal change,and it increases rapidly in the morning with the rising of solar radiation intensity,but decreases in the afternoon. The mercury flux increases with sediment temperature and solar radiation intensity. The rapid release of mercury in intertidal sediment plays an important role in the regional mercury cycle.

Model Evaluation and Projection on the Linkage between Hadley Circulation and Atmospheric Background Related to the Tropical Cyclone Frequency over the Western North Pacific

The performance of climate models in simulating the linkage of the spring Hadley circulation (HC) to the vertical zonal wind shear and atmospheric divergence in the lower and upper troposphere, which are related to the tropical cyclone frequency over the western North Pacific (WNPTCF) during June-September (JJAS), is evaluated on the basis of the 20th century climate simulations (20C3M). It is found that four models can simulta-neously reproduce the pattern revealed in the observation, with the spring HC in the Northern Hemisphere being positively correlated to the vertical zonal wind shear in the major tropical cyclone (TC) genesis region and negatively (positively) correlated to the atmospheric diver- gence in the upper (lower) troposphere over the western North Pacific (WNP) in the following JJAS. These four models are further used to project their relationship in the late 21st century under the A1B scenario. The results show that the association of spring HC with the vertical zonal wind shear and the upper-and lower-tropospheric divergence over the WNP will weaken in the late 21st century, thereby resulting in a weak relationship between the spring HC and the JJAS WNPTCF.

PROGRESS OF MARINE METEOROLOGICAL OBSERVATION EXPERIMENT AT MAOMING OF SOUTH CHINA

The coastal area of southern China is frequently affected by marine meteorological disasters,and is also one of the key areas that influence the short-term climate change of China.Due to a lack of observational facilities and techniques,little has been done in this area in terms of operational weather monitoring and scientific research on atmospheric and marine environment.With the support of China Meteorological Administration (CMA) and Guangdong Meteorological Bureau (GMB),the Marine Meteorological Science Experiment Base (MMSEB) at Bohe,Maoming has been jointly established by Guangzhou Institute of Tropical and Marine Meteorology (GITMM) and Maoming Meteorological Bureau (MMB) of Guangdong Province after three years of hard work.It has become an integrated coastal observation base that is equipped with a complete set of sophisticated instruments.Equipment maintenance and data quality control procedures have been implemented to ensure the long-term,steady operation of the instruments and the availability of high quality data.Preliminary observations show that the data obtained by the MMSEB reveal many interesting features in the boundary layer structure and air-sea interaction in such disastrous weather as typhoons and sea fog.The MMSEB is expected to play an important role in the scientific research of disastrous weather related to marine meteorology.

Effect of Substrate Nitridation on Properties of Thick GaN Film Grown by Hydride Vapour Phase Epitaxy

Thick GaN films were grown on the sapphire substrate by hydride vapour phase epitaxy. The properties of GaN films were found to be significantly influenced by the duration of exposing the sapphire substrate to ammonia prior to the GaN growth initiation. The crystalline quality of GaN films revealed by high resolution X-ray diffraction were strongly dependent on the nitridation time, which determined substrate surface topography. The different nitridation schemes strongly affected the morphology of GaN overlayers resulting in the blue shift of the main excitonic peak in photoluminescence spectra at room temperature.