The potassium storage performance of carbon nanosheets derived from heavy oils

As by-products of petroleum refining,heavy oils are characterized by a high carbon content,low cost and great variability,making them competitive precursors for the anodes of potassium ion batteries(PIBs).However,the relationship between heavy oil composition and potassium storage performance remains unclear.Using heavy oils containing distinct chemical groups as the carbon source,namely fluid catalytic cracking slurry(FCCS),petroleum asphalt(PA)and deoiled asphalt(DOA),three carbon nanosheets(CNS)were prepared through a molten salt method,and used as the anodes for PIBs.The composition of the heavy oil determines the lamellar thicknesses,sp3-C/sp2-C ratio and defect concentration,thereby affecting the potassium storage performance.The high content of aromatic hydrocarbons and moderate amount of heavy component moieties in FCCS produce carbon nanosheets(CNS-FCCS)that have a smaller layer thickness,larger interlayer spacing(0.372 nm),and increased number of folds than in CNS derived from the other three precursors.These features give it faster charge/ion transfer,more potassium storage sites and better reaction kinetics.CNS-FCCS has a remarkable K^(+)storage capacity(248.7 mAh g^(-1) after 100 cycles at 0.1 A g^(-1)),long cycle lifespan(190.8 mAh g^(-1) after 800 cycles at 1.0 A g^(-1))and excellent rate capability,ranking it among the best materials for this application.This work sheds light on the influence of heavy oil composition on carbon structure and electrochemical performance,and provides guidance for the design and development of advanced heavy oil-derived carbon electrodes for PIBs.

《黄老帛书·十六经》之《五正》等七篇释论

《黄老帛书·十六经》中有《五正》等七篇,托黄帝君臣之名讨论问答者,分别从政治、经济、军事及思想文化等各层面,具体记述了黄帝时所推行的各项举措,取得的功业成就,从而反映出黄帝时代的社会历史风貌,可以窥见到黄老信奉者心中所构想的黄帝时代社会文化格局。此诚为不可多得的记载资料,对于深入揭示黄老学内涵,具有极高价值。

工程认证背景下实践课程成绩评定方法与应用

随着非标准化考试等教学改革的推进,课程成绩评定成为高校实践类课程的重要考核方式。然而,由于缺乏客观定量的评价方法,主观性考核方式在认定考生成绩时存在较大不确定性。如何有效降低主观评判的随意性和不确定性成为课程成绩核定亟须解决的问题。研究提出基于师生协作的综合成绩评估方法,采用动态权重法综合学生打分和教师打分,形成更加合理的综合成绩分布,并以本科必修课程“环境规划与管理”期末成绩评定为例开展案例研究。结果表明,合理应用学生打分能够改善学生成绩分布,但要注意规避学生打分可能存在的均一化倾向和简单等权评分带来的成绩偏态分布问题。研究成果以期为大学实训类课程成绩评定提供一种新的方法。

Synthesis of Crystalline Hydroxyapatite from CaCO_3 and CaHPO_4·2H_2O by Mechanochemical Method

The mixture of CaHPO 4·2H 2O and CaCO 3 was ground in an aqueous system under appropriate conditions to investigate the mechanochemical reaction for the synthesis of crystalline hydroxyapatite (HA) powder. Hydroxyapatite of high crystallinity powder including trace Ca 10 (PO 4) 6CO 3(OH) and Ca 9HPO 4(PO 4) 6OH can be synthesized by mechanical activation without further thermal treatment at a high temperature. The synthesis reaction during the grinding process was almost completed within 1h. The as-ground powder exhibits a particle distribution of 20-100nm in size with a spherical or rodlike morphology. The composition and degree of crystallinity of the mechanochemical synthesized hydroxyapatite powders were coincident with the cement-type hydroxyapatite.

Preparation, Characterization and Photocatalytic Activity of Fe, La Co-doped Nanometer Titanium Dioxide Photocatalysts

A series of photocatalysts of un-doped, single-doped and co-doped nanometer titanium diox- ide （TiO2） have been successfully prepared by template method using Fe（NO3）3.9H2O, La（NO3）3.6H2O, and tetrabutyl titanate as precursors and glucan as template. Scanning electron microscopy, X-ray diffraction, and N2 adsorption-desorption measurement were employed to characterize the morphology, crystal structure and surface structure of the samples. The photo-absorbance of the obtained catalysts was measured by UV-Vis absorption spectroscopy, and the photocatalytic activities of the prepared samples under UV and visible light were estimated by measuring the degradation rate of methyl orange in an aqueous solution. The characterizations indicated that the prepared photocatalysts consisted of anatase phase and possessed high surface area of ca. 163-176 m2/g. It was shown that the Fe and La co-doped nano-TiO2 could be activated by visible light and could thus be used as an effective catalyst in photo-oxidation reactions. The synergistic effect of Fe and La co-doping played an important role in improving the photocatalytic activity. In addition, the possibility of cyclic usage of co-doped nano-TiO2 was also confirmed, the photocatalytic activity of codoped nano-TiO2 remained above 89.6% of the fresh sample after being used four times.

Advances in the Research of Chemical Constituents in Thalictrum Plants

Thalictrum plants are perennial herbs in the family Ranuneulaceae, many of which are of important medicinal values. Alkaloids are major active constituents in Thalictrum plants in addition to a small amount of triterpene and flavonoids. The major pharmacological functions of the active constituents include： anti-tumor, anti- virus, antibiosis, antiphlogosis, hypotensive action, and etc. This paper summarizes the methods for determining the contents of chemical constituents in Thalictrum plants and new chemical constituents discovered in this genus in recent ten years.

Controlled illumination and seismic acquisition geometry for target-oriented imaging

The conventional method of seismic data acquisition geometry design is based on the assumption of horizontal subsurface reflectors, which often is not suitable for complex structure. We start from a controlled illumination analysis and put forward a method of seismic survey geometry design for target-oriented imaging. The method needs a velocity model obtained by a preliminary seismic interpretation. The one-way Fourier finite-difference wave propagator is used to extrapolate plane wave sources on the target layer to the surface. By analyzing the wave energy distribution at the surface extrapolated from the target layer, the shot or receiver locations needed for target layer imaging can be determined. Numerical tests using the SEG-EAGE salt model suggest that this method is useful for confirming the special seismic acquisition geometry layout for target-oriented imaging.

TWO IMPROVED GRAPH-THEORETICAL CLUSTERING ALGORITHMS

Graph-theoretical approaches have been widely used for data clustering and image segmentation recently. The goal of data clustering is to discover the underlying distribution and structural information of the given data, while image segmentation is to partition an image into several non-overlapping regions. Therefore, two popular graph-theoretical clustering methods are analyzed, including the directed tree based data clustering and the minimum spanning tree based image segmentation. There are two contributions： （1） To improve the directed tree based data clustering for image segmentation, （2） To improve the minimum spanning tree based image segmentation for data clustering. The extensive experiments using artificial and real-world data indicate that the improved directed tree based image segmentation can partition images well by preserving enough details, and the improved minimum spanning tree based data clustering can well cluster data in manifold structure.

Mesh Generation for Finite Element Analysis of Electric Machines

This paper describes two modified methods for triangular and quadrilateral meshing for finite element analysis of 2D electric machines. One is coupling the classic Delaunay method and advancing front method to generate optimal triangulation; the other is coupling the classic paving and Delaunay triangulation for optimal quadrilateral meshing. Various electric machine models are meshed successfully to demonstrate the robustness and effectiveness of the methods.

Modified MK model combined with ductile fracture criterion and its application in warm hydroforming

A modified MK model combined with ductile fracture criterion（DFC-MK model） is proposed to compute the forming limit diagrams（FLDs） of 5A06-O aluminum alloy sheet at different temperatures.The material constant（C） of ductile fracture criterion and initial thickness imperfection parameter（f0） at various temperatures are determined by using a new computing method based on wide sheet bending test.The FLDs at 20 and 200 °C are calculated through the DFC-MK model.The DFC-MK model,which includes the influence of through-thickness normal stress,is written into the subroutine VUMAT embedded in Abaqus/ Explicit.The cylindrical cup hydroforming tests are carried out to verify the model.The results show that compared with experimental observations,the predicted FLDs based on DFC-MK model are more accurate than the conventional MK model;the errors between the simulations and experiments in warm hydroforming are 8.23% at 20 °C and 9.24% at 200 °C,which verify the effectiveness of the proposed model.

Fabrication and characterization of tungsten-containing mesoporous silica for heterogeneous oxidative desulfurization

A series of functional,tungsten-containing mesoporous silica materials（W-SiO2） have been fabricated directly from an ionic liquid that contained imidazole and polyoxometalate,which acted as mesoporous template and metal source respectively.These materials were then characterized through X-ray diffraction（XRD）,transmission electron microscopy（TEM）,Raman spectroscopy,Fourier transform infrared spectra（FTIR）,diffuse reflectance spectra（DRS）,and N2 adsorption-desorption,which were found to contain tungsten species that were effectively dispersed throughout the structure.The as-prepared materials W-SiO2 were also found to possess a mesoporous structure.The pore diameters of the respective sample W-SiO2-20 determined from the TEM images ranged from 2 to 4 nm,which was close to the average pore size determined from the nitrogen desorption isotherm（2.9 nm）.The materials were evaluated as catalysts for the heterogeneous oxidative desulfurization of dibenzothiophene（DBT）,which is able to achieve deep desulfurization within 40 min under the optimal conditions（Catalyst（W-SiO2-20）= 0.01 g,temperature = 60℃,oxidant（H2O2）= 20 μL）.For the removal of different organic sulfur compounds within oil,the ability of the catalyst（W-SiO2-20） under the same conditions to remove sulfur compounds decreased in the order：4,6-dimethyldibenzothiophene Dibenzothiophene Benzothiophene 1-dodecanethiol.Additionally,they did not require organic solvents as an extractant in the heterogeneous oxidative desulfurization process.After seven separate catalytic cycles,the desulfurization efficiency was still as high as 90.3%.From the gas chromatography-mass spectrometer analysis,DBT was entirely oxidized to its corresponding sulfone DBTO2 after reaction.A mechanism for the heterogeneous desulfurization reaction was proposed.

Effects of zinc on Fe-based catalysts during the synthesis of light olefins from the Fischer-Tropsch process

Fe‐based catalysts for the production of light olefins via the Fischer‐Tropsch synthesis were modi‐fied by adding a Zn promoter using both microwave‐hydrothermal and impregnation methods. The physicochemical properties of the resulting catalysts were determined by scanning electron mi‐croscopy, the Brunauer‐Emmett‐Teller method, X‐ray diffraction, H2 temperature‐programed re‐duction and X‐ray photoelectron spectroscopy. The results demonstrate that the addition of a Zn promoter improves both the light olefin selectivity over the catalyst and the catalyst stability. The catalysts prepared via the impregnation method, which contain greater quantities of surface ZnO, exhibit severe carbon deposition following activity trials. In contrast, those materials synthesized using the microwave‐hydrothermal approach show improved dispersion of Zn and Fe phases and decreased carbon deposition, and so exhibit better CO conversion and stability.

Adaptive genetic algorithm with the criterion of premature convergence

To counter the defect of traditional genetic algorithms, an improved adaptivegenetic algorithm with the criterion of premature convergence is provided. The occurrence ofpremature convergence is forecasted using colony entropy and colony variance. When prematureconvergence occurs, new individuals are generated in proper scale randomly based on superiorindividuals in the colony. We use these new individuals to replace some individuals in the oldcolony. The updated individuals account for 30 percent - 40 percent of all individuals and the sizeof scale is related to the distribution of the extreme value of the target function. Simulationtests show that there is much improvement in the speed of convergence and the probability of globalconvergence.

Preparation and characterization of ZnSe/CdSe core-shell microspheres

The preparation of Zn Se/Cd Se core-shell structure nanocomposites by using the re-prepared Zn Se microspheres as the template under the hydrothermal condition was presented. The influence of different mole ratios of ZnS e to Cd（NO3）2 on the morphology and structure of the final product was investigated. And the performances of ZnS e/Cd Se core-shell structure nanocomposites were characterized by the means of X-ray diffraction（XRD） analyses, scanning electron microscopy（SEM）, transmission electron microscopy（TEM） and photoluminescence（PL） spectroscopy. The results indicate that the core-shell structure product can be prepared, when the mole ratio of Zn Se to Cd（NO3）2 is larger than 1：1; and the product will be ball solid structure, when the mole ratio of Zn Se to Cd（NO3）2 is equal to 1：1. The photo luminescence results show that Zn Se/Cd Se core-shell structures have high photo luminescence emission properties, and the product with mole ratio of Zn Se to Cd（NO3）2 being 1：0.5 has the best luminescence properties.

A RECURSIVE GENERATIVE APPROACH IN OPTICAL PRISM CAPP

In this paper, the generative approach utilizes recursion to generate process sequence for a part, and then match detail procedure design and select process equipment. A set of recursive formulas are found. Finally a complete process program is produced. The method is simple than that of the knowledge system, the artificial neural networks and variant approach computer aided process planning(VACAPP).

An automatical infill shot method for uniform imaging of target layer

Seismic imaging quality is critical to describing reservoirs. There are many methods that can improve imaging quality; some rely on advanced processing means, whereas others rely on changing the field acquisition methods. However, most of the acquisition methods focus on improving imaging by using infill shots without considering the target-layer illumination energy. Moreover, total infill shooting greatly increases the acquisition cost. In this paper, we present a new method for maximizing the contribution to the target shadow area illumination by automatic local infill shooting. Thus, we designed 2D and 3D models and obtained the depth migration section by forward modeling, infill shots, depth migration, etc. The model results also show that by choosing the most appropriate number of shot points, we can enhance the shadow area energy and improve the target-layer imaging quality at low cost.

A Fast and Efficient Global Router for Congestion Optimization

An efficient parallel global router using random optimization that is independent of net ordering is proposed.Parallel approaches are described and strategies guaranteeing the routing quality are discussed.The wire length model is implemented on multiprocessor,which enables the algorithm to approach feasibility of large scale problems.Timing driven model on multiprocessor and wire length model on distributed processors are also presented.The parallel algorithm greatly reduces the run time of routing.The experimental results show good speedups with no degradation of the routing quality.

Evaluation of volcanic reservoirs with the "QAPM mineral model" using a genetic algorithm

Gas-bearing volcanic reservoirs have been found in the deep Songliao Basin, China. Choosing proper interpretation parameters for log evaluation is difficult due to complicated mineral compositions and variable mineral contents. Based on the QAPF classification scheme given by IUGS, we propose a method to determine the mineral contents of volcanic rocks using log data and a genetic algorithm. According to the QAPF scheme, minerals in volcanic rocks are divided into five groups： Q（quartz）, A （Alkaline feldspar）, P （plagioclase）, M （mafic） and F （feldspathoid）. We propose a model called QAPM including porosity for the volumetric analysis of reservoirs. The log response equations for density, apparent neutron porosity, transit time, gamma ray and volume photoelectrical cross section index were first established with the mineral parameters obtained from the Schlumberger handbook of log mineral parameters. Then the volumes of the four minerals in the matrix were calculated using the genetic algorithm （GA）. The calculated porosity, based on the interpretation parameters, can be compared with core porosity, and the rock names given in the paper based on QAPF classification according to the four mineral contents are compatible with those from the chemical analysis of the core samples.

3-Dimensional Irradiance Imaging with a Single Camera System

The focusing tomography is presented to reconstruct 3 dimensional irradiance distribution. A 3 dimensional luminous body could be considered as the combination of many 2 dimensional parallel luminous sections. Focus on these discrete sections respectively by a single camera, a group of images would be captured to form governing equations of irradiance. After inversion procedure, the irradiance distribution of different sections could be decoded. In this experimentation two lightbulbs are used to simulate two luminous sections. Reasonable results demonstrate that this technique could be a useful method in irradiance reconstruction after further development.

Numerical analysis of coupled finite element with element-free Galerkin in sheet flexible-die forming

A numerical method for coupled deformation between sheet metal and flexible-die was proposed. Based on the updated Lagrangian （UL） formulation, the elastoplastic deformation of sheet metal was analyzed with finite element method （FEM） and the bulk deformation of flexible-die was analyzed with element-free Galerkin method （EFGM）. The frictional contact between sheet metal and flexible-die was treated by the penalty function method. The sheet elastic flexible-die bulging process was analyzed with the FEM-EFGM program for coupled deformation between sheet metal and bulk flexible-die, called CDSB-FEM-EFGM for short. Compared with finite element code DEFORM-2D and experiment results, the CDSB-FEM-EFGM program is feasible. This method provides a suitable numerical method to analyze sheet flexible-die forming.