Meretricis concha is a kind of marine traditional Chinese medicine(TCM), and has been commonly used for the treatment of asthma and scald burns. In order to investigate the relationship between the inorganic elemental...Meretricis concha is a kind of marine traditional Chinese medicine(TCM), and has been commonly used for the treatment of asthma and scald burns. In order to investigate the relationship between the inorganic elemental fingerprint and the geographical origin identification of Meretricis concha, the elemental contents of M. concha from five sampling points in Rushan Bay have been determined by means of inductively coupled plasma optical emission spectrometry(ICP-OES). Based on the contents of 14 inorganic elements(Al, As, Cd, Co, Cr, Cu, Fe, Hg, Mn, Mo, Ni, Pb, Se, and Zn), the inorganic elemental fingerprint which well reflects the elemental characteristics was constructed. All the data from the five sampling points were discriminated with accuracy through hierarchical cluster analysis(HCA) and principle component analysis(PCA), indicating that a four-factor model which could explain approximately 80% of the detection data was established, and the elements Al, As, Cd, Cu, Ni and Pb could be viewed as the characteristic elements. This investigation suggests that the inorganic elemental fingerprint combined with multivariate statistical analysis is a promising method for verifying the geographical origin of M. concha, and this strategy should be valuable for the authenticity discrimination of some marine TCM.展开更多
In order to discuss the effect of tectonic stress on the structural evolution of coal, given the importance attached to High-resolution Transmission Electron Microscopy (HTEM), we investigated several aspects of mater...In order to discuss the effect of tectonic stress on the structural evolution of coal, given the importance attached to High-resolution Transmission Electron Microscopy (HTEM), we investigated several aspects of material structures of high-rank Carboniferous period coal, located in the northern foreland basin of the Dabie orogenic belt in eastern China. High powered crystal lattice images of Bright Fields (BF) and Selected Area Diffraction patterns (SAD) of different types of metamorphism in coal were obtained. The results show that the Basic Structural Units (BSU) become increasingly more compact as a function of rising tem-perature and pressure. Under pressure, the local orientation of molecules is strengthened, the arrangement of BSU speeds up and the degree of order is clearly enhanced.展开更多
Seed long-distance dispersal(LDD) events are typically rare, but are important in the population processes that determine large-scale forest changes and the persistence of species in fragmented landscapes. However, pr...Seed long-distance dispersal(LDD) events are typically rare, but are important in the population processes that determine large-scale forest changes and the persistence of species in fragmented landscapes. However, previous studies focused on species dispersed via animal-mediated LDD, and ignored those dispersed by wind. The aim of this study was to assess the effects of canopy openness, edge, seed source, and patch tree density on the LDD of seeds by wind in forest. We collected birch seeds, a typical wind-dispersed species, throughout a larch plantation. We then assessed the relationship between birch LDD and each factor that may influence LDD of seeds by wind including distance to edge, canopy openness size, distance to mature forest, and the tree density of the larch plantation. We used univariate linear regression analysis to assess the influence of those factors on birch LDD, and partial correlations to calculate the contribution of each factor to LDD. The results showed that both canopy openness and edge had significant influences on birch LDD. Specifically, a negative relationship was observed between distance to edge and birch LDD, whereas there was a positive correlation between canopy openness size and LDD. In contrast, the distance to the mature forest was not correlated with birch LDD. Our results suggest that patch tree density could potently affect the probability of LDD by wind vectors, which provides novel and revealing insights regarding the effect of fragmentation on wind dynamics. The data also provide compelling evidence for the previously undocumented effect of habitat fragmentation on wind-dispersed organisms. As such, these observations will facilitate reasonable conservation planning, which requires a detailed understanding of the mechanisms by which patch properties hamper the delivery of seeds of wind-dispersed plants to fragmented areas.展开更多
Atmospheric particle samples were collected at an urban site of Datong, Shanxi Province, during December 2004 and their element concentrations at different sizes were analyzed by particle-induced X-ray emission (PIXE)...Atmospheric particle samples were collected at an urban site of Datong, Shanxi Province, during December 2004 and their element concentrations at different sizes were analyzed by particle-induced X-ray emission (PIXE). Analysis of the observation data showed that particle pollution was heavy in winter at Datong and that concentrations of most elements were high in the coarse range. Factor analysis (FA) results indicated that the soil and dust, coal combustion dust, and industry dust are main sources for atmospheric particles in winter at Datong. The enrichment factors of element concentrations showed that particle pollution at Datong impacts the down-wind region-Beijing-in the dust season.展开更多
The material sources and control factors of rare earth elemems (REEs) for 25 borehole bulk samples from the Late Permian Longtan Formation in Mount Huaying (borehole number: ZK10-6), Sichuan Province, South China...The material sources and control factors of rare earth elemems (REEs) for 25 borehole bulk samples from the Late Permian Longtan Formation in Mount Huaying (borehole number: ZK10-6), Sichuan Province, South China, were investigated. All samples were determined by inductively coupled plasma mass spectrometry (ICP-MS). The chondrite-normalized distribution patterns of mudstone samples are uniform. All samples belong to the light rare earth element (LREE)-rich type and are enriched in LREEs relative to heavy rare earth elements (HREEs). The distribution curves of REEs in mudstone are highly similar to Mount Emei basalt and the three periods of REEs enrichment correspond to three Mount Emei basalt eruption cycles in Longtan period. The results indicate that REE patterns are not controlled by materials from the seawater or land plants. The predominant sources of REEs are from terrigenous material as indicated by negative Eu anomaly. So, the sources of REEs are controlled by terrigenous material, and the Mount Emei basalt is the predominant source of terrigenous material. Thus, transgression-regression is another control factor of REEs enrichment.展开更多
LA-ICPMS zircon U-Pb dating of intrusive rocks from the Shizishan ore field,Tongling,Anhui Province shows that the crystallization ages of Baimangshan pyroxene diorite,Shizishan and Dongguashan quartz diorite are 139&...LA-ICPMS zircon U-Pb dating of intrusive rocks from the Shizishan ore field,Tongling,Anhui Province shows that the crystallization ages of Baimangshan pyroxene diorite,Shizishan and Dongguashan quartz diorite are 139±1.9,138.0±1.7,and 138.4±1.7 Ma,respectively.These three intrusions are high-potassium,alkali-rich,meta-aluminous,and are characterized by enrichment of light rare earth elements and large-ion lithophile elements,depletion of heavy rare-earth elements(HREE) and high field strength elements,and slightly negative Eu anomalies.In-situ Hf analysis of zircon for these three intrusions shows large ranges of Hf isotope compositions:the ε Hf(t) values are ε Hf(t)= 3.3 to 14.4 for Baimangshan,14.1 to 23.9 Dongguashan,and 14.7 to 26.9 for Shizishan.The ε Hf(t) values of both the Dongguashan and Shizishan quartz diorites are significantly lower than those of Baimangshan pyroxene diorite.Elemental geochemistry and in-situ zircon Hf isotope analyses indicate that the three intrusions were formed through mixing of granitic magma formed by partial melting of the lower crust and water-rich basic magma derived from the enriched lithospheric mantle.The Dongguashan and Shizishan quartz diorites involved greater crustal components than Baimangshan pyroxene diorite.The Dongguashan and Shizishan quartz diorites have geochemical features similar to the adakite,such as high Sr,low Y,and high Sr/Y ratios.Such geochemical features can be attributed to some fractional crystallization of apatite and sphene,and insignificant plagioclase fractional crystallization after magma mixing.These three intrusions are the products of complex crust-mantle interaction during the regional tectonic regime transition from compression to extension.展开更多
Age determinations of the Triassic lithostratigraphic units of the Yanshan belt were previously based on plant fossils and regional correlations of lithologies. The Liujiagou and Heshanggou Formations were assigned as...Age determinations of the Triassic lithostratigraphic units of the Yanshan belt were previously based on plant fossils and regional correlations of lithologies. The Liujiagou and Heshanggou Formations were assigned as the Lower Triassic, and the Ermaying Formation was regarded as the Middle Triassic. We carried out a geochronologic study of detrital zircon grains from the Triassic sandstone in the Xiabancheng and Yingzi basins in northern Hebei where the Triassic strata are exceptionally well preserved. The results show that the Liujiagou, Heshanggou, and Ermaying Formations are all Late Triassic in age. The ages of detrital zircons also revealed that the upper part of the Shihezi Formation and the overlying Sunjiagou Formation, both of which were thought to be the Middle-Late Permian units, are actually late Early to Middle Triassic deposits. This study combines the upper Shihezi and Sunjiagou Formations into a single unit termed as the Yingzi Formation. We also substitute the widely-used Liujiagou, Heshanggou, and Ermaying Formations with the Dingjiagou, Xiabancheng, and Huzhangzi Formations, respectively. Field observations and facies analysis show that the top of the Shihezi Formation is an erosive surface, marking a parallel unconformity between the Middle Permian and Lower Triassic. The Yingzi Formation is composed mainly of meandering river deposits, indicative of tectonic quiescence and low-relief landform in the Early to Middle Triassic. In contrast, the Dingjiagou, Xiabancheng, and Huzhangzi Formations are interpreted as the deposits of sandy/gravelly braided rivers, alluvial fans, fan deltas, and deep lakes in association with volcanism, thus indicating an intense rifting setting. A new Triassic lithostratigraphic division is proposed according to age constraints and facies analysis, and the results are of significance for understanding the early Mesozoic tectonic evolution of the Yanshan belt.展开更多
There are a series of special mountain soils on the Tibetan Plateau of China in an alpine environment for the high altitude. However, very few studies have focused on major soil elements in relation to soil formation ...There are a series of special mountain soils on the Tibetan Plateau of China in an alpine environment for the high altitude. However, very few studies have focused on major soil elements in relation to soil formation in this area. Aluminum (Al), iron (Fe), calcium (Ca), sodium (Na), potassium (K) and magnesium (Mg) contents of 237 topsoil samples covering a 2.8-km altitudinal gradient in uncultivated areas along the Qinghai-Tibet Railway of China were measured using inductively coupled plasma atomic emission spectroscopy. The spatial distribution of the elements and its relationship to the parent rocks and climatic parameters were analyzed. Soils along the gradient are derived from a range of parent materials, but most are less than 30 cm deep with little development (Cambisols). Soil Al, Fe and Mg contents showed a decreasing trend from the start station (Xining Station) to end station (Lhasa Station) of the Qinghai-Tibet Railway, whereas soil K and Na contents were relative stable from Xining Station to the Kunlun Mountains and then increased gradually. Soil Ca content was lower in the southern part of the Tanggula Mountains. The major soil element contents clearly reflected the parent rock and climatic influences. Soils with higher Ca content appeared in areas with Ca-Mg carbonate rocks, soils with higher Al were found in areas with silicate-rich and high-Al silicate clastic rocks and silicate-rich aluminosilicate loose sediments. Soils with higher K and Na contents appeared in areas with high-K, high-Na and silicate-rich aluminosilicate rocks. Soil Na and K contents were affected by temperature, whereas the contents of Mg, Fe, Ca and Al were more affected by precipitation. Soil Na and K contents increased with increasing temperatures, whereas the contents of Mg, Fe, Ca and Al decreased with increasing precipitation. This analysis provides a relationship between soil properties and rapidly changing environmental conditions. The data can be used to investigate the effect of the climate or land use change on soil properties.展开更多
基金supposed by the Program for Science and Technology of Shandong Province (2011GHY11521)the Department of Education of Shandong Province (No. J11LB07)the Natural Science Foundation of Qingdao City (Nos. 12-1-3-52-(1)-nsh and 12-1-4-16-(7)-jch)
文摘Meretricis concha is a kind of marine traditional Chinese medicine(TCM), and has been commonly used for the treatment of asthma and scald burns. In order to investigate the relationship between the inorganic elemental fingerprint and the geographical origin identification of Meretricis concha, the elemental contents of M. concha from five sampling points in Rushan Bay have been determined by means of inductively coupled plasma optical emission spectrometry(ICP-OES). Based on the contents of 14 inorganic elements(Al, As, Cd, Co, Cr, Cu, Fe, Hg, Mn, Mo, Ni, Pb, Se, and Zn), the inorganic elemental fingerprint which well reflects the elemental characteristics was constructed. All the data from the five sampling points were discriminated with accuracy through hierarchical cluster analysis(HCA) and principle component analysis(PCA), indicating that a four-factor model which could explain approximately 80% of the detection data was established, and the elements Al, As, Cd, Cu, Ni and Pb could be viewed as the characteristic elements. This investigation suggests that the inorganic elemental fingerprint combined with multivariate statistical analysis is a promising method for verifying the geographical origin of M. concha, and this strategy should be valuable for the authenticity discrimination of some marine TCM.
基金support for this work, provided by the National Natural Science Foundation of China (No40872105)the Scientific Research Foundation of the North China Institute of Science Technology (NoA08002)
文摘In order to discuss the effect of tectonic stress on the structural evolution of coal, given the importance attached to High-resolution Transmission Electron Microscopy (HTEM), we investigated several aspects of material structures of high-rank Carboniferous period coal, located in the northern foreland basin of the Dabie orogenic belt in eastern China. High powered crystal lattice images of Bright Fields (BF) and Selected Area Diffraction patterns (SAD) of different types of metamorphism in coal were obtained. The results show that the Basic Structural Units (BSU) become increasingly more compact as a function of rising tem-perature and pressure. Under pressure, the local orientation of molecules is strengthened, the arrangement of BSU speeds up and the degree of order is clearly enhanced.
基金National Natural Science Foundation of China(No.31300526)National Key Technologies R&D Program of China(No.2012BAD22B04)Chinese Forest Ecosystem Research Network&GENE Award Funds on Ecological Paper
文摘Seed long-distance dispersal(LDD) events are typically rare, but are important in the population processes that determine large-scale forest changes and the persistence of species in fragmented landscapes. However, previous studies focused on species dispersed via animal-mediated LDD, and ignored those dispersed by wind. The aim of this study was to assess the effects of canopy openness, edge, seed source, and patch tree density on the LDD of seeds by wind in forest. We collected birch seeds, a typical wind-dispersed species, throughout a larch plantation. We then assessed the relationship between birch LDD and each factor that may influence LDD of seeds by wind including distance to edge, canopy openness size, distance to mature forest, and the tree density of the larch plantation. We used univariate linear regression analysis to assess the influence of those factors on birch LDD, and partial correlations to calculate the contribution of each factor to LDD. The results showed that both canopy openness and edge had significant influences on birch LDD. Specifically, a negative relationship was observed between distance to edge and birch LDD, whereas there was a positive correlation between canopy openness size and LDD. In contrast, the distance to the mature forest was not correlated with birch LDD. Our results suggest that patch tree density could potently affect the probability of LDD by wind vectors, which provides novel and revealing insights regarding the effect of fragmentation on wind dynamics. The data also provide compelling evidence for the previously undocumented effect of habitat fragmentation on wind-dispersed organisms. As such, these observations will facilitate reasonable conservation planning, which requires a detailed understanding of the mechanisms by which patch properties hamper the delivery of seeds of wind-dispersed plants to fragmented areas.
基金supported by Financial Project of the Beijing Municipal Financial Bureau (No. PXM2008_ 178305_06995)the Pilot Project of the Knowledge Innovation Program of the Chinese Academy of Sciences (KZCX2-YW-Q11-03)the 100 Talents Program (Aerosol Characteristics and Its Climatic Impact) of the Chinese Academy of Sciences
文摘Atmospheric particle samples were collected at an urban site of Datong, Shanxi Province, during December 2004 and their element concentrations at different sizes were analyzed by particle-induced X-ray emission (PIXE). Analysis of the observation data showed that particle pollution was heavy in winter at Datong and that concentrations of most elements were high in the coarse range. Factor analysis (FA) results indicated that the soil and dust, coal combustion dust, and industry dust are main sources for atmospheric particles in winter at Datong. The enrichment factors of element concentrations showed that particle pollution at Datong impacts the down-wind region-Beijing-in the dust season.
基金Project(40839910) supported by the National Natural Science Foundation of China
文摘The material sources and control factors of rare earth elemems (REEs) for 25 borehole bulk samples from the Late Permian Longtan Formation in Mount Huaying (borehole number: ZK10-6), Sichuan Province, South China, were investigated. All samples were determined by inductively coupled plasma mass spectrometry (ICP-MS). The chondrite-normalized distribution patterns of mudstone samples are uniform. All samples belong to the light rare earth element (LREE)-rich type and are enriched in LREEs relative to heavy rare earth elements (HREEs). The distribution curves of REEs in mudstone are highly similar to Mount Emei basalt and the three periods of REEs enrichment correspond to three Mount Emei basalt eruption cycles in Longtan period. The results indicate that REE patterns are not controlled by materials from the seawater or land plants. The predominant sources of REEs are from terrigenous material as indicated by negative Eu anomaly. So, the sources of REEs are controlled by terrigenous material, and the Mount Emei basalt is the predominant source of terrigenous material. Thus, transgression-regression is another control factor of REEs enrichment.
基金supported by National Basic Research Program of China (GrantNo. 2012CB416702)National Natural Science Foundation of China(Grant No. 40930742)+1 种基金Key Project of Natural Science Foundation of Jiangsu Province (Grant No. BK2008026)National Key Technology R&D Program (Grant No. 2009BAB43B03)
文摘LA-ICPMS zircon U-Pb dating of intrusive rocks from the Shizishan ore field,Tongling,Anhui Province shows that the crystallization ages of Baimangshan pyroxene diorite,Shizishan and Dongguashan quartz diorite are 139±1.9,138.0±1.7,and 138.4±1.7 Ma,respectively.These three intrusions are high-potassium,alkali-rich,meta-aluminous,and are characterized by enrichment of light rare earth elements and large-ion lithophile elements,depletion of heavy rare-earth elements(HREE) and high field strength elements,and slightly negative Eu anomalies.In-situ Hf analysis of zircon for these three intrusions shows large ranges of Hf isotope compositions:the ε Hf(t) values are ε Hf(t)= 3.3 to 14.4 for Baimangshan,14.1 to 23.9 Dongguashan,and 14.7 to 26.9 for Shizishan.The ε Hf(t) values of both the Dongguashan and Shizishan quartz diorites are significantly lower than those of Baimangshan pyroxene diorite.Elemental geochemistry and in-situ zircon Hf isotope analyses indicate that the three intrusions were formed through mixing of granitic magma formed by partial melting of the lower crust and water-rich basic magma derived from the enriched lithospheric mantle.The Dongguashan and Shizishan quartz diorites involved greater crustal components than Baimangshan pyroxene diorite.The Dongguashan and Shizishan quartz diorites have geochemical features similar to the adakite,such as high Sr,low Y,and high Sr/Y ratios.Such geochemical features can be attributed to some fractional crystallization of apatite and sphene,and insignificant plagioclase fractional crystallization after magma mixing.These three intrusions are the products of complex crust-mantle interaction during the regional tectonic regime transition from compression to extension.
基金supported by the National Natural Science Foundation of China(Grant Nos.91114204 and 40972151)
文摘Age determinations of the Triassic lithostratigraphic units of the Yanshan belt were previously based on plant fossils and regional correlations of lithologies. The Liujiagou and Heshanggou Formations were assigned as the Lower Triassic, and the Ermaying Formation was regarded as the Middle Triassic. We carried out a geochronologic study of detrital zircon grains from the Triassic sandstone in the Xiabancheng and Yingzi basins in northern Hebei where the Triassic strata are exceptionally well preserved. The results show that the Liujiagou, Heshanggou, and Ermaying Formations are all Late Triassic in age. The ages of detrital zircons also revealed that the upper part of the Shihezi Formation and the overlying Sunjiagou Formation, both of which were thought to be the Middle-Late Permian units, are actually late Early to Middle Triassic deposits. This study combines the upper Shihezi and Sunjiagou Formations into a single unit termed as the Yingzi Formation. We also substitute the widely-used Liujiagou, Heshanggou, and Ermaying Formations with the Dingjiagou, Xiabancheng, and Huzhangzi Formations, respectively. Field observations and facies analysis show that the top of the Shihezi Formation is an erosive surface, marking a parallel unconformity between the Middle Permian and Lower Triassic. The Yingzi Formation is composed mainly of meandering river deposits, indicative of tectonic quiescence and low-relief landform in the Early to Middle Triassic. In contrast, the Dingjiagou, Xiabancheng, and Huzhangzi Formations are interpreted as the deposits of sandy/gravelly braided rivers, alluvial fans, fan deltas, and deep lakes in association with volcanism, thus indicating an intense rifting setting. A new Triassic lithostratigraphic division is proposed according to age constraints and facies analysis, and the results are of significance for understanding the early Mesozoic tectonic evolution of the Yanshan belt.
基金supported by the Strategic Priority Research Program of Chinese Academy of Sciences (No.XDB03030500)the National Key Technology Research and Development Program of China (No.2013BAC04B02)the National Natural Science Foundation of China (Nos.40801042 and 90202012)
文摘There are a series of special mountain soils on the Tibetan Plateau of China in an alpine environment for the high altitude. However, very few studies have focused on major soil elements in relation to soil formation in this area. Aluminum (Al), iron (Fe), calcium (Ca), sodium (Na), potassium (K) and magnesium (Mg) contents of 237 topsoil samples covering a 2.8-km altitudinal gradient in uncultivated areas along the Qinghai-Tibet Railway of China were measured using inductively coupled plasma atomic emission spectroscopy. The spatial distribution of the elements and its relationship to the parent rocks and climatic parameters were analyzed. Soils along the gradient are derived from a range of parent materials, but most are less than 30 cm deep with little development (Cambisols). Soil Al, Fe and Mg contents showed a decreasing trend from the start station (Xining Station) to end station (Lhasa Station) of the Qinghai-Tibet Railway, whereas soil K and Na contents were relative stable from Xining Station to the Kunlun Mountains and then increased gradually. Soil Ca content was lower in the southern part of the Tanggula Mountains. The major soil element contents clearly reflected the parent rock and climatic influences. Soils with higher Ca content appeared in areas with Ca-Mg carbonate rocks, soils with higher Al were found in areas with silicate-rich and high-Al silicate clastic rocks and silicate-rich aluminosilicate loose sediments. Soils with higher K and Na contents appeared in areas with high-K, high-Na and silicate-rich aluminosilicate rocks. Soil Na and K contents were affected by temperature, whereas the contents of Mg, Fe, Ca and Al were more affected by precipitation. Soil Na and K contents increased with increasing temperatures, whereas the contents of Mg, Fe, Ca and Al decreased with increasing precipitation. This analysis provides a relationship between soil properties and rapidly changing environmental conditions. The data can be used to investigate the effect of the climate or land use change on soil properties.