牢记历史 珍爱和平——纪念太原审判日本战犯65周年兼评《残留》一书的价值

1956年6月中华人民共和国最高人民法院特别军事法庭,在太原开庭审判城野宏等8名日本战犯。案件中,“被告人在中国犯下了双重的战争罪行,他们不仅在日本军国主义侵略中国期间,是侵略战争的坚决执行者,而且在日本投降以后,还是新的侵略武装的拼凑者和新的侵略战争阴谋组织者”。这一拼凑新的侵略武装、组织新的侵略战争阴谋的历史事件,就是二战结束后侵华日军“残留”事件。文中概述这次审判的过程与重要意义,深入揭示侵华日军“残留”的历史真相和“残留”日军纲领宗旨、罪恶事实,兼评史著《残留》全景纵深记述日军“残留”经过、结局,把历史真实与现实警示告诸世界、留给历史的重要价值。

畜禽产品中药物残留的控制策略

本刊上期刊登了《兽药残留的危害及解诀对策》一文后,我们陆续接到了一些读者的来电,希望我们在今后应多刊登一些这方面的稿件,以便能够引起有关部门的高度重视,进一步规范兽药市场,正确引导广大的养殖场户正确使用兽药。为满足这些热心读者的要求,我们于本期特刊登了下面这篇文章,借此,我们相信广大读者将对兽筠残留的危害会有更进一步的认识和了解。

残留的蜡烛

布莱克探长到一个偏僻的小村子处理一个案件。村里有一对老姐妹，姐姐叫梅丽，妹妹叫丽曼，两人相依为命，靠开一家小店为生。日子过得非常俭朴，有一点积蓄。妹妹年轻时嫁过人，生了一个儿子叫马可。后来，她的丈夫不知去向，马可却长成了十足的无赖。

Microstructure and mechanical properties of TC21 titanium alloy by near-isothermal forging

Microstructure and tensile properties of TC21 titanium alloy after near-isothermal forging with different parameters plus solution treatment and aging were investigated. It is found that the residual β matrix, which was strengthened by fine secondary α platelets forming during aging, exists in all the samples; while primary equiaxed α phase, bent lamellar α phase and α plates are simultaneously or individually present in one sample. The strength of alloy increases proportionally with increasing the content of residual β matrix, which is the result of increasing α/β interphase boundary. The plasticity of alloy has a downward trend as the content of residual β matrix increases. This attributes to the increase of fine secondary α platelets, which are cut by dislocations during the deformation. Additionally, coarse α plates with long axis parallel to the maximum resolved shear stress（MRSS） also reduce the plasticity of TC21 alloy.

Microstructural evolution of Al-Zn-Mg-Zr alloy with trace amount of Sc during homogenization treatment

The microstructural evolution of Al-Zn-Mg-Zr alloy with trace amount of Sc during homogenization treatment was studied by means of metallographic analysis, scanning electron microscopy （SEM）, energy dispersive X-ray （EDX） and differential scanning calorimetry （DSC）. The results show that serious dendritic segregation exists in studied alloy ingot. There are many eutectic phases with low melting-point at grain boundary and the distribution of main elements along interdendritic region varies periodically. Elements Zn, Mg and Cu distribute unevenly from grain boundary to the inside of alloy. With increasing the homogenization temperature or prolonging the holding time, the residual phases are dissolved into matrix α（Al） gradually during homogenization treatment, all elements become more homogenized. The overburnt temperature of studied alloy is 476.7 °C. When homogenization temperature increases to 480 °C, some spherical phases and redissolved triangular constituents at grain boundaries can be easily observed. Combined with microstructural evolution and differential scanning calorimeter, the optimum homogenization parameter is at 470 °C for 24 h.

Determination of 2 Amides Pesticide Residues in Agricultural Products by Terahertz Time-domain Spectroscopy

[Objective] The aim was to explore the application of terahertz （THz） technique in pesticide recognition and residue determination. [Method] THz far-infrared spectral characteristics of 2 herbicides （butachlor and metolachlor） were measured by THz time-domain spectroscopy （THz-TDS） under conditions of room temperature and nitrogen,meanwhile their refractive index and absorption coefficient between 0.2 and 2.2 THz were calculated by using models based on Fresenl equations. [Result] The 2 pesticides both had a series of different characteristic absorption peaks between 0.2 and 2.2 THz,respectively. Their molecular structures were similar,but there were great difference in absorption and refractive index spectrum between them. [Conclusion] THz-TDS technique is feasible to detect pesticide residues,especially there is a greater advantage in identifying the structure of similar substances.

Simultaneous Determination of Four Pesticide Residues in Fruit Juice by HPLC

[Objective] This study was conducted to develop a system for simultaneous determination of imidacloprid, diflubenzuron, thiabendazole and carbendazim in fruit juice by HPLC. [Method] Using acetonitrile as the extraction solvent, the pesticides in fruit juice were purified through a NH2 solid phase extraction （SPE） cartridge, then detected by HPLC. [Result] There was a good linear relationship between the peak area and the concentrations of imidacloprid, diflubenzuron, thiabendazole and carbendazim in a range of 0.05-5.0 μg/ml, and the linear correlation coefficient varied in a range of 0.999 0-0.999 8; the limit of detection for imidacloprid, diflubenzuron, thiabendazole and carbendazim was 0.003, 0.005, 0.003 and 0.007 mg/kg, respectively. The recovery rate of imidacloprid, diflubenzuron, thiabendazole and carbendazim standards added at three levels （0.1, 0.5 and 1.0 mg/kg） ranged from 82% to 107%, with RSD less than 4.5%. [Conclusion] The sensitivity, accuracy and precision of this method were able to meet the requirements for pesticide residue analysis.

Gel Filtration Chromatography Combined with Bradford Method for Determination of Total Residual Protein in Ferment Antibiotics

Aim A novel method has been developed for evaluation of the levels of total residual protein in antibiotics produced by fermentation using gel filtration chromatography (GFC) combined with Bradford assay based on determination of residual protein in lincomycin hydrochloride. Methods The chromatographic conditions were SuperdexTM peptide column, 0.01 mol*L-1 phosphate buffer solution as mobile phase, and flow rate of 1 mL·min-1. Five hundred microliters of lincomycin hydrochloride solution (3 g of lincomycin hydrochloride dissolved in 10 mL of mobile phase) was injected into the chromatograph and the eluted solution was collected between 6 min and 14.5 min (protein eluted from column within this period), and the residual content of total protein in the eluted solution was assayed using Bradford assay method. Results The average recovery was more than 90% for bovine serum albumin, the calibration equation for the range of 0-12 μg·mL-1 of protein was y=-0.002 4x2+0.064 2x+0.002 9, r2=0.999 9, RSD=0.1%-0.9%, and the LOD and LOQ were 3 and 10 ng·mL-1 of protein, respectively. Conclusion The novel method for determining the residual protein in ferment antibio-tics is simple, rapid, and precise.

Study on Detection of Organochlorine Pesticide Residue in Ginseng

To investigate the residue situation of pesticides in ginseng, total 17 samples of ginseng-growing soil, ginseng roots and ginseng seeds were collected from 5 regions of Fusong County, and the contents of organochlorine pesticide residues in the samples were detected by using ultrasonic-assisted extraction and gas chromatography with acetone-ligroin as the solvent, thereby providing suitable recommendations and scientific basis for the selection of ginseng-growing soil.

Investigation and Analysis of Pesticide Residues in Citrus from Parts of Hubei Province

The analysis of pesticide residues in Citrus from Yichang, Danjiangkou, Zigui and Xingshan in Hubei Province was accomplished by UPLC-MS and GC-MS. The results showed that the detection rate of pesticide residues in Citrus reticulate was 91.9%. The detection rate of banned pesticides was 1.6%. The detection rate of restricted pesticides was 9.5%. The detection rate of allowed pesticides was 68.3%. The detection rate of unregistered pesticides was 15.9%. The pesticide used in citrus was relatively common. Because of the banned and restricted pesticides were both in the control degree, on the whole, the quality and security of Citrus reticulata was safe.

Residue and Degradation Dynamics of Bensulfuron-methyl·Mefenacet 4.2 g/kg Granule in Paddy Field

This study was conducted to determine the safety of bensulfuron-methyl and mefenacet in rice ecosystem. A field experiment was carried to reveal residual dynamics and final residue of bensulfuron-methyl.mefenacet 4.2 g/kg granule in rice and paddy system in Hangzhou, Changsha and Nanning of China during 2010 to 2011. The results showed that the average recoveries of bensulfuron-methyl and mefenacet spiked in the paddy soil, paddy water, rice, husk and rice plant at the 3 concentration levels of 0.05, 0.10 and 1.00 mg/kg ranged from 70.78% to 116.06% with the relative standard deviations of 0.91%-10.24%. The limit of detection （LOD） values of bensulfuron-methyl and mefenacet were 0.02 mg/L, and the minimum de- tection quantities were 4.0×10-9 g. The degradation dynamics test was done by spraying at a high dose （270 kg/hm2, bensulfuron-methyl active ingredient was 64.8 g/hm2, mefenacet active ingredient was 1 069.2 g/hm2） by direct spreading method 5-7 d after transplanting, and the final residual test carried out at a low dose （180 kg/hm2, bensuifuron-methyl active ingredient was 43.2 g/hm2, mefenacet active in- gredient was 712.8 g/hm2） and a high dose （270 kg/hm2）. The degradation research of bensulfuron-methyl and mefenacet in paddy water, soil and rice plant suggested that the degradation curves accorded with the first-order kinetics equation, the aver- age half life of bensulfuron-methyl was 5.35, 3.05 and 3.71 d in water, soil and rice plant, respectively, and the average half life of mefenacet was 3.61, 3.29 and 3.88 d in water, soil and rice plant, respectively. The final residues of bensulfuron-methyl and mefenacet were not detected in normal harvest paddy soil, rice straw, husk and brown rice.

Determination of 10 Pyrethroids Pesticide Residues in Rice by GC-MS-MS

[Objective] A method was developed for the determination of 10 pyrethroids pesticide residues in rice by GC-MS-MS. [Method] Pyrethroids were extracted with acetonitrile, followed by a salting-out step with anhydrous magnesium sulfate and sodium chloride, cleaned up by florisil solid phase extraction （SPE） cartridge, and determined by multiple reaction monitoring mode. [Result] The method showed good linearity over the range of 0.010-0.500 mg/L for 10 pyrethroid pesticide with correlation coefficients over 0.99. The detection limits were 0.005 -0.010 mg/kg. The method was validated by analyzing samples spiked with 0.05, 0.10, 0.20 mg/kg of 10 pyrethroid pesticides, respectively. The average recoveries in rice ranged from 75.0-115.5%, and the relative standard deviations （RSD） were between 3.9%-6.9%. [Conclusion] The method is easy, accurate and reliable, which can meet the requirement for the simultaneous determination and confirmation of pyrethroid pesticide residues in rice.

Quality Detection of Hainan Honey Pomelo

Quality analysis was performed to major cultivars, ‘Hongxin pomelo’ and ‘Wuzi pomelo＇ with uniform maturity. Total soluble solid （TSS）, titratable acid, vita- min C, juice yield, edible rate, single-fruit weight and pesticide residues of the 2 cultivars were detected. The results showed that： the TSS contents of ‘Hongxin pomelo＇ and ‘Wuzi pomelo＇ were in the range of 8%-12%, the vitamin C contents were in the range of 0.3-0.6 g/L, the juice yields were in the range of 56%-68%, the edible rates were in the range of 52%-68%, and the single-fruit weights were in the range of 1-2.5 kg. The titratable acid content was higher in ‘Hongxin pomelo＇ than in ‘Wuzi pomelo＇. Only Dursban and imidacloprid were detected at low con- centrations in pericarp, and the residues of the 3 pesticides were all lower than their detection limits. Therefore, honey pomelo produced in Hainan all could be ate safely.

Quality Detection of Fresh Longan Fruit in Hainan

[Objective] This study was conducted to investigate the fresh eating-quality of Hainan Iongan. [Methed] The quality analysis was conducted on on-season and off-season Iongan, which are main cultivars in Hainan consistent in maturity. In order to understand the quality characteristics of Hainan fresh Iongan, saccharide contents, vitamin C content, edible rate, TSS, weight of single fruit, weight per fruit cluster and pesticide residues were detected in this study. [Result] There were no significant differences in quality between on-season and off-season Iongan, and the content of TSS in off-season fruit was slightly higher than that in on-season Iongan. The two main cultivars ‘Shixia＇ and ＇Chuliang＇ in Hainan differed significantly in edible quality. The weight of single fruit and edible rate of ‘Chuliang＇ were slightly higher than those of ‘Shixia＇ Iongan, and their sucrose contents were nearly equivalent. Vitamin C and TSS contents in ‘Shixia＇ Ionganwere higher than those in ‘Chuliang＇.‘Shixia＇ had a monosaccharide content significantly higher than ‘Chuliang＇, while its sucrose content was lower than ‘Chuliang＇. Only low contents of residual cypermethrin and diflubenzuron were detected in pericarp, and the contents of the 9 pesticides in fruit flesh were all lower than their detection limits. [Conclusion] Longan fruit produced in Hainan could all be eaten safely.

Residue and Degradation Dynamic of Buprofezin in Citrus and Soil

[Objective] The paper was to detect the residue of buprofezin in citrus and soil.[Method] Gas chromatography（GC）method was used to measure the residue of buprofezin in citrus and soil.[Result] The average recovery rate of buprofezin in entire citrus fruit was 96.17%-97.38%,and the variation coefficient was 6.10%-9.07%;the average recovery rate in pulp was 95.24%-105.46%,and the variation coefficient was 3.30%-6.01%;the average recovery rate in peel was 88.76%-93.64%,and the variation coefficient was 5.12%-6.27%;the average recovery rate in soil was 97.79%-104.3%,and the variation coefficient was 2.45%-9.21%.The degradation dynamics and the final residue results of buprofezin in citrus and soil showed that the degradation half-lives in citrus in Changsha（Hunan）,Hangzhou（Zhejiang）and Guiyang（Guizhou）were 7.65,7.64 and 8.40 d,and the degradation half-lives in soil in three places were 13.75,9.97 and 10.18 d,respectively.[Conclusion] When 25% buprofezin SC watered agent were sprayed in citrus fruits for 2-3 times according to the recommended dose of 166.7-250.0 mg/L,the safe period of buprofezin in citrus could be set as 14 d.

Effects of Soil Nitrate Nitrogen Residues and Leaching for Different Kinds of Slow-release Nitrogen Fertilizers in Tall-fescue Soil

ObjectiveThe aim was to explore the movement of nitrate nitrogen in tall-fescue soils by different kinds of slow release nitrogen fertilizers. MethodBased on infiltration-tanks and test plots, a new and environment friendly fertilizer was explored. ResultThe results show that compared with urea treatment, slow-release nitrogen fertilizer treatments could reduce nitrate nitrogen content and leaching amount in soils. Compared with PCU30 and IU treatments, the PCU60 treatment became more efficient in reducing nitrate content and leaching amount in 0-90 cm soil layer. ConclusionIn summary, slow-release nitrogen fertilizer, which can reduce soil nitrate content and leaching losses, is a kind of novel fertilizer with high environmental benefit and promising application.

Usage of Pesticides and Control Measures in Qujing City

[Objective] The aim was to investigate pesticide use in Qujing city and explore the control measures.[Method] Surveys were made on pesticide use by farmers in five vegetable bases in Qujing city by questionnaires to study pesticide use and existing problems by farmers.[Result] Some problems existed in pesticide use in Qujing,such as non-standard pesticide source,lower-recognition of pesticide and impacts of pesticide residues on environment,and without professional guidance.[Conclusion] The existing problems can be resolved by enhancing technical trainings of technicians or pesticide managers,strengthening pesticide promotion,and reinforcing examination of pesticide residues.

Study on Pesticide Residues of Phorate and Emamectin Benzoate in Cauliflower with Ball Well Protected

In order to study the difference between cauliflower varieties with ball well protected and unprotected in terms of pesticide residue and its causes, Jinpin 70, a new male sterile cauliflower variety with ball well protected, and Xuebao with ball unprotected were sprayed with high-toxic pesticide phorate and efficient bio-pesticide emamectin benzoate at a regular dose to investigate the impact of different cauliflower varieties on the pesticide residue. The results showed that from the 3rd to the 5th day after spraying, phorate and emamectin benzoate residues in Jinpin 70 with ball well protected reduced by 76.47%-87.65% and 67.86%-80.82% re- spectively compared with Xubao, and decreased by 9.23%-81.82% and 57.14%- 79.84% respectively compared with Jinpin 70 with ball unprotected. The results above demonstrates that inner leaves of cauliflower with ball well protected can prevent the ball from being polluted by phorate and emamectin benzoate, thereby improving its edible safety.

Effects of N, P and K on Output and Nutrient Cycle of Vegetables in Greenhouses

ObjectiveThe aim was to increase farmers’ income and reduce the waste of fertilizer by exploring effects of N, P and K fertilizations on vegetable yields and the accumulation of N, P and K in vegetable and soils. MethodThe fertilization tests were conducted on tomato, cauliflower and celery in greenhouses. ResultWhen N, P and K were not applied in tomato, cauliflower or celery, the yields reduced in 6.0%-13.8% and total annual income reduced by 39 220, 36 902 and 22 023 yuan/hm 2 respectively, suggesting that N, P and K are limiting factors of yield. The absorbed N amounts of tomato and cauliflower were higher compared with celery; the absorbed P amount of cauliflower was higher compared with tomato and celery; the absorbed K amount of tomato was the highest, followed by celery and cauliflower. The absorbed N in tomato fruit was lower than that of cauliflower and the absorbed N amount of other parts of tomato was also lower. Furthermore, the absorbed amounts of P and K by tomato and cauliflower fruits were higher than it absorbed by the other parts, especially the absorbed of K was significantly high. Total absorbed amounts of N, P and K from high to low were cauliflower, tomato and celery. After harvesting of tomato, cauliflower and celery, N, P and K in soils were all higher compared with soils before planting. Influenced by fertilizers, residual N content in soils grown with tomato and residual P content in soils grown with celery both doubled compared with base soils. Cauliflower plants were not applied with organic fertilizer, and residual N and K contents in soils were lower compared with tomato and celery. ConclusionResidual P content in soils is higher, which is a kind of waste and would cause pollution on soils. It is necessary to improve the proportion of organic and inorganic fertilizers in fertilization.

Study on Analytical Method of Endosulfan Residue in Apple

This study was conducted to establish an analytical method for endosulfan residue in apple. Samples were extracted with 30 ml of acetone ： ethyl acetate （9：1）, purified with FlorisiL （containing activated carbon）, and detected by GC. Under those detection conditions, the detection limits of α-endosulfan, 15-endosulfan and endosulfate were 10^-11, 10^-11, and 2.5×10^-11 g, respectively. The recoveries of α-en- dosulfan were in the range of 89.49%-95.34%, with CVs in the range of 1.45%- 2.69%; the recoveries of β-endosulfan were in the range of 99.35%-100.63%, with CVs in the range of 1.39%-4.72%; and the recoveries of endosulfan suffate were in the range of 95.32%-101.15%, with CVs in the range of 1.19%-3.21%. The accu- racy, precision and sensitivity of the method all satisfy the requirements of pesticide residue analysis.