水波

回过头 远远望去 南湖那片水域 浪花簇拥 洁白

Effects of zinc on Fe-based catalysts during the synthesis of light olefins from the Fischer-Tropsch process

Fe‐based catalysts for the production of light olefins via the Fischer‐Tropsch synthesis were modi‐fied by adding a Zn promoter using both microwave‐hydrothermal and impregnation methods. The physicochemical properties of the resulting catalysts were determined by scanning electron mi‐croscopy, the Brunauer‐Emmett‐Teller method, X‐ray diffraction, H2 temperature‐programed re‐duction and X‐ray photoelectron spectroscopy. The results demonstrate that the addition of a Zn promoter improves both the light olefin selectivity over the catalyst and the catalyst stability. The catalysts prepared via the impregnation method, which contain greater quantities of surface ZnO, exhibit severe carbon deposition following activity trials. In contrast, those materials synthesized using the microwave‐hydrothermal approach show improved dispersion of Zn and Fe phases and decreased carbon deposition, and so exhibit better CO conversion and stability.

Microwave-hydrothermal preparation of flower-like ZnO microstructure and its photocatalytic activity

The flower-like ZnO microstructure was prepared by a straightforward microwave-hydrothermal technique using zinc chloride and arginine solution as reactants. The as-synthesized crystal structure and morphology were characterized by X-ray diffraction （XRD）, scanning electron microscopy （SEM） and the optical properties of the ZnO nanostructure were studied by Raman and photoluminescence （PL） spectra, which confirms the high crystal quality of ZnO microstructure. The as-synthesized ZnO flowers exhibit a significant enhancement of photocatalytic capability toward degrading methyl blue （MB） under UV light, the photodegradation of MB reaches 95.60%, only within 2 h of adding the as-synthesized ZnO in the MB solution under UV irradiation. Furthermore, the photodegradation could be described as the pseudo-first-order kinetics with degradation rate constant of 1.0675-1.6275 h-1, which is relative to the morphology of the structures.

Acoustic evaluation of cementing quality using obliquely incident ultrasonic signals

Ultrasonic cement bond logging is a widely used method for evaluating cementing quality. Conventional ultrasonic cement bond logging uses vertical incidence and cannot accurately evaluate lightweight cement bonding. Oblique incidence is a new technology for evaluating cement quality with improved accuracy for lightweight cements. In this study, we simulated models of acoustic impedance of cement and cementing quality using ultrasonic oblique incidence, and we obtained the relation between cementing quality, acoustic impedance of cement, and the acoustic attenuation coeffi cient of the A0-mode and S0-mode Lamb waves. Then, we simulated models of different cement thickness and we obtained the relation between cement thickness and the time difference of the arrival between the A0 and A0′ modes.

EXPERIMENTAL STUDY ON DARCY′S LAW IN HELE-SHAW CELLS

The basic physics of unsteady Hele-Shaw flow at high Reynolds numbers is mainly studied by an experimental measurement. In order to confirm the Darcy′s law in Hele-Shaw cell, since there is an analogy between flow in cells and that in porous media, progressive water waves are utilized to build an unsteady flow in a Hele-Shaw cell, and which complex wave number is measured by a wave height gauge. Meanwhile, theoretical analyses are used to compare with experimental data. Result shows Darcy′s Law is not exactly correct for unsteady Hele-Shaw flows, and it is expected to conduct a modified Darcy′s Law.

The influence of sea water velocity variation on seismic traveltimes,ray paths,and amplitude

The main factors affecting seismic exploration is the propagation velocity of seismic waves in the medium. In the past, during marine seismic data processing, the propagation velocity of sea water was generally taken as a constant 1500 m/s. However, for deep water exploration, the sound velocity varies with the season, time, location, water depth, ocean currents, and etc.. It also results in a layered velocity distribution, so there is a difference of seismic traveltime, ray paths, and amplitude, which affect the migration imaging results if sea water propagation velocity is still taken as constant for the propagation wavefield. In this paper, we will start from an empirical equation of seismic wave velocity in seawater with changes of temperature, salinity, and depth, consider the variation of their values, build a seawater velocity model, and quantitatively analyze the impact of seawater velocity variation on seismic traveltime, ray paths, and amplitude in the seawater velocity model.

Microwave drying characteristics and kinetics of ilmenite

The microwave drying of ilmenite was investigated.The effects of power levels and sample mass on drying characteristics of moisture content,drying rate,moisture ratio were studied,with microwave power ranging from 119 W to 700 W and sample mass from 5 g to 25 g.The drying processes were completed within 2-8 min at different conditions.The moisture content and drying rates are found to be dramatically affected by microwave power density.For all drying processes the prior microwave absorption of moisture produces an accelerating peak on the drying rate curves in the initial stage.For the sample mass of 25 g and power of 385 W,the drying kinetics were studied.The experimental results fit better to the Henderson-Pabis index model rather than the Page＇s semi-empirical model;the drying rate constant k is increased with the increase of microwave power and decrease of sample mass.

NONLINEAR WATER WAVE PROPAGATING OVER UNEVEN BOTTOMS

Various types of wave group solutions of the weakly nonlinear waves may exist over uneven bottoms. In this paper, the variation of the zeroes of the dispersive and nonlinear terms,and the wave group solution in the third-order evolution equations are described for the case of mild and locally fastvarying water depths.

Analysis and application of the response characteristics of DLL and LWD resistivity in horizontal well

There exist different response characteristics in the resistivity measurements of dual laterolog （DLL） and logging while drilling （LWD） electromagnetic wave propagation logging in highly deviated and horizontal wells due to the difference in their measuring principles. In this study, we first use the integral equation method simulated the response characteristics of LWD resistivity and use the three dimensional finite element method （3D-FEM） simulated the response characteristics of DLL resistivity in horizontal wells, and then analyzed the response differences between the DLL and LWD resistivity. The comparative analysis indicated that the response differences may be caused by different factors such as differences in the angle of instrument inclination, anisotropy, formation interface, and mud intrusion. In the interface, the curves of the LWD resistivity become sharp with increases in the deviation while those of the DLL resistivity gradually become smooth. Both curves are affected by the anisotropy although the effect on DLL resistivity is lower than the LWD resistivity. These differences aid in providing a reasonable explanation in the horizontal well. However, this can also simultaneously lead to false results. At the end of the study, we explain the effects of the differences in the interpretation of the horizontal well based on the results and actual data analysis.

Digital watermarking algorithm based on neural network in multiwavelet domain

A novel blind digital watermarking algorithm based on neural networks and multiwavelet transform is presented. The host image is decomposed through multiwavelet transform. There are four subblocks in the LL- level of the multiwavelet domain and these subblocks have many similarities. Watermark bits are added to low- frequency coefficients. Because of the learning and adaptive capabilities of neural networks, the trained neural networks almost exactly recover the watermark from the watermarked image. Experimental results demonstrate that the new algorithm is robust against a variety of attacks, especially, the watermark extraction does not require the original image.

River channel flood forecasting method of coupling wavelet neural network with autoregressive model

Based on analyzing the limitations of the commonly used back-propagation neural network （BPNN）, a wavelet neural network （WNN） is adopted as the nonlinear river channel flood forecasting method replacing the BPNN. The WNN has the characteristics of fast convergence and improved capability of nonlinear approximation. For the purpose of adapting the timevarying characteristics of flood routing, the WNN is coupled with an AR real-time correction model. The AR model is utilized to calculate the forecast error. The coefficients of the AR real-time correction model are dynamically updated by an adaptive fading factor recursive least square（RLS） method. The application of the flood forecasting method in the cross section of Xijiang River at Gaoyao shows its effectiveness.

Research on the Agglomeration and Fluctuation Situation of Rice Production in Hunan Province

[Objective] This paper aimed at studying the agglomeration and fluctuation situation of rice production in Hunan Province during the past 10 years.[Method] Data were collected from Hunan Rural Statistical Yearbook（2001-2010）.Taking the concentration index of sown area and production（CDI） and the volatility index（VI） as the main indicators,the agglomeration and fluctuation situation of paddy rice,early-season rice,middle-season rice and single-season late rice,late-season rice,good quality early-season rice,good quality middle-season rice and good quality single-season late rice,good quality late-season rice production in each major rice-producing area of Hunan Province during the past 10 years had been studied.[Result] The orders of concentration index of sown areas and production of paddy rice,early-season rice,middle-season rice and single-season late rice,late-season rice,good quality early-season rice,good quality middle-season rice and good quality single-season late rice,good quality late-season rice in Hunan Province varied,but the orders of volatility index were consistent.The stable areas,relatively stable areas and fluctuant areas in sown areas and production of different major rice-producing areas were defined.[Conclusion] The research had provided basis for optimizing the layout of rice production in Hunan Province,promoting agglomeration and development of rice production and translating the comparative advantages into the competitive advantages.

WAVE TRANSFORMATION AND BREAKING OVER A RECTANGULAR STEP

An idealized numerical wave flume has been established by finite element method on the bases of Navier Stokes equations through prescribing the appropriate boundary conditions for the open boundary,incident boundary,free surface and solid boundary in this paper.The characteristics of waves propagating over a step have been investigated by this numerical model.The breaker wave height is determined depending on the kinetic criterion.The numerical model is verified by laboratory experiments,and the empirical formula for the damping of wave height due to breaking is also given by experiments.

Two New Species of Nymphulinae(Lepidoptera:Crambidae) from China

Two following new species of Nymphulinae are described: Paracymoriza convallata, sp. nov., Parapoynx candida, sp. nov. They are collected separately from Fujian and Tianjin. The photographs and the male or female genitalia of the new species are provided.

Rock-physics models of hydrate-bearing sediments in permafrost,Qilian Mountains,China

Rock-physics models are constructed for hydrate-bearing sediments in the Qilian Mountains permafrost region using the K–T equation model, and modes I and II of the effective medium model. The K–T equation models the seismic wave propagation in a two-phase medium to determine the elastic moduli of the composite medium. In the effective medium model, mode I, the hydrate is a component of the pore inclusions in mode I and in mode II it is a component of the matrix. First, the P-wave velocity, S-wave velocity, density, bulk modulus, and shear modulus of the sediment matrix are extracted from logging data.. Second, based on the physical properties of the main components of the sediments, rock-physics model is established using the K–T equation, and two additional rock-physics models are established assuming different hydrate-filling modes for the effective medium. The model and actual velocity data for the hydrate-bearing sediments are compared and it is found that the rock-physics model for the hydrate-filling mode II well reproduces the actual data.

A seafloor electromagnetic receiver for marine magnetotellurics and marine controlled-source electromagnetic sounding

In planning and executing marine controlled-source electromagnetic methods, seafloor electromagnetic receivers must overcome the problems of noise, clock drift, and power consumption. To design a receiver that performs well and overcomes the abovementioned problems, we performed forward modeling of the E-field abnormal response and established the receiver＇s characteristics. We describe the design optimization and the properties of each component, that is, low-noise induction coil sensor, low-noise Ag/AgCI electrode, low-noise chopper amplifier, digital temperature-compensated crystal oscillator module, acoustic telemetry modem, and burn wire system. Finally, we discuss the results of onshore and offshore field tests to show the effectiveness of the developed seafloor electromagnetic receiver and its performance： typical E-field noise of 0.12 nV/m/rt（Hz） at 0.5 Hz, dynamic range higher than 120 dB, clock drift lower than 1 ms/day, and continuous operation of at least 21 days.

GC-MS Analysis of Essential oil and n-Hexane Extract from Moso Bamboo

[Objective] This study aimed to analyze the chemical composition and yield of essential oil and n-hexane extract from moso bamboo to find active compounds with potential value. [Method] Essential oil and n-hexane extract were respectively extracted from moso bamboo of four different ages by using hydrodistillation and ultrasonic-assisted extraction with n-hexane, and analyzed with gas chromatography/mass spectrometry （GC/MS）. [Result] The results show that cedrol （46.39%） is the first principal volatile component in essential oil of the middle stem of 7-year old moso bamboo; dibutyl phthalate （59.46%） is the first principal volatile component in n-hexane extract of the middle stem of 3-year old moso bamboo; yield of n-hexane extract is higher than that of essential oil from moso bamboo. [Conclusion] Cedrol is an active compound with potential value.

Structures and Intermolecular Interactions in Dimethyl Sulfoxide-Water System Studied by All-atom Molecular Simulations

An all-atom dimethyl sulfoxide （DMSO） and water model have been used for molecular dynamics simulation. The NMR and IR spectra are also performed to study the structures and interactions in the DMSO-water system. And there are traditional strong hydrogen bonds and weak C-H- ~ ~ O contacts existing in the mixtures according to the analysis of the radial distribution functions. The insight structures in the DMSO-water mixtures can be classified into different regions by the analysis of the hydrogen-bonding network. Interestingly, the molar fraction of DMSO 0.35 is found to be a special concentration by the network. It is the transitional region which is from the water rich region to the DMSO rich region. The stable aggregates of （DMSO）m＇S=O…… HW-OW-（H20）n might play a key role in this region. Moreover, the simulation is compared with the chemical shifts in NMR and wavenumbers in IR with concentration dependence. And the statistical results of the average number hydrogen bonds in the MD simulations are in agreement with the experiment data in NMR and IR spectra.

Freak wave simulation based on nonlinear model and the research on the time-frequency energy spectrum of simulation results

VOF （volume of fluid） method has been used to make the numerical simulation of freak wave come true. The comparisons between the numerical results and linear theoretical results corresponding to Eq.（5） have been carried out to show that the numerical results have a better exhibition of nonlinear characteristics. Wavelet analysis method has been adopted to investigate the time-frequency energy spectrum of simulation freak waves and the results reveal strong nonlinear interaction enables energy to be transferred to high harmonics during the progress of its formation. Varying water depth can enhance the nonlinear interaction, making much more energy be transferred to high harmonics and freak waves with higher asymmetry be generated.

Effects of salinity fluctuation and dietary protein/ carbohydrate ratio on the survival and growth of Juvenile Litopenaeus vannamei

A factorial study was conducted to determine the effects of salinity （constant （SO） and fluctuating （S10）） and isoenergetic diet of different protein/carbohydrate ratios （P/C： 4.1, 1.9, 1.0 and 0.6） on the survival and growth of juvenile Litopenaeus vannamei. The experiment lasted for 35 days. The results showed that I） At S0 and S10, specific growth rate and apparent digestibility coefficient exhibited decreasing trend, while food conversion ratio exhibited increasing trend, with decreasing P/C ratio. At SO, food consumption and specific growth rate of the shrimp fed 4.1 P/C were significantly higher than those fed 1.0 and 0.6 P/C, whereas at S10, no significant differences were detected among different treatments; II） At 4.1 and 1.9 P/C, food consumption and specific growth rate were higher in the shrimp maintained at SO as compared with those at S10, while at 1.0 and 0.6 P/C, an inverse trend was observed. Among four P/C ratios, food conversion ratio of the shrimp at SO was the lowest.