The thermal decomposition kinetics of high iron gibbsite ore was investigated under non-isothermal conditions.Popescu method was applied to analyzing the thermal decomposition mechanism.The results show that the most ...The thermal decomposition kinetics of high iron gibbsite ore was investigated under non-isothermal conditions.Popescu method was applied to analyzing the thermal decomposition mechanism.The results show that the most probable thermal decomposition mechanism is the three-dimensional diffusion model of Jander equation,and the mechanism code is D3.The activation energy and pre-exponential factor for thermal decomposition of high iron gibbsite ore calculated by the Popescu method are 75.36 kJ/mol and 1.51×10-5 s-(-1),respectively.The correctness of the obtained mechanism function is validated by the activation energy acquired by the iso-conversional method.Popescu method is a rational and reliable method for the analysis of the thermal decomposition mechanism of high iron gibbsite ore.展开更多
For the low-grade gibbsitic bauxite,the leaching rate of alumina is very low during the Bayer process.The acid leaching method is attracting more attention,and the hydrochloric acid leaching was developed rapidly.The ...For the low-grade gibbsitic bauxite,the leaching rate of alumina is very low during the Bayer process.The acid leaching method is attracting more attention,and the hydrochloric acid leaching was developed rapidly.The mineral composition and chemical composition were investigated by X-ray diffraction analysis and semi-quantitative analysis.The thermodynamics of leaching process was analyzed.The results show that the major minerals in the bauxite are gibbsite,secondly goethite and quartz,anatase and so on.The acid leaching reactions of the bauxite would be thermodynamically easy and completed.Under the conditions that ore granularity is less than-55 μm,the L/S ratio is 100:7,and the leaching temperature is 373-383 K,the leaching time is 120 min and the concentration of HCl is 10%,both the leaching rates of Al and Fe are over 95%.The main composition of leaching slag is SiO2 which is easy for comprehensive utilization.展开更多
In Yuanmou dry-hot valley of Yunnan Province,three typical vegetation restoration patterns including production forest transformed from sloping fields to terracing,ecological afforestation within the gully and ecologi...In Yuanmou dry-hot valley of Yunnan Province,three typical vegetation restoration patterns including production forest transformed from sloping fields to terracing,ecological afforestation within the gully and ecological aforestation in gully head and slope were selected to compare their effects on soil and water conservation.Soil and water loss,soil infiltration rate and the soil moisture dynamics of soil profile with the depth of 0-100 cm of these three patterns and their controls were observed by established standard observation plots in rainy season.The results showed that the soil and water loss of ecological afforestation and production forest terrace reduced by over 30% and 60% compared with their controls(without growth of any vegetation)respectively,showing significant control effect on the soil and water loss.Vegetation restoration also apparently increased the infiltration rate of soil(increased by 100%-200%).In rainy season,the soil moisture content of ecological afforestation and production forest terrace increased by over 30% and 100% compared with their controls.This indicated that vegetation restoration will not lead to soil aridity during the rainy season;vegetation restoration not only reduced the loss of surface water and soil fine particles,but also enhanced the infiltration of precipitation.These two effects made the soil moisture content increase throughout the profile.展开更多
[Objective] This study aimed to reveal distribution characteristics of soil nutrients in tropical farmland, thereby providing a reference for cropland management and balanced fertilization in the tropical area. [Metho...[Objective] This study aimed to reveal distribution characteristics of soil nutrients in tropical farmland, thereby providing a reference for cropland management and balanced fertilization in the tropical area. [Method] Combining field survey and laboratory analysis, distribution status of nutrients in arable land of Baisha Li Autonomous County of Hainan Province was investigated. [Result] The soil in Baisha Li Autonomous County was acidic in overall with average pH value of 5.0. it had medium organic matter level (average of 19.3 g/kg) and rich alkali-hydrolyzable nitrogen content, but was lack of available phosphorus and available potassium. The spatial distribution of available nitrogen, available phosphorus and available potassi- um in the soil was uneven. The spatial distribution of soil nutrients was mainly related to soil parent materials of the investigated area and pH value of the investigated soil. [Conclusion] According to the distribution characteristics of nutrients in the soil, awareness of land use and land maintenance should be strengthened, application amount of organic fertilizers should be increased, chemical fertilizers should be applied rationally, and fertilization structure should be optimized in the future.展开更多
[Objective]The research aimed to study the effects of vegetation coverage on the changes of soil moisture in rainy season in dry-hot valley.[Method]The surface runoff and soil moisture of slope with vegetation coverag...[Objective]The research aimed to study the effects of vegetation coverage on the changes of soil moisture in rainy season in dry-hot valley.[Method]The surface runoff and soil moisture of slope with vegetation coverage and bare land in rainy reason in Jinsha River at Yuanmou County of Yunnan Province were observed continuously.Moreover,the statistical analysis was made based on the observation data.[Result]The vegetation coverage could decrease surface runoff and the surface runoff on bare land(CK) was 22 times as the plot with vegetation coverage.The soil water content in 0-180 cm layer with vegetation coverage increased by 37.8% than bare land.The stability of soil moisture content in deep layer was enhanced and the physical properties stability of soil was maintained.The soil moisture content in different depth of soil had significant difference and the changes of soil moisture content were obviously different.[Conclusion]The vegetation coverage of slope could change the soil hydrology obviously and keep soil moisture at the higher level,especially at soil layer below 20 cm.展开更多
To simulate the concrete shrinkage in varying temperature and moisture environments, a simulate procedure comprising an analytical process and a finite element analysis is proposed based on the coupled partial differe...To simulate the concrete shrinkage in varying temperature and moisture environments, a simulate procedure comprising an analytical process and a finite element analysis is proposed based on the coupled partial differential equations describing heat and moisture transfer in a porous medium. Using the Laplace transformation method and transfer function to simplify and solve the coupled equations in Laplace domain, the moisture and temperature distribution in time domain are obtained by inverse Laplace transformation. The shrinkage deformations of concrete are numerically simulated by the finite element method (FEM) based on the obtained temperature and moisture distribution. This approach avoids the complex eigenvalues, coupling difficulty and low accuracy found in other solving methods, and also effectively calculates the moisture induced shrinkage which is almost impossible using familiar FEM software. The validity of the simulation procedure is verified by Hundt's test data. The results reveal that the proposed approach can be considered a reliable and efficient method to simulate the coupling moisture and temperature shrinkage of concrete.展开更多
A surface soil moisture model with improved spatial resolution was developed using remotely sensed apparent thermal inertia(ATI).The model integrates the surface temperature derived from TM/ETM+ image and the mean ...A surface soil moisture model with improved spatial resolution was developed using remotely sensed apparent thermal inertia(ATI).The model integrates the surface temperature derived from TM/ETM+ image and the mean surface temperature from MODIS images to improve the spatial resolution of soil temperature difference based on the heat conduction equation,which is necessary to calculate the ATI.Consequently,the spatial resolution of ATI and SMC can be enhanced from 1 km to 120 m(TM) or 60m(ETM+).Moreover,the enhanced ATI has a much stronger correlation coefficient(R^2) with SMC(0.789) than the surface reflectance(0.108) or the ATI derived only from MODIS images(0.264).Based on the regression statistics of the field SMC measurement and enhanced ATI,a linear regression model with an RMS error of 1.90%was found.展开更多
A hybrid ground-coupled heat pump(HGCHP)project in Nanjing,China is chosen to analyze the building energy-consumption properties in terms of different control strategies,building envelope and the terminal air-condit...A hybrid ground-coupled heat pump(HGCHP)project in Nanjing,China is chosen to analyze the building energy-consumption properties in terms of different control strategies,building envelope and the terminal air-conditioning system.The HGCHP uses a supplemental heat rejecter to dissipate extra thermal energy to guarantee underground soil heat balance.The software EnergyPlus is employed to simulate the project and design the heat flow of the cooling tower and the borehole heat exchanger(BHE).Then two feasible control strategies for the cooling tower and the borehole heat exchanger are proposed.The energy-saving potential of the building envelope is analyzed in terms of the surface color of the wall/roof.With the same terminal system,it is found that in the cooling season the heat flow of the insulated building with black wall/roof is 1.2 times more than that with white wall/roof.With the same insulated building and gray wall/roof,it is concluded that the heat pump units for a primary air fan-coil system show an annual energy consumption increase of 44.7 GJ compared with a radiant floor system.展开更多
Rare earth oxide was prepared via direct pyrolysis of rare earth chloride solution. Based on this technique, a new-type jet-flow pyrolysis reactor was designed, and then the fluid dynamics (pressure and velocity) insi...Rare earth oxide was prepared via direct pyrolysis of rare earth chloride solution. Based on this technique, a new-type jet-flow pyrolysis reactor was designed, and then the fluid dynamics (pressure and velocity) inside the reactor was numerically simulated using a computational fluid dynamics method. The self-produced pressure (p) and the fuel inlet velocity (v) satisfied a quadratic function,p=0.06v2+0.23v?4.49. To fully utilize the combustion-generated heat in pyrolysis of rare earth chloride, an appropriate external pressure p=v2+3v?4.27 should be imposed at the feed inlet. The 1.25- and 1.5-fold increase of feed inlet diameter resulted in decline of adsorption dynamic pressure, but the intake of rare earth chloride increased by more than 30% and 60%, respectively. The fluid flow in the reactor was affected by the feeding rate; the fluid flow peaked near the throat of venturi and gradually smoothed down at the jet-flow reactor’s terminal along with the sharp decline of feeding rate.展开更多
3Gd2O3-3Yb2O3-4Y2O3 (mole fraction, %) co-doped ZrO2 (GY-YSZ) thermal barrier coatings (TBCs) were produced by electron beam physical vapor deposition (EB-PVD). The oxidation behavior of GY-YSZ at 1 050 ℃ was...3Gd2O3-3Yb2O3-4Y2O3 (mole fraction, %) co-doped ZrO2 (GY-YSZ) thermal barrier coatings (TBCs) were produced by electron beam physical vapor deposition (EB-PVD). The oxidation behavior of GY-YSZ at 1 050 ℃ was investigated using impedance spectroscopy (IS) combined with scanning electron microscopy (SEM), Raman spectroscopy and X-ray diffractometry (XRD). Various electrical responses observed in the impedance spectra corresponding to GY-YSZ grains and grain boundaries were explained using circuit modeling. The change in the conduction mechanism of GY-YSZ was found to be related to the O^2- vacancy and lattice distortion due to the stabilizer diffusion during the oxidation. The results also suggested that the specific oxidation information about the GY-YSZ grains and grain boundaries should be acquired at a moderate measurement temperature, which was related to the resistance value in the impedance spectra. The resistance values of the GY-YSZ grains and grain boundaries should be measured at 200 ℃ and 300 ℃, respectively.展开更多
The microstructure evolution of the Mg 5Zn 0.63Er(mass fraction,%) alloy containing quasicrystalline phase(I-phase) under the as-cast condition was investigated via different heat treatments.The results show that ...The microstructure evolution of the Mg 5Zn 0.63Er(mass fraction,%) alloy containing quasicrystalline phase(I-phase) under the as-cast condition was investigated via different heat treatments.The results show that apart from the precipitation of the W-phase particles,the I-phase almost dissolves into the matrix after solid solution treatment at 480℃ for 10 h(T4 state).The solution-treated alloy was aged at 175℃ for 6-100 h(T6 state).The ultimate tensile strength of the peak-aged alloy is approximately 261 MPa companying with an elongation of 10.5%.The improvement of the tensile strength is mainly attributed to the presence of the rod-like MgZn 2 particles.展开更多
Dynamics of soil organic matter in a cultivation chronosequence of paddy fields were studied in subtropical China.Mineralization of soil organic matter was determined by measuring CO2 evolution from soil during 20 day...Dynamics of soil organic matter in a cultivation chronosequence of paddy fields were studied in subtropical China.Mineralization of soil organic matter was determined by measuring CO2 evolution from soil during 20 days of laboratoryincubation. In the first 30 years of cultivation, soil organic C and N contents increased rapidly. After 30 years, 0-10 cmsoil contained 19.6 g kg-1 organic C and 1.62 g kg-1 total N, with the corresponding values of 18.1 g kg-1 and 1.50g kg-1 for 10-20 cm, and then remained stable even after 80 years of rice cultivation. During 20 days incubation themineralization rates of organic C and N in surface soil (0-10 cm) ranged from 2.2% to 3.3% and from 2.8% to 6.7%,respectively, of organic C and total N contents. Biologically active C size generally increased with increasing soil organicC and N contents. Soil dissolved organic C decreased after cultivation of wasteland to 10 years paddy field and thenincreased. Soil microbial biomass C increased with number of years under cultivation, while soil microbial biomass Nincreased during the first 30 years of cultivation and then stabilized. After 30 years of cultivation surface soil (0-10 cm)contained 332.8 mg kg-1 of microbial biomass C and 23.85 mg kg-1 of microbial biomass N, which were 111% and 47%higher than those in soil cultivated for 3 years. It was suggested that surface soil with 30 years of rice cultivation insubtropical China would have attained a steady state of organic C content, being about 19 g kg-1.展开更多
The effect of activation properties of the precursors of zeolite directly prepared from kaolin influenced by microwave field and conventional heating was investigated.XRD,TG-DSC,FT-IR,SEM,particle size analysis,specif...The effect of activation properties of the precursors of zeolite directly prepared from kaolin influenced by microwave field and conventional heating was investigated.XRD,TG-DSC,FT-IR,SEM,particle size analysis,specific surface area(BET),pore size distribution(BJH)and N2 adsorption-desorption were discussed to determine the optimal activation temperature.It is concluded that the conversion of kaolin to metakaolin in the microwave field is at 500°C holding for 30 min,which is 100°C lower than that in conventional calcination and 90 min shorter,and the phase transition process of kaolin under the effect of microwave field is the same as that of conventional heating method.SEM analysis indicates that the particle size is more uniform and agglomeration appears slightly in the microwave field.The N2 adsorption-desorption isotherm,BET and BJH of kaolin indicate that the pore properties are almost invariable regardless of calcination route during the process of calcining kaolin into metakaolin.It indicates that microwave calcination is superior to conventional calcination in the activation pathway of kaolin.It is attributed to microwave heating relying on objects to absorb microwave energy and convert it into thermal energy,which can simultaneously and uniformly heat the entire substance.展开更多
Highly weathered soils are distributed in the humid and wet-dry tropics, as well as in the humid subtropics. As a result of strong weathering, these soils are characterized by low activity clays, which develop variabl...Highly weathered soils are distributed in the humid and wet-dry tropics, as well as in the humid subtropics. As a result of strong weathering, these soils are characterized by low activity clays, which develop variable surface charge and related specific properties. Surface reactions regarding base exchange and soil acidification, heavy metal sorption and mobility, and phosphorus sorption and availability of the tropical highly weathered soils are reviewed in this paper.Factors controlling surface reactivity towards cations and anions, including ion exchange and specific adsorption processes, are discussed with consideration on practical implications for rational management of these soils. Organic matter content and pH value are major basic factors that should be controlled through appropriate agricultural practices, in order to optimise favorable effects of colloid surface properties on soil fertility and environmental quality.展开更多
基金Project(51374058)supported by the National Natural Science Foundation of China
文摘The thermal decomposition kinetics of high iron gibbsite ore was investigated under non-isothermal conditions.Popescu method was applied to analyzing the thermal decomposition mechanism.The results show that the most probable thermal decomposition mechanism is the three-dimensional diffusion model of Jander equation,and the mechanism code is D3.The activation energy and pre-exponential factor for thermal decomposition of high iron gibbsite ore calculated by the Popescu method are 75.36 kJ/mol and 1.51×10-5 s-(-1),respectively.The correctness of the obtained mechanism function is validated by the activation energy acquired by the iso-conversional method.Popescu method is a rational and reliable method for the analysis of the thermal decomposition mechanism of high iron gibbsite ore.
基金Projects(50974035,51074047,51004033) supported by the National Natural Science Foundation of ChinaProject(2008BAB34B01) supported by the National Science and Technology Pillar Program of China during the Eleventh Five-Year Plan Period+1 种基金Project (N100302005) supported by the National Higher-education Institution General Research and Development Funding,ChinaProject (2010AA03A405) supported by the Hi-tech Research and Development Program of China
文摘For the low-grade gibbsitic bauxite,the leaching rate of alumina is very low during the Bayer process.The acid leaching method is attracting more attention,and the hydrochloric acid leaching was developed rapidly.The mineral composition and chemical composition were investigated by X-ray diffraction analysis and semi-quantitative analysis.The thermodynamics of leaching process was analyzed.The results show that the major minerals in the bauxite are gibbsite,secondly goethite and quartz,anatase and so on.The acid leaching reactions of the bauxite would be thermodynamically easy and completed.Under the conditions that ore granularity is less than-55 μm,the L/S ratio is 100:7,and the leaching temperature is 373-383 K,the leaching time is 120 min and the concentration of HCl is 10%,both the leaching rates of Al and Fe are over 95%.The main composition of leaching slag is SiO2 which is easy for comprehensive utilization.
基金Supported by National Natural Science Foundation of China(40871013)National Support Scheme Program(2006BAC01A11)~~
文摘In Yuanmou dry-hot valley of Yunnan Province,three typical vegetation restoration patterns including production forest transformed from sloping fields to terracing,ecological afforestation within the gully and ecological aforestation in gully head and slope were selected to compare their effects on soil and water conservation.Soil and water loss,soil infiltration rate and the soil moisture dynamics of soil profile with the depth of 0-100 cm of these three patterns and their controls were observed by established standard observation plots in rainy season.The results showed that the soil and water loss of ecological afforestation and production forest terrace reduced by over 30% and 60% compared with their controls(without growth of any vegetation)respectively,showing significant control effect on the soil and water loss.Vegetation restoration also apparently increased the infiltration rate of soil(increased by 100%-200%).In rainy season,the soil moisture content of ecological afforestation and production forest terrace increased by over 30% and 100% compared with their controls.This indicated that vegetation restoration will not lead to soil aridity during the rainy season;vegetation restoration not only reduced the loss of surface water and soil fine particles,but also enhanced the infiltration of precipitation.These two effects made the soil moisture content increase throughout the profile.
文摘[Objective] This study aimed to reveal distribution characteristics of soil nutrients in tropical farmland, thereby providing a reference for cropland management and balanced fertilization in the tropical area. [Method] Combining field survey and laboratory analysis, distribution status of nutrients in arable land of Baisha Li Autonomous County of Hainan Province was investigated. [Result] The soil in Baisha Li Autonomous County was acidic in overall with average pH value of 5.0. it had medium organic matter level (average of 19.3 g/kg) and rich alkali-hydrolyzable nitrogen content, but was lack of available phosphorus and available potassium. The spatial distribution of available nitrogen, available phosphorus and available potassi- um in the soil was uneven. The spatial distribution of soil nutrients was mainly related to soil parent materials of the investigated area and pH value of the investigated soil. [Conclusion] According to the distribution characteristics of nutrients in the soil, awareness of land use and land maintenance should be strengthened, application amount of organic fertilizers should be increased, chemical fertilizers should be applied rationally, and fertilization structure should be optimized in the future.
基金Supported by National Key Project of Scientific and Technical Supporting Programs (2006BAC01A11 )National Natural Science Foundation of China (2006AA202A04)~~
文摘[Objective]The research aimed to study the effects of vegetation coverage on the changes of soil moisture in rainy season in dry-hot valley.[Method]The surface runoff and soil moisture of slope with vegetation coverage and bare land in rainy reason in Jinsha River at Yuanmou County of Yunnan Province were observed continuously.Moreover,the statistical analysis was made based on the observation data.[Result]The vegetation coverage could decrease surface runoff and the surface runoff on bare land(CK) was 22 times as the plot with vegetation coverage.The soil water content in 0-180 cm layer with vegetation coverage increased by 37.8% than bare land.The stability of soil moisture content in deep layer was enhanced and the physical properties stability of soil was maintained.The soil moisture content in different depth of soil had significant difference and the changes of soil moisture content were obviously different.[Conclusion]The vegetation coverage of slope could change the soil hydrology obviously and keep soil moisture at the higher level,especially at soil layer below 20 cm.
基金The National Natural Science Foundation of China(No50539040)the Trans-Century Training Programme Foundation forthe Talents by the State Education Commission (NoNCET-05-0473)
文摘To simulate the concrete shrinkage in varying temperature and moisture environments, a simulate procedure comprising an analytical process and a finite element analysis is proposed based on the coupled partial differential equations describing heat and moisture transfer in a porous medium. Using the Laplace transformation method and transfer function to simplify and solve the coupled equations in Laplace domain, the moisture and temperature distribution in time domain are obtained by inverse Laplace transformation. The shrinkage deformations of concrete are numerically simulated by the finite element method (FEM) based on the obtained temperature and moisture distribution. This approach avoids the complex eigenvalues, coupling difficulty and low accuracy found in other solving methods, and also effectively calculates the moisture induced shrinkage which is almost impossible using familiar FEM software. The validity of the simulation procedure is verified by Hundt's test data. The results reveal that the proposed approach can be considered a reliable and efficient method to simulate the coupling moisture and temperature shrinkage of concrete.
基金Project (2013CB227904) supported by the National Basic Research Program of ChinaProject (2012QNB09) supported by the Fundamental Research Funds for the Central University,ChinaProject (NCET-12-0956) supported by the Program for New Century Excellent Talents
文摘A surface soil moisture model with improved spatial resolution was developed using remotely sensed apparent thermal inertia(ATI).The model integrates the surface temperature derived from TM/ETM+ image and the mean surface temperature from MODIS images to improve the spatial resolution of soil temperature difference based on the heat conduction equation,which is necessary to calculate the ATI.Consequently,the spatial resolution of ATI and SMC can be enhanced from 1 km to 120 m(TM) or 60m(ETM+).Moreover,the enhanced ATI has a much stronger correlation coefficient(R^2) with SMC(0.789) than the surface reflectance(0.108) or the ATI derived only from MODIS images(0.264).Based on the regression statistics of the field SMC measurement and enhanced ATI,a linear regression model with an RMS error of 1.90%was found.
文摘A hybrid ground-coupled heat pump(HGCHP)project in Nanjing,China is chosen to analyze the building energy-consumption properties in terms of different control strategies,building envelope and the terminal air-conditioning system.The HGCHP uses a supplemental heat rejecter to dissipate extra thermal energy to guarantee underground soil heat balance.The software EnergyPlus is employed to simulate the project and design the heat flow of the cooling tower and the borehole heat exchanger(BHE).Then two feasible control strategies for the cooling tower and the borehole heat exchanger are proposed.The energy-saving potential of the building envelope is analyzed in terms of the surface color of the wall/roof.With the same terminal system,it is found that in the cooling season the heat flow of the insulated building with black wall/roof is 1.2 times more than that with white wall/roof.With the same insulated building and gray wall/roof,it is concluded that the heat pump units for a primary air fan-coil system show an annual energy consumption increase of 44.7 GJ compared with a radiant floor system.
基金Projects(51204040,U1202274)supported by the National Natural Science Foundation of ChinaProjects(2010AA03A405,2102AA062303)supported by the National High-tech Research and Development Program of China+1 种基金Project(2012BAE01B02)supported by the National Science and Technology Support Program of ChinaProject(N130702001)supported by the Fundamental Research Funds for the Central Universities,China
文摘Rare earth oxide was prepared via direct pyrolysis of rare earth chloride solution. Based on this technique, a new-type jet-flow pyrolysis reactor was designed, and then the fluid dynamics (pressure and velocity) inside the reactor was numerically simulated using a computational fluid dynamics method. The self-produced pressure (p) and the fuel inlet velocity (v) satisfied a quadratic function,p=0.06v2+0.23v?4.49. To fully utilize the combustion-generated heat in pyrolysis of rare earth chloride, an appropriate external pressure p=v2+3v?4.27 should be imposed at the feed inlet. The 1.25- and 1.5-fold increase of feed inlet diameter resulted in decline of adsorption dynamic pressure, but the intake of rare earth chloride increased by more than 30% and 60%, respectively. The fluid flow in the reactor was affected by the feeding rate; the fluid flow peaked near the throat of venturi and gradually smoothed down at the jet-flow reactor’s terminal along with the sharp decline of feeding rate.
基金Projects (50771009, 50731001 and 51071013) supported by the National Natural Science Foundations of China Project (2010CB631200) supported by the National Basic Research Program of China
文摘3Gd2O3-3Yb2O3-4Y2O3 (mole fraction, %) co-doped ZrO2 (GY-YSZ) thermal barrier coatings (TBCs) were produced by electron beam physical vapor deposition (EB-PVD). The oxidation behavior of GY-YSZ at 1 050 ℃ was investigated using impedance spectroscopy (IS) combined with scanning electron microscopy (SEM), Raman spectroscopy and X-ray diffractometry (XRD). Various electrical responses observed in the impedance spectra corresponding to GY-YSZ grains and grain boundaries were explained using circuit modeling. The change in the conduction mechanism of GY-YSZ was found to be related to the O^2- vacancy and lattice distortion due to the stabilizer diffusion during the oxidation. The results also suggested that the specific oxidation information about the GY-YSZ grains and grain boundaries should be acquired at a moderate measurement temperature, which was related to the resistance value in the impedance spectra. The resistance values of the GY-YSZ grains and grain boundaries should be measured at 200 ℃ and 300 ℃, respectively.
基金Project(2007CB613706) supported by the National Basic Research Program of ChinaProjects(151071004,51101002) supported by the National Natural Science Foundation of China
文摘The microstructure evolution of the Mg 5Zn 0.63Er(mass fraction,%) alloy containing quasicrystalline phase(I-phase) under the as-cast condition was investigated via different heat treatments.The results show that apart from the precipitation of the W-phase particles,the I-phase almost dissolves into the matrix after solid solution treatment at 480℃ for 10 h(T4 state).The solution-treated alloy was aged at 175℃ for 6-100 h(T6 state).The ultimate tensile strength of the peak-aged alloy is approximately 261 MPa companying with an elongation of 10.5%.The improvement of the tensile strength is mainly attributed to the presence of the rod-like MgZn 2 particles.
基金the National Natural Science Foundation of China (No. 40471066) and the Knowledge InnovationProgram of the Chinese Academy of Sciences (No. KZCX1-SW-01-05).
文摘Dynamics of soil organic matter in a cultivation chronosequence of paddy fields were studied in subtropical China.Mineralization of soil organic matter was determined by measuring CO2 evolution from soil during 20 days of laboratoryincubation. In the first 30 years of cultivation, soil organic C and N contents increased rapidly. After 30 years, 0-10 cmsoil contained 19.6 g kg-1 organic C and 1.62 g kg-1 total N, with the corresponding values of 18.1 g kg-1 and 1.50g kg-1 for 10-20 cm, and then remained stable even after 80 years of rice cultivation. During 20 days incubation themineralization rates of organic C and N in surface soil (0-10 cm) ranged from 2.2% to 3.3% and from 2.8% to 6.7%,respectively, of organic C and total N contents. Biologically active C size generally increased with increasing soil organicC and N contents. Soil dissolved organic C decreased after cultivation of wasteland to 10 years paddy field and thenincreased. Soil microbial biomass C increased with number of years under cultivation, while soil microbial biomass Nincreased during the first 30 years of cultivation and then stabilized. After 30 years of cultivation surface soil (0-10 cm)contained 332.8 mg kg-1 of microbial biomass C and 23.85 mg kg-1 of microbial biomass N, which were 111% and 47%higher than those in soil cultivated for 3 years. It was suggested that surface soil with 30 years of rice cultivation insubtropical China would have attained a steady state of organic C content, being about 19 g kg-1.
基金Projects(51604135,51504116)supported by the National Natural Science Foundational of ChinaProject(YNWR-QNBJ-2018-323)supported by the Yunan Ten Thousand Talents Plan Young&Elite Talents Project,China。
文摘The effect of activation properties of the precursors of zeolite directly prepared from kaolin influenced by microwave field and conventional heating was investigated.XRD,TG-DSC,FT-IR,SEM,particle size analysis,specific surface area(BET),pore size distribution(BJH)and N2 adsorption-desorption were discussed to determine the optimal activation temperature.It is concluded that the conversion of kaolin to metakaolin in the microwave field is at 500°C holding for 30 min,which is 100°C lower than that in conventional calcination and 90 min shorter,and the phase transition process of kaolin under the effect of microwave field is the same as that of conventional heating method.SEM analysis indicates that the particle size is more uniform and agglomeration appears slightly in the microwave field.The N2 adsorption-desorption isotherm,BET and BJH of kaolin indicate that the pore properties are almost invariable regardless of calcination route during the process of calcining kaolin into metakaolin.It indicates that microwave calcination is superior to conventional calcination in the activation pathway of kaolin.It is attributed to microwave heating relying on objects to absorb microwave energy and convert it into thermal energy,which can simultaneously and uniformly heat the entire substance.
文摘Highly weathered soils are distributed in the humid and wet-dry tropics, as well as in the humid subtropics. As a result of strong weathering, these soils are characterized by low activity clays, which develop variable surface charge and related specific properties. Surface reactions regarding base exchange and soil acidification, heavy metal sorption and mobility, and phosphorus sorption and availability of the tropical highly weathered soils are reviewed in this paper.Factors controlling surface reactivity towards cations and anions, including ion exchange and specific adsorption processes, are discussed with consideration on practical implications for rational management of these soils. Organic matter content and pH value are major basic factors that should be controlled through appropriate agricultural practices, in order to optimise favorable effects of colloid surface properties on soil fertility and environmental quality.