Unveiling the planar deformation mechanisms for improved formability in pre-twinned AZ31 Mg alloy sheet at warm temperature

To investigate the role of pre-twins in Mg alloy sheets during warm planar deformation,the stretch forming is conducted at 200℃.Results suggest the formability of the pre-twinned AZ31 Mg alloy sheet is enhanced to 11.30 mm.The mechanisms for the improved formability and the deformation behaviors during the planar stretch forming are systematically investigated based on the planar stress states.The Schmid factor for deformation mechanisms are calculated,the results reveal that planar stress states extremely affect the Schmid factor for{10-12}twinning.The detwinning is activated and the prismatic slip is enhanced in the pre-twinned sheet,especially under the planar extension stress state in the outer region.Consequently,the thickness-direction strain is accommodated better.The dynamic recrystallization(DRX)type is continuous DRX(CDRX)regardless of the planar stress state.However,the CDRX degree is greater under the planar extension stress state.Some twin lattices deviate from the perfect{10-12}twinning relation due to the planar compression stress state and the CDRX.The basal texture is weakened when the planar stress state tends to change the texture components.

31PNMR在阻燃剂DOPO合成中的应用

9,10-二氢-9氧杂-10-膦杂菲-10-氧化物(DOPO)的合成涉及酯化、酰基化、水解和脱水环化反应.通过核磁共振磷谱(^(31)P NMR)对各步反应得到的产物进行表征,分析各反应产物的组成,由此得出各步反应规律,并找出了影响DOPO的产率和纯度的一些关键因素.

AZ31镁合金疲劳变形过程中{10-12}-{10-12}二次孪晶诱发疲劳断裂的裂纹扩展机制的研究

目的为了对镁合金裂纹萌生及材料的宏观失效进行更深入的分析,对二次孪晶诱发疲劳断裂的裂纹扩展机制进行研究。方法以AZ31镁合金为实验对象,采用室温条件下沿板材轴向方向(Normaldirection,ND),1%应变幅值的全反向拉-压循环加载,通过电子背散射衍射(ElectronBackscatterDiffraction,EBSD)和扫描电镜(ScanningElectronMicroscope,SEM)等技术手段,对疲劳断口显微组织及形貌特征进行分析。结果发现在沿ND方向1%循环加载条件下材料内部发生{10-12}-{10-12}二次孪晶,并且通过疲劳断口的金相显微图发现,裂纹附近存在大量孪晶片层,并且对这些孪晶片层通过扫描电镜放大研究,从观察的结果来看,断口裂纹处附近有微小裂纹产生,也就是{10-12}-{10-12}孪晶所形成的二次微裂纹,表现为在{10-12}一次孪晶界面内部的{10-12}-{10-12}二次孪晶界面所形成的台阶状裂纹。结论{10-12}-{10-12}二次孪晶在{10-12}一次孪晶交互处产生,微裂纹起始于{10-12}一次孪晶边界与{10-12}-{10-12}二次孪晶边界的交界处,分别沿一次{10-12}孪晶界和{10-12}-{10-12}二次孪晶界进行扩展,随着循环次数的增加,{10-12}-{10-12}二次孪晶界面的微裂纹会与一次孪晶界面的裂纹相互融合,并扩展到相邻晶粒内部,形成引发疲劳失效的长程裂纹,最终导致材料内部裂纹不断扩大,进而使材料发生断裂。

DFT Study on Molecule C_(20)H_(10): Five Carbon-carbon Single Bonds Linking Two Pentaprismane Cages

Using geometry optimization and DFT method at the B3LYP/6-31G* level for C20H10, an equilibrium geometry is identified to have the form of polyhedral hydrocarbon with five carbon-carbon single bonds linking two pentaprismane cages. Thus, C20H10 is a tri-cage molecule with three pentaprismane cages. Vibrational frequencies and infrared spectrum are computed at the same level. The heat of formation for this molecule has also been estimated in this paper.

新锐歼-10的最新“情报”

近十几年来，中国人民解放军空军的现代化进程和装备采购计划，一直采取了和美国空军一样的传统做法，即走“高低”搭配的路子。中国空军的前线战斗机和战斗轰炸机部队陆续装备了先进的苏—27(单座)和苏—30(双座)，这两种机型使用的都是俄罗斯“土星”公司生产的推力为12。

DFT Study on the Bilayer Pentaprismane C_(15)H_(10)

Using geometry optimization and DFT method at the B3LYP/6-31G* level for C15H10, an equilibrium geometry was identified to have bilayer pentaprismane formed by two pentaprismane cages sharing the same pentagon. The vibrational frequencies and infrared spectrum were computed at the same level, and the heat of formation was also estimated.

"赛珍珠"与"贤内助":《箴言》与《牛郎织女》传说中贤妻形象比较研究

希伯来文学经典《箴言》和中国民间传说《牛郎织女》都塑造了能力超群的贤妻形象.希伯来贤妻植根于古代近东智慧形象,她的贤德体现在能力和敬虔方面,《箴言》用"赛珍珠"比喻贤妻.中国民间传说的织女下凡俯就牛郎,成为凡人生活上的得力助手,是名副其实的"贤内助".本文比较"赛珍珠"与"贤内助"宜家室、和邻里的能力与美德,突出表现她们为家庭和社群做出的贡献.她们各自隶属的阶层差异表明希伯来智慧传统强大的王室背景,中国贫苦农民意识深处普遍的贤妻情结使得民间传说出现大量仙女配凡夫的情节.希伯来贤妻是智慧的人格化身,体现了她与世俗分别的超越性;中国民间传说里的织女最终与牛郎离别,是天人两分宗教观念的必然结果.

国际

波黑部长会议1月10日在萨拉热窝宣布，波黑已决定成立一个调查贫铀弹危害的专门委员会，并要求北约提供贫铀弹分布图等有关信息。