Optical frequency combbased Fourier transform spectroscopy has the features of broad spectral bandwidth,high sensitivity,andmultiplexed trace gas detection,which has valuable application potential in the fields of pre...Optical frequency combbased Fourier transform spectroscopy has the features of broad spectral bandwidth,high sensitivity,andmultiplexed trace gas detection,which has valuable application potential in the fields of precision spectroscopy and trace gas detection.Here,we report the development of a mid-infrared Fourier transform spectrometer based on an optical frequency comb combined with a Herriott-type multipass cell.Using this instrument,the broadband absorption spectra of several important molecules,including methane,acetylene,water molecules and nitrous oxide,are measured by near real-time data acquisition in the 2800-3500 cm^(-1)spectral region.The achieved minimum detectable absorption of the instrument is 4.4×10^(-8)cm^(-1)·Hz^(-1/2)per spectral element.Broadband spectra of H_(2)0 are fited using the Voigt profile multispectral fitting technique and the consistency of the concentration inversion is 1%.Our system also enables precise spectroscopic measurements,and it allows the determination of the spectral line positions and upper state constants of N_(2)O in the(0002)-(1000)band,with results in good agreement with those reported by Toth[Appl.Opt.30,5289(1991)].展开更多
The precipitation distribution quantity of canopy in broadleaved/Korean pine forest was measured during the growing season (Jun.–Sept.) in 2001 in the Changbai Mountain, Jilin Province, P. R. China. Results indicated...The precipitation distribution quantity of canopy in broadleaved/Korean pine forest was measured during the growing season (Jun.–Sept.) in 2001 in the Changbai Mountain, Jilin Province, P. R. China. Results indicated that the amounts of stemflow, throughfall, and interception were 37.39, 322.12 and 109.69 mm, accounting for 7.97%, 68.65% and 23.38% of the total rainfall, respectively. The rate of stemflow was higher in Jul. and Aug. than other months. The rate of throughfall dropped off from Jun. to Sept., however, rate of interception changed contrarily from 19.43% to 31.02% during the growing season. According to our analysis, the concentration of nutrient elements were arranged as Ca>Mg>N>K>Fe>P>Cu>Mn for rainfall, K>N>Mg>Ca>P>Fe>Mn>Cu for throughfall, and Mn>P>K>Cu>Fe>N>Mg>Ca for being leached through canopy. Nutrients concentration in stewflow and throughfall changed significantly when rainfall passed canopy, and concentration of all elements increased except for Ca and Mg.展开更多
To understand influence of litters on the emission/absorption of CO2, N2O and CH4 in broadleaved/Korean pine forest in Changbai Mountain, fluxes of soil CO2, N2O and CH4 were measured by closed static chamber techniqu...To understand influence of litters on the emission/absorption of CO2, N2O and CH4 in broadleaved/Korean pine forest in Changbai Mountain, fluxes of soil CO2, N2O and CH4 were measured by closed static chamber technique, from Sept 3, 2002 to Oct 30, 2003 in two types of soil ecosystems, of which one was covered with litters on the surface soil, and the other had no litters. The results showed that litters had significant influences on CO2, N2O and CH4 fluxes (p<0.05). Their diurnal change patterns of plot with litters and litter-free plot were similar, and they all showed emission/absorption peak at 18:00. The diurnal change fluxes of CO2 and N2O of plot with litters were significantly higher than those of the litter-free plot, while the diurnal flux of CH4 of plot with litters was lower than that of litter-free plot. The fluxes of CO2, N2O, and CH4 showed the similar seasonal patternsfor both plots. The fluxes of CO2, CH4 showed their peak fluxes in June, but the fluxes of N2O showed its peak emissions in August. The annual fluxes of CO2 and N2O of plot with litters were significantly higher than those of the litter-free plot, while the annual flux of CH4 of plot with litters was lower than that of litter-free plot. Keywords Flux - CO2, N2O and CH4 - Seasonal variation - Diurnal variation CLC number S718.5 Document code A Foundation item: The study was supported by innovation research project of Institute of Appiied Ecology, Chinese Academy of Sciences (SCXZD0101-02) and National Natural Science Foundation of China (30271068)Bigraphy: XIAO Dong-mei (1979-), female, master of Institute of Applied Ecology. Chinese Academy of Sciences, Shenyang 110016. P. R. China.Responsible editor: Song Funan展开更多
A study of the storage dynamics in the mixed broadleaved and Korean pine forests was carried out in the Changbai Mountains, Jilin Province, P. R. China. The modifying law of fallen trees was the storage dynamics of th...A study of the storage dynamics in the mixed broadleaved and Korean pine forests was carried out in the Changbai Mountains, Jilin Province, P. R. China. The modifying law of fallen trees was the storage dynamics of the existing fallen trees and the annual input in the mixed broadleaved and Korean pine forest. The current storage of fallen trees was 16.25 t昲m-2 in the initially, but after 100 years, 85% of the storage in dry weight was decomposed, and little material was left after 300 years. The average annual input of fallen trees was 0.6 t昲m-2and it increased with time to 31.0 t昲m-2after 200 years, which was maintained until the climax community ended. The total storage of fallen trees increased in the early stage. The decomposition of fallen trees eventually reached equilibrium with storage being identical with the annual input of fallen trees.展开更多
The taxonomy characteriazation and cadmium （Cd） biosorption of the high Cd-resistant fungus M1 were investigated. The internal transcribed spacers （ITS） region and β-tubulin genes of the strain were amplified, se...The taxonomy characteriazation and cadmium （Cd） biosorption of the high Cd-resistant fungus M1 were investigated. The internal transcribed spacers （ITS） region and β-tubulin genes of the strain were amplified, sequenced and analyzed by molecular biology technology. The Cd biosorption assay was performed by shaking flask. Fourier transform infrared spectroscopy was used to analyze the mycelium. The similarity of gene sequences and phylogenetic trees show the very close relation between the strain and Paecilomyces lilacinus, and the fungus M1 was identified as P. Lilacinus. The initial pH 6 and Cd concentration about 100 mg/L are optimum. Zn and Mn have a little effect on the Cd biosorption of the strain, while Cu and Pb present obvious effects. FTIR analysis shows that the fungus adsorbs Cd by esters, anhydride, and amide. With the preferable absorption capacity, fungus M1 is considered to have good prospects in bioremediation.展开更多
A 112 m×8 m sample pot which includes 14 sub-plots was set up along the slope in Hongshi Forestry Farm of Baihe Forestry Bureau (127°55′E, 42°30′ N), Jilin Province in August 2002. Community structure...A 112 m×8 m sample pot which includes 14 sub-plots was set up along the slope in Hongshi Forestry Farm of Baihe Forestry Bureau (127°55′E, 42°30′ N), Jilin Province in August 2002. Community structure, soil moisture contents at 0–10 cm and 10–20 cm in depth, water content of litter as well as the contents of C, N and P of litter, living leaves and branches in the broad-leaved/Korean pine (Pinus korraiensis) forest were measured in each sub-plot on different slope positions. The analytical results showed that there existed an obvious soil moisture gradient along the slope: upper slope <middle slope< lower slope. The difference in soil moisture contents on different positions of slope led to a change of the stand structure of the braod-leaved/Korean pine forest. The proportion ofQuercus mongolica gradually increased with the decrease of soil moisture content and that of other major tree species in the broad-leaved/Korean pine forest gradually decreased or disappeared. The dynamic of soil moisture contents in the litter layer was as same as that in mineral soils. The decomposition rates of the litter on different slope positions were different and the dry weights of existent litter varied significantly. The soil nutrients in the litter on the lower slope was richer than that on the upper slope due to the different stand structure on the different slope positions. The moisture content and nutrient contents of soil had effects on the composition, decomposition, and the nutrient release of litter, thus affecting stands growth and stand structure and finally leading to the change of ecosystem. Key words Soil moisture gradient - nutrient - Stand structure - Broad-leaved/Korean pine forest CLC number S718.5 Document code A Foundation item: This study was supported by the NKBRSF (G1999043407-1), Tackle Key Problem of Science and technology of China (2001BA510B-07), Knowledge Innovation Program of the Chinese Academy of Sciences (KZCX2-406, SCXZD0101), NKTRDP (2001BA510B-07. 2002BA516A20).Biography: WANG Yan (1970-), female, Ph. D, associate professorResponsible editor: Song Funan展开更多
The measurement and observation for this study were carried out by using a three-dimensional (u, v, w) Sonic anemometer (IAP-SA 485), at Forest Ecosystem Opened Research Station of Changbai Mountains (12828扙 and 4224...The measurement and observation for this study were carried out by using a three-dimensional (u, v, w) Sonic anemometer (IAP-SA 485), at Forest Ecosystem Opened Research Station of Changbai Mountains (12828扙 and 4224?N, Jilin Province, P. R. China) in August 2001. The basic characteristics of turbulence, such as turbulence intensity, atmospheric stability, time scales, and convection state, near the forest floor were analyzed. It is concluded that the airflow near forest floor is characterized by high intermittence and asymmetry, and the active and upward movement takes the leading position. Near forest floor, the vertical turbulence is retained and its time scale and length scale are much less than that of u, v components. The eddy near forest floor shows a flat structure and look like a ’Disk’. Buoyancy plays a leading role in the generation and maintenance of local turbulence展开更多
The forest ecosystem plays an important role in the global carbon cycling. A study was conducted to evaluate soil CO2 flux and its seasonal and diurnal variation with the air and soil temperatures by using static clos...The forest ecosystem plays an important role in the global carbon cycling. A study was conducted to evaluate soil CO2 flux and its seasonal and diurnal variation with the air and soil temperatures by using static closed chamber technique in a typical broad-leaved/Korean pine mixed forest area on the northern slope of Changbai Mountain, Jilin Province, China. The experiment was carried out through the day and night in the growing season (from June to September) in situ and sample gas was analyzed by a gas chromatograph. Results showed that the forest floor was a large net source of carbon, and soil CO2 fluxes had an obvi-ous law of seasonal and diel variation. The soil CO2 flux of broad-leaved/Korean pine mixed forest was in the range of 0.302.42 mmol穖-2穝-1 with the mean value of 0.98 mmol穖-2穝-1. An examination on the seasonal pattern of soil CO2 emission suggested that the variability in soil CO2 flux could be correlated with variations in soil temperature, and the maximum of mean CO2 flux occurred in July ((1.27±23%) mmol穖-2穝-1) and the minimum was in September ((0.50±28%) mmol穖-2穝-1). The fluctuations in diel soil CO2 flux were also correlated with changes in soil temperature; however, there existed a factor for a time lag. Soil CO2 flux from the forest floor was strongly related to soil temperature and had the highest correlation with temperature at 6-cm depth of soil. Q10 values based on air temperature and soil temperature of different soil depths were at the ranges of 2.09–3.40.展开更多
Using complete and orthogonal design, fertilization trials were conducted for the young growth of Populus deltoids cv. Zhonghua hongye in the fluviogenic soil in Xindu District, Chengdu City. The results showed that t...Using complete and orthogonal design, fertilization trials were conducted for the young growth of Populus deltoids cv. Zhonghua hongye in the fluviogenic soil in Xindu District, Chengdu City. The results showed that the application ef- fect of the single nutrient elements ranked as K〉N〉P, and that of the fertilization combinations ranked as N＋P＋K〉N＋K〉N＋P, P＋K. The optimum fertilization formula was urea [（NH2）2CO, 150 g/plant] ＋ calcium superphosphate [Ca（H2PO4）2.H20, 220 g/plant] ＋ potassium sulphate （K2SO4, 75 g/plant）.展开更多
Fourier transform infrared spectroscopy (FTIR) was used to detect the spectral difference among leaf tips from rice ( Oryza sativa L.) plants with different nitrogen fertilizer rates. The proposed spectral index,...Fourier transform infrared spectroscopy (FTIR) was used to detect the spectral difference among leaf tips from rice ( Oryza sativa L.) plants with different nitrogen fertilizer rates. The proposed spectral index, ( A 3400 - A 1653 )/( A 3400 + A 1653 ) ( A denotes absorption value at certain frequency (cm -1 )), was found to decline with the increase of nitrogen fertilizer rates and the results suggested that FTIR may be useful to diagnose nitrogen status in crops.展开更多
基金supported by the National Natural Science Foundation China(No.42022051,No.U21A2028)Youth Innovation Promotion Association of the Chinese Academy of Sciences(No.Y202089)the HFIPS Director's Fund(No.YZJJ202101,No.BJPY2023A02).
文摘Optical frequency combbased Fourier transform spectroscopy has the features of broad spectral bandwidth,high sensitivity,andmultiplexed trace gas detection,which has valuable application potential in the fields of precision spectroscopy and trace gas detection.Here,we report the development of a mid-infrared Fourier transform spectrometer based on an optical frequency comb combined with a Herriott-type multipass cell.Using this instrument,the broadband absorption spectra of several important molecules,including methane,acetylene,water molecules and nitrous oxide,are measured by near real-time data acquisition in the 2800-3500 cm^(-1)spectral region.The achieved minimum detectable absorption of the instrument is 4.4×10^(-8)cm^(-1)·Hz^(-1/2)per spectral element.Broadband spectra of H_(2)0 are fited using the Voigt profile multispectral fitting technique and the consistency of the concentration inversion is 1%.Our system also enables precise spectroscopic measurements,and it allows the determination of the spectral line positions and upper state constants of N_(2)O in the(0002)-(1000)band,with results in good agreement with those reported by Toth[Appl.Opt.30,5289(1991)].
基金This paper was supported by Chinese Academy of Science (KZCX2-406) Institute of Applied Ecology (SCXZD0101)+1 种基金 Chinese Academy of Science Shenyang and the Open Research Station of Changbai Mountain Forest Ecosystem.
文摘The precipitation distribution quantity of canopy in broadleaved/Korean pine forest was measured during the growing season (Jun.–Sept.) in 2001 in the Changbai Mountain, Jilin Province, P. R. China. Results indicated that the amounts of stemflow, throughfall, and interception were 37.39, 322.12 and 109.69 mm, accounting for 7.97%, 68.65% and 23.38% of the total rainfall, respectively. The rate of stemflow was higher in Jul. and Aug. than other months. The rate of throughfall dropped off from Jun. to Sept., however, rate of interception changed contrarily from 19.43% to 31.02% during the growing season. According to our analysis, the concentration of nutrient elements were arranged as Ca>Mg>N>K>Fe>P>Cu>Mn for rainfall, K>N>Mg>Ca>P>Fe>Mn>Cu for throughfall, and Mn>P>K>Cu>Fe>N>Mg>Ca for being leached through canopy. Nutrients concentration in stewflow and throughfall changed significantly when rainfall passed canopy, and concentration of all elements increased except for Ca and Mg.
基金The study was supported by innovation research project of Institute of Applied Ecology Chinese Academy of Sciences (SCXZD0101-02) and National Natural Science Foundation of China (302
文摘To understand influence of litters on the emission/absorption of CO2, N2O and CH4 in broadleaved/Korean pine forest in Changbai Mountain, fluxes of soil CO2, N2O and CH4 were measured by closed static chamber technique, from Sept 3, 2002 to Oct 30, 2003 in two types of soil ecosystems, of which one was covered with litters on the surface soil, and the other had no litters. The results showed that litters had significant influences on CO2, N2O and CH4 fluxes (p<0.05). Their diurnal change patterns of plot with litters and litter-free plot were similar, and they all showed emission/absorption peak at 18:00. The diurnal change fluxes of CO2 and N2O of plot with litters were significantly higher than those of the litter-free plot, while the diurnal flux of CH4 of plot with litters was lower than that of litter-free plot. The fluxes of CO2, N2O, and CH4 showed the similar seasonal patternsfor both plots. The fluxes of CO2, CH4 showed their peak fluxes in June, but the fluxes of N2O showed its peak emissions in August. The annual fluxes of CO2 and N2O of plot with litters were significantly higher than those of the litter-free plot, while the annual flux of CH4 of plot with litters was lower than that of litter-free plot. Keywords Flux - CO2, N2O and CH4 - Seasonal variation - Diurnal variation CLC number S718.5 Document code A Foundation item: The study was supported by innovation research project of Institute of Appiied Ecology, Chinese Academy of Sciences (SCXZD0101-02) and National Natural Science Foundation of China (30271068)Bigraphy: XIAO Dong-mei (1979-), female, master of Institute of Applied Ecology. Chinese Academy of Sciences, Shenyang 110016. P. R. China.Responsible editor: Song Funan
基金Supported by NKBRSF (Grant No. G1999043407) the Institute of Applied Ecology (grant No. SCXZD0101)+2 种基金 CAS the National Natural Science Foundation of China (NSFC39970123) and by the Changbai Mountain Open Research Station.
文摘A study of the storage dynamics in the mixed broadleaved and Korean pine forests was carried out in the Changbai Mountains, Jilin Province, P. R. China. The modifying law of fallen trees was the storage dynamics of the existing fallen trees and the annual input in the mixed broadleaved and Korean pine forest. The current storage of fallen trees was 16.25 t昲m-2 in the initially, but after 100 years, 85% of the storage in dry weight was decomposed, and little material was left after 300 years. The average annual input of fallen trees was 0.6 t昲m-2and it increased with time to 31.0 t昲m-2after 200 years, which was maintained until the climax community ended. The total storage of fallen trees increased in the early stage. The decomposition of fallen trees eventually reached equilibrium with storage being identical with the annual input of fallen trees.
基金Project(50925417)supported by the National Funds for Distinguished Young Scientist,ChinaProject(2012BAC09B04)supported by the National Key Technology Research and Development Program,China+2 种基金Project supported by the Post-doctoral Program of Central South University,ChinaProjects(31100082,61171061)supported by the National Natural Science Foundation of ChinaProject(2012SK4028)supported by the Science and Technology Program of Hunan Province,China
文摘The taxonomy characteriazation and cadmium （Cd） biosorption of the high Cd-resistant fungus M1 were investigated. The internal transcribed spacers （ITS） region and β-tubulin genes of the strain were amplified, sequenced and analyzed by molecular biology technology. The Cd biosorption assay was performed by shaking flask. Fourier transform infrared spectroscopy was used to analyze the mycelium. The similarity of gene sequences and phylogenetic trees show the very close relation between the strain and Paecilomyces lilacinus, and the fungus M1 was identified as P. Lilacinus. The initial pH 6 and Cd concentration about 100 mg/L are optimum. Zn and Mn have a little effect on the Cd biosorption of the strain, while Cu and Pb present obvious effects. FTIR analysis shows that the fungus adsorbs Cd by esters, anhydride, and amide. With the preferable absorption capacity, fungus M1 is considered to have good prospects in bioremediation.
基金This study was supported by the NKBRSF (G1999043407-1) Tackle Key Problem of Science and technology of China (2001BA510B-07) Knowledge Innovation Program of the Chinese Academy of Sciences (KZCX2-406SCXZD0101)NKTRDP (2001BA510B
文摘A 112 m×8 m sample pot which includes 14 sub-plots was set up along the slope in Hongshi Forestry Farm of Baihe Forestry Bureau (127°55′E, 42°30′ N), Jilin Province in August 2002. Community structure, soil moisture contents at 0–10 cm and 10–20 cm in depth, water content of litter as well as the contents of C, N and P of litter, living leaves and branches in the broad-leaved/Korean pine (Pinus korraiensis) forest were measured in each sub-plot on different slope positions. The analytical results showed that there existed an obvious soil moisture gradient along the slope: upper slope <middle slope< lower slope. The difference in soil moisture contents on different positions of slope led to a change of the stand structure of the braod-leaved/Korean pine forest. The proportion ofQuercus mongolica gradually increased with the decrease of soil moisture content and that of other major tree species in the broad-leaved/Korean pine forest gradually decreased or disappeared. The dynamic of soil moisture contents in the litter layer was as same as that in mineral soils. The decomposition rates of the litter on different slope positions were different and the dry weights of existent litter varied significantly. The soil nutrients in the litter on the lower slope was richer than that on the upper slope due to the different stand structure on the different slope positions. The moisture content and nutrient contents of soil had effects on the composition, decomposition, and the nutrient release of litter, thus affecting stands growth and stand structure and finally leading to the change of ecosystem. Key words Soil moisture gradient - nutrient - Stand structure - Broad-leaved/Korean pine forest CLC number S718.5 Document code A Foundation item: This study was supported by the NKBRSF (G1999043407-1), Tackle Key Problem of Science and technology of China (2001BA510B-07), Knowledge Innovation Program of the Chinese Academy of Sciences (KZCX2-406, SCXZD0101), NKTRDP (2001BA510B-07. 2002BA516A20).Biography: WANG Yan (1970-), female, Ph. D, associate professorResponsible editor: Song Funan
基金This study was supported by the grand of the Knowledge Innovation Program of the Chinese Academy of Sciences (KZCX1-SW-01) and National Natural Science Foundation (30070158).
文摘The measurement and observation for this study were carried out by using a three-dimensional (u, v, w) Sonic anemometer (IAP-SA 485), at Forest Ecosystem Opened Research Station of Changbai Mountains (12828扙 and 4224?N, Jilin Province, P. R. China) in August 2001. The basic characteristics of turbulence, such as turbulence intensity, atmospheric stability, time scales, and convection state, near the forest floor were analyzed. It is concluded that the airflow near forest floor is characterized by high intermittence and asymmetry, and the active and upward movement takes the leading position. Near forest floor, the vertical turbulence is retained and its time scale and length scale are much less than that of u, v components. The eddy near forest floor shows a flat structure and look like a ’Disk’. Buoyancy plays a leading role in the generation and maintenance of local turbulence
基金This research was supported by National Natural Science Foundation of China (Grant No. 40171092).
文摘The forest ecosystem plays an important role in the global carbon cycling. A study was conducted to evaluate soil CO2 flux and its seasonal and diurnal variation with the air and soil temperatures by using static closed chamber technique in a typical broad-leaved/Korean pine mixed forest area on the northern slope of Changbai Mountain, Jilin Province, China. The experiment was carried out through the day and night in the growing season (from June to September) in situ and sample gas was analyzed by a gas chromatograph. Results showed that the forest floor was a large net source of carbon, and soil CO2 fluxes had an obvi-ous law of seasonal and diel variation. The soil CO2 flux of broad-leaved/Korean pine mixed forest was in the range of 0.302.42 mmol穖-2穝-1 with the mean value of 0.98 mmol穖-2穝-1. An examination on the seasonal pattern of soil CO2 emission suggested that the variability in soil CO2 flux could be correlated with variations in soil temperature, and the maximum of mean CO2 flux occurred in July ((1.27±23%) mmol穖-2穝-1) and the minimum was in September ((0.50±28%) mmol穖-2穝-1). The fluctuations in diel soil CO2 flux were also correlated with changes in soil temperature; however, there existed a factor for a time lag. Soil CO2 flux from the forest floor was strongly related to soil temperature and had the highest correlation with temperature at 6-cm depth of soil. Q10 values based on air temperature and soil temperature of different soil depths were at the ranges of 2.09–3.40.
基金Supported by Special Scientific Research Fund of Forestry Public Welfare Profession of China(201104026)~~
文摘Using complete and orthogonal design, fertilization trials were conducted for the young growth of Populus deltoids cv. Zhonghua hongye in the fluviogenic soil in Xindu District, Chengdu City. The results showed that the application ef- fect of the single nutrient elements ranked as K〉N〉P, and that of the fertilization combinations ranked as N＋P＋K〉N＋K〉N＋P, P＋K. The optimum fertilization formula was urea [（NH2）2CO, 150 g/plant] ＋ calcium superphosphate [Ca（H2PO4）2.H20, 220 g/plant] ＋ potassium sulphate （K2SO4, 75 g/plant）.
文摘Fourier transform infrared spectroscopy (FTIR) was used to detect the spectral difference among leaf tips from rice ( Oryza sativa L.) plants with different nitrogen fertilizer rates. The proposed spectral index, ( A 3400 - A 1653 )/( A 3400 + A 1653 ) ( A denotes absorption value at certain frequency (cm -1 )), was found to decline with the increase of nitrogen fertilizer rates and the results suggested that FTIR may be useful to diagnose nitrogen status in crops.
