A novel self-alignment method for high precision silicon diffraction microlens arrays preparation and its integration with infrared focal plane arrays

Silicon(Si)diffraction microlens arrays are usually used to integrating with infrared focal plane arrays(IRFPAs)to improve their performance.The errors of lithography are unavoidable in the process of the Si diffrac-tion microlens arrays preparation in the conventional engraving method.It has a serious impact on its performance and subsequent applications.In response to the problem of errors of Si diffraction microlens arrays in the conven-tional method,a novel self-alignment method for high precision Si diffraction microlens arrays preparation is pro-posed.The accuracy of the Si diffractive microlens arrays preparation is determined by the accuracy of the first li-thography mask in the novel self-alignment method.In the subsequent etching,the etched area will be protected by the mask layer and the sacrifice layer or the protective layer.The unprotection area is carved to effectively block the non-etching areas,accurately etch the etching area required,and solve the problem of errors.The high precision Si diffraction microlens arrays are obtained by the novel self-alignment method and the diffraction effi-ciency could reach 92.6%.After integrating with IRFPAs,the average blackbody responsity increased by 8.3%,and the average blackbody detectivity increased by 10.3%.It indicates that the Si diffraction microlens arrays can improve the filling factor and reduce crosstalk of IRFPAs through convergence,thereby improving the perfor-mance of the IRFPAs.The results are of great reference significance for improving their performance through opti-mizing the preparation level of micro nano devices.

A monolithic integrated medium wave Mercury Cadmium Telluride polarimetric focal plane array

A medium wave(MW)640×512(25μm)Mercury Cadmium Telluride(HgCdTe)polarimetric focal plane array(FPA)was demonstrated.The micro-polarizer array(MPA)has been carefully designed in terms of line grating structure optimization and crosstalk suppression.A monolithic fabrication process with low damage was explored,which was verified to be compatible well with HgCdTe devices.After monolithic integration of MPA,NETD<9.5 mK was still maintained.Furthermore,to figure out the underlying mechanism that dominat⁃ed the extinction ratio(ER),specialized MPA layouts were designed,and the crosstalk was experimentally vali⁃dated as the major source that impacted ER.By expanding opaque regions at pixel edges to 4μm,crosstalk rates from adjacent pixels could be effectively reduced to approximately 2%,and promising ERs ranging from 17.32 to 27.41 were implemented.

《红楼》外的诗意行走——记贺信民教授的学术研究

贺信民教授数十年的学术人生,可谓是梁启超所倡导的追求学与术结合的孜孜以求者。近期面世的《红外集》,广泛涉猎多个领域,兼顾"学"与"术",是贺信民教授平生为学、为人、为政的才学与智慧的体现,凝聚了著者红学之外平生学术之菁华。

Semantic Knowledge Acquisition from Blogs with Tag-Topic Model

This paper focuses on semantic knowl- edge acquisition from blogs with the proposed tag- topic model. The model extends the Latent Dirichlet Allocation （LDA） model by adding a tag layer be- tween the document and the topic. Each document is represented by a mixture of tags; each tag is as- sociated with a multinomial distribution over topics and each topic is associated with a multinomial dis- trNution over words. After parameter estimation, the tags are used to descrNe the underlying topics. Thus the latent semantic knowledge within the top- ics could be represented explicitly. The tags are treated as concepts, and the top-N words from the top topics are selected as related words of the con- cepts. Then PMI-IR is employed to compute the re- latedness between each tag-word pair and noisy words with low correlation removed to improve the quality of the semantic knowledge. Experiment re- sults show that the proposed method can effectively capture semantic knowledge, especially the polyse- me and synonym.

Catchment-based Imperviousness Metrics Impacts on Floods in Niushou River Basin,Nanjing City,East China

Concerns regarding urbanization impacts on floods gradually moved from end-of-pipe solutions, based on open channel hydraulics improvement, to imperviousness ratio limiting and then to land use control and to integrated planning at local and large scale levels. The Niushou River basin is one of the fastest urbanizing areas in Nanjing City, East China, however, the high urban land percentage has leaded to series of flooding events. The paper aims to reveal the impact of imperviousness ratio, patterns and drainage system on flooding areas based on the unit of catchment and Storm Water Management Model(SWMM). The following conclusions were reached. 1) The ratio or spatial characteristics of the impervious surface affected the runoff volumes and associated floods areas. Despite the well-established drainage system, the high imperviousness ratio, particularly clustered pattern in locations such as hydrological sensitive zones aggravated the flooding tension across the basin. 2) The poor drainage hydraulic efficiency in local areas, and the lack of integral processes of infiltration, yield, storage and discharge in local catchment and larger basin are also significant factors. 3) The Niushou River basin development should improve the drainage transformations from a single local, short-term drainage process into integral, elastic processes of infiltration, yield, storage, and discharge.

Infrared thin layer drying of saffron(Crocus sativus L.) stigmas:Mass transfer parameters and quality assessment

Saffron is the most precious and expensive agricultural product. A dehydration treatment is necessary to convert Crocus sativus L. stigmas into saffron spice. To the best of our knowledge, no information on mass transfer parameters of saffron stigmas is available in the literature. This study aimed at investigating the moisture transfer parameters and quality attributes of saffron stigmas under infrared treatment at different temperatures（60,70, …, 110 ℃）. It was observed that the dehydration process of the samples occurred in a short accelerating rate period at the start followed by a falling rate period. The effective moisture diffusivity and convective mass transfer coefficient were determined by using the Dincer and Dost model. The diffusivity values varied from1.1103 × 10^-10m^2·s^-1to 4.1397 × 10^-10m^2·s^-1 and mass transfer coefficient varied in the range of 2.6433 × 10^-7–8.7203 × 10^-7m·s^-1. The activation energy was obtained to be 27.86 kJ·mol^-1. The quality assessment results showed that the total crocin content increased, when the temperature increased up to90 ℃ but, in higher temperatures, the amount of crocin decreased slightly. The total safranal content of the samples decreased slightly when drying temperature increased from 60 ℃ to 70 ℃ and then continuously increased up to 110 ℃. Also, the amount of picrocrocin increased from 83.1 to 93.3 as the drying temperature increased from 60 ℃ to 100 ℃.

Influences of collector DLZ on chalcopyrite and pyrite flotation

The interaction mechanism of collector DLZ in the flotation process of chalcopyrite and pyrite was investigated through flotation experiments,zeta potential measurements and infrared spectrum analysis.Flotation test results indicate that DLZ is the selective collector of chalcopyrite.Especially,the recovery of chalcopyrite is higher than 90% in neutral and weak alkaline systems,while the recovery of pyrite is less than 10%.When using CaO as pH regulator,at pH=7-11,the floatability of pyrite is depressed and the recovery is less than 5%.Zeta potential analysis shows that the zeta potential of chalcopyrite decreases more obviously than that of pyrite after interaction with DLZ,confirming that collector DLZ shows selectivity to chalcopyrite and pyrite.And FTIR results reveal that the flotation selectivity of collector DLZ is due to chemical absorption onto chalcopyrite surface and only physical absorption onto pyrite surface.

Characterization of calcium deposition induced by Synechocystis sp. PCC6803 in BG11 culture medium

Calcium carbonate （CaCO3） crystals in their preferred orientation were obtained in BG11 culture media inoculated with Synechocystis sp. PCC6803 （inoculated BG11）. In this study, the features of calcium carbonate deposition were investigated. Inoculated BGll in different calcium ion concentrations was used for the experimental group, while the BGll culture medium was used for the control group. The surface morphologies of the calcium carbonate deposits in the experimental and control groups were determined by scanning and transmission electron microscopy. The deposits were analyzed by electronic probe micro-analysis, Fourier transform infrared spectrum, X-ray diffraction, thermal gravimetric analysis and differential scanning calorimetry. The results show that the surfaces of the crystals in the experimental group were hexahedral in a scaly pattern. The particle sizes were micrometer-sized and larger than those in the control group. The deposits of the control group contained calcium （Ca）, carbon （C）, oxygen （O）, phosphorus （P）, iron （Fe）, copper （Cu）, zinc （Zn）, and other elements. The deposits in the experimental group contained Ca, C, and O only. The deposits of both groups contained calcite. The thermal decomposition temperature of the deposits in the control group was lower than those in the experimental group. It showed that the CaCO3 deposits of the experimental group had higher thermal stability than those of the control group. This may be due to the secondary metabolites produced by the algae cells, which affect the carbonate crystal structure and result in a close-packed structure. The algae cells that remained after thermal weight loss were heavier in higher calcium concentrations in BGll culture media. There may be more calcium- containing crystals inside and outside of these cells. These results shall be beneficial for understanding the formation mechanism of carbonate minerals.

Tetraphenylethylene-BODIPY aggregation-induced emission luminogens for near-infrared polymer light-emitting diodes

The aggregation-induced emission(AIE) phenomenon provides a new direction for the development of organic light-emitting devices. Here, we present a new class of emitters based on 4,4-difluoro-4-bora-3 a,4 a-diaza-s-indacene(BODIPY), functionalized at different positions with tetraphenylethylene(TPE), which is one of the most famous AIE luminogens. Thanks to this modification, we were able to tune the photoluminescence of the BODIPY moiety from the green to the near-infrared(NIR)spectral range and achieve PL efficiencies of ~50% in the solid state. Remarkably, we observed an enhancement of the AIE and up to ~100% photoluminescence efficiencies by blending the TPE-substituted BODIPY fluorophores with a poly[(9,9-di-noctylfluorene-2,7-diyl)-alt-(benzo[2,1,3]thiadiazol-4,7-diyl)](F8 BT) matrix. By incorporating these blends in organic lightemitting diodes(OLEDs), we obtained electroluminescence peaked in the range 650–700 nm with up to 1.8% external quantum efficiency and ~2 m W/cm2 radiance, a remarkable result for red/NIR emitting and solution-processed OLEDs.

Chemically exfoliated WS2 nanosheets efficiently inhibit amyloid β-peptide aggregation and can be used for photothermal treatment of Alzheimer＇s disease

Polymerization of amyloid-β peptide （Aβ） into amyloid fibrils is a critical step in the pathogenesis of Alzheimer＇s disease （AD）. Inhibition of Aβ aggregation and destabilization of preformed Aβ fibrils have promising effects against AD and have been used in clinic trials. Herein, we demonstrate, for the first time, the application of WS2 nanosheets, to not only effectively inhibit Aβ aggregation, but also dissociate preformed Aβ aggregates upon near infrared （NIR） irradiation. Additionally, the biocompatible WS2 nanosheets possess the ability to cross the blood-brain barrier （BBB） to overcome the limitations of most previously reported Aβ inhibitors. Through van der Waals and electrostatic interactions between Aβ40 and WS2, Aβ40 monomers can be selectively adsorbed on the surface of the nanosheet to inhibit the Aβ40 aggregation process. Intriguingly, the unique high NIR absorption property of WS2 enables amyloid aggregates to be dissolved upon NIR irradiation. These results will promote biological applications of WS2 and provide new insight into the design of multifunctional nanomaterials for AD treatment.