The de-eutrophication abilities and characteristics of Ulva pertusa, a marine green alga, were investigated in Qingdao Yihai Hatchery Center from spring to summer in 2005 by analyzing the dynamic changes in NH4-, NO3-...The de-eutrophication abilities and characteristics of Ulva pertusa, a marine green alga, were investigated in Qingdao Yihai Hatchery Center from spring to summer in 2005 by analyzing the dynamic changes in NH4-, NO3-, NO2- as well as the total dissolved inorganic nitrogen (DIN). The results show that the effluent wastewater produced by fish aquaculture had typical eutrophication levels with an average of 34.3 ~mol L-1 DIN. This level far exceeded the level IV quality of the national seawater standard and could easily lead to phytoplankton blooms in nature if discarded with no treatment. The de-eutrophication abilities of U. pertusa varied greatly and depended mainly on the original eutrophic level the U. pertusa material was derived from. U. pertusa used to living in low DIN conditions had poor DIN removal abilities, while materials cultured in DIN-enriched seawater showed strong de-eutrophication abilities. In other words, the de-eutrophication ability of U. pertusa was evidently induced by high DIN levels. The de-eutrophication capacity of U. pertusa seemed to also be light dependent, because it was weaker in darkness than under illumination. However, no further improvement in the de-eutrophication capacity of U. pertusa was observed once the light intensity exceeded 300 pmolM2 S1. Results of semi-continuous wastewater replacement experiments showed that U. pertusa permanently absorbed nutrients from eutrophicated wastewater at a mean rate of 299 mg/kg fresh weight per day (126 mg/kg DIN during the night, 173 mg/kg in daytime). Based on the above results, engineered de-eutrophication of wastewater by using a U. pertusa filter system seems feasible. The algal quantity required to purify all the eutrophicated outflow wastewater from the Qingdao Yihai Hatchery Center into oligotrophic level I dean seawater was also estimated using the daily discharged wastewater, the average DIN concentration released and the de-eutrophication capacity of U. pertusa.展开更多
Based on the stress distribution characteristics of rock burst multiple sites, the criterion of horizontal stress inducing layer dislocation rock burst was established. Accordingly, the influencing factors were analyz...Based on the stress distribution characteristics of rock burst multiple sites, the criterion of horizontal stress inducing layer dislocation rock burst was established. Accordingly, the influencing factors were analyzed. The analysis results indicate that the stress condition, edge of etastic zone depth, supporting strength, and the friction angle and cohesion among coal stratum, roof and floor are sensitive factors. By introducing double-couple model, the layer dislocation rock burst was explained and the energy radiation characteristics were analyzed. The SOS micro-seismic monitoring system was applied to observe the rock burst hazards about a mining face. The results show that P- and S-wave energy radiations produced by rock burst have directional characteristics. The energy radiation characteristics of the 22 rock bursts occurring on 79Z6 long-wall face are basically the same as theoretical results, that is, the ratio of S-wave energy of sensor 4 to 6 is about 1.5 and that of P-wave is smaller than 0.5. The consistency of the monitored characteristics of the energy radiation theoretically increases with the total energy increasing.展开更多
A three-dimensional advection-diffusion model coupled with the degradation process is established for describing the transport of chemical oxygen demand (COD). Comparison of the simulated distribution of COD at the su...A three-dimensional advection-diffusion model coupled with the degradation process is established for describing the transport of chemical oxygen demand (COD). Comparison of the simulated distribution of COD at the surface in the Bohai Sea in August, 2001 with field observations, shows that the model simulates the dataset reasonably well. The Laizhou Bay, Bohai Bay, and Liaodong Bay were contaminated heavily near shore. Based on the optimal discharge flux method, the Environmental Capacity (EC) and allocated capacities of COD in the Bohai Sea are calculated. For seawater of Grades I to IV of the Chinese National Standard, the ECs of COD in the Bohai Sea were 77×104 t/a, 116×104 t/a, 154×104 t/a and 193×104 t/a, respectively. The Huanghe (Yellow) River pollutant discharge accounted for the largest percentage of COD at 14.3%, followed by that of from the Liugu River (11.5%), and other nine local rivers below 10%. The COD level in 2005 was worse than that of Grade II seawater and was beyond the environmental capacity. In average, 35% COD reduction is called to meet the standard of Grade I seawater.展开更多
It is discussed in this paper the capability requirements of modern communication industry for smart pipe or Network Intelligence Capability Enhancement (NICE), Domestic and international researches on smart pipe ar...It is discussed in this paper the capability requirements of modern communication industry for smart pipe or Network Intelligence Capability Enhancement (NICE), Domestic and international researches on smart pipe are elaborated in the essay as well.展开更多
Dementia is a loss of mental ability (ability to think, remember and make logical conclusions) which, in principle affects normal everyday life of a person. Dementia is not a disease but a group of symptoms that may...Dementia is a loss of mental ability (ability to think, remember and make logical conclusions) which, in principle affects normal everyday life of a person. Dementia is not a disease but a group of symptoms that may cause different diseases. Symptoms include change of behaviour, character and unexpected changes in the mood. Poor quality of nutrition affects significantly the intensity of dementia. Balanced diet that meets healthy safety standards and requirements will satisfy the needs of an organism for vitamins and minerals and special attention should be given to intake of folic acid, vitamin B12 and minerals zinc and selenium. Intake of omega3 fatty acids is a source of fuel for blood vessels, particularly for the ones of the nervous tissues.展开更多
There are more than eight different design standards in use for the existing railway bridges in China, which have different applicabilities for bridges built in different periods. In this paper, the design load standa...There are more than eight different design standards in use for the existing railway bridges in China, which have different applicabilities for bridges built in different periods. In this paper, the design load standards in different periods are introduced and compared; The working status of the railway is investigated. According to the developing trend of separating passenger and freight transports, by comparing the computed results of the bridge effect and the fatigue cumulative damage, the applicabilities of bearing capacity and fatigue are analyzed for existing bridges. The results indicate that the bearing capacities of 99% existing bridges are suitable for the demand of 26.5 t (axle-weight) freight trains. However, for culverts, bridges with spans less than 20 m, longitudinal and transverse beams of through bridges, suspenders of truss bridges and other locally-stressed members should be evaluated and reinforced due to the increasing axle-weight.展开更多
The molar heat capacities(C_p) of guaiacol(CAS 90-50-1) and acetyl guaiacol ester(AGE, CAS 613-70-7) were determinated from 290 K to 350 K by differential scanning calorimetry(DSC), and expressed as a function of temp...The molar heat capacities(C_p) of guaiacol(CAS 90-50-1) and acetyl guaiacol ester(AGE, CAS 613-70-7) were determinated from 290 K to 350 K by differential scanning calorimetry(DSC), and expressed as a function of temperature. Two kinds of group contribution models were used to estimate the molar heat capacities of both guaiacol and AGE, the average relative deviation is less than 10%. The standard molar enthalpies of combustion of guaiacol and AGE were- 3590.0 k J·mol^(-1)and- 4522.1 k J·mol^(-1) by a precise thermal isolation Oxygen Bomb Calorimeter. The standard molar enthalpies of formation of guaiacol and AGE in a liquid state at298.15 K were calculated to be- 307.95 k J·mol^(-1) and- 448.72 k J·mol^(-1), respectively, based on the standard molar enthalpies of combustion. The thermodynamic properties are useful for exploiting the new synthesis method, engineering design and industry production of AGE using guaiacol as a raw material.展开更多
In the test, internal inlay drip irrigation pipes with different wal thicknesses or diameters (¢at 12 mm and 16 mm) were tested under varying tension forces and it was concluded that 90 N is the rational one. What...In the test, internal inlay drip irrigation pipes with different wal thicknesses or diameters (¢at 12 mm and 16 mm) were tested under varying tension forces and it was concluded that 90 N is the rational one. What’s more, the smal er drip-irrigation inner diameter, the thinner wal thickness, and the higher tension force, the lower acceptability, and the larger drip-irrigation inner diameter, the thicker wal thickness, and the lower tension force, the higher acceptability. The causes were analyzed in the research, including manufacturing technique leading to disqualifica-tion and different specifications with the same demands on techniques, and inadap-tation to tension force at 130 N.展开更多
Many factors,such as deck motion and air wave,influence the determination of the approach speed which has an important effect on landing safety. Until recently,there are no design criteria about approach speed of carr...Many factors,such as deck motion and air wave,influence the determination of the approach speed which has an important effect on landing safety. Until recently,there are no design criteria about approach speed of carrier aircraft in the current standards and available publications. Therefore,the requirements of stall margin, longitudinal acceleration ability,altitude correction and field-of-view on approach speed were researched. Based on the flight dynamics model,the flight simulations were conducted to study the effect of the response time of engine,wave off requirements,elevator efficiency and deflection rate on the approach speed. The results presented that the approach longitudinal acceleration and altitude correction ability had crucial influence on the approach speed envelope of the aircraft. The limitations of the control requirements,field- of- view requirements and gear were also given through the simulation and analysis. Based on the above results,the approach speed envelope were determined.展开更多
It is of great significance to make comparative analyses of seismic fortification criteria at home and abroad for improving the anti-seismic capability of electrical equipment and revising the relevant national standa...It is of great significance to make comparative analyses of seismic fortification criteria at home and abroad for improving the anti-seismic capability of electrical equipment and revising the relevant national standards.A brief overview of American,Japanese,IEC standards and Chinese seismic design codes for electrical equipment is presented.Differences between these seismic fortification standards of electrical equipment are compared and analyzed in respect of the goal and level of seismic fortification and the seismic design spectrum.The advantages and disadvantages of Chinese standards are pointed out.Through learning from foreign experience on the determination of seismic fortification standards,recommendations are made for the improvement and revision of Chinese seismic fortification standards for electrical equipment.展开更多
Research, performed by the authors proved that one of the most significant factors affecting the increase in flexibility and competitive ability of a firm is the conceptual, complex intra-plant standardization. The en...Research, performed by the authors proved that one of the most significant factors affecting the increase in flexibility and competitive ability of a firm is the conceptual, complex intra-plant standardization. The enterprise implementing the standardization is capable of flexible responding to customer's demands for the assortment, accelerates considerably research, and offers satisfactory delivery terms. That means the selection of types of the input factors and the method how to use them, the selection of working procedures and procedures of intermediary consumption, definition of the relations in the process of control, rational structure of the final products etc.. The permanent innovative atmosphere is presupposed.展开更多
Service standards communication and servant leadership are both important mechanisms to improve an organization's service process. Therefore, they are likely to affect strategic competence and customer orientation sk...Service standards communication and servant leadership are both important mechanisms to improve an organization's service process. Therefore, they are likely to affect strategic competence and customer orientation skills of organizations. In this research, customer orientation and strategic competence are undertaken in relation with servant leadership and service standards communication, using a sample of 106 Turkish firms' executive assistants. The results prove that service standards communication and servant leadership have a strong positive relationship with both strategic competence and customer orientation.展开更多
Essentially, it is the lack of these basic abilities: The ability to secure efficiently the production based on the qualitatively reasonable organization and control of the manufacturing processes, and consequently t...Essentially, it is the lack of these basic abilities: The ability to secure efficiently the production based on the qualitatively reasonable organization and control of the manufacturing processes, and consequently to reach production and technical standards and time and financial parameters, supporting the reasonable strategic objectives of an enterprise. This efficiency must be manifested in elimination of basic lasting shortcomings (i.e., inability to meet time schedule of products delivery, the long time of production, the insufficient survey of their course--especially at products with long-run production cycle).展开更多
"EQ" has become one of the modem professional qualities; it is a capacity to deal with emotions. In the current work, the pressure of living is low and the ability to make personal frustration TV presenter faced sev..."EQ" has become one of the modem professional qualities; it is a capacity to deal with emotions. In the current work, the pressure of living is low and the ability to make personal frustration TV presenter faced severe psychological crisis. "EQ" on the TV show host has important implications; they focus on "emotional intelligence" training TV show host; the "EQ" Test selection criteria included the host, it is to improve the professional competence of TV presenter quality.展开更多
The arguments in this paper lead to a new definition of thermodynamic equilibrium that remedies the deficiencies of the current forms. This definition relates thermodynamic equilibrium to its physical causes and accou...The arguments in this paper lead to a new definition of thermodynamic equilibrium that remedies the deficiencies of the current forms. This definition relates thermodynamic equilibrium to its physical causes and accounts for all factors that determine it for all types of equilibrium. Standard definitions of thermodynamic equilibrium are incomplete. They do not take account of all factors that determine such equilibriums, discuss the impediments which may prevent them being reached or relate the properties that define equilibriums to the physical reasons that determine them when impediments are present. The laws of thermodynamics determine the requirements for equilibrium. These laws arise from the physical behaviour of the molecules in molecular systems and are consequences of the conservation of energy, the energies of molecules, statistics, Newton's laws of motion, and the equi-partition of energy. The standard definition of thermodynamic equilibrium correctly defines equilibrium whenever impediments are not factors. The discussion demonstrates how impediments arise, accounts for their role in defining equilibrium and how they relate to the energies of molecules at the conditions of the system. The new definition applies to all types of equilibrium.展开更多
The study results of the internal friction character of geomaterials conclude that the internal friction exists in mechanical elements all the time having a direction opposite to the shear stress,and the deformation f...The study results of the internal friction character of geomaterials conclude that the internal friction exists in mechanical elements all the time having a direction opposite to the shear stress,and the deformation failure mechanism of geomaterials greatly differs from that of metals. For metals,the failure results from shear stresses make the crystal structure slip; whereas for geomaterials,owing to its attribute of granular structures,their deformation follows the friction law,it is the co-action of shear stresses and perpendicular stresses that makes grains overcome the frictions between them,thus leading to the final failure of relative sliding.Therefore,on the basis of the cognition above,a triple shear energy criterion is proposed. Its corresponding Drucker-Prager criterion for geomaterials is also given. The new criterion can be rewritten to the Mohr-Coulomb criterion by neglecting the effect of the intermediate principal stress,and to the Mises criterion by not taking the internal friction angle into consideration. Then the studies of yield criteria commonly used are conducted systematically from the points of stress,strain and energy of geomaterials. The results show that no matter which expression form of stress,strain or energy is used for the yield criterion,the essence is the same and the triple shear energy yield criterion is the unified criterion of materials. Finally,the experimental verification is conducted in connection with the practical application of the triple shear energy yield criterion in an engineering project,and the calculation result shows that the Mohr-Coulomb criterion which only takes the single shear surface into account is more conservative than the energy criterion that does consider the effect of triple shear surfaces.展开更多
基金Supported by the Knowledge Innovation Program of the Chinese Adademy of Sciences (No. KZCX3-SW-215)Special Project for Marine Public Walfare Industry (No. 200705010)
文摘The de-eutrophication abilities and characteristics of Ulva pertusa, a marine green alga, were investigated in Qingdao Yihai Hatchery Center from spring to summer in 2005 by analyzing the dynamic changes in NH4-, NO3-, NO2- as well as the total dissolved inorganic nitrogen (DIN). The results show that the effluent wastewater produced by fish aquaculture had typical eutrophication levels with an average of 34.3 ~mol L-1 DIN. This level far exceeded the level IV quality of the national seawater standard and could easily lead to phytoplankton blooms in nature if discarded with no treatment. The de-eutrophication abilities of U. pertusa varied greatly and depended mainly on the original eutrophic level the U. pertusa material was derived from. U. pertusa used to living in low DIN conditions had poor DIN removal abilities, while materials cultured in DIN-enriched seawater showed strong de-eutrophication abilities. In other words, the de-eutrophication ability of U. pertusa was evidently induced by high DIN levels. The de-eutrophication capacity of U. pertusa seemed to also be light dependent, because it was weaker in darkness than under illumination. However, no further improvement in the de-eutrophication capacity of U. pertusa was observed once the light intensity exceeded 300 pmolM2 S1. Results of semi-continuous wastewater replacement experiments showed that U. pertusa permanently absorbed nutrients from eutrophicated wastewater at a mean rate of 299 mg/kg fresh weight per day (126 mg/kg DIN during the night, 173 mg/kg in daytime). Based on the above results, engineered de-eutrophication of wastewater by using a U. pertusa filter system seems feasible. The algal quantity required to purify all the eutrophicated outflow wastewater from the Qingdao Yihai Hatchery Center into oligotrophic level I dean seawater was also estimated using the daily discharged wastewater, the average DIN concentration released and the de-eutrophication capacity of U. pertusa.
基金Project(2012LWB63) supported by the Fundamental Research Funds for the Central Universities, ChinaProject(SZBF2011-6-B35) supported by the Priority Acadamic Program Development of Jiangsu Higher Education Institutions (PAPD),China
文摘Based on the stress distribution characteristics of rock burst multiple sites, the criterion of horizontal stress inducing layer dislocation rock burst was established. Accordingly, the influencing factors were analyzed. The analysis results indicate that the stress condition, edge of etastic zone depth, supporting strength, and the friction angle and cohesion among coal stratum, roof and floor are sensitive factors. By introducing double-couple model, the layer dislocation rock burst was explained and the energy radiation characteristics were analyzed. The SOS micro-seismic monitoring system was applied to observe the rock burst hazards about a mining face. The results show that P- and S-wave energy radiations produced by rock burst have directional characteristics. The energy radiation characteristics of the 22 rock bursts occurring on 79Z6 long-wall face are basically the same as theoretical results, that is, the ratio of S-wave energy of sensor 4 to 6 is about 1.5 and that of P-wave is smaller than 0.5. The consistency of the monitored characteristics of the energy radiation theoretically increases with the total energy increasing.
基金Supported by 908 Program of the State Ocean Administration of China (Nos.908-02-02-02,908-02-02-03)the State Ocean Administration Foundation of China (No.200805065)
文摘A three-dimensional advection-diffusion model coupled with the degradation process is established for describing the transport of chemical oxygen demand (COD). Comparison of the simulated distribution of COD at the surface in the Bohai Sea in August, 2001 with field observations, shows that the model simulates the dataset reasonably well. The Laizhou Bay, Bohai Bay, and Liaodong Bay were contaminated heavily near shore. Based on the optimal discharge flux method, the Environmental Capacity (EC) and allocated capacities of COD in the Bohai Sea are calculated. For seawater of Grades I to IV of the Chinese National Standard, the ECs of COD in the Bohai Sea were 77×104 t/a, 116×104 t/a, 154×104 t/a and 193×104 t/a, respectively. The Huanghe (Yellow) River pollutant discharge accounted for the largest percentage of COD at 14.3%, followed by that of from the Liugu River (11.5%), and other nine local rivers below 10%. The COD level in 2005 was worse than that of Grade II seawater and was beyond the environmental capacity. In average, 35% COD reduction is called to meet the standard of Grade I seawater.
文摘It is discussed in this paper the capability requirements of modern communication industry for smart pipe or Network Intelligence Capability Enhancement (NICE), Domestic and international researches on smart pipe are elaborated in the essay as well.
文摘Dementia is a loss of mental ability (ability to think, remember and make logical conclusions) which, in principle affects normal everyday life of a person. Dementia is not a disease but a group of symptoms that may cause different diseases. Symptoms include change of behaviour, character and unexpected changes in the mood. Poor quality of nutrition affects significantly the intensity of dementia. Balanced diet that meets healthy safety standards and requirements will satisfy the needs of an organism for vitamins and minerals and special attention should be given to intake of folic acid, vitamin B12 and minerals zinc and selenium. Intake of omega3 fatty acids is a source of fuel for blood vessels, particularly for the ones of the nervous tissues.
文摘There are more than eight different design standards in use for the existing railway bridges in China, which have different applicabilities for bridges built in different periods. In this paper, the design load standards in different periods are introduced and compared; The working status of the railway is investigated. According to the developing trend of separating passenger and freight transports, by comparing the computed results of the bridge effect and the fatigue cumulative damage, the applicabilities of bearing capacity and fatigue are analyzed for existing bridges. The results indicate that the bearing capacities of 99% existing bridges are suitable for the demand of 26.5 t (axle-weight) freight trains. However, for culverts, bridges with spans less than 20 m, longitudinal and transverse beams of through bridges, suspenders of truss bridges and other locally-stressed members should be evaluated and reinforced due to the increasing axle-weight.
文摘The molar heat capacities(C_p) of guaiacol(CAS 90-50-1) and acetyl guaiacol ester(AGE, CAS 613-70-7) were determinated from 290 K to 350 K by differential scanning calorimetry(DSC), and expressed as a function of temperature. Two kinds of group contribution models were used to estimate the molar heat capacities of both guaiacol and AGE, the average relative deviation is less than 10%. The standard molar enthalpies of combustion of guaiacol and AGE were- 3590.0 k J·mol^(-1)and- 4522.1 k J·mol^(-1) by a precise thermal isolation Oxygen Bomb Calorimeter. The standard molar enthalpies of formation of guaiacol and AGE in a liquid state at298.15 K were calculated to be- 307.95 k J·mol^(-1) and- 448.72 k J·mol^(-1), respectively, based on the standard molar enthalpies of combustion. The thermodynamic properties are useful for exploiting the new synthesis method, engineering design and industry production of AGE using guaiacol as a raw material.
文摘In the test, internal inlay drip irrigation pipes with different wal thicknesses or diameters (¢at 12 mm and 16 mm) were tested under varying tension forces and it was concluded that 90 N is the rational one. What’s more, the smal er drip-irrigation inner diameter, the thinner wal thickness, and the higher tension force, the lower acceptability, and the larger drip-irrigation inner diameter, the thicker wal thickness, and the lower tension force, the higher acceptability. The causes were analyzed in the research, including manufacturing technique leading to disqualifica-tion and different specifications with the same demands on techniques, and inadap-tation to tension force at 130 N.
文摘Many factors,such as deck motion and air wave,influence the determination of the approach speed which has an important effect on landing safety. Until recently,there are no design criteria about approach speed of carrier aircraft in the current standards and available publications. Therefore,the requirements of stall margin, longitudinal acceleration ability,altitude correction and field-of-view on approach speed were researched. Based on the flight dynamics model,the flight simulations were conducted to study the effect of the response time of engine,wave off requirements,elevator efficiency and deflection rate on the approach speed. The results presented that the approach longitudinal acceleration and altitude correction ability had crucial influence on the approach speed envelope of the aircraft. The limitations of the control requirements,field- of- view requirements and gear were also given through the simulation and analysis. Based on the above results,the approach speed envelope were determined.
基金funded by the special project of Spark Program of Earthquake Sciences (Serial number:XH12063)
文摘It is of great significance to make comparative analyses of seismic fortification criteria at home and abroad for improving the anti-seismic capability of electrical equipment and revising the relevant national standards.A brief overview of American,Japanese,IEC standards and Chinese seismic design codes for electrical equipment is presented.Differences between these seismic fortification standards of electrical equipment are compared and analyzed in respect of the goal and level of seismic fortification and the seismic design spectrum.The advantages and disadvantages of Chinese standards are pointed out.Through learning from foreign experience on the determination of seismic fortification standards,recommendations are made for the improvement and revision of Chinese seismic fortification standards for electrical equipment.
文摘Research, performed by the authors proved that one of the most significant factors affecting the increase in flexibility and competitive ability of a firm is the conceptual, complex intra-plant standardization. The enterprise implementing the standardization is capable of flexible responding to customer's demands for the assortment, accelerates considerably research, and offers satisfactory delivery terms. That means the selection of types of the input factors and the method how to use them, the selection of working procedures and procedures of intermediary consumption, definition of the relations in the process of control, rational structure of the final products etc.. The permanent innovative atmosphere is presupposed.
文摘Service standards communication and servant leadership are both important mechanisms to improve an organization's service process. Therefore, they are likely to affect strategic competence and customer orientation skills of organizations. In this research, customer orientation and strategic competence are undertaken in relation with servant leadership and service standards communication, using a sample of 106 Turkish firms' executive assistants. The results prove that service standards communication and servant leadership have a strong positive relationship with both strategic competence and customer orientation.
文摘Essentially, it is the lack of these basic abilities: The ability to secure efficiently the production based on the qualitatively reasonable organization and control of the manufacturing processes, and consequently to reach production and technical standards and time and financial parameters, supporting the reasonable strategic objectives of an enterprise. This efficiency must be manifested in elimination of basic lasting shortcomings (i.e., inability to meet time schedule of products delivery, the long time of production, the insufficient survey of their course--especially at products with long-run production cycle).
文摘"EQ" has become one of the modem professional qualities; it is a capacity to deal with emotions. In the current work, the pressure of living is low and the ability to make personal frustration TV presenter faced severe psychological crisis. "EQ" on the TV show host has important implications; they focus on "emotional intelligence" training TV show host; the "EQ" Test selection criteria included the host, it is to improve the professional competence of TV presenter quality.
文摘The arguments in this paper lead to a new definition of thermodynamic equilibrium that remedies the deficiencies of the current forms. This definition relates thermodynamic equilibrium to its physical causes and accounts for all factors that determine it for all types of equilibrium. Standard definitions of thermodynamic equilibrium are incomplete. They do not take account of all factors that determine such equilibriums, discuss the impediments which may prevent them being reached or relate the properties that define equilibriums to the physical reasons that determine them when impediments are present. The laws of thermodynamics determine the requirements for equilibrium. These laws arise from the physical behaviour of the molecules in molecular systems and are consequences of the conservation of energy, the energies of molecules, statistics, Newton's laws of motion, and the equi-partition of energy. The standard definition of thermodynamic equilibrium correctly defines equilibrium whenever impediments are not factors. The discussion demonstrates how impediments arise, accounts for their role in defining equilibrium and how they relate to the energies of molecules at the conditions of the system. The new definition applies to all types of equilibrium.
基金National Natural Science Foundation of China (No.50609027)
文摘The study results of the internal friction character of geomaterials conclude that the internal friction exists in mechanical elements all the time having a direction opposite to the shear stress,and the deformation failure mechanism of geomaterials greatly differs from that of metals. For metals,the failure results from shear stresses make the crystal structure slip; whereas for geomaterials,owing to its attribute of granular structures,their deformation follows the friction law,it is the co-action of shear stresses and perpendicular stresses that makes grains overcome the frictions between them,thus leading to the final failure of relative sliding.Therefore,on the basis of the cognition above,a triple shear energy criterion is proposed. Its corresponding Drucker-Prager criterion for geomaterials is also given. The new criterion can be rewritten to the Mohr-Coulomb criterion by neglecting the effect of the intermediate principal stress,and to the Mises criterion by not taking the internal friction angle into consideration. Then the studies of yield criteria commonly used are conducted systematically from the points of stress,strain and energy of geomaterials. The results show that no matter which expression form of stress,strain or energy is used for the yield criterion,the essence is the same and the triple shear energy yield criterion is the unified criterion of materials. Finally,the experimental verification is conducted in connection with the practical application of the triple shear energy yield criterion in an engineering project,and the calculation result shows that the Mohr-Coulomb criterion which only takes the single shear surface into account is more conservative than the energy criterion that does consider the effect of triple shear surfaces.