Falling Free is a novel written by Chinese American writer Diana Chang who described a woman's choosing of her identity in the very work which is typical of Chinese American
The development of efficient nonprecious bifunctional electrocatalysts for water electrolysis is crucial to enhance the sluggish kinetics of the oxygen evolution reaction(OER)and hydrogen evolution reaction(HER).A sel...The development of efficient nonprecious bifunctional electrocatalysts for water electrolysis is crucial to enhance the sluggish kinetics of the oxygen evolution reaction(OER)and hydrogen evolution reaction(HER).A self-supporting,multiscale porous NiFeZn/NiZn-Ni catalyst with a triple interface heterojunction on nickel foam(NF)(NiFeZn/NiZn-Ni/NF)was in-situ fabricated using an electroplating-annealing-etching strategy.The unique multiinterface engineering and three-dimensional porous scaffold significantly modify the mass transport and electron interaction,resulting in superior bifunctional electrocatalytic performance for water splitting.The NiFeZn/NiZn-Ni/NF catalyst demonstrates low overpotentials of 187 m V for HER and 320 mV for OER at a current density of 600 mA/cm^(2),along with high durability over 150 h in alkaline solution.Furthermore,an electrolytic cell assembled with NiFeZn/NiZn-Ni/NF as both the cathode and anode achieves the current densities of 600 and 1000 m A/cm^(2) at cell voltages of 1.796 and 1.901 V,respectively,maintaining the high stability at 50 mA/cm^(2) for over 100 h.These findings highlight the potential of NiFeZn/NiZn-Ni/NF as a cost-effective and highly efficient bifunctional electrocatalyst for overall water splitting.展开更多
The function mechanism of Sb(V) in As, Sb and Bi impurities removal from copper electrolyte was investigated by adding Sb(V) ion in a synthetic copper electrolyte containing 45 g/L Cu2+, 185 g/L H2SO4, 10 g/L As ...The function mechanism of Sb(V) in As, Sb and Bi impurities removal from copper electrolyte was investigated by adding Sb(V) ion in a synthetic copper electrolyte containing 45 g/L Cu2+, 185 g/L H2SO4, 10 g/L As and 0.5 g/L Bi. The electrolyte was filtered, and the precipitate structure, morphology and composition were characterized by chemical analysis, SEM, TEM, EDS, XRD and FTIR. The results show that the precipitate is in the shape of many irregular lumps with size of 50-200 μm, and it mainly consists of As, Sb, Bi and O elements. The main characteristic bands in the FTIR spectra of the precipitate are As-O-As, As-O-Sb, Sb-O-Bi, Sb-O-Sb and Bi-O-Bi. The precipitate is the mixture of microcrystalline of AsSbO4, BiSbO4 and Bi3SbO7 by XRD and electronic diffraction. The removal of As, Sb and Bi impurities by Sb(V) ion can be mainly ascribed to the formation of antimonate in copper electrolytes.展开更多
To lower the cost of bauxite electrolysis desulfurization using NaOH solution as the supporting electrolyte, effects of electrolyte recycling on bauxite electrolysis desulfurization were investigated. The results in...To lower the cost of bauxite electrolysis desulfurization using NaOH solution as the supporting electrolyte, effects of electrolyte recycling on bauxite electrolysis desulfurization were investigated. The results indicate that electrode corrosion, cell voltage, the desulfurization rate and the pH value of the electrolyte have no obvious changes with the increase of cycle times. Additionally, there were some transitive valence S-containing ions in electrolyte after the electrolysis, such as SO3^2-,S2O3^2- . However, most of the sulfur in bauxite was eventually oxidized into SO4^2- into the electrolyte, and these S-containing ions did not affect the recycling utilization for electrolyte.展开更多
Floating production storage and offioading (FPSO) vessels offer a cost-effective field development solution, especially in deepwater areas lacking an adequate pipeline network. Most FPSOs are permanently moored, i.e...Floating production storage and offioading (FPSO) vessels offer a cost-effective field development solution, especially in deepwater areas lacking an adequate pipeline network. Most FPSOs are permanently moored, i.e. the complete system is designed to withstand any kind of extreme environment at the field location. FPSOs that can be quickly disconnected from their moorings and risers have also been designed and deployed. The key feature of this type of disconnectable FPSO is that it can be disconnect and so avoid dangerous environmental conditions such as icebergs, hurricanes in the Gulf of Mexico and typhoons in the South China Sea. In this paper, the concept of disconnectable FPSOs for deepwater field development is presented. Key technologies and their engineering analyses are highlighted. The merits and demerits of disconnectable vs permanent FPSOs are then evaluated. The paper concludes that both permanent and disconnectable FPSOs are versatile floating systems and their selection depends on safety, technological, cost and operational considerations.展开更多
Based on ADS-B surveillance data,this paper proposes a multi-unmanned aerial vehicle(multi-UAV)collision detection method based on linear extrapolation for ground-based UAV collision detection and resolution,thus to p...Based on ADS-B surveillance data,this paper proposes a multi-unmanned aerial vehicle(multi-UAV)collision detection method based on linear extrapolation for ground-based UAV collision detection and resolution,thus to provide early warning of possible conflicts.To address the problem of multi-UAV conflict,the basic ant colony algorithm is introduced.The conflict simplification model of the traditional basic ant colony algorithm is optimized by adding a speed regulation strategy.A multi-UAV conflict resolution scheme is presented based on speed regulation and heading strategies.The ant colony algorithm is improved by adding angle information and a queuing system.The results show that the improved ant colony algorithm can provide multi-UAV joint escape routes for a multi-UAV conflict situation in airspace.Unlike the traditional ant colony algorithm,our approach converges to the optimization target.The time required for the calculation is reduced by 43.9%,and the total delay distance caused by conflict resolution is reduced by 58.4%.展开更多
Titanium germanium intermetallics (TixGey)were directly prepared from titanium oxide (TiO2) and germanium oxide(GeO2) powders mixture by using an electrodeoxidation process. The electrochemical experiment was ca...Titanium germanium intermetallics (TixGey)were directly prepared from titanium oxide (TiO2) and germanium oxide(GeO2) powders mixture by using an electrodeoxidation process. The electrochemical experiment was carried out in a molten fluxCaCl2-NaCl at 800℃ with a potential of 3.0 V. The results show that monolithic germanide Ti5Ge3 intermetallic can be directlyproduced from TiO2-GeO2 or CaTiO3-GeO2 precursors (both molar ratios are 5:3), and the obtained Ti5Ge3 powders exhibithomogenous particle structure. In addition, the phase composition of the final product can be dramatically affected by the initialmolar ratio of TiO2 to GeO2. The reaction mechanism of the electrodeoxidation process was discussed based on the experimentalresults. It is suggested that the electrodeoxidation process is an environmentally friendly method for the preparation of Ti-Geintermetallics.展开更多
This article presents the successful experience in adopting the Isodewaxing technology in the lube oil unit of Shanghai Gaoqiao refinery. In line with the demand of different crude slate for different reaction depth, ...This article presents the successful experience in adopting the Isodewaxing technology in the lube oil unit of Shanghai Gaoqiao refinery. In line with the demand of different crude slate for different reaction depth, and good match between the optimal product quality and the yield, the refinery has make strenuous efforts to optimize the operation and reduce the energy consumption to manufacture high-quality hydrogenated base stocks.展开更多
Several methods ofdehalogenation by pyrolysis were summarized in this paper. Some crucial academic problems have been brought forward after analyzing and comparing the technical character as well as dehalogenation eff...Several methods ofdehalogenation by pyrolysis were summarized in this paper. Some crucial academic problems have been brought forward after analyzing and comparing the technical character as well as dehalogenation efficiency of these methods, which should be emphasized in the future research.展开更多
A one-step molten salt electrochemical strategy was proposed to synthesize SiC nanoparticles from ultra-fine silicon dioxide/carbon(SiO_(2)/C)mixtures.The electrosynthesis process and physicochemical properties of the...A one-step molten salt electrochemical strategy was proposed to synthesize SiC nanoparticles from ultra-fine silicon dioxide/carbon(SiO_(2)/C)mixtures.The electrosynthesis process and physicochemical properties of the synthesized products were systematically analyzed via X-ray diffraction,electron microscopy,Raman spectroscopy and photoluminescence spectroscopy,etc.A combined chemical/electrochemical reaction,electrochemical deoxidation,and in-situ carbonization reaction mechanism was proposed to reveal the electrochemical synthesis process of SiC nanoparticles from SiO_(2)/C in molten CaCl_(2).The as-prepared SiC with particle size ranging from 8 to 14 nm possesses a polycrystalline structure.In addition,the SiC nanoparticles demonstrate obvious photoluminescence property due to the synergetic size effect and microstructural characteristics.展开更多
In the present work, we reported a novel route for the conversion of lignocellulosic biomass (sawdust) to a high-value chemical of benzoic acid under atmospheric pressure. The trans- formation involved the catalytic...In the present work, we reported a novel route for the conversion of lignocellulosic biomass (sawdust) to a high-value chemical of benzoic acid under atmospheric pressure. The trans- formation involved the catalytic pyrolysis of sawdust into aromatics, the decomposition of heavier alkylaromatics to toluene, and the liquid-phase oxidation of toluene-rich aromatics to benzoic acid. The production of the desired benzoic acid from the sawdust-derived aro- matics, with the benzoic acid selectivity of 85.1 C-mol% and nearly complete conversion of toluene, was achieved using the MnO2/NHPI catalyst at 100 ℃ for 5 h. The in uence of adding methanol on the catalytic conversion of sawdust to the core intermediate of toluene was also investigated in detail.展开更多
Ultrasound-assisted solvent extraction was confirmed as a novel,effective method for separating lipid from mackerel pro-tein,resulting in a degreasing rate (DR) of 95% and a nitrogen recovery (NR) of 88.6%.To obtain p...Ultrasound-assisted solvent extraction was confirmed as a novel,effective method for separating lipid from mackerel pro-tein,resulting in a degreasing rate (DR) of 95% and a nitrogen recovery (NR) of 88.6%.To obtain protein hydrolysates with high ni-trogen recovery and low bitter taste,enzymatic hydrolysis was performed using eight commercially available proteases.It turned out that the optimum enzyme was the ‘Mixed enzymes for animal proteolysis’.An enzyme dosage of 4%,a temperature of 50℃,and a hydrolysis time of 300 min were found to be the optimum conditions to obtain high NR (84.28%) and degree of hydrolysis (DH,16.18%) by orthogonal experiments.Glutamic acid was the most abundant amino acid of MDP (defatted mackerel protein) and MDPH (defatted mackerel protein hydrolysates).Compared with the FAO/WHO reference protein,the essential amino acid chemical scores (CS) were greater than 1.0 (1.0 1.7) in MDPH,which is reflective of high nutritional value.This,coupled with the light color and slight fishy odor,indicates that MDPH would potentially have a wide range of applications such as nutritional additives,functional ingredients,and so on.展开更多
The adsorption and desorption of algae Cladophora fascicularis and their relation with initial Cd2+ concentration, initial pH, and co-existing ions were studied. Adsorption equilibrium and biosorption kinetics were es...The adsorption and desorption of algae Cladophora fascicularis and their relation with initial Cd2+ concentration, initial pH, and co-existing ions were studied. Adsorption equilibrium and biosorption kinetics were established from batch experiments. The adsorption equilibrium was adequately described by the Langmuir isotherm, and biosorption kinetics was in pseudo-second order model. The experiment on co-existing ions showed that the biosorption capacity of biomass decreased with an increasing concentration of competing ions. Desorption experiments indicated that EDTA was efficient desorbent for recovery from Cd2+. With high capacities of metal biosorption and desorption, the biomass of Cladophora fascicularis is promising as a cost-effective biosorbent for the removal of Cd2+ from wastewater.展开更多
The influence of crown ether on behaviors of arsenic at different temperatures and residence time was investigated during the pyrolysis of Tuanbo (TB) coal. The modes of occurrence of arsenic were determined by sequ...The influence of crown ether on behaviors of arsenic at different temperatures and residence time was investigated during the pyrolysis of Tuanbo (TB) coal. The modes of occurrence of arsenic were determined by sequential chemical extraction, density fractionation and demineralization. The results indicated that at the same temperature and residence time, the arsenic removal adding dibenzo-18-crown-6 was higher than that adding 18-crown-6, and were all higher than that of TB coal during pyrolysis. When temperature was 850 ℃ and residence time was 30 min, the arsenic removal of TB coal was 30.63%; at the same condition, the arsenic removal while adding 18-crown-6 was 33.21%, higher than that of TB coal; and the arsenic removal while adding dibenzo-18-crown-6 was 67.41%, significantly higher than that of TB coal. From the results, we can see that adding crown ether can improve the arsenic removal during coal pyrolysis, and especially be conducive to the arsenic which is mainly associated with sulfates & monosulfides and that in stable forms.展开更多
Efficient destruction of cyanide by thermal decomposition with ferric oxide addition was proposed. The mechanism of destruction of sodium cyanide with or without ferric oxide addition under various conditions was exam...Efficient destruction of cyanide by thermal decomposition with ferric oxide addition was proposed. The mechanism of destruction of sodium cyanide with or without ferric oxide addition under various conditions was examined by XRD, DSC-TG, and chemical analysis technologies. In the absence of ferric oxide, sodium cyanide decomposes at 587.4 ℃ in air and 879.2 ℃ in argon atmosphere. In the presence of ferric oxide, about 60% of sodium cyanide decomposes at 350 ℃ for 30 min in argon, while almost all sodium cyanide decomposes within 30 min in air or O2 with mass ratio of ferric oxide to sodium cyanide of 1:1. The increase of ferric oxide addition, temperature, and heating time facilitates the destruction of sodium cyanide. It is believed that with ferric oxide addition, NaCN reacts with Fe2O3 to form Na4Fe(CN)6, Na2CO3, NaNO2 and Fe3O4 in argon. NaCN decomposes into NaCNO, Na4Fe(CN)6, minor NaNO2, and the formed NaCNO and Na4Fe(CN)6 further decompose into Na2CO3, CO2, N2, FeOx, and minor NOx in air or O2.展开更多
文摘Falling Free is a novel written by Chinese American writer Diana Chang who described a woman's choosing of her identity in the very work which is typical of Chinese American
基金financially supported from the National Natural Science Foundation of China(No.52201254)the Natural Science Foundation of Shandong Province,China(Nos.ZR2023ME155,ZR2020MB090,ZR2020QE012,ZR2020MB027)+1 种基金the Project of“20 Items of University”of Jinan,China(No.202228046)the Taishan Scholar Project of Shandong Province,China(No.tsqn202306226)。
文摘The development of efficient nonprecious bifunctional electrocatalysts for water electrolysis is crucial to enhance the sluggish kinetics of the oxygen evolution reaction(OER)and hydrogen evolution reaction(HER).A self-supporting,multiscale porous NiFeZn/NiZn-Ni catalyst with a triple interface heterojunction on nickel foam(NF)(NiFeZn/NiZn-Ni/NF)was in-situ fabricated using an electroplating-annealing-etching strategy.The unique multiinterface engineering and three-dimensional porous scaffold significantly modify the mass transport and electron interaction,resulting in superior bifunctional electrocatalytic performance for water splitting.The NiFeZn/NiZn-Ni/NF catalyst demonstrates low overpotentials of 187 m V for HER and 320 mV for OER at a current density of 600 mA/cm^(2),along with high durability over 150 h in alkaline solution.Furthermore,an electrolytic cell assembled with NiFeZn/NiZn-Ni/NF as both the cathode and anode achieves the current densities of 600 and 1000 m A/cm^(2) at cell voltages of 1.796 and 1.901 V,respectively,maintaining the high stability at 50 mA/cm^(2) for over 100 h.These findings highlight the potential of NiFeZn/NiZn-Ni/NF as a cost-effective and highly efficient bifunctional electrocatalyst for overall water splitting.
基金Project(50904023)supported by the National Natural Science Foundation of ChinaProject(2010B450001)supported by the Natural Science Fund of Department of Education of Henan Province,ChinaProject(092300410064)supported by the Basic and Frontier Technologies Research Projects of Henan Province,China
文摘The function mechanism of Sb(V) in As, Sb and Bi impurities removal from copper electrolyte was investigated by adding Sb(V) ion in a synthetic copper electrolyte containing 45 g/L Cu2+, 185 g/L H2SO4, 10 g/L As and 0.5 g/L Bi. The electrolyte was filtered, and the precipitate structure, morphology and composition were characterized by chemical analysis, SEM, TEM, EDS, XRD and FTIR. The results show that the precipitate is in the shape of many irregular lumps with size of 50-200 μm, and it mainly consists of As, Sb, Bi and O elements. The main characteristic bands in the FTIR spectra of the precipitate are As-O-As, As-O-Sb, Sb-O-Bi, Sb-O-Sb and Bi-O-Bi. The precipitate is the mixture of microcrystalline of AsSbO4, BiSbO4 and Bi3SbO7 by XRD and electronic diffraction. The removal of As, Sb and Bi impurities by Sb(V) ion can be mainly ascribed to the formation of antimonate in copper electrolytes.
基金Projects(51004090,51474198)supported by the National Natural Science Foundation of ChinaProject(KF13-03)supported by State Key Laboratory of Advanced Metallurgy University of Science and Technology BeijingProject(2015036)supported by Youth Innovation Promotion Association,Chinese Academy of Sciences
文摘To lower the cost of bauxite electrolysis desulfurization using NaOH solution as the supporting electrolyte, effects of electrolyte recycling on bauxite electrolysis desulfurization were investigated. The results indicate that electrode corrosion, cell voltage, the desulfurization rate and the pH value of the electrolyte have no obvious changes with the increase of cycle times. Additionally, there were some transitive valence S-containing ions in electrolyte after the electrolysis, such as SO3^2-,S2O3^2- . However, most of the sulfur in bauxite was eventually oxidized into SO4^2- into the electrolyte, and these S-containing ions did not affect the recycling utilization for electrolyte.
基金Supported by China National 111 Project Under Grant No.B07019
文摘Floating production storage and offioading (FPSO) vessels offer a cost-effective field development solution, especially in deepwater areas lacking an adequate pipeline network. Most FPSOs are permanently moored, i.e. the complete system is designed to withstand any kind of extreme environment at the field location. FPSOs that can be quickly disconnected from their moorings and risers have also been designed and deployed. The key feature of this type of disconnectable FPSO is that it can be disconnect and so avoid dangerous environmental conditions such as icebergs, hurricanes in the Gulf of Mexico and typhoons in the South China Sea. In this paper, the concept of disconnectable FPSOs for deepwater field development is presented. Key technologies and their engineering analyses are highlighted. The merits and demerits of disconnectable vs permanent FPSOs are then evaluated. The paper concludes that both permanent and disconnectable FPSOs are versatile floating systems and their selection depends on safety, technological, cost and operational considerations.
基金supported by the National Natural Science Foundation of China (No. 61773202)the National Key Laboratory of Air Traffic Control (No.SKLATM201706)the Sichuan Science and Technology Plan Project(No. 2018JZ0030).
文摘Based on ADS-B surveillance data,this paper proposes a multi-unmanned aerial vehicle(multi-UAV)collision detection method based on linear extrapolation for ground-based UAV collision detection and resolution,thus to provide early warning of possible conflicts.To address the problem of multi-UAV conflict,the basic ant colony algorithm is introduced.The conflict simplification model of the traditional basic ant colony algorithm is optimized by adding a speed regulation strategy.A multi-UAV conflict resolution scheme is presented based on speed regulation and heading strategies.The ant colony algorithm is improved by adding angle information and a queuing system.The results show that the improved ant colony algorithm can provide multi-UAV joint escape routes for a multi-UAV conflict situation in airspace.Unlike the traditional ant colony algorithm,our approach converges to the optimization target.The time required for the calculation is reduced by 43.9%,and the total delay distance caused by conflict resolution is reduced by 58.4%.
基金Project(51574164)supported by the National Natural Science Foundation of ChinaProject(2014CB643403)supported by the National Basic Research Program of China
文摘Titanium germanium intermetallics (TixGey)were directly prepared from titanium oxide (TiO2) and germanium oxide(GeO2) powders mixture by using an electrodeoxidation process. The electrochemical experiment was carried out in a molten fluxCaCl2-NaCl at 800℃ with a potential of 3.0 V. The results show that monolithic germanide Ti5Ge3 intermetallic can be directlyproduced from TiO2-GeO2 or CaTiO3-GeO2 precursors (both molar ratios are 5:3), and the obtained Ti5Ge3 powders exhibithomogenous particle structure. In addition, the phase composition of the final product can be dramatically affected by the initialmolar ratio of TiO2 to GeO2. The reaction mechanism of the electrodeoxidation process was discussed based on the experimentalresults. It is suggested that the electrodeoxidation process is an environmentally friendly method for the preparation of Ti-Geintermetallics.
文摘This article presents the successful experience in adopting the Isodewaxing technology in the lube oil unit of Shanghai Gaoqiao refinery. In line with the demand of different crude slate for different reaction depth, and good match between the optimal product quality and the yield, the refinery has make strenuous efforts to optimize the operation and reduce the energy consumption to manufacture high-quality hydrogenated base stocks.
文摘Several methods ofdehalogenation by pyrolysis were summarized in this paper. Some crucial academic problems have been brought forward after analyzing and comparing the technical character as well as dehalogenation efficiency of these methods, which should be emphasized in the future research.
基金the National Natural Science Foundation of China(Nos.52022054,51974181,52004157)the Shanghai Rising-Star Program,China(No.19QA1403600)+4 种基金the Shanghai Sailing Program,China(No.21YF1412900)and the Iron and Steel Joint Research Fund of National Natural Science Foundation of China and China Baowu Steel Group Corporation Limited(No.U1860203)the Program for Professor of Special Appointment(Eastern Scholar)at Shanghai Institutions of Higher Learning,China(No.TP2019041)the Shanghai Postdoctoral Excellence Program,China(No.2021160)the“Shuguang Program”supported by the Shanghai Education Development Foundation and the Shanghai Municipal Education Commission,China(No.21SG42).
文摘A one-step molten salt electrochemical strategy was proposed to synthesize SiC nanoparticles from ultra-fine silicon dioxide/carbon(SiO_(2)/C)mixtures.The electrosynthesis process and physicochemical properties of the synthesized products were systematically analyzed via X-ray diffraction,electron microscopy,Raman spectroscopy and photoluminescence spectroscopy,etc.A combined chemical/electrochemical reaction,electrochemical deoxidation,and in-situ carbonization reaction mechanism was proposed to reveal the electrochemical synthesis process of SiC nanoparticles from SiO_(2)/C in molten CaCl_(2).The as-prepared SiC with particle size ranging from 8 to 14 nm possesses a polycrystalline structure.In addition,the SiC nanoparticles demonstrate obvious photoluminescence property due to the synergetic size effect and microstructural characteristics.
文摘In the present work, we reported a novel route for the conversion of lignocellulosic biomass (sawdust) to a high-value chemical of benzoic acid under atmospheric pressure. The trans- formation involved the catalytic pyrolysis of sawdust into aromatics, the decomposition of heavier alkylaromatics to toluene, and the liquid-phase oxidation of toluene-rich aromatics to benzoic acid. The production of the desired benzoic acid from the sawdust-derived aro- matics, with the benzoic acid selectivity of 85.1 C-mol% and nearly complete conversion of toluene, was achieved using the MnO2/NHPI catalyst at 100 ℃ for 5 h. The in uence of adding methanol on the catalytic conversion of sawdust to the core intermediate of toluene was also investigated in detail.
基金supported by the National Natural Science Foundation of China (No.30871943)the National Natural Science Foundation of China (No.3080 0858)
文摘Ultrasound-assisted solvent extraction was confirmed as a novel,effective method for separating lipid from mackerel pro-tein,resulting in a degreasing rate (DR) of 95% and a nitrogen recovery (NR) of 88.6%.To obtain protein hydrolysates with high ni-trogen recovery and low bitter taste,enzymatic hydrolysis was performed using eight commercially available proteases.It turned out that the optimum enzyme was the ‘Mixed enzymes for animal proteolysis’.An enzyme dosage of 4%,a temperature of 50℃,and a hydrolysis time of 300 min were found to be the optimum conditions to obtain high NR (84.28%) and degree of hydrolysis (DH,16.18%) by orthogonal experiments.Glutamic acid was the most abundant amino acid of MDP (defatted mackerel protein) and MDPH (defatted mackerel protein hydrolysates).Compared with the FAO/WHO reference protein,the essential amino acid chemical scores (CS) were greater than 1.0 (1.0 1.7) in MDPH,which is reflective of high nutritional value.This,coupled with the light color and slight fishy odor,indicates that MDPH would potentially have a wide range of applications such as nutritional additives,functional ingredients,and so on.
基金Supported by 863 Program (No.2006AA06Z362)NSFC (No. 30530080)National Science & Technology Pillar Program (No. 2006BAB03A12)
文摘The adsorption and desorption of algae Cladophora fascicularis and their relation with initial Cd2+ concentration, initial pH, and co-existing ions were studied. Adsorption equilibrium and biosorption kinetics were established from batch experiments. The adsorption equilibrium was adequately described by the Langmuir isotherm, and biosorption kinetics was in pseudo-second order model. The experiment on co-existing ions showed that the biosorption capacity of biomass decreased with an increasing concentration of competing ions. Desorption experiments indicated that EDTA was efficient desorbent for recovery from Cd2+. With high capacities of metal biosorption and desorption, the biomass of Cladophora fascicularis is promising as a cost-effective biosorbent for the removal of Cd2+ from wastewater.
基金Supported by the Research Fund for the Doctoral Program of Higher Education of China for New Teachers (20091404120002) the Shanxi Provincial Science Foundation for Youths of China (2011021008-1)
文摘The influence of crown ether on behaviors of arsenic at different temperatures and residence time was investigated during the pyrolysis of Tuanbo (TB) coal. The modes of occurrence of arsenic were determined by sequential chemical extraction, density fractionation and demineralization. The results indicated that at the same temperature and residence time, the arsenic removal adding dibenzo-18-crown-6 was higher than that adding 18-crown-6, and were all higher than that of TB coal during pyrolysis. When temperature was 850 ℃ and residence time was 30 min, the arsenic removal of TB coal was 30.63%; at the same condition, the arsenic removal while adding 18-crown-6 was 33.21%, higher than that of TB coal; and the arsenic removal while adding dibenzo-18-crown-6 was 67.41%, significantly higher than that of TB coal. From the results, we can see that adding crown ether can improve the arsenic removal during coal pyrolysis, and especially be conducive to the arsenic which is mainly associated with sulfates & monosulfides and that in stable forms.
基金financial supports from the National Key R&D Program of China (2018YFC0604604)the National Natural Science Foundation of China-Yunnan Joint Fund (U1702252)+1 种基金the Fundamental Research Funds for Central Universities of China (N182506003)the Key Scientific Research Project of Liaoning Province,China (2019JH2/10300051)。
文摘Efficient destruction of cyanide by thermal decomposition with ferric oxide addition was proposed. The mechanism of destruction of sodium cyanide with or without ferric oxide addition under various conditions was examined by XRD, DSC-TG, and chemical analysis technologies. In the absence of ferric oxide, sodium cyanide decomposes at 587.4 ℃ in air and 879.2 ℃ in argon atmosphere. In the presence of ferric oxide, about 60% of sodium cyanide decomposes at 350 ℃ for 30 min in argon, while almost all sodium cyanide decomposes within 30 min in air or O2 with mass ratio of ferric oxide to sodium cyanide of 1:1. The increase of ferric oxide addition, temperature, and heating time facilitates the destruction of sodium cyanide. It is believed that with ferric oxide addition, NaCN reacts with Fe2O3 to form Na4Fe(CN)6, Na2CO3, NaNO2 and Fe3O4 in argon. NaCN decomposes into NaCNO, Na4Fe(CN)6, minor NaNO2, and the formed NaCNO and Na4Fe(CN)6 further decompose into Na2CO3, CO2, N2, FeOx, and minor NOx in air or O2.