The differences of grain-refining effect between Sc and Ti additions in aluminum,which cannot be substantially explained by traditional theories,were carefully studied.The empirical electron theory(EET) of solids and ...The differences of grain-refining effect between Sc and Ti additions in aluminum,which cannot be substantially explained by traditional theories,were carefully studied.The empirical electron theory(EET) of solids and molecules was employed to calculate the valence electron structures(VES) of Al3Ti and Al3Sc.The conclusions can be drawn that,in the two alloys Al-Ti and Al-Sc,the different valence electron structures of Al3Ti and Al3Sc and the consequent differences of growth habit of the two particles,and the different interfacial electron density between particles and matrix fundamentally lead to the differences of grain-refining effect between Sc and Ti additions on aluminum and make Sr the better grain-refiner of aluminum.展开更多
The degradation process of organosol coated tinplate in beverage was investigated by electrochemical noise (EN) technique combined with morphology characterization.EN data were analyzed using phase space reconstructio...The degradation process of organosol coated tinplate in beverage was investigated by electrochemical noise (EN) technique combined with morphology characterization.EN data were analyzed using phase space reconstruction theory.With the correlation dimensions obtained from the phase space reconstruction,the chaotic behavior of EN was quantitatively evaluated.The results show that both electrochemical potential noise (EPN) and electrochemical current noise (ECN) have chaotic properties.The correlation dimensions of EPN increase with corrosion extent,while those of ECN seem nearly unchanged.The increased correlation dimensions of EPN during the degradation process are associated with the increased susceptibility to local corrosion.展开更多
Based on the decomposition theory of the U(1) gauge potential, the inner structure of the statistical gauge potential in the Chern-Simons-Ginzburg-Landau (CSGL) theory is studied. We give a new creation mechanism ...Based on the decomposition theory of the U(1) gauge potential, the inner structure of the statistical gauge potential in the Chern-Simons-Ginzburg-Landau (CSGL) theory is studied. We give a new creation mechanism of the statistical gauge potential, Furthermore, making use of the b-mapping topological current theory, we obtain the precise topological expression of the statistical magnetic field, which takes the topological information of the vortices.展开更多
This paperprovides a historical overview intending to clarify the methods of interpretation of timber-framed buildings by different authors of construction treatises, and structural intentions of the carpentry designe...This paperprovides a historical overview intending to clarify the methods of interpretation of timber-framed buildings by different authors of construction treatises, and structural intentions of the carpentry designers and master builders, throughout the centuries, until the period when it became scientific structural theory. It describes the "box-frame" construction that appeared in Lisbon, after the earthquake of 1755, characterized by its good seismic resistance. This knowledge is important to determine a strategy of an efficient restoration practice in historical constructions which require an intervention subordinated to its raised patrimonial and artistic value, minimum, which respects the authenticity of its structural and construction conception and which is reversible and compatible, in physical, chemical, mechanic and aesthetic terms. Empirical understanding of the most important properties of wood to structure purposes, the defects of structural timbers, the framing and the preliminary survey followed by the structural survey were some of the difficulties which can be overcame in practice.展开更多
Density functional theory calculations were carried out to study the thermal cracking for chrysene molecule to estimate the bond energies for breaking C 10b-C 11, C 11-H 11 and C4a-C 12a bonds as well as the activatio...Density functional theory calculations were carried out to study the thermal cracking for chrysene molecule to estimate the bond energies for breaking C 10b-C 11, C 11-H 11 and C4a-C 12a bonds as well as the activation energies. It was found that for C 10b-C 11 C11-HI 1 and C4a-C12a reactions, it is often possible to identify one pathway for bond breakage through the singlet or triplet states. Thus, the C 11-H11 and C11-C10b bonds ruptured in triplet state whilst the C12a-C4a in singlet state. Also, it was fond that the activation energy value for C4a-C12a bond breakage is lower than required for C10b-C11 and C11-H11 bonds that enquired the C4a-C12a bond "bridge bond" is a weaker and ruptured firstly in thermal cracking process. It seems that the characteristic planarity for polyaromatic hydrocarbons is an important factor to acquire the molecule structure the required stability along the reaction paths as well as the full octet rule and Clar's n-sextet structure, especially when chrysene molecular lose the property of planarity. The atomic charges supported the observation that the breaking bonds C10b-C11, CI1-H11 and C4a-C12a in triplet or singlet states. The configurations in transition state and the conformation for the end products reaction were explained and discussed.展开更多
The debate on the state of the art of philosophy in Italy shows many differences from the three main currents of contemporary philosophy, namely deconstructionism, critical theory, and analytic philosophy. On one hand...The debate on the state of the art of philosophy in Italy shows many differences from the three main currents of contemporary philosophy, namely deconstructionism, critical theory, and analytic philosophy. On one hand, the philosophical stance towards language, and on the other hand, the strong separation between science and philosophy are the distinctive features of the Italian thought. In particular, philosophy of language shows a fragmented framework in which current researches are an example for future studies on language and human nature. The basic idea behind the Philosophy of Language in Italy is that language has a biological and social nature. The aim of this paper is to give an account of the range of "bio" through a dialogue between philosophy and neuroscience. I will review the Italian research on mirror neurons with particular attention to the developments in embodied simulation proposed by Vittorio Gallese. I will underline the philosophical aspects of this neuroscientific theory, providing some remarks on intersubjectivity, intentions, and language. Finally, I will suggest future joint studies in neuroscience and the philosophy of language.展开更多
In this paper, using the kernel weight function, we obtain the parameter estimation of p-norm distribution in semi-parametric regression model, which is effective to decide the distribution of random errors. Under the...In this paper, using the kernel weight function, we obtain the parameter estimation of p-norm distribution in semi-parametric regression model, which is effective to decide the distribution of random errors. Under the assumption that the distribution of observations is unimodal and symmetry, this method can give the estimates of the parametric. Finally, two simulated adjustment problem are constructed to explain this method. The new method presented in this paper shows an effective way of solving the problem; the estimated values are nearer to their theoretical ones than those by least squares adjustment approach.展开更多
This paper critically reviews Hossein Nassaji's Language Learning article, which systematically overviews the recent language processing theories, it is especially pertinent to schema theory as well as Walter Kint...This paper critically reviews Hossein Nassaji's Language Learning article, which systematically overviews the recent language processing theories, it is especially pertinent to schema theory as well as Walter Kintsch's construction-integration (CI) theory in reading comprehension. The article thoroughly investigates the unified theory (as Kintsch defines), construction-integration theory in text comprehension, which is mainly based upon the comparison with and analysis of the applications of schema theory from the perspective of language reading comprehension. The author tries to work out and illustrate this model as an alternative approach to the schema-oriented models previously used to solve reading comprehension problems in language teaching and leaning.展开更多
Weak intermolecular interactions in aniline-pyrrole dimer clusters have been studied by the dispersion-corrected density functional theory(DFT) calculations. Two distinct types of hydrogen bonds are demonstrated with ...Weak intermolecular interactions in aniline-pyrrole dimer clusters have been studied by the dispersion-corrected density functional theory(DFT) calculations. Two distinct types of hydrogen bonds are demonstrated with optimized geometric structures and largest interaction energy moduli. Comprehensive spectroscopic analysis is also addressed revealing the orientation-dependent interactions by noting the altered red-shifts of the infrared and Raman activities. Then we employ natural bond orbital(NBO)analysis and atom in molecules(AIM) theory to have determined the origin and relative energetic contributions of the weak interactions in these systems. NBO and AIM calculations confirm the V-shaped dimer cluster is dominated by N.H···N and C.H···π hydrogen bonds, while the J-aggregated isomer is stabilized by N.H···π, n→π* and weak π···π* stacking interactions.The noncovalent interactions are also demonstrated via energy decomposition analysis associated with electrostatic and dispersion contributions.展开更多
基金Project(20050003042) supported by Research Fund for the Doctoral Program of Higher Education of China
文摘The differences of grain-refining effect between Sc and Ti additions in aluminum,which cannot be substantially explained by traditional theories,were carefully studied.The empirical electron theory(EET) of solids and molecules was employed to calculate the valence electron structures(VES) of Al3Ti and Al3Sc.The conclusions can be drawn that,in the two alloys Al-Ti and Al-Sc,the different valence electron structures of Al3Ti and Al3Sc and the consequent differences of growth habit of the two particles,and the different interfacial electron density between particles and matrix fundamentally lead to the differences of grain-refining effect between Sc and Ti additions on aluminum and make Sr the better grain-refiner of aluminum.
基金Supported by Major State Basic Research Program of China ("973" Program,No. 2011CB610505)Specialized Research Fund for the Doctoral Program of Higher Education (No. 20120032110029)
文摘The degradation process of organosol coated tinplate in beverage was investigated by electrochemical noise (EN) technique combined with morphology characterization.EN data were analyzed using phase space reconstruction theory.With the correlation dimensions obtained from the phase space reconstruction,the chaotic behavior of EN was quantitatively evaluated.The results show that both electrochemical potential noise (EPN) and electrochemical current noise (ECN) have chaotic properties.The correlation dimensions of EPN increase with corrosion extent,while those of ECN seem nearly unchanged.The increased correlation dimensions of EPN during the degradation process are associated with the increased susceptibility to local corrosion.
文摘Based on the decomposition theory of the U(1) gauge potential, the inner structure of the statistical gauge potential in the Chern-Simons-Ginzburg-Landau (CSGL) theory is studied. We give a new creation mechanism of the statistical gauge potential, Furthermore, making use of the b-mapping topological current theory, we obtain the precise topological expression of the statistical magnetic field, which takes the topological information of the vortices.
文摘This paperprovides a historical overview intending to clarify the methods of interpretation of timber-framed buildings by different authors of construction treatises, and structural intentions of the carpentry designers and master builders, throughout the centuries, until the period when it became scientific structural theory. It describes the "box-frame" construction that appeared in Lisbon, after the earthquake of 1755, characterized by its good seismic resistance. This knowledge is important to determine a strategy of an efficient restoration practice in historical constructions which require an intervention subordinated to its raised patrimonial and artistic value, minimum, which respects the authenticity of its structural and construction conception and which is reversible and compatible, in physical, chemical, mechanic and aesthetic terms. Empirical understanding of the most important properties of wood to structure purposes, the defects of structural timbers, the framing and the preliminary survey followed by the structural survey were some of the difficulties which can be overcame in practice.
文摘Density functional theory calculations were carried out to study the thermal cracking for chrysene molecule to estimate the bond energies for breaking C 10b-C 11, C 11-H 11 and C4a-C 12a bonds as well as the activation energies. It was found that for C 10b-C 11 C11-HI 1 and C4a-C12a reactions, it is often possible to identify one pathway for bond breakage through the singlet or triplet states. Thus, the C 11-H11 and C11-C10b bonds ruptured in triplet state whilst the C12a-C4a in singlet state. Also, it was fond that the activation energy value for C4a-C12a bond breakage is lower than required for C10b-C11 and C11-H11 bonds that enquired the C4a-C12a bond "bridge bond" is a weaker and ruptured firstly in thermal cracking process. It seems that the characteristic planarity for polyaromatic hydrocarbons is an important factor to acquire the molecule structure the required stability along the reaction paths as well as the full octet rule and Clar's n-sextet structure, especially when chrysene molecular lose the property of planarity. The atomic charges supported the observation that the breaking bonds C10b-C11, CI1-H11 and C4a-C12a in triplet or singlet states. The configurations in transition state and the conformation for the end products reaction were explained and discussed.
文摘The debate on the state of the art of philosophy in Italy shows many differences from the three main currents of contemporary philosophy, namely deconstructionism, critical theory, and analytic philosophy. On one hand, the philosophical stance towards language, and on the other hand, the strong separation between science and philosophy are the distinctive features of the Italian thought. In particular, philosophy of language shows a fragmented framework in which current researches are an example for future studies on language and human nature. The basic idea behind the Philosophy of Language in Italy is that language has a biological and social nature. The aim of this paper is to give an account of the range of "bio" through a dialogue between philosophy and neuroscience. I will review the Italian research on mirror neurons with particular attention to the developments in embodied simulation proposed by Vittorio Gallese. I will underline the philosophical aspects of this neuroscientific theory, providing some remarks on intersubjectivity, intentions, and language. Finally, I will suggest future joint studies in neuroscience and the philosophy of language.
文摘In this paper, using the kernel weight function, we obtain the parameter estimation of p-norm distribution in semi-parametric regression model, which is effective to decide the distribution of random errors. Under the assumption that the distribution of observations is unimodal and symmetry, this method can give the estimates of the parametric. Finally, two simulated adjustment problem are constructed to explain this method. The new method presented in this paper shows an effective way of solving the problem; the estimated values are nearer to their theoretical ones than those by least squares adjustment approach.
文摘This paper critically reviews Hossein Nassaji's Language Learning article, which systematically overviews the recent language processing theories, it is especially pertinent to schema theory as well as Walter Kintsch's construction-integration (CI) theory in reading comprehension. The article thoroughly investigates the unified theory (as Kintsch defines), construction-integration theory in text comprehension, which is mainly based upon the comparison with and analysis of the applications of schema theory from the perspective of language reading comprehension. The author tries to work out and illustrate this model as an alternative approach to the schema-oriented models previously used to solve reading comprehension problems in language teaching and leaning.
基金supported by the National Project“Development of Advanced Scientific Instruments Based on Deep Ultraviolet Laser Source”(Y31M0112C1)the National Basic Research Program of China(2011CB808402)Z.Luo acknowledges the Young Professionals Programme in Institute of Chemistry,Chinese Academy of Sciences(ICCAS-Y3297B1261)
文摘Weak intermolecular interactions in aniline-pyrrole dimer clusters have been studied by the dispersion-corrected density functional theory(DFT) calculations. Two distinct types of hydrogen bonds are demonstrated with optimized geometric structures and largest interaction energy moduli. Comprehensive spectroscopic analysis is also addressed revealing the orientation-dependent interactions by noting the altered red-shifts of the infrared and Raman activities. Then we employ natural bond orbital(NBO)analysis and atom in molecules(AIM) theory to have determined the origin and relative energetic contributions of the weak interactions in these systems. NBO and AIM calculations confirm the V-shaped dimer cluster is dominated by N.H···N and C.H···π hydrogen bonds, while the J-aggregated isomer is stabilized by N.H···π, n→π* and weak π···π* stacking interactions.The noncovalent interactions are also demonstrated via energy decomposition analysis associated with electrostatic and dispersion contributions.