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Recommendation Method for Contrastive Enhancement of Neighborhood Information
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作者 Hairong Wang Beijing Zhou +1 位作者 Lisi Zhang He Ma 《Computers, Materials & Continua》 SCIE EI 2024年第1期453-472,共20页
Knowledge graph can assist in improving recommendation performance and is widely applied in various person-alized recommendation domains.However,existing knowledge-aware recommendation methods face challenges such as ... Knowledge graph can assist in improving recommendation performance and is widely applied in various person-alized recommendation domains.However,existing knowledge-aware recommendation methods face challenges such as weak user-item interaction supervisory signals and noise in the knowledge graph.To tackle these issues,this paper proposes a neighbor information contrast-enhanced recommendation method by adding subtle noise to construct contrast views and employing contrastive learning to strengthen supervisory signals and reduce knowledge noise.Specifically,first,this paper adopts heterogeneous propagation and knowledge-aware attention networks to obtain multi-order neighbor embedding of users and items,mining the high-order neighbor informa-tion of users and items.Next,in the neighbor information,this paper introduces weak noise following a uniform distribution to construct neighbor contrast views,effectively reducing the time overhead of view construction.This paper then performs contrastive learning between neighbor views to promote the uniformity of view information,adjusting the neighbor structure,and achieving the goal of reducing the knowledge noise in the knowledge graph.Finally,this paper introduces multi-task learning to mitigate the problem of weak supervisory signals.To validate the effectiveness of our method,experiments are conducted on theMovieLens-1M,MovieLens-20M,Book-Crossing,and Last-FM datasets.The results showthat compared to the best baselines,our method shows significant improvements in AUC and F1. 展开更多
关键词 contrastive learning knowledge graph recommendation method
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A Second-Order Image Denoising Model for Contrast Preservation
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作者 Wei Zhu 《Communications on Applied Mathematics and Computation》 EI 2024年第2期1406-1427,共22页
In this work,we propose a second-order model for image denoising by employing a novel potential function recently developed in Zhu(J Sci Comput 88:46,2021)for the design of a regularization term.Due to this new second... In this work,we propose a second-order model for image denoising by employing a novel potential function recently developed in Zhu(J Sci Comput 88:46,2021)for the design of a regularization term.Due to this new second-order derivative based regularizer,the model is able to alleviate the staircase effect and preserve image contrast.The augmented Lagrangian method(ALM)is utilized to minimize the associated functional and convergence analysis is established for the proposed algorithm.Numerical experiments are presented to demonstrate the features of the proposed model. 展开更多
关键词 Image denoising Variational model Image contrast Augmented Lagrangian method(ALM)
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金属有机骨架和g-C_(3)N_(4)共掺杂改性TiO_(2)光催化性能
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作者 李宁 臧书杰 +1 位作者 蒋托红 赵鹬 《精细化工》 EI CAS CSCD 北大核心 2024年第9期1941-1948,共8页
以钛酸四丁酯、三聚氰胺、二甲基咪唑和Co(NO_(3))_(2)•6H_(2)O为原料,采用溶胶-凝胶法、高温煅烧法,将类石墨相氮化碳(g-C_(3)N_(4))和二甲基咪唑钴(ZIF-67)与TiO_(2)共掺杂,制备了TiO_(2)-g-C_(3)N_(4)-ZIF-67光催化剂。采用XRD、XPS... 以钛酸四丁酯、三聚氰胺、二甲基咪唑和Co(NO_(3))_(2)•6H_(2)O为原料,采用溶胶-凝胶法、高温煅烧法,将类石墨相氮化碳(g-C_(3)N_(4))和二甲基咪唑钴(ZIF-67)与TiO_(2)共掺杂,制备了TiO_(2)-g-C_(3)N_(4)-ZIF-67光催化剂。采用XRD、XPS、SEM和紫外-可见漫反射光谱(UV-Vis DRS)对TiO_(2)-g-C_(3)N_(4)-ZIF-67进行了表征,对TiO_(2)-g-C_(3)N_(4)-ZIF-67光催化降解甲基橙的催化活性进行了评价,并对其催化机理进行了推测。结果表明,TiO_(2)-g-C_(3)N_(4)-ZIF-67同时包含锐钛矿及少量金红石相TiO_(2)、g-C_(3)N_(4)及ZIF-67;g-C_(3)N_(4)的加入使TiO_(2)的带隙降至2.45 eV,ZIF-67将带隙进一步降至1.91 eV;g-C_(3)N_(4)和ZIF-67的共掺杂降低了带隙,显著提高了TiO_(2)可见光吸收范围(492~649 nm);TiO_(2)-g-C_(3)N_(4)-ZIF-67形成了Ⅱ型异质结,TiO_(2)-g-C_(3)N_(4)与金属有机骨架的结合增强了TiO_(2)光催化降解甲基橙的能力。Co质量分数21.5%的TiO_(2)-g-C_(3)N_(4)-ZIF-67-2具有最佳的光催化降解甲基橙活性,在可见光照射40 min时,甲基橙降解率可达79.92%,3次循环后甲基橙降解率为58.86%(90 min),光催化反应对ZIF-67的结晶度有所影响,进而影响了循环时的光催化活性。 展开更多
关键词 光催化 溶胶-凝胶法 高温煅烧法 TiO_(2) g-C_(3)N_(4) ZIF-67 功能材料
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自牺牲法合成氮空位g-C_(3)N_(4)/Cu_(2)(OH)_(2)CO_(3)异质结及其广谱光固氮性能
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作者 梁红玉 王斌 +1 位作者 陆光 商丽艳 《材料导报》 EI CAS CSCD 北大核心 2024年第16期62-67,共6页
本研究采用原位自牺牲法合成了N空位掺杂的g-C_(3)N_(4)/Cu_(2)(OH)_(2)CO_(3)(VCN/Cu)异质结催化剂,该催化剂体现出优异的可见-近红外宽光谱驱动性。实验结果表明,g-C_(3)N_(4)与Cu_(2)(OH)_(2)CO_(3)之间的电荷迁移遵循“Z”型机制。... 本研究采用原位自牺牲法合成了N空位掺杂的g-C_(3)N_(4)/Cu_(2)(OH)_(2)CO_(3)(VCN/Cu)异质结催化剂,该催化剂体现出优异的可见-近红外宽光谱驱动性。实验结果表明,g-C_(3)N_(4)与Cu_(2)(OH)_(2)CO_(3)之间的电荷迁移遵循“Z”型机制。氮空位的存在抑制了电荷载流子的重组,降低了界面电荷转移的能量屏障,对N 2和O_(2)的吸附和活化激发了固氮还原反应的进行,并提供了更多的反应活性位点。体系中甲醇作为空穴清除剂时O_(2)的添加对制备的催化剂的光固氮性能有显著的促进作用,在50%O_(2)和50%N_(2)混合气氛下VCN/Cu异质结催化剂的铵离子产率高达14.52 mg·L^(-1)·h^(-1)·g^(-1),是纯N 2气氛下的2.7倍,且按照“三线”光固氮机理运行。本研究为低耗、绿色环保固氮工艺提供了一条新途径。 展开更多
关键词 石墨相氮化碳 碱式碳酸铜 光催化固氮 氮空位 自牺牲法
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Compare and Contrast the Strengths and Weaknesses of Task-based Language Teaching Method and Audio Lingual Teaching Method and Study How They Impact Upon Both the Teachers and the Learners 被引量:1
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作者 曹怡之 《科技视界》 2013年第25期193-194,共2页
This essay focused on comparing and contrasts audio lingual method and Task-based language teaching method,demonstrating the strengths and weaknesses of the two methods and discusses how they impact upon both the teac... This essay focused on comparing and contrasts audio lingual method and Task-based language teaching method,demonstrating the strengths and weaknesses of the two methods and discusses how they impact upon both the teachers and the learners.TBLT is the contemporary teaching method with a great number of strong points.It seems that if there is more relatively scientific and effective method,TBLT should give way to it.The ultimate goal is to advocate the comparatively successful teaching method in the field of foreign language education. 展开更多
关键词 英语教学 教学方法 阅读教学 英语翻译
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模板法合成g-C_(3)N_(4)基复合材料及其光催化性能的研究进展 被引量:1
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作者 唐浩宇 刘成宝 +4 位作者 陈丰 钱君超 邱永斌 孟宪荣 陈志刚 《功能材料》 CAS CSCD 北大核心 2024年第4期4062-4071,共10页
石墨相氮化碳(g-C_(3)N_(4))作为一种新型非金属高聚物半导体,具有易于合成、无毒无害、耐酸碱腐蚀、环境亲和性好等性质。独特的层状结构赋予了其较高的比表面积,适中的禁带宽度给予了其较好的光催化性能,使得其在光催化领域受到了广... 石墨相氮化碳(g-C_(3)N_(4))作为一种新型非金属高聚物半导体,具有易于合成、无毒无害、耐酸碱腐蚀、环境亲和性好等性质。独特的层状结构赋予了其较高的比表面积,适中的禁带宽度给予了其较好的光催化性能,使得其在光催化领域受到了广泛的关注。然而,纯相g-C_(3)N_(4)存在着比表面积小、活性位点不足、载流子复合过快和氧化还原能力偏弱等缺点,制约了其光催化领域的有效应用。研究表明,使用模板诱导工艺对g-C_(3)N_(4)进行结构调控可以有效解决上述问题。综述了目前常用于制备石墨相氮化碳的模板法(即硬模板法、软模板法和生物模板法),扩展讨论了多相复合工艺的进展情况,并归纳总结了g-C_(3)N_(4)基材料在光催化降解、CO_(2)转化和制氢等方面的应用情况。 展开更多
关键词 类石墨相氮化碳 光催化 模板法诱导
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Bi_(2)WO_(6)/g-C_(3)N_(4)复合光催化剂的制备及其光催化性能研究 被引量:1
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作者 韩碧波 刘世凯 +3 位作者 宋志健 王嘉琳 吴昊承 闫国晋 《现代化工》 CAS CSCD 北大核心 2024年第4期175-179,共5页
以尿素、硝酸铋、钨酸钠等为主要原料,在热缩聚法制备g-C_(3)N_(4)的基础上,通过水热法制备Bi_(2)WO_(6)/g-C_(3)N_(4)复合光催化剂。在模拟太阳光照射下,研究Bi_(2)WO_(6)/g-C_(3)N_(4)复合光催化剂对甲基橙的光催化降解性能。结果表明... 以尿素、硝酸铋、钨酸钠等为主要原料,在热缩聚法制备g-C_(3)N_(4)的基础上,通过水热法制备Bi_(2)WO_(6)/g-C_(3)N_(4)复合光催化剂。在模拟太阳光照射下,研究Bi_(2)WO_(6)/g-C_(3)N_(4)复合光催化剂对甲基橙的光催化降解性能。结果表明,复合光催化剂相比于单体光催化剂的性能有显著提高。在Bi_(2)WO_(6)与g-C_(3)N_(4)质量比为2∶1、水热温度为180℃、水热时间为12 h条件下,复合光催化剂的性能最好。光照时间210 min时,甲基橙降解率达到了98.15%,相比于单体Bi_(2)WO_(6)和g-C_(3)N_(4)光催化剂的效率分别提高了25.1%和37.7%,且光催化降解过程符合一级动力学方程。复合光催化剂具有优异的稳定性,经过4次重复性实验,甲基橙降解率仍达到95.17%。 展开更多
关键词 g-C_(3)N_(4) Bi_(2)WO_(6) 水热法 光催化 甲基橙
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NGP_G-STABILITY OF LINEAR MULTISTEP METHODS FOR SYSTEMS OF GENERALIZED NEUTRAL DELAY DIFFERENTIAL EQUATIONS 被引量:1
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作者 CONG Yu-hao(丛玉豪) 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2001年第7期827-835,共9页
The stability analysis of linear multistep methods for the numerical solutions of the systems of generalized neutral delay differential equations is discussed. The stability behaviour of linear multistep methods was a... The stability analysis of linear multistep methods for the numerical solutions of the systems of generalized neutral delay differential equations is discussed. The stability behaviour of linear multistep methods was analysed for the solution of the generalized system of linear neutral test equations, After the establishment of a sufficient condition for asymptotic stability of the solutions of the generalized system, it is shown that a linear multistep method is NGP(G)-stable if and only if it is A-stable. 展开更多
关键词 generalized neutral delay differential system asymptotic stability linear multistep methods NgP(g)-stability
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CQDs/g-C_(3)N_(4)复合材料合成及其光催化性能的研究进展
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作者 刘志信 刘成宝 +5 位作者 郑磊之 陈丰 钱君超 邱永斌 孟宪荣 陈志刚 《机械工程材料》 CAS CSCD 北大核心 2024年第7期1-10,共10页
石墨氮化碳(g-C_(3)N_(4))在新能源开发和环境修复方面具有巨大的应用潜力,但纯g-C_(3)N_(4)存在的光吸收范围小、结晶度高、光生载流子复合率高和活性位点偏少等缺点限制了其应用范围。引入碳量子点(CQDs)构建复合相,可以增加g-C_(3)N_... 石墨氮化碳(g-C_(3)N_(4))在新能源开发和环境修复方面具有巨大的应用潜力,但纯g-C_(3)N_(4)存在的光吸收范围小、结晶度高、光生载流子复合率高和活性位点偏少等缺点限制了其应用范围。引入碳量子点(CQDs)构建复合相,可以增加g-C_(3)N_(4)的反应活性位点,加快其表面电荷的转移,抑制载流子的复合,从而提升其光催化活性。对CQDs的制备方法和原料来源,以及CQDs/g-C_(3)N_(4)复合材料的合成方法(溶剂热法、煅烧法、自组装法)和光催化性能的提升策略等方面的研究进展进行了综述,介绍了近年来CQDs/g-C_(3)N_(4)复合材料在氢气制取、污染物降解、抗菌方面的应用,最后对CQDs/g-C_(3)N_(4)复合材料的未来发展方向进行了展望。 展开更多
关键词 CQDs/g-C_(3)N_(4)复合材料 合成方法 光催化性能 污染物降解 氢气制取 抗菌
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载铁活性炭对酸性嫩黄G的吸附机理
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作者 赵博宇 张羽彤 +3 位作者 姜宇彤 李晓悦 肖鹏飞 吴德东 《净水技术》 CAS 2024年第5期133-142,共10页
为获得高效处理酸性嫩黄G(AYG)废水方法,采用浸渍法制备载铁活性炭(Fe-AC)作为吸附剂,并采用傅里叶红外光谱、扫描电镜及比表面积方法对改性前后活性炭进行表征分析。研究采用Box-Behnken Design响应面分析了各因素及其交互作用对AYG的... 为获得高效处理酸性嫩黄G(AYG)废水方法,采用浸渍法制备载铁活性炭(Fe-AC)作为吸附剂,并采用傅里叶红外光谱、扫描电镜及比表面积方法对改性前后活性炭进行表征分析。研究采用Box-Behnken Design响应面分析了各因素及其交互作用对AYG的去除影响,并探讨了Fe-AC吸附处理AYG的机理。结果表明:3个因素对AYG去除影响的显著顺序为Fe-AC投加量>处理时间>pH。最佳处理条件:Fe-AC投加量为9.51g/L、处理时间为40.79 min、pH值为4.23。Fe-AC吸附AYG遵循准二级动力学模型,反应速率常数为0.0102~0.6193 g/(mg·min),吸附过程符合Temkin吸附等温模型。机理分析结果表明,Fe-AC含氧官能团增加,表面粗糙,比表面积及单点吸附总孔容增加,裂缝、凹陷丰富,存在多层吸附现象,为其吸附AYG提供了更多结合位点,更利于其与吸附质结合,增加其对AYG吸附量。 展开更多
关键词 载铁活性炭(Fe-AC) 酸性嫩黄g(AYg) 表征分析 响应面法(RSM) 吸附机理
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High-contrast imaging based on wavefront shaping to improve low signal-to-noise ratio photoacoustic signals using superpixel method
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作者 Xinjing Lv Xinyu Xu +3 位作者 Qi Feng Bin Zhang Yingchun Ding Qiang Liu 《Chinese Physics B》 SCIE EI CAS CSCD 2020年第3期251-258,共8页
Photoacoustic(PA) imaging has drawn tremendous research interest for various applications in biomedicine and experienced exponential growth over the past decade. Since the scattering effect of biological tissue on ult... Photoacoustic(PA) imaging has drawn tremendous research interest for various applications in biomedicine and experienced exponential growth over the past decade. Since the scattering effect of biological tissue on ultrasound is two-to three-orders magnitude weaker than that of light, photoacoustic imaging can effectively improve the imaging depth.However, as the depth of imaging further increases, the incident light is seriously affected by scattering that the generated photoacoustic signal is very weak and the signal-to-noise ratio(SNR) is quite low. Low SNR signals can reduce imaging quality and even cause imaging failure. In this paper, we proposed a new wavefront shaping and imaging method of low SNR photoacoustic signal using digital micromirror device(DMD) based superpixel method. We combined the superpixel method with DMD to modulate the phase and amplitude of the incident light, and the genetic algorithm(GA) was used as the wavefront shaping algorithm. The enhancement of the photoacoustic signal reached 10.46. Then we performed scanning imaging by moving the absorber with the translation stage. A clear image with contrast of 8.57 was obtained while imaging with original photoacoustic signals could not be achieved. The proposed method opens new perspectives for imaging with weak photoacoustic signals. 展开更多
关键词 PHOTOACOUSTIC IMAgINg WAVEFRONT SHAPINg superpixel method high contrast IMAgINg
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The Inheritance and Application of Chinese Reverse Contrast Typeface Style
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作者 Suimeng Qin Albert Young Choi 《Psychology Research》 2024年第2期70-80,共11页
This paper discusses the inheritance and application of Chinese character reverse contrast typeface style.It begins by analyzing the visual features of Western reverse contrast typeface styles,with a focus on Caslon I... This paper discusses the inheritance and application of Chinese character reverse contrast typeface style.It begins by analyzing the visual features of Western reverse contrast typeface styles,with a focus on Caslon Italian and French Clarendon,providing a Western perspective reference for subsequent Chinese character reverse contrast typeface style designs.The paper then traces the origins of the Chinese reverse contrast style,from the calligraphy style"Lacquer Script"to the earliest printing type"フワンテール形",exploring the historical background and cultural significance of the Chinese reverse contrast style.In the methodology section of Chinese character reverse contrast typeface style design,the discussion is conducted from two dimensions:inheritance and application.In terms of inheritance,through an in-depth analysis of"Lacquer Script"and"フワンテール形"typeface style,the paper summarizes three basic theories for modern Chinese character reverse contrast typeface style design.In the application section,it examines in detail the two most influential recent typeface styles,"Ribaasu"and"Basic Artistic",outlining three directions of application:extreme horizontal stroke variations,exaggerated contrast,and diverse decorative strokes,showcasing new directions and possibilities for Chinese character reverse contrast typeface style design.This paper not only reviews the developmental history of the Chinese character reverse contrast typeface style but also analyzes the design methodology of Chinese character reverse contrast typeface style through specific case studies. 展开更多
关键词 reverse contrast fonts Chinese character font design design method
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Exact Travelling Wave Solutions of Two Nonlinear Schr&#246;dinger Equations by Using Two Methods
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作者 Qingmei Zhang Mei Xiong Longwei Chen 《Journal of Applied Mathematics and Physics》 2019年第12期3101-3115,共15页
The special kind of (G’/G)-expansion method and the new mapping method are easy and significant mathematical methods. In this paper, exact travelling wave solutions of the higher order dispersive Cubic-quintic nonlin... The special kind of (G’/G)-expansion method and the new mapping method are easy and significant mathematical methods. In this paper, exact travelling wave solutions of the higher order dispersive Cubic-quintic nonlinear Schr&#246;dinger equation and the generalized nonlinear Schr&#246;dinger equation are studied by using the two methods. Finally, the solitary wave solutions, singular soliton solutions, bright and dark soliton solutions and periodic solutions of the two nonlinear Schr&#246;dinger equations are obtained. The results show that this method is effective for solving exact solutions of nonlinear partial differential equations. 展开更多
关键词 The Special Kind of (g’/g)-Expansion method the New Mapping method the Partial Differential Equations the EXACT TRAVELLINg Wave Solutions
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Exact Traveling Wave Solutions to Phi-4 Equation and Joseph-Egri (TRLW) Equation and Calogro-Degasperis (CD) Equation by Modified (G'/G2)-Expansion Method
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作者 Maha Al-Harbi Waleed Al-Hamdan Luwai Wazzan 《Journal of Applied Mathematics and Physics》 2023年第7期2103-2120,共18页
In this study, we will introduce the modified (G'/G<sup>2</sup>)-expansion method to explore some of the exact traveling wave solutions of some nonlinear partial differential equations namely, Phi-4 eq... In this study, we will introduce the modified (G'/G<sup>2</sup>)-expansion method to explore some of the exact traveling wave solutions of some nonlinear partial differential equations namely, Phi-4 equation, Joseph-Egri (TRLW) equation, and Calogro-Degasperis (CD) equation. As a result, we have obtained solutions for the equations expressed in terms of trigonometric, hyperbolic and rational functions. Moreover, some selected solutions are plotted using some specific values for the parameters. 展开更多
关键词 Exact Solutions Modified (g'/g2)-Expansion method Phi-4 Equation Joseph-Egri (TRLW) Equation Calogro-Degasperis (CD) Equation
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双(G/G',1/G)展开法求解(3+1)维mKdvZK方程和(3+1)维YTSF方程的新孤子解
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作者 杨超 孙峪怀 韩梦娜 《内蒙古师范大学学报(自然科学汉文版)》 CAS 2024年第1期1-9,共9页
研究(3+1)维修正Korteweg-devries-Zakharov-Kuznestsov方程和(3+1)维Yu-Toda-Sassa-Fukuymama方程的解。首先利用行波变换和代入变换将(3+1)维mKdvZKE和(3+1)维YTSFE转化为常微分方程,而后选择双(G/G’,1/G)展开法得到多个与现有的文... 研究(3+1)维修正Korteweg-devries-Zakharov-Kuznestsov方程和(3+1)维Yu-Toda-Sassa-Fukuymama方程的解。首先利用行波变换和代入变换将(3+1)维mKdvZKE和(3+1)维YTSFE转化为常微分方程,而后选择双(G/G’,1/G)展开法得到多个与现有的文献不同的精确解。本方法丰富了(3+1)维修正Korteweg-devries-Zakharov-Kuznestsov方程和(3+1)维Yu-Toda-Sassa-Fukuymama方程的解,说明所用方法和过程对构造非线性演化方程的精确解具有科学性和通用性。 展开更多
关键词 双(g/g 1/g)展开法 修正Korteweg-devries-Zakharov-Kuznestsov方程 Yu-Toda-Sassa-Fukuymama方程 精确解
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遥感卫星地面站12米口径天线Ka频段G/T值测试方法综述
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作者 吴威葳 《电子技术应用》 2024年第7期107-113,共7页
Ka频段G/T值是遥感卫星地面站12米口径天线最重要的指标之一,其测试方法与遥感站目前常用的X频段测试方法相比,适用条件更加严苛,因此如何选取最佳的测试方法成为本文研究的主要内容。首先介绍了Ka频段12米口径天线特点;然后分别论述了... Ka频段G/T值是遥感卫星地面站12米口径天线最重要的指标之一,其测试方法与遥感站目前常用的X频段测试方法相比,适用条件更加严苛,因此如何选取最佳的测试方法成为本文研究的主要内容。首先介绍了Ka频段12米口径天线特点;然后分别论述了分段测试法、信标法、比较法和射电源法的原理及其优缺点,并提出了Ka频段对月测试的这一最方便简洁的测试方法及其修正系数的研究方向;最后通过实测结果进行比较,给出Ka频段G/T值测试方法选取建议,为工程师现场测试提供了科学的指导和参考。 展开更多
关键词 遥感地面站 KA频段 12米天线 g/T值 分段测试法 信标法 比较法 射电源法
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Evaluation of Quantum Chemical Methods and Basis Sets Applied in the Molecular Modeling of Artemisinin
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作者 Cleydson B. R. dos Santos Cleison C. Lobato +5 位作者 Josinete B. Vieira Davi S. B. Brasil Alaan U. Brito Williams J. C. Macêdo José Carlos T. Carvalho José C. Pinheiro 《Computational Molecular Bioscience》 2013年第3期66-79,共14页
In this paper, we evaluate semiempirical methods (AM1, PM3, and ZINDO), HF and DFT (B3LYP) in different basis sets to determine which method best describes the sign and magnitude of the geometrical parameters of artem... In this paper, we evaluate semiempirical methods (AM1, PM3, and ZINDO), HF and DFT (B3LYP) in different basis sets to determine which method best describes the sign and magnitude of the geometrical parameters of artemisinin in the region of the endoperoxide ring compared to crystallographic data. We also classify these methods using statistical analysis. The results of PCA were based on three main components, explaining 98.0539% of the total variance, for the geometrical parameters C3O13, O1O2C3, O13C12C12a, and O2C3O13C12. The DFT method (B3LYP) corresponded well with the experimental data in the hierarchical cluster analysis (HCA). The experimental and theoretical angles were analyzed by simple linear regression, and statistical parameters (correlation coefficients, significance, and predictability) were evaluated to determine the accuracy of the calculations. The statistical analysis exhibited a good correlation and high predictive power for the DFT (B3LYP) method in the 6-31G** basis set. 展开更多
关键词 ARTEMISININ MOLECULAR Modeling QUANTUM CHEMICAL methods STATISTICAL Analysis B3LYP/6-31g**
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基于流导法的G-M制冷机低温泵抽速测试与分析
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作者 余彦飞 李晓刚 +2 位作者 胡湘娥 陈进文 陈洁心 《真空》 CAS 2024年第3期20-25,共6页
抽气速率是衡量低温泵产品抽真空性能优劣的重要指标之一。除国内企业常用的流量法外,流导法亦是测量低温泵抽速的重要方法。本文依据现行标准中所规定的基于流导法原理测试真空泵气体抽速的方法,对ZD-200口径G-M制冷机低温泵对不同气... 抽气速率是衡量低温泵产品抽真空性能优劣的重要指标之一。除国内企业常用的流量法外,流导法亦是测量低温泵抽速的重要方法。本文依据现行标准中所规定的基于流导法原理测试真空泵气体抽速的方法,对ZD-200口径G-M制冷机低温泵对不同气体抽速测试进行了详细介绍。结果表明:流导法测得低温泵对N^(2)和Ar的抽速分别为2410 L/s、1884 L/s,明显优于国内外同类产品指标;低温泵对H^(2)抽速为2577 L/s,与国内外产品公开技术指标处于相同水平。依照流导法获得的测试结果具有较高的准确度和可信度。 展开更多
关键词 g-M制冷机低温泵 流导法 抽速测试 性能分析
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g-C_(3)N_(4)/TiO_(2)/RGO三元复合材料的制备及催化果糖脱水制5-羟甲基糠醛的研究
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作者 邵梦莎 洪雯雯 +3 位作者 刘思乐 张申奥 王思祺 李金源 《化工科技》 CAS 2024年第3期18-25,共8页
采用水热法制备g-C_(3)N_(4)/TiO_(2)/RGO三元复合材料,并将其应用于果糖脱水制备5-羟甲基糠醛(5-HMF)。利用SEM、TEM、XRD、FTIR、BET等检测手段对g-C_(3)N_(4)/TiO_(2)/RGO三元复合材料的形貌、晶型、基团和比表面积进行了表征,同时... 采用水热法制备g-C_(3)N_(4)/TiO_(2)/RGO三元复合材料,并将其应用于果糖脱水制备5-羟甲基糠醛(5-HMF)。利用SEM、TEM、XRD、FTIR、BET等检测手段对g-C_(3)N_(4)/TiO_(2)/RGO三元复合材料的形貌、晶型、基团和比表面积进行了表征,同时研究了反应温度、反应时间、催化剂用量及溶剂种类对果糖转化率、5-HMF的收率和选择性的影响,此外,还考察了催化剂的稳定性。结果表明,g-C_(3)N_(4)/TiO_(2)/RGO三元复合材料具有三维立体网状结构,比表面积达到了31.4782 m^(2)/g,对果糖脱水反应具有良好的催化活性;在果糖质量为5.0 g、二甲基亚砜用量15 mL、g-C_(3)N_(4)/TiO_(2)/RGO用量1.0 g、反应时间3 h、反应温度150℃的条件下,果糖的转化率为98.5%,5-HMF的收率为69.7%,选择性为70.8%;5次循环使用后,5-HMF的收率仍能达到58.8%,表明g-C_(3)N_(4)/TiO_(2)/RGO三元复合材料的催化稳定性良好。 展开更多
关键词 g-C_(3)N_(4)/TiO_(2)/RgO三元复合材料 水热法 5-羟甲基糠醛 果糖
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Zr基MOFs材料UiO-66-NH_(2)负载g-C_(3)N_(4)催化剂的制备及光催化性能
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作者 刘思乐 洪雯雯 +2 位作者 单译 回梁川 张磊 《印染》 CAS 北大核心 2024年第3期15-19,共5页
通过溶剂热法制备了UiO-66-NH_(2)/g-C_(3)N_(4)催化剂,以甲基橙(MO)染料溶液为模拟污染物,研究可见光照射下UiO-66-NH_(2)/g-C_(3)N_(4)光催化活性和循环使用稳定性。结果表明:UiO-66-NH_(2)均匀地负载在层状g-C_(3)N_(4)表面,UiO-66-N... 通过溶剂热法制备了UiO-66-NH_(2)/g-C_(3)N_(4)催化剂,以甲基橙(MO)染料溶液为模拟污染物,研究可见光照射下UiO-66-NH_(2)/g-C_(3)N_(4)光催化活性和循环使用稳定性。结果表明:UiO-66-NH_(2)均匀地负载在层状g-C_(3)N_(4)表面,UiO-66-NH_(2)与g-C_(3)N_(4)形成Ⅱ型异质结,抑制了光生电子-空穴的复合;当催化剂质量浓度为1.25 g/L时,其对MO的光催化降解率达到了95.6%,催化剂循环使用5次后其对MO的光催化降解率仍达到了85.2%。 展开更多
关键词 UiO-66-NH_(2)/g-C_(3)N_(4) 甲基橙 光催化降解 溶剂热法 MOFS 层状多孔
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