The intrinsic kinetic models of the Langmuir-Hinshelwood type were investigated in terms of the reaction rates of CO hydrogenation and CO_2 hydrogenation in theform of reactant fugacity. The parameters were estimated ...The intrinsic kinetic models of the Langmuir-Hinshelwood type were investigated in terms of the reaction rates of CO hydrogenation and CO_2 hydrogenation in theform of reactant fugacity. The parameters were estimated by the Universal Global Optimization using the Marquardt method. Residual error distribution and statistic tests show thatthe intrinsic kinetic models are reliable and acceptable. The mathematic model of a combined converter formed by gas-cooled and water-cooled reactor was developed and thegas-cooled reactor and the water-cooled reactor were characterized with one-dimensionalmathematic model. The distributions of temperature and concentration in the catalytic bedof the gas-cooled reactor and the water-cooled reactor in a combined converter with ayield of 1.2 Mt/a were simulated. The parallel cross linking pore model was used to describe the transfer process of multi-component diffusion system in the catalyst. The calculated value computed by the internal diffusion efficiency factor calculation model established for methanol synthesis catalyst fit the experimental value very well.展开更多
In cryogenic wind tunnel tests,piezoelectric stacks are adopted to realize the vibration control of the cantilever sting.However,the free stroke and blocking force of the piezoelectric stack would decrease dramaticall...In cryogenic wind tunnel tests,piezoelectric stacks are adopted to realize the vibration control of the cantilever sting.However,the free stroke and blocking force of the piezoelectric stack would decrease dramatically as the temperature decreases.This paper proposes a convenient and effective warming structure for the piezoelectric stack,which could keep it working at operating temperatures when the ambient temperature drops.The piezoelectric stack actuator is wrapped with the heating film,and this resulting assembly is then wrapped with the aerogel material for thermal insulation.Both ends of the piezoelectric stack actuator make direct contact with the payload structure.Both one-dimensional and two-dimensional theoretical analyses of the heating conduction problem of the piezoelectric stack actuator are conducted.These analyses results are compared with those of the finite element simulation analysis.The finite element method results show a good consistency with the two-dimensional theoretical results,and a slight deviation of only 0.91 K is observed,indicating its potential for protecting piezoelectric stacks at low temperatures.展开更多
基金Supported by the National Science & Technology Support Project Task of China(2006BAE02B02)
文摘The intrinsic kinetic models of the Langmuir-Hinshelwood type were investigated in terms of the reaction rates of CO hydrogenation and CO_2 hydrogenation in theform of reactant fugacity. The parameters were estimated by the Universal Global Optimization using the Marquardt method. Residual error distribution and statistic tests show thatthe intrinsic kinetic models are reliable and acceptable. The mathematic model of a combined converter formed by gas-cooled and water-cooled reactor was developed and thegas-cooled reactor and the water-cooled reactor were characterized with one-dimensionalmathematic model. The distributions of temperature and concentration in the catalytic bedof the gas-cooled reactor and the water-cooled reactor in a combined converter with ayield of 1.2 Mt/a were simulated. The parallel cross linking pore model was used to describe the transfer process of multi-component diffusion system in the catalyst. The calculated value computed by the internal diffusion efficiency factor calculation model established for methanol synthesis catalyst fit the experimental value very well.
基金the National Natural Science Foundation of China(No.11872207)Aeronautical Science Foundation of China(No.20180952007)+2 种基金Foundation of National Key Laboratory on Ship Vibration and Noise(No.614220400307)Natural Science Foundation of Jiangsu Province(No.BK20200413)the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)。
文摘In cryogenic wind tunnel tests,piezoelectric stacks are adopted to realize the vibration control of the cantilever sting.However,the free stroke and blocking force of the piezoelectric stack would decrease dramatically as the temperature decreases.This paper proposes a convenient and effective warming structure for the piezoelectric stack,which could keep it working at operating temperatures when the ambient temperature drops.The piezoelectric stack actuator is wrapped with the heating film,and this resulting assembly is then wrapped with the aerogel material for thermal insulation.Both ends of the piezoelectric stack actuator make direct contact with the payload structure.Both one-dimensional and two-dimensional theoretical analyses of the heating conduction problem of the piezoelectric stack actuator are conducted.These analyses results are compared with those of the finite element simulation analysis.The finite element method results show a good consistency with the two-dimensional theoretical results,and a slight deviation of only 0.91 K is observed,indicating its potential for protecting piezoelectric stacks at low temperatures.