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考虑热扩散情况下有机污染物在复合衬垫中一维瞬态运移的解析模型
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作者 江文豪 李江山 +1 位作者 黄啸 程鑫 《土木工程学报》 EI CSCD 北大核心 2023年第9期146-157,188,共13页
考虑到污染场地内部产热会使得复合衬垫处于非等温分布状态,以土工膜(GMB)+压实黏土衬垫(CCL)组成的双层复合衬垫为例,建立有机污染物的一维瞬态运移模型,并通过分离变量法求解得到该模型的解析解。该解析模型可考虑分子扩散、对流、吸... 考虑到污染场地内部产热会使得复合衬垫处于非等温分布状态,以土工膜(GMB)+压实黏土衬垫(CCL)组成的双层复合衬垫为例,建立有机污染物的一维瞬态运移模型,并通过分离变量法求解得到该模型的解析解。该解析模型可考虑分子扩散、对流、吸附、降解和热扩散等因素对有机污染物运移过程的影响。通过将解析模型的计算结果分别与热扩散试验结果和已有解析解的计算结果进行对比分析,对所建解析模型的正确性进行验证。基于所建解析模型,以击穿时间为主要参数,通过某一算例分析Soret系数ST、渗滤液水头h_(w)、降解半衰期t_(1/2)和Robin边界常数α对有机污染物运移过程的影响。分析结果表明:Soret系数ST和渗滤液水头h_(w)的增大均会加快运移速率,缩短击穿时间,但当S_(T)不超过0.01K-1或h_(w)低于0.3m时,热扩散和对流作用对运移过程的影响较小;降解半衰期t_(1/2)的增大会缩短击穿时间,增大底部浓度和底部通量,当t_(1/2)不超过100年时,应考虑降解作用;Robin边界常数α的增大会降低底部浓度,延长击穿时间,但不同α下击穿时间的差异相对较小。 展开更多
关键词 有机污染物 热扩散 复合衬垫 一维瞬态运移 解析模型 击穿时间
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An analytical solution for one-dimension transient solute transport
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作者 CAI Song-bai SHAO Ming-an +1 位作者 LIU Chun-ping LU Dian-qing 《Journal of Environmental Science and Engineering》 2008年第1期78-81,共4页
The mechanism of transport of chemicals in soil is an important research topic of environmental science and engineering, and some models and methods for a variety of solute transport problems have been done. Howeve... The mechanism of transport of chemicals in soil is an important research topic of environmental science and engineering, and some models and methods for a variety of solute transport problems have been done. However. most of previous works are usually for a soil column of infinite dimension. Starting from the one-dimension transient solute transport equation and its boundary and initial condition for a solute transport problem of soil column of finite length, this work has successfully applied a variable transformation to simplify the partial differential equation of solute transport problem. And an analytical serial solution for the simplified equation is then established by the so-called separated variable method and the superposition method. Compared with numerical methods such as finite different method and finite element method, this analytical solution is more accurate and of higher computation efficiency. In addition, the solution procedure presented could be extended for applications such as quality analysis, design of physical experimentation, or parameter estimation and measurement of solute transport problems. 展开更多
关键词 analytical solution soil colunm of finite length solute transport transient problem
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