This paper presents research aimed at identifying the methods with which prehistoric man interacted with marine and inland water environments. The objective is to determine the degree to which resources from these env...This paper presents research aimed at identifying the methods with which prehistoric man interacted with marine and inland water environments. The objective is to determine the degree to which resources from these environments influenced the socio-economic organization of these peoples. The coastline around Cagliari and its hinterland (southern Sardinia, Italy) were chosen as the subject, on the basis of the presence of both the sea and several ponds. The territory is noted as being home to both Neolithic and Eneolithic settlements. Among these the archaeological excavation of the village of Su Coddu/Canelles produced a large quantity of malacofauna. Data has been processed from part of the settlement that gave radiocarbon dating from the period between 3640 and 2900 cal. BC, and in which it was possible to carry out the level of sampling that was necessary to complete the research. In particular this interdisciplinary project, which aims to make an overall study of the settlement, the data relating to the geography of the area, the archaeological documentation, the fauna and shell artefacts will be extrapolated. Numerous methods are applied above all in reference to the marines and ponds resources. Additionally, the morphological anatomical-comparative analysis (in order to determine the typology of the faunal remains and to identify each individual species) and the technological analysis of the manufactured shells (so as to detect the selection and the transformation type of raw materials) are accomplished. The research has led to the identification of a settlement model in which agriculture formed the primary means of subsistence, that was complemented by the rearing of livestock, through hunting and gathering. The exploitation of marine and inland waters resources, as food source, have to be important because 99% of the faunal remains are shells. Different shell species are recognized, among those the Ostrea edulis provides the raw material to produce bevelled objects, which are documented inside the settlement in considerable number. Some plant species, typical of the lagoon ecosystem, were used for building and craft production.展开更多
Butyl-levulinate has been identified as a promising fuel candidate with high oxygen content. Its com- bustion in diesel engines yields very low soot and NOx emissions. It can be produced by the esterification of butan...Butyl-levulinate has been identified as a promising fuel candidate with high oxygen content. Its com- bustion in diesel engines yields very low soot and NOx emissions. It can be produced by the esterification of butanol and levulinic acid, which themselves are platform chemicals in a biorenewables-based chemical supply chain. Since the equilibrium of esterification limits the conversion in a conventional reactor, reactive distillation can be applied to overcome this limitation. The presence of the high-boiling catalyst sulfuric acid requires a further separation step downstream of the reactive distillation column to recover the catalyst for recycle. Optimal design specifications and an optimal operating point are determined using rigorous flowsheet optimization. The challenging optimization problem is solved by a favorable initialization strategy and continuous reformulation. The design identified has the potential to produce a renewable transportation fuel at reasonable cost.展开更多
文摘This paper presents research aimed at identifying the methods with which prehistoric man interacted with marine and inland water environments. The objective is to determine the degree to which resources from these environments influenced the socio-economic organization of these peoples. The coastline around Cagliari and its hinterland (southern Sardinia, Italy) were chosen as the subject, on the basis of the presence of both the sea and several ponds. The territory is noted as being home to both Neolithic and Eneolithic settlements. Among these the archaeological excavation of the village of Su Coddu/Canelles produced a large quantity of malacofauna. Data has been processed from part of the settlement that gave radiocarbon dating from the period between 3640 and 2900 cal. BC, and in which it was possible to carry out the level of sampling that was necessary to complete the research. In particular this interdisciplinary project, which aims to make an overall study of the settlement, the data relating to the geography of the area, the archaeological documentation, the fauna and shell artefacts will be extrapolated. Numerous methods are applied above all in reference to the marines and ponds resources. Additionally, the morphological anatomical-comparative analysis (in order to determine the typology of the faunal remains and to identify each individual species) and the technological analysis of the manufactured shells (so as to detect the selection and the transformation type of raw materials) are accomplished. The research has led to the identification of a settlement model in which agriculture formed the primary means of subsistence, that was complemented by the rearing of livestock, through hunting and gathering. The exploitation of marine and inland waters resources, as food source, have to be important because 99% of the faunal remains are shells. Different shell species are recognized, among those the Ostrea edulis provides the raw material to produce bevelled objects, which are documented inside the settlement in considerable number. Some plant species, typical of the lagoon ecosystem, were used for building and craft production.
基金funded by the Excellence Initiative of the German federal and state governments to promote science and research at German universities
文摘Butyl-levulinate has been identified as a promising fuel candidate with high oxygen content. Its com- bustion in diesel engines yields very low soot and NOx emissions. It can be produced by the esterification of butanol and levulinic acid, which themselves are platform chemicals in a biorenewables-based chemical supply chain. Since the equilibrium of esterification limits the conversion in a conventional reactor, reactive distillation can be applied to overcome this limitation. The presence of the high-boiling catalyst sulfuric acid requires a further separation step downstream of the reactive distillation column to recover the catalyst for recycle. Optimal design specifications and an optimal operating point are determined using rigorous flowsheet optimization. The challenging optimization problem is solved by a favorable initialization strategy and continuous reformulation. The design identified has the potential to produce a renewable transportation fuel at reasonable cost.