Objective:In order that the adhesive character could be improved to modify the octyl-α-cyanoacrylate(OCA) medical adhesive.Methods:Suitable modifiers involving polycaprolactone(PCL),dibutyl phthalate (DBP),dioctyl ph...Objective:In order that the adhesive character could be improved to modify the octyl-α-cyanoacrylate(OCA) medical adhesive.Methods:Suitable modifiers involving polycaprolactone(PCL),dibutyl phthalate (DBP),dioctyl phthalate(DOP) and poly octyl methacrylat(POMA) have been chosen to modify the OCA adhesive,then tensile shear strength and adhesive strength are tested to evaluate the bond character of adhesives.Results:The PCL group's tensile shear strength and adhesive strength in normal temperature are descended while the other groups'are all enhanced.Conclusion:The modification of properties of the other groups is effectively promoted in the aspect of the bond character,except the PCL group treated in normal temperature and the PCL modified group treated by rectification get a best improvement in the agglutinate intention, while the stability is expected to be improved.展开更多
Phthalate esters （PAEs）, which can disturb human endocrine system, have been widely detected in vegetable greenhouse agriculture in China. To investigate the effects of environmental factors on PAEs in soils, pollut...Phthalate esters （PAEs）, which can disturb human endocrine system, have been widely detected in vegetable greenhouse agriculture in China. To investigate the effects of environmental factors on PAEs in soils, pollution sources were identified, and the cumulative risks of PAEs to humans through vegetables in the diet were evaluated in this study. Ninety-eight vegetable samples were collected from 10 markets along with 128 vegetable and 111 soil samples from agricultural greenhouses and open field. All soil and vegetable samples were contaminated with PAEs, and the total concentrations of the 5 PAEs, including dimethyl phthalate （DMP）, diethyl phthalate （DEP）, di-iso-butyl phthalate （DiBP）, di-n-butyl phthalate （DnBP）, and di-2-ethylhexyl phthalate （DEHP）, were in the ranges of 0.26-2.53 mg kg-1 for soils and 0.95-8.09 mg kg-1 for vegetables. Three components extracted from principle component analysis could explain 51.2%, 19.8%, and 15.3% of the total variance of the 5 PAEs in soils, which may represent three major sources of PAEs, i.e., wastewater irrigation, application of fertilizers and pesticides, and plastic film. Long-term greenhouse cultivation could accumulate DEHP in soils, and a higher soil FeOx content reduced the DnBP concentration. Based on a survey of vegetables in the diet, the hazard index of PAEs was 〈 0.15 for individuals in different cities. The exposure of PAEs through vegetable intake was higher than the total exposure from other food stuffS, inhalation, and dermal absorption. More attention should be g!ven to controlling PAEs in greenhouse vegetables.展开更多
文摘Objective:In order that the adhesive character could be improved to modify the octyl-α-cyanoacrylate(OCA) medical adhesive.Methods:Suitable modifiers involving polycaprolactone(PCL),dibutyl phthalate (DBP),dioctyl phthalate(DOP) and poly octyl methacrylat(POMA) have been chosen to modify the OCA adhesive,then tensile shear strength and adhesive strength are tested to evaluate the bond character of adhesives.Results:The PCL group's tensile shear strength and adhesive strength in normal temperature are descended while the other groups'are all enhanced.Conclusion:The modification of properties of the other groups is effectively promoted in the aspect of the bond character,except the PCL group treated in normal temperature and the PCL modified group treated by rectification get a best improvement in the agglutinate intention, while the stability is expected to be improved.
基金supported by the National Basic Research Program of China (No. 2014CB441105)the National Natural Science Foundation of China (No. 21377136)+1 种基金the One Hundred Person Project of Chinese Academy of Sciences (No. 2012133)the 135 Research Program of Chinese Academy of Sciences
文摘Phthalate esters （PAEs）, which can disturb human endocrine system, have been widely detected in vegetable greenhouse agriculture in China. To investigate the effects of environmental factors on PAEs in soils, pollution sources were identified, and the cumulative risks of PAEs to humans through vegetables in the diet were evaluated in this study. Ninety-eight vegetable samples were collected from 10 markets along with 128 vegetable and 111 soil samples from agricultural greenhouses and open field. All soil and vegetable samples were contaminated with PAEs, and the total concentrations of the 5 PAEs, including dimethyl phthalate （DMP）, diethyl phthalate （DEP）, di-iso-butyl phthalate （DiBP）, di-n-butyl phthalate （DnBP）, and di-2-ethylhexyl phthalate （DEHP）, were in the ranges of 0.26-2.53 mg kg-1 for soils and 0.95-8.09 mg kg-1 for vegetables. Three components extracted from principle component analysis could explain 51.2%, 19.8%, and 15.3% of the total variance of the 5 PAEs in soils, which may represent three major sources of PAEs, i.e., wastewater irrigation, application of fertilizers and pesticides, and plastic film. Long-term greenhouse cultivation could accumulate DEHP in soils, and a higher soil FeOx content reduced the DnBP concentration. Based on a survey of vegetables in the diet, the hazard index of PAEs was 〈 0.15 for individuals in different cities. The exposure of PAEs through vegetable intake was higher than the total exposure from other food stuffS, inhalation, and dermal absorption. More attention should be g!ven to controlling PAEs in greenhouse vegetables.
