针对三元乙丙橡胶接枝顺酐接枝率测定的误差较大的现象,研究了影响接枝率测定的各种因素,如:沉淀剂及其用量、溶剂及其用量、KOH用量、回流时间、光照时间等.研究表明EPDM-g-MAH接枝率测定的最适宜条件为:反应混合物与沉淀剂丙酮的体积...针对三元乙丙橡胶接枝顺酐接枝率测定的误差较大的现象,研究了影响接枝率测定的各种因素,如:沉淀剂及其用量、溶剂及其用量、KOH用量、回流时间、光照时间等.研究表明EPDM-g-MAH接枝率测定的最适宜条件为:反应混合物与沉淀剂丙酮的体积比为1 4;光照时间为4～8 h,以接枝物不被烤黄(焦)为宜.测定接枝率时以甲苯为溶剂与接枝物的用量比为1 g 200 mL;回流时间为2～3 h;接枝物与氢氧化钾-乙醇溶液用量比为1 g 100 mL.展开更多
In this paper, we report a technique for the surface modification of poly-(p-phenylene terephthamide)(PPTA) powder coated with polydopamine(PDOPA). We used air oxidation to self-polymerize dopamine(DOPA) to ensure tha...In this paper, we report a technique for the surface modification of poly-(p-phenylene terephthamide)(PPTA) powder coated with polydopamine(PDOPA). We used air oxidation to self-polymerize dopamine(DOPA) to ensure that the PPTA powder was coated. Our results indicate that the modified surface of PPTA powder enhances compatibility with the polymer matrix without damaging its structure. Additionally, it is possible to control the coating thickness of PDOPA by regulating the reaction time. The modified PPTA powder improved the comprehensive property of ethylene-propylene-diene-terpolymer grafted maleic anhydride(EPDM-g-MAH), and it proved that this method can enhance the strength and electric insulativity of EPDM-g-MAH.展开更多
文摘针对三元乙丙橡胶接枝顺酐接枝率测定的误差较大的现象,研究了影响接枝率测定的各种因素,如:沉淀剂及其用量、溶剂及其用量、KOH用量、回流时间、光照时间等.研究表明EPDM-g-MAH接枝率测定的最适宜条件为:反应混合物与沉淀剂丙酮的体积比为1 4;光照时间为4～8 h,以接枝物不被烤黄(焦)为宜.测定接枝率时以甲苯为溶剂与接枝物的用量比为1 g 200 mL;回流时间为2～3 h;接枝物与氢氧化钾-乙醇溶液用量比为1 g 100 mL.
基金supported by the National Natural Science Foundation of China (51273157)Program for New Century Excellent Talents in University (NCET-10-0659)Key Program of Natural Science Foundation of Hubei Province of China (2013CFA020)
文摘In this paper, we report a technique for the surface modification of poly-(p-phenylene terephthamide)(PPTA) powder coated with polydopamine(PDOPA). We used air oxidation to self-polymerize dopamine(DOPA) to ensure that the PPTA powder was coated. Our results indicate that the modified surface of PPTA powder enhances compatibility with the polymer matrix without damaging its structure. Additionally, it is possible to control the coating thickness of PDOPA by regulating the reaction time. The modified PPTA powder improved the comprehensive property of ethylene-propylene-diene-terpolymer grafted maleic anhydride(EPDM-g-MAH), and it proved that this method can enhance the strength and electric insulativity of EPDM-g-MAH.
