三轴X射线衍射技术广泛应用于半导体材料参数的精确测试,然而应用于纤锌矿n-GaN位错密度的测试却可能隐藏极大的误差.本文采用三轴X射线衍射技术测试了两个氢化物气相外延方法生长的n-GaN样品,发现两样品对应衍射面的半高全宽都基本一致...三轴X射线衍射技术广泛应用于半导体材料参数的精确测试,然而应用于纤锌矿n-GaN位错密度的测试却可能隐藏极大的误差.本文采用三轴X射线衍射技术测试了两个氢化物气相外延方法生长的n-GaN样品,发现两样品对应衍射面的半高全宽都基本一致,按照镶嵌结构模型,采用Srikant方法或Williamson-Hall方法,两样品的位错密度也应基本一致.但van der Pauw变温霍尔效应测试表明,其中的非故意掺杂样品是莫特相变材料,而掺Si样品则是非莫特相变材料,位错密度有数量级的差别.实验表明,位错沿晶界生长导致的晶粒尺寸效应,表现为三轴X射线衍射技术检测不到晶界晶格畸变区域的位错,给测试带来极大误差,这对正确使用Srikant方法和Williamson-Hall方法提出了测试要求.分析表明,当扭转角与倾转角之比β_(twist)/β_(tiit)≥2.0时,Srikant方法是准确的,否则需进一步由Williamson-Hall方法确定晶粒大小(面内共格长度L//),当L//≥1.5μm时,Srikant方法是准确的.展开更多
To accurately analyze the impact of casting pores in steel,high-resolution 3D X-ray tomography technology was used to gather detailed statistical information about micropores.These micropores were classified as gas,sh...To accurately analyze the impact of casting pores in steel,high-resolution 3D X-ray tomography technology was used to gather detailed statistical information about micropores.These micropores were classified as gas,shrinkage,and gas-shrinkage pores depending on their formation origin and morphology.Clustering tendencies and affinity parameters were defined to characterize the spatial correlations among these three types of pores.The 3D data from X-ray tomography scans were then integrated into finite element analysis(FEA)software to predict how micropore shape,size,and distribution influence stress distribution within the material.The results show that certain inflection points with small local radii within the cast pores are major contributors to stress concentration.Therefore,cast pores cannot be simply modeled as ideal spherical pores.The sphericity and volume of pores have a significant impact on the stress concentration of the model.Specifically,lower sphericity and larger pore volumes result in higher stress concentrations.Moreover,the internal pores of steel castings exhibit specific global distribution characteristics.Pores located on the surface of the specimen lead to significantly higher stress concentrations compared to those located inside the specimen.展开更多
To address the problem of subdividing inflexible rectangular grid models and their poor definition of velocity interfaces,we propose a complex structure triangular net for a minimum traveltime ray tracing global algor...To address the problem of subdividing inflexible rectangular grid models and their poor definition of velocity interfaces,we propose a complex structure triangular net for a minimum traveltime ray tracing global algorithm.Our procedure is:(1) Subdivide a triangle grid based on the Delaunay triangular subdivision criterion and the relationships of the points,lines,and the surfaces in the subdividing area.(2) Define the topology relationships and related concepts of triangular unit ray tracing.(3) The source point and wave arrival points at any time compose the propagating plane wave and the minimum traveltime and secondary source positions are calculated during the plane wave propagation.We adopt the hyperbolic approximation global algorithm for secondary source retrieving.(4) By minimum traveltime ray tracing,collect the path from receiver to source points with the neighborhood point's traveltime and the direction of the secondary source.Numerical simulation examples are given to test the algorithm.The results show that the triangular net ray tracing method demonstrates model subdivision flexibility,precise velocity discontinuity interfaces,and accurate computations.展开更多
The pseudo-ternary system(Na Cl + Na_2SO_4+ H_2O) of coal gasification wastewater was studied at T =(268.15 to 373.15) K. The solubility and density of the equilibrium liquid phase were determined by the isothermal so...The pseudo-ternary system(Na Cl + Na_2SO_4+ H_2O) of coal gasification wastewater was studied at T =(268.15 to 373.15) K. The solubility and density of the equilibrium liquid phase were determined by the isothermal solution saturation method. The equilibrium solids were also investigated by the Schreinemaker's method of wet residues and X-ray powder diffraction(XRD). According to the experimental data, the phase diagrams were determined. It was found that there was no significant solubility difference on the Na Cl-rich side between the ternary system(Na Cl + Na_2SO_4+ H_2O) in coal gasification wastewater and in pure water. However, the solubility on the Na_2SO_4-rich side of coal gasification wastewater was apparently higher than that of pure water. The increase in the solubility of Na_2SO_4 was most likely caused by the effects of other impurities apart from Na Cl and Na_2SO_4 in coal gasification wastewater. The measured data and phase equilibrium diagrams can provide fundamental basis for salt recovery in coal gasification wastewater.展开更多
Thermal shocking effect occurs when the coalbed methane(CBM)reservoirs meet liquid nitrogen(LN2)of extremely low temperature.In this study,3D via X-ray microcomputer tomography(μCT)and scanning electron microscope(SE...Thermal shocking effect occurs when the coalbed methane(CBM)reservoirs meet liquid nitrogen(LN2)of extremely low temperature.In this study,3D via X-ray microcomputer tomography(μCT)and scanning electron microscope(SEM)are employed to visualize and quantify morphological evolution characteristics of fractures in coal after LN2 thermal shocking treatments.LN2 thermal shocking leads to a denser fracture network than its original state with coal porosity growth rate increasing up to 183.3%.The surface porosity of theμCT scanned layers inside the coal specimen is influenced by LN2 thermal shocking which rises from 18.76%to 215.11%,illustrating the deformation heterogeneity of coal after LN2 thermal shocking.The cracking effect of LN2 thermal shocking on the surface of low porosity is generally more effective than that of high surface porosity,indicating the applicability of LN2 thermal shocking on low-permeability CBM reservoir stimulation.The characteristics of SEM scanned coal matrix in the coal powder and the coal block after the LN2 thermal shocking presented a large amount of deep and shallow progressive scratch layers,fracture variation diversity(i.e.extension,propagation,connectivity,irregularity)on the surface of the coal block and these were the main reasons leading to the decrease of the uniaxial compressive strength of the coal specimen.展开更多
Fissures play a significant role in predicting the unstable failure of rock mass engineering.For deep rock underground engineering,rock mass containing pre-existing fissures is usually located in triaxial stress state...Fissures play a significant role in predicting the unstable failure of rock mass engineering.For deep rock underground engineering,rock mass containing pre-existing fissures is usually located in triaxial stress state.Therefore,not only pre-existing fissure but also confining pressure affects the failure mechanical behavior of rock material.In this research,the granite specimens containing two non-coplanar open fissures were investigated by a series of conventional triaxial compression tests.First,the effect of bridge angle and confining pressure on strength and deformation characteristics of granite specimens was evaluated.Results show that the triaxial compressive strength,failure axial strain,and crack damage threshold increased nonlinearly with confining pressure.Under high confining pressures,elastic modulus was insensitive to bridge angle.Then,an X-ray micro-CT scanning technique was used to analyze the internal fracture characteristics of granite specimens with respect to various bridge angles and confining pressures.Five typical crack coalescence modes were identified,namely,indirect coalescence,shear coalescence and three types of tensile coalescence.The reconstructed 3-D CT images indicated that under uniaxial or low confining pressures,the bridge angle had a significant effect on crack evolution behavior,while under high confining pressures,shear-dominated failures occurred with the development of anti-wing cracks.展开更多
The phase relationships in the Zn-Al-Ti system at 450 and 600℃ were experimentally determined using equilibrated alloys method.The specimens were investigated by means of scanning electron microscopy coupled with ene...The phase relationships in the Zn-Al-Ti system at 450 and 600℃ were experimentally determined using equilibrated alloys method.The specimens were investigated by means of scanning electron microscopy coupled with energy dispersive spectroscopy and X-ray diffractometry.Eleven and eight three-phase regions are confirmed in the 450 and 600℃ isothermal sections,respectively.The Ti2Al5 which only exists at high temperature(990-1199.4℃)in Ti-Al binary system is confirmed in two isothermal sections due to the dissolution of zinc.The T phase is confirmed as a ternary compound rather than an extension phase of TiZn3 at 450℃.The T2 phase is a new ternary phase stable at 450 and 600℃ in Zn-Al-Ti ternary system.展开更多
文摘三轴X射线衍射技术广泛应用于半导体材料参数的精确测试,然而应用于纤锌矿n-GaN位错密度的测试却可能隐藏极大的误差.本文采用三轴X射线衍射技术测试了两个氢化物气相外延方法生长的n-GaN样品,发现两样品对应衍射面的半高全宽都基本一致,按照镶嵌结构模型,采用Srikant方法或Williamson-Hall方法,两样品的位错密度也应基本一致.但van der Pauw变温霍尔效应测试表明,其中的非故意掺杂样品是莫特相变材料,而掺Si样品则是非莫特相变材料,位错密度有数量级的差别.实验表明,位错沿晶界生长导致的晶粒尺寸效应,表现为三轴X射线衍射技术检测不到晶界晶格畸变区域的位错,给测试带来极大误差,这对正确使用Srikant方法和Williamson-Hall方法提出了测试要求.分析表明,当扭转角与倾转角之比β_(twist)/β_(tiit)≥2.0时,Srikant方法是准确的,否则需进一步由Williamson-Hall方法确定晶粒大小(面内共格长度L//),当L//≥1.5μm时,Srikant方法是准确的.
基金The National Natural Science Foundation of China(No.51578137).
文摘To accurately analyze the impact of casting pores in steel,high-resolution 3D X-ray tomography technology was used to gather detailed statistical information about micropores.These micropores were classified as gas,shrinkage,and gas-shrinkage pores depending on their formation origin and morphology.Clustering tendencies and affinity parameters were defined to characterize the spatial correlations among these three types of pores.The 3D data from X-ray tomography scans were then integrated into finite element analysis(FEA)software to predict how micropore shape,size,and distribution influence stress distribution within the material.The results show that certain inflection points with small local radii within the cast pores are major contributors to stress concentration.Therefore,cast pores cannot be simply modeled as ideal spherical pores.The sphericity and volume of pores have a significant impact on the stress concentration of the model.Specifically,lower sphericity and larger pore volumes result in higher stress concentrations.Moreover,the internal pores of steel castings exhibit specific global distribution characteristics.Pores located on the surface of the specimen lead to significantly higher stress concentrations compared to those located inside the specimen.
基金the National Natural Science Foundation of China(Grant Nos.50974081,50774051, 51034003)the Foundation for the Author of National Excellent Doctoral Dissertation of PR China(Grant No.200958)+1 种基金the Program for Changjiang Scholars and Innovative Research Team in University(Grant No.IRT0843)the Open Research Fund Program of the State Key Laboratory of Coal Resources and Safe Mining(China University of Mining and Technology, Beijing)(No.2007-07)
文摘To address the problem of subdividing inflexible rectangular grid models and their poor definition of velocity interfaces,we propose a complex structure triangular net for a minimum traveltime ray tracing global algorithm.Our procedure is:(1) Subdivide a triangle grid based on the Delaunay triangular subdivision criterion and the relationships of the points,lines,and the surfaces in the subdividing area.(2) Define the topology relationships and related concepts of triangular unit ray tracing.(3) The source point and wave arrival points at any time compose the propagating plane wave and the minimum traveltime and secondary source positions are calculated during the plane wave propagation.We adopt the hyperbolic approximation global algorithm for secondary source retrieving.(4) By minimum traveltime ray tracing,collect the path from receiver to source points with the neighborhood point's traveltime and the direction of the secondary source.Numerical simulation examples are given to test the algorithm.The results show that the triangular net ray tracing method demonstrates model subdivision flexibility,precise velocity discontinuity interfaces,and accurate computations.
基金Supported by the National Key Research and Development Program of China(2016YFB0600504)
文摘The pseudo-ternary system(Na Cl + Na_2SO_4+ H_2O) of coal gasification wastewater was studied at T =(268.15 to 373.15) K. The solubility and density of the equilibrium liquid phase were determined by the isothermal solution saturation method. The equilibrium solids were also investigated by the Schreinemaker's method of wet residues and X-ray powder diffraction(XRD). According to the experimental data, the phase diagrams were determined. It was found that there was no significant solubility difference on the Na Cl-rich side between the ternary system(Na Cl + Na_2SO_4+ H_2O) in coal gasification wastewater and in pure water. However, the solubility on the Na_2SO_4-rich side of coal gasification wastewater was apparently higher than that of pure water. The increase in the solubility of Na_2SO_4 was most likely caused by the effects of other impurities apart from Na Cl and Na_2SO_4 in coal gasification wastewater. The measured data and phase equilibrium diagrams can provide fundamental basis for salt recovery in coal gasification wastewater.
基金Project(2017XKQY012)supported by the Fundamental Research Funds for the Central Universities,China。
文摘Thermal shocking effect occurs when the coalbed methane(CBM)reservoirs meet liquid nitrogen(LN2)of extremely low temperature.In this study,3D via X-ray microcomputer tomography(μCT)and scanning electron microscope(SEM)are employed to visualize and quantify morphological evolution characteristics of fractures in coal after LN2 thermal shocking treatments.LN2 thermal shocking leads to a denser fracture network than its original state with coal porosity growth rate increasing up to 183.3%.The surface porosity of theμCT scanned layers inside the coal specimen is influenced by LN2 thermal shocking which rises from 18.76%to 215.11%,illustrating the deformation heterogeneity of coal after LN2 thermal shocking.The cracking effect of LN2 thermal shocking on the surface of low porosity is generally more effective than that of high surface porosity,indicating the applicability of LN2 thermal shocking on low-permeability CBM reservoir stimulation.The characteristics of SEM scanned coal matrix in the coal powder and the coal block after the LN2 thermal shocking presented a large amount of deep and shallow progressive scratch layers,fracture variation diversity(i.e.extension,propagation,connectivity,irregularity)on the surface of the coal block and these were the main reasons leading to the decrease of the uniaxial compressive strength of the coal specimen.
基金Project(42077231) supported by the National Natural Science Foundation of China。
文摘Fissures play a significant role in predicting the unstable failure of rock mass engineering.For deep rock underground engineering,rock mass containing pre-existing fissures is usually located in triaxial stress state.Therefore,not only pre-existing fissure but also confining pressure affects the failure mechanical behavior of rock material.In this research,the granite specimens containing two non-coplanar open fissures were investigated by a series of conventional triaxial compression tests.First,the effect of bridge angle and confining pressure on strength and deformation characteristics of granite specimens was evaluated.Results show that the triaxial compressive strength,failure axial strain,and crack damage threshold increased nonlinearly with confining pressure.Under high confining pressures,elastic modulus was insensitive to bridge angle.Then,an X-ray micro-CT scanning technique was used to analyze the internal fracture characteristics of granite specimens with respect to various bridge angles and confining pressures.Five typical crack coalescence modes were identified,namely,indirect coalescence,shear coalescence and three types of tensile coalescence.The reconstructed 3-D CT images indicated that under uniaxial or low confining pressures,the bridge angle had a significant effect on crack evolution behavior,while under high confining pressures,shear-dominated failures occurred with the development of anti-wing cracks.
基金Project(51971189)supported by the National Natural Science Foundation of ChinaProject(2019JJ60011)supported by Zhuzhou Joint Fund of Hunan Natural Science Foundation,ChinaProject(KFBM20180001)supported by Jiangsu Key Laboratory of Materials Surface Science and Technology(Changzhou University),China。
文摘The phase relationships in the Zn-Al-Ti system at 450 and 600℃ were experimentally determined using equilibrated alloys method.The specimens were investigated by means of scanning electron microscopy coupled with energy dispersive spectroscopy and X-ray diffractometry.Eleven and eight three-phase regions are confirmed in the 450 and 600℃ isothermal sections,respectively.The Ti2Al5 which only exists at high temperature(990-1199.4℃)in Ti-Al binary system is confirmed in two isothermal sections due to the dissolution of zinc.The T phase is confirmed as a ternary compound rather than an extension phase of TiZn3 at 450℃.The T2 phase is a new ternary phase stable at 450 and 600℃ in Zn-Al-Ti ternary system.