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分子构型的预测及中心原子上的孤对电子
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作者 SalehM.AL-Mousawi 许琳 郭俐 《山西大同大学学报(自然科学版)》 1995年第6期83-84,共2页
如果象在一般的化学课本和文献中所表示的那样,分子的路易斯结构能被正确书写出来,那么著名的价层电子对互斥理论(VSEPR)就可能被用来预测分子的几何形状.但是,有时学生们在确定中心原子上有多少个孤对电子时仍感到有一定的困难.这里所... 如果象在一般的化学课本和文献中所表示的那样,分子的路易斯结构能被正确书写出来,那么著名的价层电子对互斥理论(VSEPR)就可能被用来预测分子的几何形状.但是,有时学生们在确定中心原子上有多少个孤对电子时仍感到有一定的困难.这里所提出的方法可使这个问题明显简化,并能很容易地预测出分子的几何形状.即首先计算出分子或离子中价电子总数T,然后被8除得出一个整数n,这样即可获得分子的基本构型,如表1所示.但是,T/8并不总是整数,在许多情况下还会有一个余数.这时,分子或离子中电子总数被8除所得的余数即为中心原子上未成键电子的个数.据此,便能得知AXnEm型分子的几何形状,如表2所示. 展开更多
关键词 中心原子 分子构 价电子总数 成键电子 孤对电子 几何形状 电子对 原子 互斥理论 氧化硫
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Full Quantum Theory of Transient-State Electromagnetically Induced Transparency
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作者 KUANGLe-Man ZENGAi-Hua KUANGZhen-Hua 《Communications in Theoretical Physics》 SCIE CAS CSCD 2004年第3X期407-412,共6页
We develop a full quantum theory of transient-state electromagnetically induced transparency (EIT) in thevapor of three-level A-type atoms interacting with probe and coupling lasers. As applications of the full quantu... We develop a full quantum theory of transient-state electromagnetically induced transparency (EIT) in thevapor of three-level A-type atoms interacting with probe and coupling lasers. As applications of the full quantum theory,we show that transient-state EIT medium exhibits normal dispersion and find that group velocities of both coupling andprobe lasers are greatly reduced. It is shown that the group velocity of the probe laser in the transient-state EIT case isequal to that in the adiabatic EIT case and that the coupling laser group velocity in the transient-state EIT is generallyless than that in the adiabatic EIT. 展开更多
关键词 耦合激光 探测激光 电磁诱导透射 全量子理论 三层∧型原子相互作用 群速度 激光物理
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Multi-component Entangled State Generation for Three-Level Atomic System with Hyperfine Structure via Dispersive Interactions
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作者 YANGWen-Xing LIJia-Hua JINLi-Xia 《Communications in Theoretical Physics》 SCIE CAS CSCD 2004年第4X期517-520,共4页
We discuss the generation of certain kinds of multi-component entangled states for three-level atomic system with hyperfine structure. The method proposed here is based on the interactions of dispersive cavity with on... We discuss the generation of certain kinds of multi-component entangled states for three-level atomic system with hyperfine structure. The method proposed here is based on the interactions of dispersive cavity with only one atom driven by a strong classical field. It is shown that, with a judicious choice of the cavity detuning and applied coherent field detuning, the atom can interact dispersively with the quantized field but the classical driving field gives rise to the creation or destruction of photons conditional on the state of the system. In comparison with previous schemes,our method is likely to be extremely easy to realize in 展开更多
关键词 原子系统 多组分纠缠态 超精细结构 原子物理学 色散相互作用
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Influence of Intrinsic Decoherence on Nonclassical Effects of System of a Three-LevelAtom in [1] Configuration
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作者 XUJing-Bo ZOUXu-Bo GAOXiao-Chun FUJian 《Communications in Theoretical Physics》 SCIE CAS CSCD 2004年第2X期275-280,共6页
With the help of an SU(3) dynamicalalgebraic structure, we ~nd an exact solutionof the Milburn equationfor the system of a three-levelatom in the [1] configuration interacting with one quantized field mode with arbitr... With the help of an SU(3) dynamicalalgebraic structure, we ~nd an exact solutionof the Milburn equationfor the system of a three-levelatom in the [1] configuration interacting with one quantized field mode with arbitrary detuning ,The exact solution is then used to discuss the influence of the intrinsic decoherence on the nonclassical properties of the system,such as collapes and revivals of the atomic populations,oscillations of the photon number distribution,and squeezing of the radiation field. 展开更多
关键词 非经典效应 原子-场相互作用 原子物理学 原子结构 本征脱散 Milburn方程
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Nonclassical Properties in the Resonant Interaction of a Three Level A-type Atom with Two-mode Coherent state
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作者 吴怀志 苏万钧 《量子光学学报》 CSCD 北大核心 2006年第B08期28-28,共1页
关键词 非经典性 谐振交互作用 A原子 双模连贯态
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