As an improvement on the conventional two-layer electrode （active material layerlcurrent collector）, a novel sandwich-like three-layer electrode （conductive layerlactive material layertcurrent collector） for catho...As an improvement on the conventional two-layer electrode （active material layerlcurrent collector）, a novel sandwich-like three-layer electrode （conductive layerlactive material layertcurrent collector） for cathode material LiFePO4/C was introduced in order to improve its electrochemical performance. LiFePO4/C in the three-layer electrode exhibited superior rate capability in comparison with that in the two-layer electrode in accordance with charge-discharge examination. Cyclic voltammetry and electrochemical impedance spectroscopy indicated that Fe3＋/Fe2＋ redox couple for LiFePO4 in the three-layer electrode displayed faster kinetics, better reversibility and much lower charge transfer resistance than that in the two-layer electrode in electrochemical process. For three-layer electrode, the holes in the surface of active material layer were filled by smaller acetylene black grains, which formed electrical connections and provided more pathways to electron transport to/from LiFePO4/C particles exposed to the bulk electrolyte.展开更多
The controlled source extremely low frequency （CSELF） electromagnetic method is characterized by extremely long and powerful sources and a huge measurement range. Its electromagnetic field can therefore be affected ...The controlled source extremely low frequency （CSELF） electromagnetic method is characterized by extremely long and powerful sources and a huge measurement range. Its electromagnetic field can therefore be affected by the ionosphere and displacement current. Research on 3D forward modeling and inversion of CSELF electromagnetic data is currently in its infancy. This paper makes exploratory attempts to firstly calculate the 1D extremely low frequency electromagnetic field under ionosphere-air-earth coupling circumstances, and secondly analyze the propagation characteristics of the background electromagnetic field. The 3D staggered-grid finite difference scheme for solving for the secondary electric field is adopted and incorporated with the 1D modeling algorithm to complete 3D forward modeling. Considering that surveys can be carried out in the near field and transition zone for lower frequencies, the 3D Limited-memory Broyden-Fletcher-Goldfarb-Shanno （LBFGS） inversion of CSELF electromagnetic data is presented （in which the sources, or primary fields, are included）, with the aim of directly inverting the impedance data, regardless of where it is acquired. Derivation of the objective functional gradient is the core component in the inversion. Synthetic tests indicate that the well-chosen approximation to the Hessian can significantly speed up the inversion. The model responses corresponding to the coexistence of conductive and resistive blocks show that the off-diagonal components of tensor impedance are much more sensitive to the resistivity variation than the diagonal components. In comparison with conventional scalar inversion, tensor inversion is superior in the recoveries of electric anomalies and background resistivity.展开更多
基金Project(2010ZCO51)supported by Natural Science Foundation of Yunnan ProvinceProject supported by Analysis and Testing Foundation(2009-041)Starting Research Fund(14118245)from Kunming University of Science and Technology
文摘As an improvement on the conventional two-layer electrode （active material layerlcurrent collector）, a novel sandwich-like three-layer electrode （conductive layerlactive material layertcurrent collector） for cathode material LiFePO4/C was introduced in order to improve its electrochemical performance. LiFePO4/C in the three-layer electrode exhibited superior rate capability in comparison with that in the two-layer electrode in accordance with charge-discharge examination. Cyclic voltammetry and electrochemical impedance spectroscopy indicated that Fe3＋/Fe2＋ redox couple for LiFePO4 in the three-layer electrode displayed faster kinetics, better reversibility and much lower charge transfer resistance than that in the two-layer electrode in electrochemical process. For three-layer electrode, the holes in the surface of active material layer were filled by smaller acetylene black grains, which formed electrical connections and provided more pathways to electron transport to/from LiFePO4/C particles exposed to the bulk electrolyte.
基金supported by the National Natural Science Foundation of China(No.41374078)geological survey project of Ministry of Land and Resources of China(No.12120113101300)
文摘The controlled source extremely low frequency （CSELF） electromagnetic method is characterized by extremely long and powerful sources and a huge measurement range. Its electromagnetic field can therefore be affected by the ionosphere and displacement current. Research on 3D forward modeling and inversion of CSELF electromagnetic data is currently in its infancy. This paper makes exploratory attempts to firstly calculate the 1D extremely low frequency electromagnetic field under ionosphere-air-earth coupling circumstances, and secondly analyze the propagation characteristics of the background electromagnetic field. The 3D staggered-grid finite difference scheme for solving for the secondary electric field is adopted and incorporated with the 1D modeling algorithm to complete 3D forward modeling. Considering that surveys can be carried out in the near field and transition zone for lower frequencies, the 3D Limited-memory Broyden-Fletcher-Goldfarb-Shanno （LBFGS） inversion of CSELF electromagnetic data is presented （in which the sources, or primary fields, are included）, with the aim of directly inverting the impedance data, regardless of where it is acquired. Derivation of the objective functional gradient is the core component in the inversion. Synthetic tests indicate that the well-chosen approximation to the Hessian can significantly speed up the inversion. The model responses corresponding to the coexistence of conductive and resistive blocks show that the off-diagonal components of tensor impedance are much more sensitive to the resistivity variation than the diagonal components. In comparison with conventional scalar inversion, tensor inversion is superior in the recoveries of electric anomalies and background resistivity.
