The critical properties of five compounds, including propanal,butanal, 1-pentanal, 2-methel butanal and trimer of ethanal, weredetermined for the first time by a new capillary quick-flow method.The apparatus was impro...The critical properties of five compounds, including propanal,butanal, 1-pentanal, 2-methel butanal and trimer of ethanal, weredetermined for the first time by a new capillary quick-flow method.The apparatus was improved with a capillary tube and checked withhexane and 10heptene as standard reagents. The experimental resultsproved that the determination of critical properties by quick-flowmethod with a capillary tube apparatus was successful.展开更多
In liquid-liquid systems, the substrates in the liquids are inaccessible to each other for the reaction. By adding a small quantity of phase transfer catalyst, the reaction can be made accessible and accelerated. The ...In liquid-liquid systems, the substrates in the liquids are inaccessible to each other for the reaction. By adding a small quantity of phase transfer catalyst, the reaction can be made accessible and accelerated. The present study involves the phase transfer catalyzed oxidation of 2-methyl-l-butanol by quaternary ammonium permanganate （tricaprylyl methyl ammonium permanganate）. The attempt was to compare the kinetics under homogeneous and heterogeneous conditions. Experiments were conducted in a batch reactor to determine the kinetics under homogeneous conditions. A baffled horosilicate agitated reactor was used to find the enhancement factor and the kinetics under heterogeneous conditions. The rate constants determined under both homogeneous and heterogeneous conditions agreed very weU. The oxidation was found to be first order with respect to each of the reactants, quaternary ammonium permanganate and the alcohol, resulting in an overall second order rate expression. Aliquat336 （tricaprylylmethylammonium chloride） was found to be the best compared with the other catalysts tested （triethylbenzylammonium chloride, tetrabutylammonium bromide, tetrabutylammonium iodide and tetrabutylammonium hydrogen sulfate） and it gave an enhancement factor of 9.8.展开更多
基金Supported by the Natural Science Foundation of Tianjin (No. 973602911).
文摘The critical properties of five compounds, including propanal,butanal, 1-pentanal, 2-methel butanal and trimer of ethanal, weredetermined for the first time by a new capillary quick-flow method.The apparatus was improved with a capillary tube and checked withhexane and 10heptene as standard reagents. The experimental resultsproved that the determination of critical properties by quick-flowmethod with a capillary tube apparatus was successful.
文摘In liquid-liquid systems, the substrates in the liquids are inaccessible to each other for the reaction. By adding a small quantity of phase transfer catalyst, the reaction can be made accessible and accelerated. The present study involves the phase transfer catalyzed oxidation of 2-methyl-l-butanol by quaternary ammonium permanganate （tricaprylyl methyl ammonium permanganate）. The attempt was to compare the kinetics under homogeneous and heterogeneous conditions. Experiments were conducted in a batch reactor to determine the kinetics under homogeneous conditions. A baffled horosilicate agitated reactor was used to find the enhancement factor and the kinetics under heterogeneous conditions. The rate constants determined under both homogeneous and heterogeneous conditions agreed very weU. The oxidation was found to be first order with respect to each of the reactants, quaternary ammonium permanganate and the alcohol, resulting in an overall second order rate expression. Aliquat336 （tricaprylylmethylammonium chloride） was found to be the best compared with the other catalysts tested （triethylbenzylammonium chloride, tetrabutylammonium bromide, tetrabutylammonium iodide and tetrabutylammonium hydrogen sulfate） and it gave an enhancement factor of 9.8.
